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Polymer Composites for Photo-Energy Conversion and Energy Storage Devices

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Applications".

Deadline for manuscript submissions: closed (20 June 2024) | Viewed by 9468

Special Issue Editor


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Guest Editor
Department of Chemical Engineering, National Chung Hsing University, 250 Kuo-Kuang Road, Taichung 402, Taiwan
Interests: dye sensitized solar cell; organic solar cell; perovskite solar cell; supercapacitor; triboelectric nanogenerator; covalent organic frameworks; 3D printing; electron-spinning fibers; copper electroplating
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Special Issue Information

Dear Colleagues,

This Special Issue “Polymer composites for photo-energy conversion and energy storage devices” covers the synthesis, characterization, and electro-optical properties of various polymer composites for optoelectronic, energy conversion, and energy storage applications. For example, polymer electroluminescence diodes, conducting polymers for dye-sensitized solar cells, low bandgap conjugated polymers for polymer solar cells, polymer composites for perovskite solar cells, and polymer composites for supercapacitors. The topics may also include the polymer composites for fuel cells and lithium battery. Both reviews and regular original papers are welcome.

Prof. Dr. Rong-Ho Lee
Guest Editor

Manuscript Submission Information

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Keywords

  • polymer composites
  • polymer LED
  • dye sensitized solar cell
  • organic solar cell
  • perovskite solar cell
  • supercapacitor
  • battery
  • fuel cells

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Published Papers (2 papers)

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Review

32 pages, 5459 KiB  
Review
An Overview of the Emerging Technologies and Composite Materials for Supercapacitors in Energy Storage Applications
by Oluwaseye Samson Adedoja, Emmanuel Rotimi Sadiku and Yskandar Hamam
Polymers 2023, 15(10), 2272; https://doi.org/10.3390/polym15102272 - 12 May 2023
Cited by 25 | Viewed by 5284
Abstract
Energy storage is one of the challenges currently confronting the energy sector. However, the invention of supercapacitors has transformed the sector. This modern technology’s high energy capacity, reliable supply with minimal lag time, and extended lifetime of supercapacitors have piqued the interest of [...] Read more.
Energy storage is one of the challenges currently confronting the energy sector. However, the invention of supercapacitors has transformed the sector. This modern technology’s high energy capacity, reliable supply with minimal lag time, and extended lifetime of supercapacitors have piqued the interest of scientists, and several investigations have been conducted to improve their development. However, there is room for improvement. Consequently, this review presents an up-to-date investigation of different supercapacitor technologies’ components, operating techniques, potential applications, technical difficulties, benefits, and drawbacks. In addition, it thoroughly highlights the active materials used to produce supercapacitors. The significance of incorporating every component (electrode and electrolyte), their synthesis approach, and their electrochemical characteristics are outlined. The research further examines supercapacitors’ potential in the next era of energy technology. Finally, concerns and new research prospects in hybrid supercapacitor-based energy applications that are envisaged to result in the development of ground-breaking devices, are highlighted. Full article
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24 pages, 10608 KiB  
Review
Enhanced Photovoltaic Performance of Inverted Perovskite Solar Cells through Surface Modification of a NiOx-Based Hole-Transporting Layer with Quaternary Ammonium Halide–Containing Cellulose Derivatives
by I-Hsiu Ho, Yi-Jou Huang, Cheng-En Cai, Bo-Tau Liu, Tzong-Ming Wu and Rong-Ho Lee
Polymers 2023, 15(2), 437; https://doi.org/10.3390/polym15020437 - 13 Jan 2023
Cited by 5 | Viewed by 3681
Abstract
In this study, we positioned three quaternary ammonium halide-containing cellulose derivatives (PQF, PQCl, PQBr) as interfacial modification layers between the nickel oxide (NiOx) and methylammonium lead iodide (MAPbI3) layers of inverted perovskite solar cells (PVSCs). Inserting PQCl between the [...] Read more.
In this study, we positioned three quaternary ammonium halide-containing cellulose derivatives (PQF, PQCl, PQBr) as interfacial modification layers between the nickel oxide (NiOx) and methylammonium lead iodide (MAPbI3) layers of inverted perovskite solar cells (PVSCs). Inserting PQCl between the NiOx and MAPbI3 layers improved the interfacial contact, promoted the crystal growth, and passivated the interface and crystal defects, thereby resulting in MAPbI3 layers having larger crystal grains, better crystal quality, and lower surface roughness. Accordingly, the photovoltaic (PV) properties of PVSCs fabricated with PQCl-modified NiOx layers were improved when compared with those of the pristine sample. Furthermore, the PV properties of the PQCl-based PVSCs were much better than those of their PQF- and PQBr-based counterparts. A PVSC fabricated with PQCl-modified NiOx (fluorine-doped tin oxide/NiOx/PQCl-0.05/MAPbI3/PC61BM/bathocuproine/Ag) exhibited the best PV performance, with a photoconversion efficiency (PCE) of 14.40%, an open-circuit voltage of 1.06 V, a short-circuit current density of 18.35 mA/cm3, and a fill factor of 74.0%. Moreover, the PV parameters of the PVSC incorporating the PQCl-modified NiOx were further enhanced when blending MAPbI3 with PQCl. We obtained a PCE of 16.53% for this MAPbI3:PQCl-based PVSC. This PQCl-based PVSC retained 80% of its initial PCE after 900 h of storage under ambient conditions (30 °C; 60% relative humidity). Full article
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