Catalysis on Zeolites and Zeolite-Like Materials, 3rd Edition

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Catalytic Materials".

Deadline for manuscript submissions: 10 March 2025 | Viewed by 842

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Fakultät Chemie und Lebensmittelchemie, Technische Universität Dresden, Helmholtzstraße 14, 01069 Dresden, Germany
Interests: heterogeneous catalysis; zeolites; micro/mesoporous aluminosilicates; microreactor systems; flow chemistry; green chemistry
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Special Issue Information

Dear Colleagues,

This Special Issue is a continuation of the previous successful Special Issues, “Catalysis on Zeolites and Zeolite-Like Materials” and “Catalysis on Zeolites and Zeolite-Like Materials II”.

The regular pore system of zeolites, with cavities and nanometric channels, as well as the resulting characteristic properties, predestine them for wide use as catalysts in chemical technology. Over the past several decades, progress in zeolite synthesis enabled the discovery of new zeolite types, which allowed for the development of new catalytic processes in petrochemical industries. Moreover, new tools for zeolite modification have allowed for additional applications of zeolite-based catalysts in the field of environmental catalysis. The development of new mesoporous and micro/mesoporous or zeolite-like materials (e.g., metal–organic frameworks), as well as progress in computational chemistry and solid-state characterization techniques, demonstrated that the potential of ordered pore materials is still far from exhausted, and that further biocatalysis, electrocatalysis, photocatalysis, and micro/nanostructure technology indicate increasing interest in this class of substances.

With great pleasure, I invite you to submit your manuscript to the Special Issue “Catalysis on Zeolites and Zeolite-Like Materials, 3rd Edition” to share developments and recent progress regarding the synthesis, characterization and application of zeolites or zeolite-like materials as catalysts.

Prof. Dr. Wladimir Reschetilowski
Guest Editor

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Keywords

  • zeolites and zeolite-like materials
  • acid-base catalysis
  • bifunctional catalysis
  • environmental catalysis
  • biocatalysis
  • electrocatalysis
  • photocatalysis
  • C1 chemistry
  • kinetic modeling of zeolite-catalyzed chemical reactions
  • computation in catalysis with ordered porous materials

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Published Papers (1 paper)

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Research

16 pages, 2920 KiB  
Article
Seeds Combining Pyrrolidine Control the Framework Al Distribution of FER Zeolite to Enhance Its Performance in the Skeletal Isomerization of n-Butene
by Jinlong Fan, Xuedong Zhu, Fan Yang, Yarong Xu and Lantian Chen
Catalysts 2024, 14(10), 697; https://doi.org/10.3390/catal14100697 - 7 Oct 2024
Viewed by 650
Abstract
FER zeolites have a unique framework structure and acid distribution, and are widely studied as a catalyst for reactions such as n-butene skeletal isomerization and dimethyl ether carbonylation. The Brönsted acid site (BAS) located in the 10-member ring (10-MR) of FER zeolites [...] Read more.
FER zeolites have a unique framework structure and acid distribution, and are widely studied as a catalyst for reactions such as n-butene skeletal isomerization and dimethyl ether carbonylation. The Brönsted acid site (BAS) located in the 10-member ring (10-MR) of FER zeolites serves as the active site for the isomerization reaction of skeletal n-butene to produce isobutene. This study prepared five types of FER zeolites using different methods: using pyrrolidine (PY) alone as a template; using Na-form FER as seeds (SN) or H-form FER as seeds without organic structure directing agents (OSDAs); and combining the seeds of SN or SH with PY as OSDAs. The differences in the structure and acid distribution of the five zeolites were investigated, as well as their catalytic performance for the skeletal isomerization of n-butene. Experiments and characterization results showed that under hydrothermal synthesis conditions, the FER-PY+SH zeolites synthesized by using both H-form zeolites seeds and pyridine exhibited the highest aluminum concentrations at T1 and T3 sites, along with the greatest BAS located in the 10-MR. This unique composition contributed to the highest selectivity of isobutene. The FER-PY+SH catalyst was continuously used for 720 h at 350 °C, 0.1 MPa, and an n-butene mass space velocity of 2.0 h−1 for three cycles of 2160 h. During this period, the conversion of n-butene was over 39%, while the selectivity of isobutene exceeded 95%. The FER-PY+SH catalyst exhibited excellent stability and activity. Full article
(This article belongs to the Special Issue Catalysis on Zeolites and Zeolite-Like Materials, 3rd Edition)
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