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From the Design of Ionic Liquids to Their Final Applications

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Applications".

Deadline for manuscript submissions: closed (30 September 2023) | Viewed by 2824

Special Issue Editors


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Guest Editor
Departamento de Engenharia Metalurgica e de Materiais, Instituto de Macromoléculas, Centro de Tecnologia, Universidade Federal do Rio de Janeiro, 21941-594 Rio de Janeiro, Brazil
Interests: polymer blends; conducting materials; nanocomposites; epoxy resins; material characterization
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Ingénierie des Matériaux Polymères, Université de Lyon, CNRS, UMR 5223, INSA Lyon, F-69621 Villeurbanne, France
Interests: ionic liquids; nanocomposites; ionic liquid monomers; epoxy thermosets; composites; recycling of thermosets; polymer-ionic liquid materials
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Ionic liquids have aroused great interest in scientific communities, especially those involved in materials science and technology, due to their wide range of applications. The versatility of ILs is based on their ionic nature and their unique physical, chemical and physicochemical properties. Some of their important applications include corrosion inhibition and as solvents for a number of organic reactions including polymerization, catalysts, additives for preparing inorganic and hybrid particles, additives and curing agents of epoxy prepolymers, additives to increase the fire resistance or to improve ionic conductivities for the development of solid electrolytes, etc.

In this context, we are pleased to launch this Special Issue “From the Design of Ionic Liquids to Their Final Applications”. Research papers and review articles focusing all aspects of this subject are greatly welcome. With this Special Issue, we hope to bring new ideas to future researchers in different fields of knowledge and also new possibilities of developing new materials from these versatile compounds. 

Prof. Dr. Bluma Guenther Soares
Dr. Sébastien Livi
Guest Editors

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Keywords

  • ionic liquid
  • applications
  • synthesis
  • polymer composites
  • catalysts
  • networked systems

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Published Papers (1 paper)

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Research

17 pages, 5081 KiB  
Article
LIonomers-New Generation of Ionomer: Understanding of Their Interaction and Structuration as a Function of the Tunability of Cation and Anion
by Liutong Hou, Sébastien Livi, Jean-François Gérard and Jannick Duchet-Rumeau
Polymers 2023, 15(2), 370; https://doi.org/10.3390/polym15020370 - 10 Jan 2023
Cited by 3 | Viewed by 2374
Abstract
In this work, by combining maleic anhydride-grafted polypropylene (PPgMA) and three different ionic liquids (ILs), i.e., tributyl (ethyl) phosphonium diethyl phosphate (denoted P+DEP), 1-ethyl-3-methylimidazolium diethyl phosphate (denoted EMIM DEP), and 1-ethyl-3-methylimidazolium acetate (denoted EMIM Ac), new ionic PP/IL polymer materials are [...] Read more.
In this work, by combining maleic anhydride-grafted polypropylene (PPgMA) and three different ionic liquids (ILs), i.e., tributyl (ethyl) phosphonium diethyl phosphate (denoted P+DEP), 1-ethyl-3-methylimidazolium diethyl phosphate (denoted EMIM DEP), and 1-ethyl-3-methylimidazolium acetate (denoted EMIM Ac), new ionic PP/IL polymer materials are generated and denoted as LIonomers. The structuration of ILs in LIonomers occurs from a nano/microphase separation process proved by TEM. NMR analyses reveal the existence of ionic–ionic and ionic–dipolar interactions between PPgMA and ILs within LIonomers. The rheological behavior of such IL/polymer combinations interpret the existence of interactions between maleic anhydride group and cation or anion composing the ionic liquid. These interactions can be tuned by the nature of cation (P+DEP vs. EMIM DEP) and anion (EMIM DEP vs. EMIM Ac) but also depend on the IL content. Thermal analyses demonstrate that IL could affect the crystallization process according to different pathways. Thanks to the maleic anhydride/IL interactions, an excellent compromise between stiffness and stretchability is obtained paving the way for processing new polyolefin-based materials. Full article
(This article belongs to the Special Issue From the Design of Ionic Liquids to Their Final Applications)
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