Structural and Optical Properties of Smectic Films
A special issue of Crystals (ISSN 2073-4352). This special issue belongs to the section "Liquid Crystals".
Deadline for manuscript submissions: closed (30 September 2020) | Viewed by 5072
Special Issue Editor
Interests: liquid crystals; nanofluidics; optics of liquid crystals; hydrodynamics of liquid crystals; free-standing smectic films
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Special Issue Information
Dear Colleagues,
One of the most interesting aspects of many smectic liquid crystals (LCs) is that, under appropriate conditions, they can form free-standing smectic films (FSSFs). In these films, thickness is quantified in units of layers, and a new class of phase transitions, when spontaneous layer-by-layer thinning transitions occur, has been observed. Because there is no substrate, these films represent an excellent model of low-dimensional systems for the study of surface effects as the film thickness is reduced. The surface tension is clearly of fundamental importance to the stability of these films. Moreover, the presence of the surface tension is believed to be responsible for intriguing surface-ordering phenomena exhibited by these films. Unlike the preferential surface melting exhibited by conventional solids, the FSSF/vapor interface appears to enhance the order of the surface layers so that they become ordered at temperatures well above the bulk SmA-Isotropic transition temperatures. Spontaneous layer-thinning transitions have been reported both for compounds exhibiting a first-order phase transition towards the isotropic phase, as well as for compounds that possess a second-order smectic-A-nematic phase transition. A great variety of phenomena can be observed in FSSFs: layer-thinning transitions, stepwise reduction of heat capacity, and sawtooth behavior of the surface tension upon heating the FSSFs above the bulk Sm-A-isotropic transition temperature.
We invite investigators to submit papers that discuss the key points dominating the structural and optical characteristics of free-standing smectic films, as well as the applications of different FSSFs, from theoretical calculations to material explorations and experimental viewing.
Dr. Alexandre Zakharov
Guest Editor
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Keywords
- Liquid crystals
- Free standing smectic films
- Structural and optical properties of FSSFs
- Dynamical properties of FSSFs
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