Multifunctional Materials for Photocatalytic and Photoactivated Processes

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Photocatalysis".

Deadline for manuscript submissions: closed (15 June 2021) | Viewed by 9848

Special Issue Editors


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Guest Editor
CNR NANOTEC, Institute of Nanotechnology, Campus Ecoteckne, Lecce, Italy
Interests: semiconductor; light; color; photocatalysis; photochromism; nano- and composite-materials; nanomaterials for light-to-energy and environmental applications; materials processing; advanced X-ray methods; surface functionalization of building materials
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Guest Editor
Department of Architecture (D\'ARCH), University of Palermo, Viale delle Scienze bld 8-14, 90128 Palermo, Italy
Interests: construction and building materials; waste-based and composite materials; sustainable construction; high-performance buildings; innovation in building construction
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

The 21st century can be considered the “Nanotechnology Era” or the “Nano-Age”. Nanomaterials may indeed provide solutions to problems that cannot be dealt with by using conventional technologies. In this context, obtaining advanced nanostructured multifunctional materials exhibiting several coexisting properties is one of the most exciting and innovative research topics. Functional nanomaterials “activated” by light are of particular interest, as solar light is the most abundant, free, and virtually limitless source of energy. Therefore, it is no surprise that photoactivated reactions for water treatment, environmental remediation, light-to-energy, and energy storage application are still very much an en-vogue research topic.

Metal oxides are a very important family of nanomaterials, having unique properties that are attractive for a number of applications. Titanium dioxide nanoparticles, because of their flexibility and versatility, are a well-investigated class of metal oxides for photocatalytic and photoactivated processes.

This Special Issue of Catalysts, “Multifunctional Materials for Photocatalytic and Photoactivated Processes”, is devoted to research works dealing with light-activated semiconductor oxides showing (at the same time) more functionalities. A particular preference will be given to materials activated by light, as they are expected to play a significant role in photocatalysis, photo-electronics, photoswitches, photo-optical sensors, smart windows, displays, optical storage memories, self-cleaning materials, building materials, and the preservation of cultural heritage.

It is therefore our pleasure to invite you to contribute to this Special Issue with your research article, communication, or review.

Dr. David Maria Tobaldi
Dr. Manfredi Saeli
Guest Editors

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Keywords

  • Photoactivated processes;
  • Photocatalysis;
  • Multifunctionality;
  • Nanostructured materials;
  • Metal oxide semiconductors;
  • Titanium dioxide;
  • Light-to-energy;
  • Environmental remediation
  • Surface functionalization of building materials
  • Preserving cultural heritage

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Published Papers (2 papers)

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Research

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21 pages, 9977 KiB  
Article
Photocatalytic Lime Render for Indoor and Outdoor Air Quality Improvement
by José Antonio Ibáñez Gómez, Andrea Giampiccolo, David Maria Tobaldi, Sabine Mair, Carla Forbela da Silva, Maria Casado Barrasa, Daniel Maskell, Martin Philip Ansell, Rajnish Kurchania, Florian Mayer, Joao Antonio Labrincha, Yolanda R. de Miguel and Richard James Ball
Catalysts 2021, 11(3), 296; https://doi.org/10.3390/catal11030296 - 25 Feb 2021
Cited by 3 | Viewed by 2412
Abstract
This article reports a novel photocatalytic lime render for indoor and outdoor air quality improvement that is composed of a lime binder and doped TiO2 (KRONOClean 7000®) nanoparticles. These nanoparticles were distributed throughout the bulk of the finishing render, instead [...] Read more.
This article reports a novel photocatalytic lime render for indoor and outdoor air quality improvement that is composed of a lime binder and doped TiO2 (KRONOClean 7000®) nanoparticles. These nanoparticles were distributed throughout the bulk of the finishing render, instead of as a thin coating, thus ensuring the durability of the photocatalytic properties upon superficial damage. The physical properties of these renders were not affected by the addition of nanoparticles except in the case of surface area, which increased significantly. In terms of their photocatalytic activity, these novel lime renders were shown to degrade up to 12% NOx under UV light and up to 11% formaldehyde under visible light. Full article
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Review

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44 pages, 16182 KiB  
Review
TiO2 Photocatalysis for the Transformation of Aromatic Water Pollutants into Fuels
by Osama Al-Madanat, Yamen AlSalka, Wegdan Ramadan and Detlef W. Bahnemann
Catalysts 2021, 11(3), 317; https://doi.org/10.3390/catal11030317 - 28 Feb 2021
Cited by 40 | Viewed by 6583
Abstract
The growing world energy consumption, with reliance on conventional energy sources and the associated environmental pollution, are considered the most serious threats faced by mankind. Heterogeneous photocatalysis has become one of the most frequently investigated technologies, due to its dual functionality, i.e., environmental [...] Read more.
The growing world energy consumption, with reliance on conventional energy sources and the associated environmental pollution, are considered the most serious threats faced by mankind. Heterogeneous photocatalysis has become one of the most frequently investigated technologies, due to its dual functionality, i.e., environmental remediation and converting solar energy into chemical energy, especially molecular hydrogen. H2 burns cleanly and has the highest gravimetric gross calorific value among all fuels. However, the use of a suitable electron donor, in what so-called “photocatalytic reforming”, is required to achieve acceptable efficiency. This oxidation half-reaction can be exploited to oxidize the dissolved organic pollutants, thus, simultaneously improving the water quality. Such pollutants would replace other potentially costly electron donors, achieving the dual-functionality purpose. Since the aromatic compounds are widely spread in the environment, they are considered attractive targets to apply this technology. In this review, different aspects are highlighted, including the employing of different polymorphs of pristine titanium dioxide as photocatalysts in the photocatalytic processes, also improving the photocatalytic activity of TiO2 by loading different types of metal co-catalysts, especially platinum nanoparticles, and comparing the effect of various loading methods of such metal co-catalysts. Finally, the photocatalytic reforming of aromatic compounds employing TiO2-based semiconductors is presented. Full article
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