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Article

Construction of g-C3N4-mNb2O5 Composites with Enhanced Visible Light Photocatalytic Activity

by
Meiyin Wang
,
Hui Wang
,
Yuanhang Ren
,
Cheng Wang
,
Zhewei Weng
,
Bin Yue
* and
Heyong He
*
Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Collaborative Innovation Center of Chemistry for Energy Materials, Fudan University, Shanghai 200433, China
*
Authors to whom correspondence should be addressed.
Nanomaterials 2018, 8(6), 427; https://doi.org/10.3390/nano8060427
Submission received: 4 May 2018 / Revised: 5 June 2018 / Accepted: 8 June 2018 / Published: 12 June 2018
(This article belongs to the Special Issue Synthesis and Applications of Nanomaterials for Photocatalysis and Electrocatalysis)
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Abstract

:
A series of composites consisting of g-C3N4 sheet and mesoporous Nb2O5 (mNb2O5) microsphere were fabricated by in situ hydrolysis deposition of NbCl5 onto g-C3N4 sheet followed by solvothermal treatment. The samples were characterized using powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), transmission electron microscopy (TEM), N2 adsorption-desorption, X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectroscopy (DRS) and photoluminescence spectroscopy (PL). The photocatalytic activity of the composites was studied by degradation of rhodamine B (RhB) and tetracycline hydrochloride (TC-HCl) in aqueous solution under visible light irradiation (λ > 420 nm). Compared with g-C3N4 and mNb2O5, g-C3N4-mNb2O5 composites have higher photocatalytic activity due to synergistic effect between g-C3N4 and mNb2O5. Among these composites, 4% g-C3N4-mNb2O5 has the highest efficiency and good recyclability for degradation of both RhB and TC-HCl.

Graphical Abstract

1. Introduction

Organic dyes and antibiotics are two types of important products which are widely used in textile and pharmaceutical industries, respectively. The direct discharge of these chemical compounds along with sewage to environment would be seriously harmful to ecosystem and human health. It is, therefore, desirable to explore efficient ways to remove them from water [1,2,3]. In the past decades, the methods of biological treatment, physical adsorption and chemical transformation have been employed in removal of the organic pollutants [1,4,5,6,7]. Among them, much attention has been focused on photocatalytic degradation of organic pollutants over semiconductors such as TiO2 [7,8], WO3 [9], ZnO [10], MoS2 [11], etc. due to their ability to oxidize organics through a redox process with low cost. Nevertheless, the majority of the above semiconductors still suffer from some problems such as limited absorption of visible light, difficult recycling of the catalyst, rapid recombination of photogenerated electrons, holes pairs, etc. n-Type transition metal oxide Nb2O5 attracts much interest in photocatalytic reactions due to its high chemical stability, water tolerance, and nontoxicity, although the light absorption of Nb2O5 with a wide band gap of ~3.4 eV limits its application only in the UV region [12,13,14]. Therefore, many efforts have been made to improve the absorption ability of Nb2O5 in the visible region, such as combination with other semiconductor material [15], ion doping [16] and deposition of noble metal [17].
Recently, graphitic carbon nitride (g-C3N4) has been widely used in photocatalytic reactions such as degradation of pollutants, hydrogen generation and selective oxidation of alcohols under visible light due to its excellent chemical/thermal stability, small band gap of 2.7 eV and low cost [18,19,20]. However, pure g-C3N4 shows low photocatalytic efficiency owing to fast recombination of photogenerated electrons and holes and small specific surface area [21,22]. It was reported that the composites of g-C3N4 and other semiconductors, such as TiO2 [23,24,25], WO3 [26], MoS2 [27], and ZnO [28], could produce a certain number of heterojunction sites which is beneficial to promote electron-hole separation and restrain the recombination efficiently. In addition, some efforts have been paid to the Nb2O5/g-C3N4 composite which exhibits photocatalytic activity in degradation of tetracycline hydrochloride (TC-HCl) [29], methylene blue (MB) and rhodamine B (RhB) under UV and visible light [30], and production of H2 under visible light [31]. However, it is still a challenge to prepare novel Nb2O5/g-C3N4 composites with strong interaction and high dispersion between mesoporous Nb2O5 microsphere and g-C3N4 layer which could be used as efficient photocatalysts.
Herein, a series of g-C3N4-mNb2O5 composites, prepared by in situ hydrolysis deposition of NbCl5 onto g-C3N4 sheet followed by solvothermal treatment, have been used as photocatalysts in degradation of RhB and TC-HCl and characterized in details. The results indicate that 4% g-C3N4-mNb2O5 exhibits low photoluminescence (PL) intensity and narrow band gap which account for its high catalytic activity.

2. Materials and Methods

2.1. Materials

Niobium chloride (NbCl5) was purchased from Strem Chemicals, Inc (Newburyport, MA, USA). Melamine (99%), absolute ethanol (analytical grade) and tetracycline hydrochloride (TC-HCl, 96%) were purchased from Shanghai Aladdin Bio-Chem Technology Co., Ltd. (Shanghai, China). Rhodamine B (RhB) was purchased from Sinopharm Chemical Reagent Co., Ltd. (Shanghai, China). Pluronic 123 (PEG-PPG-PEG, P123) was purchased from Sigma-Aldrich, Co. (ST. Louis, MO, USA). All the reagents were used without further purification.

2.2. Preparation

The bulk g-C3N4 was prepared by heating 2.50 g of melamine in an alumina crucible with a cover in air at 550 °C with ramp rate of 2 °C/min and maintained at 550 °C for 4 h [32]. After being cooled down to room temperature, the obtained product was ground into powder.
The g-C3N4-mNb2O5 composites were prepared through in situ hydrolysis of NbCl5 onto g-C3N4 and then solvothermal treatment. Typically, 0.99 g of P123 was added into 20 g of absolute ethanol with vigorous stirring until complete dissolution of P123. Bulk g-C3N4 powder was dispersed into absolute ethanol and the suspension was sonicated for 1 h. Then, 1.49 g of NbCl5 was added into a pear-shaped flask under N2 atmosphere in a glovebox. The solution of P123 and the suspension of g-C3N4 were added and the mixture was stirred for 30 min. After that, 0.50 mL of distilled water was pumped into the flask with a rate of 0.0167 mL/min under stirring. After stirring for another 30 min, the mixture was transferred into a 40 mL Teflon-lined stainless steel autoclave and heated at 180 °C for 24 h. After being cooled down to room temperature, the precipitate was obtained by filtration and washing by ethanol for four times. The solid was dried at 30 °C overnight in a drying oven under vacuum and then transferred to a tube furnace to be calcined at 400 °C for 3 h with a rate of 2 °C/min. The g-C3N4-mNb2O5 composites prepared with the g-C3N4 weight ratios of 1%, 4%, 10%, 20% and 50% were denoted as 1% g-C3N4-mNb2O5, 4% g-C3N4-mNb2O5, 10% g-C3N4-mNb2O5, 20% g-C3N4-mNb2O5, 50% g-C3N4-mNb2O5, respectively. The pure mNb2O5 was prepared by the same procedure without adding g-C3N4. In addition, the corresponding mechanic mixture of g-C3N4 and mNb2O5 with the same weight ratio of 4% g-C3N4-mNb2O5 was prepared by simple grinding and was denoted as 4% g-C3N4/mNb2O5.

2.3. Characterization

Powder X-ray diffraction (XRD) patterns were carried out on a Bruker D8 Advance diffractometer (Karlsruhe, Germany) with Cu Kα radiation (λ = 0.15418 nm) operated at 40 kV and 40 mA in the 2θ range of 5–70°. The Fourier transform infrared (FT-IR) spectra were recorded on a Thermo Fisher Nicolet iS10 instrument (Waltham, MA, USA) with KBr pellet from 4000 to 400 cm−1. X-ray photoelectron spectroscopy (XPS) was measured by a Perkin Elmer PHI 5000C spectroscope (Waltham, MA, USA). The spectra were recorded with Mg Kα line as the excitation source (hν = 1253.6 eV) at 14 kV and 20 mA. UV-vis diffuse reflectance spectroscopy (DRS) was performed on a Perkin Elmer Lambda 650 spectrophotometer (Waltham, MA, USA) using BaSO4 as reference. The transmission electron microscopic (TEM) images were obtained using a FEI Tecnai G2 F20 S-Twin field emission transmission electron microscope (Hillsboro, Oregon, USA) with an accelerating voltage of 200 kV and a JEOL JEM-2011 transmission electron microscope with an accelerating voltage of 200 kV. The samples were prepared by dropping the ethanol suspension of samples onto the copper grid. The N2 adsorption-desorption measurements were carried out at 77.3 K on a Micromeritics Tristar II 3020 analytical system. The specific surface area was calculated by the Brunauer-Emmett-Teller (BET) method. Pore size distributions were obtained from analysis of the desorption branch of the isotherms using the Barrett-Joyner-Halenda (BJH) model. Photoluminescence (PL) spectra were obtained on an Edinburgh Instruments FLS-980 spectrometer (Edinburgh, UK) with the excitation wavelength of 300 nm.

2.4. Photocatalytic Experiments

The photocatalytic activity of the as-prepared catalysts was performed by photocatalytic degradation of 15 mg/L RhB aqueous solution and 40 mg/L TC-HCl aqueous solution under visible light. The photocatalytic degradation tests were carried out in an instrument (CEL-HXF300, Beijing China Education Au-light Co., Ltd., Beijing, China) with a cylindrical glass reactor and a condensate water circulation equipment (Figure S1). The visible light was provided by a Xe lamp (14 V, 15 A) with a 420 nm cut-off filter (Figure S2). In a typical photocatalytic degradation of RhB or TC-HCl experiment, 30 mg of catalyst was added into 70 mL of RhB aqueous solution or 100 mL of TC-HCl aqueous solution. The suspension was firstly stirred in dark at room temperature to reach adsorption/desorption equilibrium. Then, the reaction was irradiated under visible light (λ > 420 nm) and the solution was vigorously stirred with air bubbling. During the process, 3 mL of suspension was taken at intervals of 20 min (for RhB) or intervals of 5 min (for TC-HCl). All suspensions were centrifuged to remove the catalyst and the concentration of the RhB and TC-HCl were analyzed by UV-vis spectrophotometer with the scanning ranges of 300–700 nm for RhB and 200–600 nm for TC-HCl. To be reused for next reaction cycle, the separated catalyst by centrifugation was washed by water and ethanol three times and then dried at 30 °C in a drying oven under vacuum.

3. Results and Discussion

3.1. Characterization of the Catalysts

3.1.1. XRD

XRD was employed to analyze mNb2O5, g-C3N4 and g-C3N4-mNb2O5 composites with different contents of g-C3N4 and the results are shown in Figure 1. For mNb2O5, the broad diffraction peak around 23.7° corresponds to partial crystallized Nb2O5 (JCPDS number: 19-0862), which results from the relatively low calcination temperature of 400 °C. The main diffractions of g-C3N4 are at 12.8° and 27.1°, which are assigned to (100) plane due to in-plane tris-s-triazine frameworks and (002) plane due to interlayer stacking of aromatic systems, respectively. The latter reflects interlayer stacking of aromatic systems and the calculated interlayer distance is 0.338 nm [33,34,35]. In the composites, the diffractions of mNb2O5 are retained and the characteristic (002) diffraction of g-C3N4 is observed when the content of g-C3N4 increases to 20% and 50%.

3.1.2. FT-IR

Figure 2 shows the FT-IR spectra of mNb2O5, g-C3N4 and g-C3N4-mNb2O5 composites. For the mNb2O5 sample, a broad band around 3382 cm−1 is attributed to vibration of O-H of the water molecules adsorbed on the sample [27,30]. The broad band at 615 cm−1 is ascribed to Nb–O–Nb angular vibration [36]. As for g-C3N4, the broad band ranging from 3000 to 3500 cm−1 is due to the stretching vibration of N–H groups in g-C3N4 and O–H of adsorbed water [25]. Other characteristic bands arisen from the typical stretching modes of C=N and C–N in heterocycles of g-C3N4 are at 1237, 1317, 1405, 1461, 1574 and 1640 cm−1. Additionally, the band at 803 cm−1 of g-C3N4 is assigned to the breathing mode of the triazine units [33,34]. For g-C3N4-mNb2O5 composites, all the characteristic bands of mNb2O5 and g-C3N4 exist except 1% g-C3N4-mNb2O5 due to small amount of g-C3N4, which confirm the existence of two components in the composites. With the increasing of g-C3N4, the band at 3382 cm−1 of mNb2O5 slightly shifts to smaller wavenumber for g-C3N4-mNb2O5 composites, which reveals the vibration of N-H. Moreover, the band of g-C3N4 at 1237 cm−1 slightly shifts to 1244 cm−1 for all g-C3N4-mNb2O5 composites except 1% g-C3N4-mNb2O5 (Figure 2b), revealing the interaction between g-C3N4 and mNb2O5.

3.1.3. TEM

The prepared samples were investigated by field emission transmission electron microscope. Figure 3 shows the TEM images of g-C3N4, mNb2O5 and 4% g-C3N4-mNb2O5. The mNb2O5 sample is mesoporous materials with pore size of 3–5 nm and its lattice fringe spacing is 0.395 nm (Figure 3a). Figure 3b shows that g-C3N4 is veil-like with lamellar structure. In Figure 3c, we could measure that the interlayer distance g-C3N4 is 0.339 nm, which is in accordance with XRD result. For the 4% g-C3N4-mNb2O5 sample, it can be observed that mNb2O5 microspheres are deposited on the surface of g-C3N4 sheet in Figure 3d,e. Moreover, the corresponding EDS of Figure 3e indicates that the sample consists of C, N, O and Nb elements (Figure 3f). The relevant element contents are shown in Table S1.

3.1.4. N2 Adsorption-Desorption

Figure 4 shows the nitrogen adsorption-desorption isotherms of g-C3N4, mNb2O5, 1% g-C3N4-mNb2O5, 4% g-C3N4-mNb2O5, 10% g-C3N4-mNb2O5 and 50% g-C3N4-mNb2O5. The isotherm of g-C3N4 belongs to the type IV isotherm with the H4 type hysteresis loop. All isotherms of mNb2O5, 1% g-C3N4-mNb2O5, 4% g-C3N4-mNb2O5, 10% g-C3N4-mNb2O5 and 50% g-C3N4-mNb2O5 are ascribed to the type V isotherm with the H3 type hysteresis loop, indicating the existence of mesoporous structure. The BET specific surface areas of g-C3N4 and mNb2O5 are 11.2 and 138 m2/g, respectively. The surface area of the composites follows the sequence: 4% g-C3N4-mNb2O5 (190 m2/g) > 10% g-C3N4-mNb2O5 (182 m2/g) > 1% g-C3N4-mNb2O5 (152 m2/g) > 50% g-C3N4-mNb2O5 (136 m2/g). Among them, 4% g-C3N4-mNb2O5 exhibits the largest surface area, which is 1.4 times larger than that of mNb2O5 and 17 times larger than that of g-C3N4. It may originate from that, after ultrasonication of g-C3N4, the interlayer distance of g-C3N4 increases and the addition of g-C3N4 leads to partial disaggregation of mNb2O5 [37,38]. When the content of g-C3N4 is 50%, high content of g-C3N4 in the composites results in g-C3N4 stacking together, thus 50% g-C3N4-mNb2O5 sample shows almost the same specific surface as mNb2O5.

3.1.5. UV-vis DRS

UV-vis diffuse reflectance spectroscopy (DRS) was performed to estimate the band gap of the catalysts, which is important to determine if the catalysts can be excited in the visible-light region [39]. Figure 5a shows the UV-vis diffuse reflectance spectra of mNb2O5, g-C3N4 and g-C3N4-mNb2O5 composites with different content of g-C3N4. Due to the high band energy value of mNb2O5 (3.34 eV), mNb2O5 only absorbs ultraviolet light with its fundamental absorption edge near 371 nm. However, g-C3N4 possesses a broad peak in the visible region with an absorption edge at ca. 458 nm. For g-C3N4-mNb2O5 composites, the absorption edge exhibits an obvious red shift relative to pristine mNb2O5, indicating the composites could absorb more visible light than mNb2O5. The band gap energy (Eg) of the samples was determined by UV-vis DRS with the Tauc model according to the following equation:
αhυ = A(hυ − Eg)n/2
where α, h, υ and A corresponds to absorption coefficient, Planck constant, light frequency and a constant, respectively, and the constant n depends on whether the transition is direct (n = 1) or indirect (n = 4) [40]. For both g-C3N4 and mNb2O5, the values of n are 1 [41,42]. Thus, the band gap values of 1% g-C3N4-mNb2O5, 4% g-C3N4-mNb2O5, 10% g-C3N4-mNb2O5, 20% g-C3N4-mNb2O5 and 50% g-C3N4-mNb2O5 are estimated as 3.34, 3.10, 3.19, 3.15 and 2.88 eV, respectively (Figure 5b). The narrowed band gaps of 4% g-C3N4-mNb2O5, 10% g-C3N4-mNb2O5 and 20% g-C3N4-mNb2O5 results from the formation of heterostructure between g-C3N4 and mNb2O5 [29]. It implies that 4% g-C3N4-mNb2O5 can harvest more visible light, which is beneficial to improve the visible-light photocatalytic activity of catalysts. Interestingly, the band gap of 50% g-C3N4-mNb2O5 is lower than that of other composites, due to high content of g-C3N4 in 50% g-C3N4-mNb2O5.

3.1.6. XPS

XPS was used to characterize the surface chemical composition and elemental valence states of the samples. As shown in Figure 6a, C and N elements are detected from g-C3N4 and Nb and O elements are detected from mNb2O5. As for the spectrum of 4% g-C3N4-mNb2O5, a very weak N 1s peak is ascribed to small content of g-C3N4. Figure 6b presents the high resolution XPS spectra of Nb 3d for 4% g-C3N4-mNb2O5 and mNb2O5. For mNb2O5, the signals of Nb 3d5/2 and 3d3/2 locate at 207.0 and 209.6 eV, respectively, whereas the signals of Nb 3d5/2 and 3d3/2 shift slightly (ΔBE ~ 0.4 eV) to a higher binding energy for 4% g-C3N4-mNb2O5. The upshift may be attributed to band bending.

3.1.7. PL Spectroscopy

To test the generation and recombination efficiency of photogenerated electrons and holes in semiconductors, PL spectroscopy is often conducted. The PL spectra of mNb2O5, 4% g-C3N4-mNb2O5, 10% g-C3N4-mNb2O5, 20% g-C3N4-mNb2O5, 50% g-C3N4-mNb2O5 and g-C3N4 with an excitation wavelength of 300 nm are shown in Figure 7. It can be observed that mNb2O5 has a strong emission peak at 474 nm and g-C3N4 has a strong emission peak at 472 nm. Compared to mNb2O5, the PL emission intensity of g-C3N4-mNb2O5 samples is significantly reduced, suggesting that the g-C3N4-mNb2O5 composite has a lower recombination rate of photogenerated electrons and holes than mNb2O5. Among the composites, the 4% g-C3N4-mNb2O5 sample shows the lowest emission intensity at the similar emission peak position which means the lowest recombination efficiency of photogenerated electrons and holes [27,43,44]. Combined with the UV-vis DRS analysis result that 4% g-C3N4-mNb2O5 has the lowest band gap, 4% g-C3N4-mNb2O5 demonstrates best potential in photocatalytic degradation reactions among the catalysts studied in this work.

3.2. Visible-Light Photocatalytic Performance and Stability of the Catalysts

The photocatalytic test of mNb2O5, g-C3N4 and g-C3N4-mNb2O5 composites with different content of g-C3N4 in degradation of RhB and TC-HCl were carried out under visible light irradiation (λ > 420 nm).

3.2.1. Photodegradation of RhB under Visible Light Irradiation

The photocatalytic degradation results are shown in Figure 8a. The standard curve of the absorbance intensity (A) vs. concentration (C) of RhB solution is shown in Figure S4a. The RhB suspension was firstly stirred in dark for 2 h at room temperature to reach adsorption/desorption equilibrium (Figure S3a) [45,46]. No evident decrease of RhB concentration is observed in the absence of catalyst. Therefore, the direct photolysis of RhB could be ignored. Pure mNb2O5 and g-C3N4 show low photocatalytic activities with only about 27.3% and 25.4% of RhB being degraded after 180 min of irradiation, respectively. The g-C3N4-mNb2O5 composites show higher degradation efficiency than mNb2O5 and g-C3N4. For the catalysts containing different content of g-C3N4, the sample 4% g-C3N4-mNb2O5 exhibits the highest degradation efficiency for RhB (97.5%) within 180 min, which is 3.6 and 3.9 times higher than that of mNb2O5 and g-C3N4, respectively. Furthermore, the corresponding mechanic mixture 4% g-C3N4/mNb2O5 shows 51% of degradation efficiency for RhB, which is much smaller than that of 4% g-C3N4-mNb2O5 composite. Therefore, the high degradation efficiency of 4% g-C3N4-mNb2O5 is ascribed to the formation of heterostructure between g-C3N4 and mNb2O5, as found in the UV-vis DRS and PL studies.
In addition to photocatalytic efficiency, stability and recyclability of the catalysts are also important for application of the catalysts. The 4% g-C3N4-mNb2O5 sample for photodegradation of RhB was further tested for five cycles. As shown in Figure 8b, after five cycles, the high efficiency for photocatalytic degradation of RhB by 4% g-C3N4-mNb2O5 is maintained, demonstrating good reusability and stability of 4% g-C3N4-mNb2O5.

3.2.2. Photodegradation of TC-HCl under Visible Light Irradiation

The photocatalytic degradation of TC-HCl results are shown in Figure 9a. The standard curve of the absorbance intensity (A) vs. concentration (C) of TC-HCl solution can be seen in Figure S4b. The TC-HCl suspension was firstly stirred in dark for 1 h at room temperature to reach adsorption/desorption equilibrium (Figure S3b) [45,46]. No evident decrease of TC-HCl concentration is observed in the absence of catalyst. The pure mNb2O5 and g-C3N4 show low photocatalytic efficiency in degradation of TC-HCl with about 49.7% and 5.3% after 60 min of irradiation, respectively. The degradation efficiency of g-C3N4-mNb2O5 composites within 60 min could be listed as the following order: 4% g-C3N4-mNb2O5 > 10% g-C3N4-mNb2O5 ≈ 20% g-C3N4-mNb2O5 > 50% g-C3N4-mNb2O5 > 1% g-C3N4-mNb2O5. All g-C3N4-mNb2O5 composites display higher degradation efficiency than that of mNb2O5 and g-C3N4. For comparison, the corresponding mechanic mixture 4% g-C3N4/mNb2O5 shows its degradation efficiency of 52%. Overall, 4% g-C3N4-mNb2O5 is the optimal catalyst, for which the degradation efficiency of TC-HCl in 60 min is 75.7%. After 30-min experimental run, for 4% g-C3N4-mNb2O5, 10% g-C3N4-mNb2O5 and 20% g-C3N4-mNb2O5, degradation reaction of TC-HCl solution has approached the endpoint. Further degradation is hard to proceed so that the degradation rate is slow and the change of absorbance change is not evident. An appropriate content of g-C3N4 leads to this composite with large surface area, narrow band gap and low PL intensity, which favors the titled photocatalytic reactions [41,44,47].
The stability and recyclability of 4% g-C3N4-mNb2O5 catalysts for photocatalytic degradation of TC-HCl were also tested for five cycles. As shown in Figure 9b, after five cycles, photodegradation efficiency of 4% g-C3N4-mNb2O5 for TC-HCl is almost unchanged. Thus, 4% g-C3N4-mNb2O5 sample could maintain good stability and it is able to be reused in the photodegradation reaction of TC-HCl as well as in photodegradation reaction of RhB.
In other words, in two photocatalytic reactions of RhB solution and TC-HCl solution under visible-light irradiation, g-C3N4-mNb2O5 composites showed enhanced photocatalytic activity than mNb2O5. The 4% g-C3N4-mNb2O5 sample shows the highest photocatalytic activity. The other photocatalytic performance of Nb2O5/g-C3N4 composites were also tested by Ribeiro et al., Shi et al., and Li et al. [29,30,31]. Compared to the reported work, our work focus on the stability of catalysts, which is greatly distinct. The strategy based on the in situ hydrolysis can efficiently avoid the aggregation of Nb2O5, thus further facilitating the full exertion of catalyst activity. Besides, the interlayer of g-C3N4 sheets can be enlarged by the existence of Nb2O5, increasing the surface area of catalyst. The stability of our catalyst is superior to many reported literatures when evaluated in the photocatalytic of RhB and TC-HCl, which can be attributed to highly uniformity and tightly anchoring of Nb2O5 on g-C3N4 sheets.

4. Conclusions

In summary, we have prepared a series of g-C3N4-mNb2O5 composites by in situ NbCl5 hydrolysis, deposition and solvothermal treatment. It is found that the g-C3N4-mNb2O5 composites exhibit lower PL intensity than pure mNb2O5 and g-C3N4 and narrower band gap than pure mNb2O5, leading to a significant enhancement of photocatalytic activity with excellent stability and recyclability for degradation of RhB and TC-HCl. Among the composites, 4% g-C3N4-mNb2O5 sample shows the highest photocatalytic activity under visible-light irradiation (λ > 420 nm), which is ascribed to the strong interaction between g-C3N4 and Nb2O5, its smallest band gap and lowest PL intensity. Based on the above characterization and photocatalytic results, the excellent photocatalytic activity of 4% g-C3N4-mNb2O5 can be attributed to combined effects between g-C3N4 and mNb2O5 as follows: (1) the induction of g-C3N4 into mNb2O5 leads to extension the absorption into visible light region; (2) the recombination of photogenerated electrons and holes is inhibited to some extent; (3) its highest surface area among all composites leads to more active sites; and (4) interaction exists between mNb2O5 and g-C3N4, as observed in XPS and FT-IR. These also account for the remarkable stability and recyclability of the catalyst 4% g-C3N4-mNb2O5 in the degradation reaction.

Highlights

  • g-C3N4-mNb2O5 composites were obtained by in situ hydrolysis deposition and solvothermal treatment.
  • Under the visible light irradiation, 4% g-C3N4-mNb2O5 exhibited the highest photocatalytic activities to degrade rhodamine B (97.5% degradation within 180 min) and tetracycline hydrochloride (75.7% degradation within 60 min) solution with excellent stability and recyclability.
  • The g-C3N4-mNb2O5 composites showed narrower band gap, lower PL intensity and larger surface area than pure mNb2O5 and g-C3N4, leading to a significant enhancement of their photocatalytic activity.

Supplementary Materials

The following are available online at https://www.mdpi.com/2079-4991/8/6/427/s1, Figure S1: A schematic diagram of photocatalytic equipment, Figure S2: Emission spectrum of Xe lamp with 420 nm filter, Figure S3: Influence of adsorption process on: (a) RhB solution (15 mg/L, 70 mL); and (b) TC-HCl solution (40 mg/L, 100 mL) containing 30 mg 4% g-C3N4-mNb2O5 powder under dark, Figure S4: Absorption changes of: (a) RhB solution (15 mg/L, 70 mL); and (b) TC-HCl solution (40 mg/L, 100 mL) containing 30 mg 4% g-C3N4-mNb2O5 powder under visible light irradiation, Figure S5: Standard curves of absorbance intensity vs. concentration of: (a) RhB solution; and (b) TC-HCl solution, Table S1: The elements content of 4% g-C3N4-mNb2O5 by EDS analysis.

Author Contributions

M.W. managed all the experiments and initial writing; H.W., Y.R., C.W. and Z.W. contributed greatly to data analysis, discussion and manuscript preparation. B.Y. and H.H. supervised and managed the project.

Acknowledgments

This work was supported by the National Natural Science Foundation of China (21673046, 21473036, 91645201 and 21371035).

Conflicts of Interest

The authors declare no conflict of interest.

References

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Figure 1. XRD patterns for mNb2O5, g-C3N4 and g-C3N4-mNb2O5 composites with different contents of g-C3N4.
Figure 1. XRD patterns for mNb2O5, g-C3N4 and g-C3N4-mNb2O5 composites with different contents of g-C3N4.
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Figure 2. (a) FT-IR spectra of mNb2O5, g-C3N4 and g-C3N4-mNb2O5 composites with different contents of g-C3N4. (a, mNb2O5; b, 1% g-C3N4-mNb2O5; c, 4% g-C3N4-mNb2O5; d, 10% g-C3N4-mNb2O5; e, 20% g-C3N4-mNb2O5; f, 50% g-C3N4-mNb2O5; g, g-C3N4); and (b) enlarged FT-IR spectra corresponding to rectangle region from (a).
Figure 2. (a) FT-IR spectra of mNb2O5, g-C3N4 and g-C3N4-mNb2O5 composites with different contents of g-C3N4. (a, mNb2O5; b, 1% g-C3N4-mNb2O5; c, 4% g-C3N4-mNb2O5; d, 10% g-C3N4-mNb2O5; e, 20% g-C3N4-mNb2O5; f, 50% g-C3N4-mNb2O5; g, g-C3N4); and (b) enlarged FT-IR spectra corresponding to rectangle region from (a).
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Figure 3. TEM images of: (a) mNb2O5; (b,c) g-C3N4; and (d,e) 4% g-C3N4-mNb2O5; (f) EDS analysis of 4% g-C3N4-mNb2O5 corresponding to (e).
Figure 3. TEM images of: (a) mNb2O5; (b,c) g-C3N4; and (d,e) 4% g-C3N4-mNb2O5; (f) EDS analysis of 4% g-C3N4-mNb2O5 corresponding to (e).
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Figure 4. Nitrogen adsorption–desorption isotherms of g-C3N4, mNb2O5, 1% g-C3N4-mNb2O5, 4% g-C3N4-mNb2O5, 10% g-C3N4-mNb2O5 and 50% g-C3N4-mNb2O5.
Figure 4. Nitrogen adsorption–desorption isotherms of g-C3N4, mNb2O5, 1% g-C3N4-mNb2O5, 4% g-C3N4-mNb2O5, 10% g-C3N4-mNb2O5 and 50% g-C3N4-mNb2O5.
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Figure 5. (a) UV-vis diffuse reflectance spectra; and (b) plots of the (αhυ)2 vs. (hυ) of mNb2O5, g-C3N4, and g-C3N4-mNb2O5 composites with different content of g-C3N4.
Figure 5. (a) UV-vis diffuse reflectance spectra; and (b) plots of the (αhυ)2 vs. (hυ) of mNb2O5, g-C3N4, and g-C3N4-mNb2O5 composites with different content of g-C3N4.
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Figure 6. (a) XPS survey spectra of g-C3N4, mNb2O5 and 4% g-C3N4-mNb2O5; and (b) Nb 3d spectra for mNb2O5 and 4% g-C3N4-mNb2O5.
Figure 6. (a) XPS survey spectra of g-C3N4, mNb2O5 and 4% g-C3N4-mNb2O5; and (b) Nb 3d spectra for mNb2O5 and 4% g-C3N4-mNb2O5.
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Figure 7. PL spectra of mNb2O5, 4% g-C3N4-mNb2O5, 10% g-C3N4-mNb2O5, 20% g-C3N4-mNb2O5, 50% g-C3N4-mNb2O5 and g-C3N4.
Figure 7. PL spectra of mNb2O5, 4% g-C3N4-mNb2O5, 10% g-C3N4-mNb2O5, 20% g-C3N4-mNb2O5, 50% g-C3N4-mNb2O5 and g-C3N4.
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Figure 8. (a) Photolysis of RhB and photocatalytic activity over as-prepared photocatalysts for RhB; and (b) recyclability for the photodegradation of RhB in the presence of 4% g-C3N4-mNb2O5 under visible light irradiation.
Figure 8. (a) Photolysis of RhB and photocatalytic activity over as-prepared photocatalysts for RhB; and (b) recyclability for the photodegradation of RhB in the presence of 4% g-C3N4-mNb2O5 under visible light irradiation.
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Figure 9. (a) Photolysis of TC-HCl and photocatalytic activity over as-prepared photocatalysts for TC-HCl; and (b) recyclability for the photodegradation of TC-HCl in the presence of 4% g-C3N4-mNb2O5 under visible light irradiation.
Figure 9. (a) Photolysis of TC-HCl and photocatalytic activity over as-prepared photocatalysts for TC-HCl; and (b) recyclability for the photodegradation of TC-HCl in the presence of 4% g-C3N4-mNb2O5 under visible light irradiation.
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MDPI and ACS Style

Wang, M.; Wang, H.; Ren, Y.; Wang, C.; Weng, Z.; Yue, B.; He, H. Construction of g-C3N4-mNb2O5 Composites with Enhanced Visible Light Photocatalytic Activity. Nanomaterials 2018, 8, 427. https://doi.org/10.3390/nano8060427

AMA Style

Wang M, Wang H, Ren Y, Wang C, Weng Z, Yue B, He H. Construction of g-C3N4-mNb2O5 Composites with Enhanced Visible Light Photocatalytic Activity. Nanomaterials. 2018; 8(6):427. https://doi.org/10.3390/nano8060427

Chicago/Turabian Style

Wang, Meiyin, Hui Wang, Yuanhang Ren, Cheng Wang, Zhewei Weng, Bin Yue, and Heyong He. 2018. "Construction of g-C3N4-mNb2O5 Composites with Enhanced Visible Light Photocatalytic Activity" Nanomaterials 8, no. 6: 427. https://doi.org/10.3390/nano8060427

APA Style

Wang, M., Wang, H., Ren, Y., Wang, C., Weng, Z., Yue, B., & He, H. (2018). Construction of g-C3N4-mNb2O5 Composites with Enhanced Visible Light Photocatalytic Activity. Nanomaterials, 8(6), 427. https://doi.org/10.3390/nano8060427

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