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Metal Organic Frameworks: Chemistry and Applications

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Porous Materials".

Deadline for manuscript submissions: closed (20 May 2022) | Viewed by 2631

Special Issue Editors


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Guest Editor
Department of Chemistry, CICECO—Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal
Interests: metal–organic framework; crystallography; solid-state electrolytes
Special Issues, Collections and Topics in MDPI journals

E-Mail Website
Guest Editor
Department of Chemistry, CICECO—Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal
Interests: organic and inorganic chemistry with emphasis in the preparation of functional metal-organic frameworks; MOF design and modification for their application as optical sensors and environmental remediation; metal organic frameworks; supramolecular chemistry; sensors; biosensors; optically-active MOFs
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear colleagus,

Metal–organic frameworks (MOF) represent a class of hybrid material built from metal ions and organic bridging ligands with well-defined coordination geometries and structures. The easy tunability of their pore size and the wide array of combinations within their constituents offers them a set of special characteristics such as porosity, large surface areas, intriguing framework architectures, and high chemical/mechanical stability. These features have made MOFs well known in applications such as catalysis, energy storage, drug delivery systems, nonlinear optics, sensing, and gas storage.

This Special Issue intends to present some of the most relevant progress on the design and development of MOFs and their applications. The Special Issue will significantly benefit from the contribution of original research articles and critical review articles in this scientific field.

Dr. Ricardo F. Mendes
Dr. Flávio Figueira
Guest Editors

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Keywords

  • metal-organic frameworks
  • nano-MOFs
  • MOF composites
  • post-synthesis modification
  • porous coordination polymer
  • porosity

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Published Papers (1 paper)

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Research

14 pages, 4626 KiB  
Article
Mesitylene Tribenzoic Acid as a Linker for Novel Zn/Cd Metal-Organic Frameworks
by Dana Bejan, Ioan-Andrei Dascalu, Sergiu Shova, Alexandru F. Trandabat and Lucian G. Bahrin
Materials 2022, 15(12), 4247; https://doi.org/10.3390/ma15124247 - 15 Jun 2022
Cited by 1 | Viewed by 1953
Abstract
Three new Metal-Organic Frameworks, containing mesitylene tribenzoic acid as a linker and zinc (1) or cadmium as metals (2,3), were synthesized through solvothermal reactions, using DMF/ethanol/water as solvents, at temperatures of 80 °C (structures 1 and 3 [...] Read more.
Three new Metal-Organic Frameworks, containing mesitylene tribenzoic acid as a linker and zinc (1) or cadmium as metals (2,3), were synthesized through solvothermal reactions, using DMF/ethanol/water as solvents, at temperatures of 80 °C (structures 1 and 3) and 120 °C (structure 2). Following single-crystal X-ray diffraction, it was found that 1 and 3 crystallize in the P21/c and C2/c space groups and form 2D networks, while 2 crystallizes in the Fdd2 space group, forming a 3D network. All three frameworks, upon heating, were found to be stable up to 350 °C. N2 sorption isotherms revealed that 1 displays a BET area of 906 m2/g. Moreover, the porosity of this framework is still present after five cycles of sorption/desorption, with a reduction of 14% of the BET area, down to 784 m2/g, after the fifth cycle. The CO2 loading capacity of 1 was found to be 2.9 mmol/g at 0 °C. Full article
(This article belongs to the Special Issue Metal Organic Frameworks: Chemistry and Applications)
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