Sustainable Extraction of Copper, Nickel and Zinc and Their By-Products from Ores, Recycled Materials and Wastes through Hydrometallurgical Processes

A special issue of Minerals (ISSN 2075-163X). This special issue belongs to the section "Mineral Processing and Extractive Metallurgy".

Deadline for manuscript submissions: 31 December 2024 | Viewed by 3806

Special Issue Editors


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Guest Editor
Department of Mining Engineering, Pontificia Universidad Católica de Chile, Santiago 8320000, Chile
Interests: leaching; hydrometallurgy; minerals; mineral processing; mineral characterization; extraction and processing industry; mining; clay minerals; extractive metallurgy; leaching processes; separation techniques; iron ore; sulfides; chemical precipitation; heap leaching; sulfuric acids; chalcopyrite recovery of metals from e-waste

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Guest Editor
Department of Chemical Engineering, University of Cape Town, Cape Town 7701, South Africa
Interests: exploration of fundamental reaction and transport phenomena during the leaching of minerals, especially the (bio)leaching of sulphide minerals, and mathematical modelling, particularly of heap leach processes; copper, zinc and nickel sulphide bioleaching; chloride and ammoniua leaching; Au and PGM cyanide leaching; extraction of REEs from ion adsorption clays; evaluating extractive technologies in a broader socio-economic context, both locally and globally, in terms of commodity cycles, such as Cu and Zn production and metals recovery from e-waste in the local South African context
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Guest Editor
1. Institute for Biological and Medical Engineering, Faculties of Engineering, Medicine and Biological Sciences, Pontificia Universidad Católica de Chile, Santiago 8320000, Chile
2. Department of Hydraulic and Environmental Engineering, School of Engineering, Pontificia Universidad Católica de Chile, Santiago 8320000, Chile
Interests: biofilm formation of bioleaching microorganisms; fluorescence microscopy, massive image analyses and OMICS techniques; microbial genetics and extracellular polymeric substances analysis and characterization; characterization of interactions and cell–cell communication in bioleaching consortia; changes in microbial diversity during bioleaching of chalcopyrite-containing ores; EPS production and analysis and development of methodologies for massive image analysis of biofilms of axenic and mixed bioleaching microbial consortia on pyrite and chalcopyrite surfaces
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Copper (Cu), nickel (Ni) and zinc (Zn) are vital non-ferrous metals in the context of a sustainable future. The importance of copper in any form of electricity generation, storage and usage cannot be overstated; it will only increase dramatically with the transition to a de-carbonized future. Similarly, Ni will be of critical significance as a battery mineral, and Zn  will be of paramount importance in ensuring long service life of construction and piping materials due to its extensive use in corrosion protection.

Classic base metals are derived from the processing of primary ores and concentrates, as well as the re-processing of historic mine tailings and recycling of scrap and end-of-life equipment.  The extraction and refining of primary base metals and their common companion metals (Mo, Au and U for C; Co and PGMs for Ni; Pb, Ge and In for Zn) usually involves hydrometallurgical processing to some degree. The respective technologies and chemistries employed are being continuously developed to address challenges such as declining ore-grades, changing mineralogy, energy supply, carbon footprint issues, SHE concerns, etc. Many of the processes applied to primary ores and concentrates are similar or adaptable to those relevant to processing of secondary resources, but with some modifications to account for the different nature and composition of the feed materials and the scale of operation.

This Special Issue is focused on new developments in the sustainable hydrometallurgical processing of materials for which Cu, Ni and Zn are the primary metal commodities recovered, with a special emphasis on the co-recovery of companion metals:  Mo, Ag, Au and U (by-products of Cu); Co and PGMs (by-products of Ni); Pb, Ge, and In (by-products of Zn).

This Special Issue will primarily cover four areas:

Area 1. Chemistries: acid ferric sulphate leaching and bioleaching, chloride leaching, ammonia leaching, leaching aids and catalysts, novel reagents.

Area 2. Leaching Technologies: atmospheric and pressure leaching, heap leaching, novel leaching systems.

Area 3. Separation: SX, IX, precipitation, and electrowinning for selective metal recovery from mixed leach liquors.

Area 4. Flowsheets: evaluation and comparison of complete flowsheets for the comprehensive recovery of metals from primary, secondary or blended feeds and the ensuing waste streams.

Dr. Lilian Velásquez-Yévenes
Prof. Dr. Jochen Petersen
Dr. Mario Vera
Guest Editors

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Keywords

  • base metal
  • leaching and bioleaching
  • leaching technology
  • chloride leaching
  • e-waste leaching
  • innovation and process improvement
  • new reagents, materials and technologies
  • solvent extraction and ion exchange
  • precipitation

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Published Papers (3 papers)

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Research

20 pages, 5864 KiB  
Article
Novel Indigenous Strains and Communities with Copper Bioleaching Potential from the Amolanas Mine, Chile
by Julián C. Casas-Vargas, Cristóbal Martínez-Bussenius, Álvaro Videla and Mario Vera
Minerals 2024, 14(9), 867; https://doi.org/10.3390/min14090867 - 26 Aug 2024
Viewed by 820
Abstract
Bioleaching, a process catalyzed by acidophilic microorganisms, offers a sustainable approach to metal extraction from sulfide minerals. Chalcopyrite, the world’s most abundant copper sulfide, presents challenges due to surface passivation limiting its bioleaching efficiency. Also, indigenous species and microbial communities may present high [...] Read more.
Bioleaching, a process catalyzed by acidophilic microorganisms, offers a sustainable approach to metal extraction from sulfide minerals. Chalcopyrite, the world’s most abundant copper sulfide, presents challenges due to surface passivation limiting its bioleaching efficiency. Also, indigenous species and microbial communities may present high copper extraction rates and offer new possibilities for application in bioleaching processes. This study examines the bioleaching potential of microbial isolates and communities obtained from Amolanas Mine in Chile. Samples were collected, cultivated, and identified by Sanger sequencing. The bioleaching potential and biofilm formation of isolates and enrichments were evaluated on pyrite and chalcopyrite. The results show the isolation of nine Leptospirillum and two Acidithiobacillus strains. The bioleaching experiments demonstrated good copper bioleaching potentials of the Leptospirillum I2CS27 strain and EICA consortium (composed mainly of Leptospirillum ferriphilum, Acidiphilium sp., and Sulfobacillus thermosulfidooxidans), with 11% and 25% copper recovery rates, respectively. Microbial attachment to the surface mineral was not mandatory for increasing the bioleaching rates. Our findings underscore the importance of indigenous microbial communities in enhancing copper bioleaching efficiency. Full article
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16 pages, 3199 KiB  
Article
Study of a Copper Oxide Leaching in Alkaline Monosodium Glutamate Solution
by Carlos G. Perea, Christian Ihle, Laurence Dyer, Simón Díaz Quezada and Humberto Estay
Minerals 2024, 14(7), 714; https://doi.org/10.3390/min14070714 - 15 Jul 2024
Cited by 1 | Viewed by 767
Abstract
Oxide copper minerals are commonly extracted via acidic leaching, using acids such as H2SO4, HCl, or HNO3. These strong acids are the most widely used because of their high dissolution kinetics. However, their main concern is the [...] Read more.
Oxide copper minerals are commonly extracted via acidic leaching, using acids such as H2SO4, HCl, or HNO3. These strong acids are the most widely used because of their high dissolution kinetics. However, their main concern is the high acid consumption because copper oxide deposits contain large amounts of acid-consuming gangue. This paper proposes using an alternative aqueous alkaline monosodium glutamate (MSG) system to leach copper oxide minerals. Tenorite (CuO) was used as the copper oxide mineral under study. The influence of process variables (such as temperature and glutamate concentration) and kinetics of this system on copper leaching from tenorite were studied. The results showed that temperature has a significant effect on copper dissolution rates. Increased temperature from 15 °C to 60 °C enhanced the copper extraction from 9.1% to 97.7% after 2 h. Leaching kinetics were analyzed using the shrinking core model (SCM) under various conditions, indicating that the leaching rate presented a mixed control. This method, however, fails to describe leaching for broad particle sizes due to its requirement for single-sized solid grains. This study demonstrated that a large particle size distribution in tenorite supported a successful extension of the SCM for leaching it from mixed glutamate solutions. The activation energy for the 15–60 °C temperature range was calculated to be 102.6 kJ/mol for the chemical control. Full article
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17 pages, 7688 KiB  
Article
Enhanced Chalcopyrite Dissolution in Acidic Culture Medium: The Impact of Arsenopyrite Presence
by Xiangdong Shangguan, Yuandong Liu, Run Liu, Kan Wang, Wissal Belqadi, Jiayu He, Yan Tong, Li Shen, Weimin Zeng, Xueling Wu, Runlan Yu and Xinlei Sun
Minerals 2024, 14(1), 50; https://doi.org/10.3390/min14010050 - 30 Dec 2023
Cited by 1 | Viewed by 1477
Abstract
Nowadays, research on promoting the dissolution of chalcopyrite is important. As a natural symbiotic mineral of chalcopyrite, arsenopyrite will have an impact on the dissolution of chalcopyrite. This paper shows the influence of arsenopyrite on the dissolution of chalcopyrite in an acidic culture [...] Read more.
Nowadays, research on promoting the dissolution of chalcopyrite is important. As a natural symbiotic mineral of chalcopyrite, arsenopyrite will have an impact on the dissolution of chalcopyrite. This paper shows the influence of arsenopyrite on the dissolution of chalcopyrite in an acidic culture medium. The leaching results showed that adding arsenopyrite increased the leaching concentration of copper by 332 mg/L. The residues showed a decrease in sulfur through X-ray diffraction analysis (XRD) and an increase in dissolution degree through scanning electron microscope (SEM). Electrochemical experiments have shown that the rest potential of arsenopyrite is higher than that of chalcopyrite, so there is a galvanic interaction, and the impact on chalcopyrite is greater than that of arsenopyrite. The polarization curve also proves this. Under the interaction of galvanic couples, the reduction of S0 production and the enhancement of Cu2+ release can promote the dissolution of chalcopyrite. In addition, X-ray photoelectron spectrometer (XPS) analysis under the action of galvanic coupling indicates that more SO42− is generated on the surface of chalcopyrite, replacing Sn2−/S0, and SEM shows a stronger corrosion morphology. All results confirm that the electrochemical effect between arsenopyrite and chalcopyrite promotes the dissolution of chalcopyrite in the acidic culture medium. Full article
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