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Recent Advancements in Organometallic Chemistry and Homogeneous Catalysis

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Organometallic Chemistry".

Deadline for manuscript submissions: closed (31 March 2022) | Viewed by 2620

Special Issue Editors


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Guest Editor
Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale, Università di Parma, Parco Area delle Scienze 17/A, I-43124 Parma, Italy
Interests: organometallic chemistry; organic chemistry; catalysis
Special Issues, Collections and Topics in MDPI journals

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Guest Editor
Université de Strasbourg, CNRS, LIMA, UMR 7042, Ecole européenne de Chimie, Polymères et Matériaux, 25 rue Becquerel, 67087 Strasbourg, France
Interests: organometallics; homogeneous catalysis; 3D metal chemistry; C–H activation; hydrofunctionalization; cross-coupling; supported catalysis; structured catalytic support
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Organometallic chemistry is at the heart of the development of new catalytic tools to promote molecular diversity utilizing the most straightforward and atom-economic routes. Progress in homogeneous catalysis allows energy issues to be addressed through the development of highly active and reactive catalysts, which, for example, enable the activation of unreactive bonds and therefore the use of less toxic and more elementary/bulk reagents. Recent developments in homogeneous catalysis also address environmental and societal issues, such as the decrease in nonrenewable resources through the development of synthetic routes from biomass-derived feedstock, as well as the use of earth-abundant metal-based catalysts as more sustainable alternatives to noble metals.

This Special Issue will be dedicated to recent advancements in organometallic chemistry and homogeneous catalysis, with a look at nickel chemistry, the development of cascade reactions, and the activation of N–C bonds.

Prof. Dr. Gianpiero Cera
Prof. Dr. Vincent Ritleng
Guest Editors

Manuscript Submission Information

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Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • organometallics
  • homogeneous catalysis
  • nickel chemistry
  • C–H activation
  • N–C activation

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Published Papers (1 paper)

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Research

11 pages, 5059 KiB  
Article
Catalytic Activity of Thermolyzed [Co(NH3)6][Fe(CN)6] in CO Hydrogenation Reaction
by Alevtina N. Gosteva, Mayya V. Kulikova, Yulya P. Semushina, Mariya V. Chudakova, Nikita S. Tsvetov and Vasilii V. Semushin
Molecules 2021, 26(13), 3782; https://doi.org/10.3390/molecules26133782 - 22 Jun 2021
Cited by 1 | Viewed by 2116
Abstract
Currently, the processes of obtaining synthetic liquid hydrocarbons and oxygenates are very relevant. Fischer-Tropsch synthesis (FTS) is the most important step in these processes. The products of thermal destruction in argon of the mixture [Co(NH3)6][Fe(CN)6] and Al(OH) [...] Read more.
Currently, the processes of obtaining synthetic liquid hydrocarbons and oxygenates are very relevant. Fischer-Tropsch synthesis (FTS) is the most important step in these processes. The products of thermal destruction in argon of the mixture [Co(NH3)6][Fe(CN)6] and Al(OH)3 were used as catalysts for CO hydrogenation. The resulting compositions were studied using powder X-ray diffraction, IR spectroscopy, elemental analysis, SEM micrographs. The specific surface area, pore and particle size distributions were determined. It was determined that the DCS-based catalysts were active in the high-temperature Fischer-Tropsch synthesis. The effect of aluminum in the catalyst composition on the distribution of reaction products was revealed. Full article
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