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Magnetochemistry, Volume 10, Issue 12 (December 2024) – 2 articles

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16 pages, 5155 KiB  
Article
Mesoxalate-Bridged Heptanuclear Copper(II) Complexes: Structure and Magnetic Properties
by Beatriz Gil-Hernández, Simon Millan, Irina Gruber, Christoph Janiak, Carlos J. Gómez-García and Joaquín Sanchiz
Magnetochemistry 2024, 10(12), 93; https://doi.org/10.3390/magnetochemistry10120093 - 22 Nov 2024
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Abstract
Two new compounds, (NH4)4[Cu7(Hmesox)6(H2O)8]∙10H2O (1) and [Ru(bpy)3]4[Cu7(Hmesox)6Cl2]Cl2∙2CH3CN∙12H2O (2), were [...] Read more.
Two new compounds, (NH4)4[Cu7(Hmesox)6(H2O)8]∙10H2O (1) and [Ru(bpy)3]4[Cu7(Hmesox)6Cl2]Cl2∙2CH3CN∙12H2O (2), were prepared and their structures were solved by single-crystal X-ray diffraction (mesoxalic acid = dihydroxypropanedioic acid, H4mesox). The triply deprotonated mesoxalate anion acts as a chelating and bridging ligand with its carboxylate and alkoxide groups, forming the anionic heptanuclear copper(II) clusters [Cu7(Hmesox)6(H2O)8]4− and [Cu7(Hmesox)6Cl2]6− in 1 and 2, respectively. Variable temperature magnetic studies revealed antiferromagnetic interactions in 1 and the coexistence of ferro and antiferromagnetic interactions in 2. The [Ru(bpy)3]2+ cations provided luminescent properties to compound 2. Full article
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4 pages, 179 KiB  
Editorial
Synthetic, Natural and Natural-Synthetic Hybrid Magnetic Structures: Technology and Application
by Kamil G. Gareev
Magnetochemistry 2024, 10(12), 92; https://doi.org/10.3390/magnetochemistry10120092 - 22 Nov 2024
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Abstract
The magnetic properties of various types of structures based on iron oxides and the other ferri- or ferromagnets strongly correlate with their origin [...] Full article
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