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Synthesis and Characterization of Novel Photofunctional Materials

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Cross-Field Chemistry".

Deadline for manuscript submissions: closed (31 March 2023) | Viewed by 3867

Special Issue Editors

Department of Applied Biology and Chemical Technology, Hong Kong Polytechnic University, Hong Kong, China
Interests: advanced functional materials; luminescent transition-metal complexes; organic semiconductors; π-conjugated compounds; organic electronics
Special Issues, Collections and Topics in MDPI journals
Guangxi Key Laboratory of Optical and Electronic Materials and Devices, College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, China
Interests: organic optoelectronic; functional materials; novel materials design; materials chemistry

Special Issue Information

Dear Colleagues,

Recently, novel photofunctional materials, including luminescent transition metal complexes (LTMCs) and thermally activated delayed fluorescent (TADF) materials, play a crucial role in the development of advanced photofunctional materials. LTMCs and TADF materials have aroused extensive attention, owing to their diverse structural/molecular design, structural diversity, and rich photophysical properties. As such, they have been widely and wisely used in the fields of photocatalysis, electroluminescence, organic solar cells, biological sensing and imaging, photodynamic therapy, etc. Synthetic chemists were able to design and prepare a wide variety of photofunctional LTMCs and TADF materials. Structural studies of these materials revealed the presence of novel photophysical phenomena, allowing a deeper understanding of the structure-property relationships and extending their potential applications. For example, with a strong spin-orbit coupling effect or the low energy gap between siglet and triplet states, phosphorescent transition metal complexes (e.g., iridium(III), platinum(II), etc.) and TADF materials can be used as triplet emitters to utilize both singlet and triplet excitons to greatly enhance the efficiency of electroluminescence, breaking the upper limit of the conventional fluorescent device efficiency. Thus, synthetic efforts in this field have produced a large number of LTMCs and TADF materials with rich photophysical properties. This Special Issue on “Synthesis and Characterization of Novel Photofunctional Materials” should become a timely status report, summarizing and showcasing the fundamental progresses and practical advancements in recent years.

Dr. Peng Tao
Dr. Song Guo
Guest Editors

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Keywords

  • nanomaterials
  • 2D materials
  • photonics
  • solar cells
  • sensors
  • microelectronics

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Published Papers (2 papers)

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Research

16 pages, 4871 KiB  
Article
Effect of Substrates Performance on the Microstructure and Properties of Phosphate Chemical Conversion Coatings on Metal Surfaces
by Chunmiao Du, Kangqing Zuo, Zongliang Ma, Minru Zhao, Yibo Li, Shuai Tian, Yupeng Lu and Guiyong Xiao
Molecules 2022, 27(19), 6434; https://doi.org/10.3390/molecules27196434 - 29 Sep 2022
Cited by 9 | Viewed by 1836
Abstract
Phosphate chemical conversion (PCC) technology has attracted extensive attention for its ability to regulate the surface properties of biomedical metals. However, titanium (Ti)-based alloys exhibit inertia because of the native passive layer, whereas zinc (Zn)-based alloys show high activity in acidic PCC solutions. [...] Read more.
Phosphate chemical conversion (PCC) technology has attracted extensive attention for its ability to regulate the surface properties of biomedical metals. However, titanium (Ti)-based alloys exhibit inertia because of the native passive layer, whereas zinc (Zn)-based alloys show high activity in acidic PCC solutions. The substrate performance affects the chemical reaction in the phosphating solution, which further leads to diversity in coating properties. In this work, the zinc-phosphate (ZnP) coatings are prepared on Ti alloy (TA) and Zn alloy (ZA) substrates using the PCC method, respectively. The coatings prepared herein are detected by a scanning electron microscope (SEM), X-ray diffractometer (XRD), laser scanning confocal microscope (LSCM), universal testing machine, contact angle goniometer, and electrochemical workstation system. The results show that the substrate performance has little effect on the phase composition but can significantly affect the crystal microstructure, thickness, and bonding strength of the coatings. In addition, the ZnP coatings improve the surface roughness of the substrates and show good hydrophilicity and electrochemical corrosion resistance. The formation mechanism of the ZnP coating is revealed using potential-time curves, indicating that the metal–solution interfacial reaction plays a dominant role in the deposition process. Full article
(This article belongs to the Special Issue Synthesis and Characterization of Novel Photofunctional Materials)
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11 pages, 3160 KiB  
Communication
Solution-Processed Yellow Organic Light-Emitting Diodes Based on Two New Ionic Ir (III) Complexes
by Chaoxiong Guo, Song Guo, Qiqing Lu, Zizhan Jiang, Yuzhen Yang, Weiqiao Zhou, Qin Zeng, Jun Liang, Yanqin Miao and Yuanli Liu
Molecules 2022, 27(9), 2840; https://doi.org/10.3390/molecules27092840 - 29 Apr 2022
Cited by 6 | Viewed by 1630
Abstract
Two new and efficient cationic yellow-emissive Ir (III) complexes (Ir1 and Ir2) are rationally designed by using 2-(4-chloro-3-(trifluoromethyl)phenyl)-4-methylquinoline as the main ligand, and, respectively, 4,4′-dimethyl-2,2′-bipyridyl and 4,4′-dimethoxy-2,2′-bipyridyl as the ancillary ligands. Both complexes show enhanced phosphorescence (546 nm with 572 nm as shoulder [...] Read more.
Two new and efficient cationic yellow-emissive Ir (III) complexes (Ir1 and Ir2) are rationally designed by using 2-(4-chloro-3-(trifluoromethyl)phenyl)-4-methylquinoline as the main ligand, and, respectively, 4,4′-dimethyl-2,2′-bipyridyl and 4,4′-dimethoxy-2,2′-bipyridyl as the ancillary ligands. Both complexes show enhanced phosphorescence (546 nm with 572 nm as shoulder and high phosphorescent quantum efficiency in solution, which is in favor of efficient solution-processed phosphorescent organic light-emitting diodes. Compared with Ir2, the Ir1-based device displays excellent device performance, with maximum external quantum efficiency, current efficiency, and power efficiency of up to 7.92%, 26.32 cd/A and 15.31 lm/W, respectively, thus proving that the two new ionic Ir (III) complexes exhibit great potential for future solution-processed electroluminescence. Full article
(This article belongs to the Special Issue Synthesis and Characterization of Novel Photofunctional Materials)
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