Single Molecule and Single Chain Magnets

A special issue of Magnetochemistry (ISSN 2312-7481).

Deadline for manuscript submissions: closed (31 December 2015) | Viewed by 6694

Special Issue Editors


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Guest Editor
Department of Chemistry, Franklin Science Center, Shippensburg University, Shippensburg, PA 17257, USA
Interests: coordination complexes; metallacrowns; single-molecule magnets

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Guest Editor
Department of Chemistry, Advanced Technology and Science Hall, Slippery Rock University, Slippery Rock, PA 17257, USA
Interests: coordination complexes; single-molecule magnets
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Special Issue Information

Dear Colleagues,

 

The interest in single-molecule magnets and single-chain magnets has increased significantly since their initial characterization approximately 20 years ago. The field has expanded from multi-metal transition metal-based coordination complexes and polymers to include single-ion transition metal molecules, mixed lanthanide-transition metal systems, single-ion lanthanide complexes, and even molecules that contain actinide metals. Challenges remain in the field, particularly in the a priori design of single-molecule and single-chain magnets. Not only must the molecular spin of the molecules must be controlled, but the magnetoanisotropy of the systems must be managed when designing a new molecule or coordination polymer. Recent advances in the area of single-ion magnets have been instrumental in understanding the behavior of magnetoanisotropy.

We invite investigators to contribute original research articles that focus on the development of novel single-molecule and single-chain magnets. We are particularly interested in articles that explore the rational synthetic design of these types of systems and the synthetic control of magnetoanisotropy.

Dr. Curtis M. Zaleski
Dr. Thaddeus Boron
Guest Editors

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Keywords

  • single-molecule magnets
  • single-ion magnets
  • single-chain magnets
  • molecular design
  • magnetoanisotropy

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Published Papers (1 paper)

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Research

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Article
Heptanuclear [FeIII6CrIII]3+ Complexes Experimentally Studied by Means of Magnetometry, X-ray Diffraction, XAS, XMCD and Spin-Polarized Electron Spectroscopy in Cross-Comparison with [MnIII6CrIII]3+ Single-Molecule Magnets
by Niklas Dohmeier, Andreas Helmstedt, Norbert Müller, Aaron Gryzia, Armin Brechling, Ulrich Heinzmann, Maik Heidemeier, Erich Krickemeier, Anja Stammler, Hartmut Bögge, Thorsten Glaser, Loïc Joly and Karsten Kuepper
Magnetochemistry 2016, 2(1), 5; https://doi.org/10.3390/magnetochemistry2010005 - 5 Feb 2016
Cited by 5 | Viewed by 6198
Abstract
Subsequent to the similar [MnIII6CrIII]3+ single-molecule magnets (SMM), the recently studied [FeIII6CrIII]3+ structural type adsorbed thin films prepared on Si and gold-coated glass substrates have been experimentally studied by means of [...] Read more.
Subsequent to the similar [MnIII6CrIII]3+ single-molecule magnets (SMM), the recently studied [FeIII6CrIII]3+ structural type adsorbed thin films prepared on Si and gold-coated glass substrates have been experimentally studied by means of spin-polarized electron spectroscopy (SPES) and X-ray magnetic circular dichroism (XMCD) at the Fe L3,2 edge using circularly-polarized synchrotron radiation. The results are cross-compared to the corresponding data obtained from the recently published measurements with Mn-based SMM [1], also in terms of the local spin and orbital magnetic moments obtained. Furthermore, [FeIII6CrIII]3+ single crystals have been experimentally studied by means of magnetometry and X-ray diffraction. Full article
(This article belongs to the Special Issue Single Molecule and Single Chain Magnets)
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