Applications of 3D Printing for Polymers, 3rd Edition

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Applications".

Deadline for manuscript submissions: 25 February 2025 | Viewed by 3726

Special Issue Editor


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Guest Editor
Mechanical Engineering, Texas Tech University, Lubbock, TX 79409, USA
Interests: engineering design; 3D printing; additive manufacturing; lattices; tissue scaffolds; finite element analysis; mechanics; polymers; computation; medicine
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Special Issue Information

Dear Colleagues,

Polymer 3D printing is an emerging technology in both research and industry and has diverse applications ranging from prototypes to end-use designs. Three-dimensional printing uses additive manufacturing processes to fabricate designed parts using polymer materials including thermoplastics, thermosets, elastomers, biomaterials, and more. Polymer printing is advantageous because of its wide range of material properties, low processing costs, and potential for complex design fabrication. Common applications for polymer 3D printing include prosthetics in the medical industry, lightweight/high-strength parts for aerospace applications, and inexpensive customized parts for consumers. 

Although 3D printing techniques have advanced substantially over the years, there are still many research challenges in materials, processing, and design. Regarding materials, there is a need for the further creation of polymers with advantageous properties and for measuring the performance of existing printed polymers. Processing challenges include the development of new ways of depositing materials to form a structure and assessing how printing processes influence end-part performance. Addressing challenges in the design of polymers to form lattices, multi-material structures, and stimuli-responsive parts will support applications that utilize these designed features for improved performance and functionality. Addressing these areas of research and further challenges will help in better understanding and utilizing 3D-printed polymers in diverse applications.

This Special Issue welcomes papers on a wide variety of topics in polymer applications in 3D printing and research that support relevant fundamental advances; these applications can range from diverse industries including (but not limited to) medical, aerospace, automobile, electronics, and consumer, with 3D printing processes for extrusion, resin, and powder-based fabrication approaches.

Dr. Paul F. Egan
Guest Editor

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Keywords

  • design
  • 3D printing
  • additive manufacturing
  • polymer
  • applications
  • functional materials
  • lattices
  • mechanics
  • plastics
  • healthcare

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Published Papers (3 papers)

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Research

23 pages, 4779 KiB  
Article
An Additive Manufacturing MicroFactory: Overcoming Brittle Material Failure and Improving Product Performance through Tablet Micro-Structure Control for an Immediate Release Dose Form
by Elke Prasad, John Robertson and Gavin W. Halbert
Polymers 2024, 16(18), 2566; https://doi.org/10.3390/polym16182566 - 11 Sep 2024
Viewed by 816
Abstract
Additive manufacturing of pharmaceutical formulations offers advanced micro-structure control of oral solid dose (OSD) forms targeting not only customised dosing of an active pharmaceutical ingredient (API) but also custom-made drug release profiles. Traditionally, material extrusion 3D printing manufacturing was performed in a two-step [...] Read more.
Additive manufacturing of pharmaceutical formulations offers advanced micro-structure control of oral solid dose (OSD) forms targeting not only customised dosing of an active pharmaceutical ingredient (API) but also custom-made drug release profiles. Traditionally, material extrusion 3D printing manufacturing was performed in a two-step manufacturing process via an intermediate feedstock filament. This process was often limited in the material space due to unsuitable (brittle) material properties, which required additional time to develop complex formulations to overcome. The objective of this study was to develop an additive manufacturing MicroFactory process to produce an immediate release (IR) OSD form containing 250 mg of mefenamic acid (MFA) with consistent drug release. In this study, we present a single-step additive manufacturing process employing a novel, filament-free melt extrusion 3D printer, the MicroFactory, to successfully print a previously ‘non-printable’ brittle Soluplus®-based formulation of MFA, resulting in targeted IR dissolution profiles. The physico-chemical properties of 3D printed MFA-Soluplus®-D-sorbitol formulation was characterised by thermal analysis, Fourier Transform Infrared spectroscopy (FTIR), and X-ray Diffraction Powder (XRPD) analysis, confirming the crystalline state of mefenamic acid as polymorphic form I. Oscillatory temperature and frequency rheology sweeps were related to the processability of the formulation in the MicroFactory. 3D printed, micro-structure controlled, OSDs showed good uniformity of mass and content and exhibited an IR profile with good consistency. Fitting a mathematical model to the dissolution data correlated rate parameters and release exponents with tablet porosity. This study illustrates how additive manufacturing via melt extrusion using this MicroFactory not only streamlines the manufacturing process (one-step vs. two-step) but also enables the processing of (brittle) pharmaceutical immediate-release polymers/polymer formulations, improving and facilitating targeted in vitro drug dissolution profiles. Full article
(This article belongs to the Special Issue Applications of 3D Printing for Polymers, 3rd Edition)
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20 pages, 5983 KiB  
Article
Mechanical Characterization and Production of Various Shapes Using Continuous Carbon Fiber-Reinforced Thermoset Resin-Based 3D Printing
by Md Zahirul Islam, Md Atikur Rahman, Luke Gibbon, Eric Hall, Chad A. Ulven and John J. La Scala
Polymers 2024, 16(13), 1828; https://doi.org/10.3390/polym16131828 - 27 Jun 2024
Cited by 1 | Viewed by 1329
Abstract
Continuous carbon fiber-reinforced (CCFR) thermoset composites have received significant attention due to their excellent mechanical and thermal properties. The implementation of 3D printing introduces cost-effectiveness and design flexibility into their manufacturing processes. The light-assisted 3D printing process shows promise for manufacturing CCFR composites [...] Read more.
Continuous carbon fiber-reinforced (CCFR) thermoset composites have received significant attention due to their excellent mechanical and thermal properties. The implementation of 3D printing introduces cost-effectiveness and design flexibility into their manufacturing processes. The light-assisted 3D printing process shows promise for manufacturing CCFR composites using low-viscosity thermoset resin, which would otherwise be unprintable. Because of the lack of shape-retaining capability, 3D printing of various shapes is challenging with low-viscosity thermoset resin. This study demonstrated an overshoot-associated algorithm for 3D printing various shapes using low-viscosity thermoset resin and continuous carbon fiber. Additionally, 3D-printed unidirectional composites were mechanically characterized. The printed specimen exhibited tensile strength of 390 ± 22 MPa and an interlaminar strength of 38 ± 1.7 MPa, with a fiber volume fraction of 15.7 ± 0.43%. Void analysis revealed that the printed specimen contained 5.5% overall voids. Moreover, the analysis showed the presence of numerous irregular cylindrical-shaped intra-tow voids, which governed the tensile properties. However, the inter-tow voids were small and spherical-shaped, governing the interlaminar shear strength. Therefore, the printed specimens showed exceptional interlaminar shear strength, and the tensile strength had the potential to increase further by improving the impregnation of polymer resin within the fiber. Full article
(This article belongs to the Special Issue Applications of 3D Printing for Polymers, 3rd Edition)
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13 pages, 2093 KiB  
Article
An Approach to a Silver Conductive Ink for Inkjet Printer Technology
by Svetlana N. Kholuiskaya, Valentina Siracusa, Gulnaz M. Mukhametova, Luybov A. Wasserman, Vladislav V. Kovalenko and Alexey L. Iordanskii
Polymers 2024, 16(12), 1731; https://doi.org/10.3390/polym16121731 - 18 Jun 2024
Viewed by 1072
Abstract
Silver-based metal–organic decomposition inks composed of silver salts, complexing agents and volatile solvents are now the subject of much research due to the simplicity and variability of their preparation, their high stability and their relatively low sintering temperature. The use of this type [...] Read more.
Silver-based metal–organic decomposition inks composed of silver salts, complexing agents and volatile solvents are now the subject of much research due to the simplicity and variability of their preparation, their high stability and their relatively low sintering temperature. The use of this type of ink in inkjet printing allows for improved cost-effective and environmentally friendly technology for the production of electrical devices, including flexible electronics. An approach to producing a silver salt-based reactive ink for jet printing has been developed. The test images were printed with an inkjet printer onto polyimide substrates, and two-stage thermal sintering was carried out at temperatures of 60 °C and 100–180 °C. The structure and electrical properties of the obtained conductive lines were investigated. As a result, under optimal conditions an electrically conductive film with low surface resistance of approximately 3 Ω/square can be formed. Full article
(This article belongs to the Special Issue Applications of 3D Printing for Polymers, 3rd Edition)
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