A series of M[Au(CN)
2]
2(analyte)
x coordination polymers (M = Co, Ni; analyte = dimethylsulfoxide (DMSO), N,N-dimethylformamide (DMF), pyridine; x = 2 or 4) was prepared and characterized. Addition of analyte vapours to solid M(μ-OH
2)[Au(CN)
2]
2
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A series of M[Au(CN)
2]
2(analyte)
x coordination polymers (M = Co, Ni; analyte = dimethylsulfoxide (DMSO), N,N-dimethylformamide (DMF), pyridine; x = 2 or 4) was prepared and characterized. Addition of analyte vapours to solid M(μ-OH
2)[Au(CN)
2]
2 yielded visible vapochromic responses for M = Co but not M = Ni; the IR ν
CN spectral region changed in every case. A single crystal structure of Zn[Au(CN)
2]
2(DMSO)
2 revealed a corrugated 2-D layer structure with
cis-DMSO units. Reacting a Ni(II) salt and K[Au(CN)
2] in DMSO yielded the isostructural Ni[Au(CN)
2]
2(DMSO)
2 product. Co[Au(CN)
2]
2(DMSO)
2 and M[Au(CN)
2]
2(DMF)
2 (M = Co, Ni) complexes have flat 2-D square-grid layer structures with
trans-bound DMSO or DMF units; they are formed via vapour absorption by solid M(μ-OH
2)[Au(CN)
2]
2 and from DMSO or DMF solution synthesis. Co[Au(CN)
2]
2(pyridine)
4 is generated via vapour absorption by Co(μ-OH
2)[Au(CN)
2]
2; the analogous Ni complex is synthesized by immersion of Ni(μ-OH
2)[Au(CN)
2]
2 in 4% aqueous pyridine. Similar immersion of Co(μ-OH
2)[Au(CN)
2]
2 yielded Co[Au(CN)
2]
2(pyridine)
2, which has a flat 2-D square-grid structure with
trans-pyridine units. Absorption of pyridine vapour by solid Ni(μ-OH
2)[Au(CN)
2]
2 was incomplete, generating a mixture of pyridine-bound complexes. Analyte-free Co[Au(CN)
2]
2 was prepared by dehydration of Co(μ-OH
2)[Au(CN)
2]
2 at 145 °C; it has a 3-D diamondoid-type structure and absorbs DMSO, DMF and pyridine to give the same materials as by vapour absorption from the hydrate.
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