1. Introduction
Immiscible displacement is a phenomenon occurring, e.g., during the process of water injection to an oil field as a secondary method of oil recovery [
1,
2]. Effectiveness of this phenomenon is estimated in laboratories by performing experiments on bore-hole cores [
3,
4]. The obtained results of laboratory tests are typically used to model this phenomenon with full-scale reservoir models [
5,
6]. However, to quantitatively characterize the phenomenon, it is necessary to apply appropriate models of laboratory experiments. To the authors’ best knowledge, there are relatively few papers reporting immiscible displacement experimental results associated with their modelling and analyses of its correctness [
7,
8]. This paper presents a unique report on the subject with regard to the carbonate rocks and reservoir fluids found in Polish petroleum formations.
Both small- and large-scale modelling are conventionally performed by an approximate description of the real-world phenomena. To assess the viability of such modelling, a scaling and dimensional analysis is performed as applied to the immiscible flow data obtained from the laboratory experiments. Scaling laws are derived by dimensional analysis from the general standpoint according to the Buckingham
Π theorem [
9].
This theorem says that every function with dimensional parameters , , of which has basic dimensions, can be represented as a function of dimensionless parameters of the following type: , , where exponents are rational numbers. The theorem provides a method for conversion of a physically meaningful equation involving physical variables into a new equation of dimensionless . The Buckingham Π theorem states that validity of the laws of physics does not depend on a specific unit system. It should be noticed that choice of dimensionless parameters is not unique. However, the theorem provides a method for computing sets of dimensionless parameters from the given variables even if the form of the equation is unknown.
If the Π parameters are identical for two different systems, then the phenomenon will proceed in the same way, despite different parameters. The parameters of the Π type is therefore called similarity parameters or criteria of similarity.
Thus, Buckingham
Π theorem allows for the reduction of the most general equations of physical variables that describe the phenomenon to equations involving only sets of dimensionless products (
Π’s) constructed from the original variables. The significance of the dimensionless
Π products is then analyzed with respect to their influence upon experimental results and confronted with the dependencies of the model. If it is positively verified, the model can be applied to the large-scale problems, according to the similarity theory [
10]. This theory is used mainly in the fluid mechanics [
11], hydraulics [
12], and aerodynamics [
13]. In the area of the fluid mechanics, there are several specific
Π products known for their unique names, such as the Reynolds number,
[
14], and Weber number,
[
15]. They have well-defined physical interpretation. The former is the ratio of inertial forces to viscous forces, and the latter is a measure of fluids inertia compared to their interfacial tension.
In this paper, we apply the procedure introduced above, to assess the viability of conventional modelling of immiscible fluid displacement as used in oil reservoir simulations and implemented in all commercial simulators. The procedure is applied to the analysis of a set of laboratory tests performed on bore-hole cores. A detailed description of the procedure is presented, and the appropriate conclusions are drawn.
2. Laboratory Tests
This paper takes advantage of the results of five laboratory tests of oil displacement by water performed on various long core sets [
16]. Each set consisted of four cores arranged according to diminishing permeability. The cores were of constant sizes: 2.5 cm in diameter and 5 cm in length. The cores in the first four tests featured similar permeability parameters, ranging between 30 and 60 mD, while in test No. 5, cores with a bigger permeability (up to 400 mD) were used. Prior to starting the displacement tests, all cores were saturated with water and then with oil, to take the irreducible water into account in tests and to estimate the effective porosity of the cores.
Displacement experiments differed between themselves in the rate and total volume of injected water. In tests No. 1 and No. 2, water was injected at the rate of 0.05 cm3/min, and altogether 1.06 of the cores pore volume (PV) was injected. In tests No. 3 and No. 4, water was injected at the same rate as in previous tests, while altogether 1.09–1.10 of the cores PV was injected. Test No. 5 differed from the others in the injection rate, which was 0.03 cm3/min, and, in a total 1.08 of the cores, PV was injected into it. The same reservoir fluids of known properties were used in all the tests. The tests were performed under constant initial and outflow pressure (a boundary condition) of Pini = Pout = 424 bars and constant temperature of T = 119 °C. The other boundary condition referred to the constant injection rate at the inflow end of the core sets.
A list of physical variables describing displacement experiments in relation to the laboratory tests, together with the variable dimensions, is shown in
Table 1.
As the pressure variation in the core sets was relatively low (below 1.2 bar, equivalent to approx. 0.003 of the initial pressure,
Pini) during the experiments, the above variables of viscosity,
μ, density,
ρ, and interfacial tension,
σ, determined in Reference [
17], were treated as constant values. The relative permeabilities for reservoir oil and water were determined from separate measurements on rock samples of the same formation [
17]. It should be noted that the rock of the cores is water-wet [
17]. As the injected water used in the tests is the original reservoir water, no changes of core wettability are expected.
Because the considered experiments are carried out on batteries of cores with a diameter much lower than their lengths and the boundary conditions (the injection rate at the inflow end and the pressure at the outflow end) were assumed to be transversely constant, the fluid flow can be modelled as a 1D phenomenon in first approximation. Consequently, only one parameter related to the position dimension was among parameters affecting this displacement phenomenon, i.e., the length of the core batteries—L.
The next parameters include the following: the final time of experiment performance—
t; averaged properties of cores—their porosities,
ϕ (not specified in
Table 1, as they are dimensionless); absolute permeabilities—
k; and phase permeabilities of oil and water defined at the residual saturations of reservoir fluids.
Other parameters, describing the process of oil displacement with water, apply to properties of reservoir fluids, such as the phase pressures, viscosities, densities, and interface tension. The last considered parameter, substantially affecting the performed experiments, was the water injection velocity—vw,inj, calculated directly from the injection rate divided by the area of the core cross-section.
The main results of the analyzed laboratory tests consisted in the obtained oil outflow and the displacement coefficient as functions of the injection time. The characteristic displacement coefficient at 1 PV of injected water amounted to 56.1%, 56.7%, 56.9%, 56.5%, and 52.8% in test Nos. 1, 2, 3, 4, and 5, respectively.
3. Dimensionless Π Products for Immiscible Displacement
A universal generator of
Π products was developed based on the Buckingham
Π theorem. The algorithm implemented in the generator was adopted from the literature [
18].
Figure 1 presents the block diagram of this algorithm. Moreover,
Π products are generated from all possible combinations (without repetition) of dimensional variables,
, of different dimensions by writing out
-element string from the
-element
set. Every
-element string is a base of the whole
Π product set. Every such set is generated by complementing
-element string with one of the
remaining elements of the
set. Thus, there are
quantities equal to the products of
dimensional variables
, each raised to an exponent that is determined from the condition of
Π being dimensionless with respect to each of the
basic dimensions. This algorithm results in
sets containing
dimensionless
Π products; however, the effective number of the sets is smaller than
, as some of the original sets are identical.
In the analyzed case of immiscible displacement, input variables of the algorithm included the list of
n = 13 physical variables from
Table 1, and basic
k = 3 dimensions from which the dimensions of these variables are derived, i.e.,
L—length,
M—mass, and
t—time. Therefore, according to the Buckingham theorem, ten (
n − k)
Πi parameters, where
i = 1, 2, …,10 can be defined to describe the immiscible displacement experiments.
Altogether there are 173 possible sets of
Π products for immiscible displacement that were generated.
Table 2 presents examples of six sets which were used in the further analysis where the basic model equations applied to describe the phenomenon were transformed to a dimensionless form.
4. Immiscible Displacement Equations
Representation of a mathematical model in a dimensionless form enables determination of coefficients, on which this model depends. Equations, conventionally referred to in the case of immiscible displacement in the water–oil system, are the two following differential equations resulting from the equation of continuity and from the Darcy’s law [
19]:
supplemented with the saturation confining relationship:
oil/water potential definitions:
and capillary pressure definition:
where
—porosity;
—water/oil saturation;
—time;
—water/oil viscosity;
—coordinates;
—water/oil phase permeability;
—water/oil potential;
—water/oil phase pressure;
—capillary pressure;
—water/oil density;
—difference of fluids density; and
—acceleration of gravity.
In the 1D horizontal case, the gravity term in the formulae for potentials is neglected, and the above equations take the following form:
Here, the porosity, , and permeability, k, are assumed constant and equal to their average values. Moreover, the pressure dependence of viscosities, , is assumed negligibly small, and corresponding terms in (6) and (7) are omitted.
Transformation of the discussed mathematical model to a dimensionless form was performed by using various sets of dimensionless variables’ definitions. The most convenient and natural one turned out to be the following:
- −
time: ;
where —injection velocity, —cores length, and —residual water saturation;
- −
position: x*;
- −
fluids saturations: ;
- −
- −
capillary pressure (J-Leverette function): .
While the definitions of dimensionless position, time, and saturations were of natural and conventional type, those of the pressures were more arbitrary and related to the sets of
Π products of
Table 2.
Using the above definitions, the Equations (6)–(9) are transformed to the dimensionless form of (10)–(13):
Here, the interface tension, σ, is assumed to be a negligible function of the water saturations, , in the observed range of .
As a result of the above transformation, three dimensionless coefficients of Equations (10), (11), and (13), i.e., , , and , are identified as Π products of Set No. 17, i.e., Π6,Π7, and Π10.
We assume that two systems (the real one and mathematical model) are similar, and the model is scalable when the following are present:
- −
Dimensionless initial and boundary conditions in the model and in the real system are identical;
- −
Relative permeabilities and the function are the same functions in the model and in the real system, where , ;
- −
The assumed dimensionless parameters are the same function of the reduced water saturation, , in both systems, from which it results that are the same functions of .
5. Model Parameters
Characteristic parameters that describe the model used to simulate laboratory tests are listed as
Mi,
i = 1 to 7, on the right part of
Table 3.
M1 and
M2 are independent variables that characterize spatial and temporal results of the tests. As no measurements were done for intermediate positions (0 <
x* < 1),
M1 is not used for further analysis.
M2 describes test results as a function of time and is used to analyze time-dependent measurements, such as total reservoir fluid outflow. Parameters
M3 and
M4 refer to initial conditions of the experiments that were fixed for all the experiments. Parameters
M5,
M6, and
M7 are essential coefficients of the model Equations (9), (10), and (12), respectively.
The complete set of dimensionless parameters generated above as Set No. 17 and selected for the comparison with model parameters is listed as
Πi,
i = 1 to 10, on the left side of
Table 3, together with each one’s variability in the experiments. As show in the table, parameters
Π2, Π6, Π7, Π8, Π9, and
Π10 take different values in the analyzed experiments, and four of them are equal to the corresponding model parameters:
Π2 = M2, Π6 = M5, Π7 = M6, and
Π10 = M7. Meanwhile, the other two (
Π8 and
Π9) are expected not to influence the experimental results.
It is worth nothing that definite physical meanings can be ascribed to some of the above
Π products. They follow from the below relations, (14) and (15):
where
is the Reynolds number for water/oil, according to Formula (16):
and
is the Weber number for water/oil, according to Formula (17):
As a consequence of Reynolds and Weber number meanings given above, and of the constant value of Π1, Π6/7 corresponds to the ratio of interface tension to viscous forces, while Π8/9 is a measure of the relative importance of the fluid inertia to their interface tension.
It should be noted that values of the parameters Π6 and Π7, as well as Π8 and Π9, are strongly correlated (co-dependent) in the analyzed experiments. As a consequence, only two of them (Π6 and Π8) are taken into account in the dependency analysis below.
6. Experimental Parameters
The basic experimental characteristics are given in
Table 4.
Two types of experimental results are used for the quantitative analysis below:
- −
The relative oil outflow velocity, vr = (qo/A)/vw,inj, where qo is the oil outflow rate, and A is the cross section area of the cores;
- −
The relative total oil outflow, N = Np/Np,max, where Np is the current total oil outflow, and Np,max is the maximum total oil outflow.
The former quantity is used to analyze the results’ dependence upon the temporary parameters (Π6, Π7, Π8, Π9, and Π10), while the latter is a natural quantity for cumulative parameters (e.g., Π2).
7. Dependence Analysis
The conventional regression analysis is used to study dependencies of experimental results (
vr and
N) upon the dimensionless parameters (
Π2, Π6, Π8, and
Π10). As regression diagnostic tests, the distributions of both dependent (
vr and
N) and independent quantities (
Π2, Π6, Π8, and
Π10) are determined as their histograms (shown in
Figure 2,
Figure 3,
Figure 4,
Figure 5,
Figure 6 and
Figure 7) and checked against their normal-like form. The appropriate sets of experimental data points are restricted by rejecting of outliers. In the case of N and
Π2, the residuals of their distributions were shown after subtracting the fitted trends of these quantities.
It is concluded that all the analyzed quantities except Π10 satisfy the requirement of their distribution, being appropriate for the conventional linear regression analysis applied to vr versus Π6 and Π8, as well as N versus Π2.
The analyses of adjusted
R square and residual distributions for various models of the regression fitting result in the selection of a bilinear model of
vr vs.
Π8 and
Π6 and a quadratic model of
N vs. 1/
Π2 (the reversal of
Π2). Detailed results of the regression analysis are presented in
Table 5 and
Table 6 for
vr and
N, respectively. Note that the format and entries of these tables follow the generally accepted convention of the regression results. The quality of regression fittings is shown as
vr vs.
Π8 and
Π6, and
N vs.
Π2 in
Figure 8,
Figure 9, and
Figure 10, respectively.
The main results of the regression analysis imply that the experimental results for the oil output velocity,
vr, depend in the significantly higher degree on
Π6 (
p-value = 0.0125) than on
Π8 (
p-value = 0.0378). According to the physical meanings of the products given in
Section 5, the experimental results for the oil output velocity,
vr, are determined mostly by the relationship between interfacial tension and viscous forces, while they are weakly dependent upon the ratio of inertial forces to the interfacial tension. The latter dependence results from both the low flow velocity of the reservoir fluids observed in the displacement experiments (
and a large value of
Π1 (
).
The analysis of N vs. Π2 shows the significant dependence of the total oil production upon the quadratic function of 1/Π2 (with p-value = 0.0210 for linear term and p-value = 0.0002 for quadratic term). Because Π2 has a direct meaning of the relative range of displacing fluid (injected water), the above quadratic dependence of N vs. Π2 indicates dispersive effects of the displacement process.
The above results lead to the following conclusions:
- -
The experimental results are consistent with the model predictions, i.e., explicit dependence upon the following:
- (1)
Model coefficients Π6 (and Π7);
- (2)
Model independent variables (experiment duration) Π2—linear dependence on Π2.
- -
The dependence of experimental results upon other parameters (such as Π8 and Π9) that do not enter the model description are much weaker and may be explained by small effects from the inertial forces under the conditions of small fluid velocities; in principle, including inertial effects goes beyond the Darcy law of fluid flow in the porous media.
- -
Non-linear dependence of the total oil outflow upon the displacement time cannot be taken into account in a simple 1D flow model with no dispersion effects; a typical smoothing-out of the displacement front obtained from such models results from a numerical dispersion defect of the standard numerical solvers of the flow equations; the correct modelling of the physical dispersion effect, responsible for the above mentioned non-linear dependence of the total oil outflow upon the displacement time, can be achieved by applying 3D model of non-uniform transport properties of the porous media and by explicit modelling of the physical dispersion effects.
- -
The last two points indicate deficiency of the modelling approach analyzed in the paper.
8. Summary and Conclusions
Correctness of using numerical modelling to quantitatively characterize the immiscible displacement phenomenon occurring in the water–oil system was discussed in the paper by studying the results of experimental tests on core sets with scaling and dimensional analysis. To this end, a complete procedure including generation of dimensionless Π products as of the Buckingham Π theorem, identifying the dimensionless parameters of the models, and regression analyses of the experimental results dependence upon the dimensionless Π products were applied.
The following conclusions were drawn from the obtained results:
- -
Using conventional mathematical flow description and 1D approximation, it is reasonable to model laboratory tests of immiscible displacement in the water-oil system of bore-hole cores.
- -
The experimental results are consistent with the model predictions, i.e., they significantly depend upon the following:
- ▪
Explicit model coefficients (Π6 and Π7) related with the ratio of the Reynolds number to the Weber number that is a measure of the relationship between interfacial tension and viscous forces;
- ▪
Model independent variables (experiment duration—Π2).
- -
The dependence of experimental results upon other parameters ((Π8 and Π9—corresponding to the ratio of inertial forces to the interfacial tension—the Weber number) that do not explicitly enter the model description is much weaker and results from both the low flow velocity of the reservoir fluids observed in the displacement experiments ( and a typically large value of Π1 parameter ().
- -
Non-linear dependence of the total oil outflow upon the displacement time (Π2) cannot be taken into account in a simple 1D flow model with no dispersion effects.
- -
The last two observations show the imperfection of the standard modelling approach used to analyze the immiscible displacement of oil by water in porous media.
- -
The potential way of model improvements consists in including the following:
- ▪
Inertial effects beyond the Darcy law of fluid flow in the porous media;
- ▪
Physical dispersion effects by applying 3D model of non-uniform transport properties of the porous media and by explicit modelling of the dispersion phenomena.