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Design, Synthesis, and Applications of Multifunctional Metal-Organic Framework Composites

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Materials Chemistry".

Deadline for manuscript submissions: closed (31 July 2024) | Viewed by 3346

Special Issue Editor

Department of Applied Chemistry and State Key Laboratory of Tea Plant Biology and Utilization, Anhui Agricultural University, Hefei 230036, China
Interests: MOFs; porous materials; nanomaterials; catalysis; adsorption

Special Issue Information

Dear Colleague,

Metal–organic frameworks (MOFs) are a class of very promising porous crystalline materials whose structure is composed of metal ion nodes and organic linkers. However, MOFs exhibit some weak points, including poor chemical stability, which primarily hamper their full potential use. Combining MOFs with a variety of nanoparticles is leading to the formation of novel multifunctional composites, which display high performance that is superior to that of individual components. This is a rapidly developing research area. This Special Issue will publish original research papers, review articles, and progress reports that are intentionally broad, covering all aspects of novel MOF-based porous nanocomposites, and the design, development, and use of nanocomposites and nanotechnologies for multifunctional applications.

Dr. Fei Ke
Guest Editor

Manuscript Submission Information

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Keywords

  • metal-organic frameworks
  • nanocomposites
  • adsorption
  • heterogeneous catalysis

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Published Papers (2 papers)

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Research

12 pages, 3828 KiB  
Article
The Development and Synthesis of a CdZnS @Metal–Organic Framework ZIF-8 for the Highly Efficient Photocatalytic Degradation of Organic Dyes
by Liu Hong, Jiaming Cao, Wenlong Zhang, Tao Jiang, Guohao Pan and Yun Wu
Molecules 2023, 28(23), 7904; https://doi.org/10.3390/molecules28237904 - 2 Dec 2023
Viewed by 1546
Abstract
The development of photocatalysts for organic degradation is a hot research topic. In this study, CdZnS was selected as the carrier, and ZIF-8 was combined with it to explore the photocatalytic performance of the composite. In addition, the compound material, CdZnS@ZIF-8, was used [...] Read more.
The development of photocatalysts for organic degradation is a hot research topic. In this study, CdZnS was selected as the carrier, and ZIF-8 was combined with it to explore the photocatalytic performance of the composite. In addition, the compound material, CdZnS@ZIF-8, was used as a photocatalyst for the decomposition of methylene blue dye, and the performance of pure CdZnS and pure ZIF-8 was compared. The photocatalytic efficiency of CdZnS@ZIF-8 was significantly higher than that of the other two. In the experimental reaction, the amount of catalyst was 0.04 g, the pH value was 7, the initial concentration of methylene blue aqueous solution was 20 mg/L, and the degradation of methylene blue in 50 mL aqueous solution could reach 99.5% under visible light irradiation for 90 min, showing excellent photocatalytic efficiency in the visible light range. It demonstrated excellent photocatalytic function in the visible light region, and the electron transfer phenomenon at the interface occurred in the het-junction and the separation of the photo-generating electron–hole as an electron acceptor of ZIF-8 further promoted the photocatalytic effect. Full article
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12 pages, 3738 KiB  
Communication
Oxygen Vacancy and Interface Effect Adjusted Hollow Dodecahedrons for Efficient Oxygen Evolution Reaction
by Huan Wang, Qian Ma, Fengmin Sun, Yachuan Shao, Di Zhang, Huilan Sun, Zhaojin Li, Qiujun Wang, Jian Qi and Bo Wang
Molecules 2023, 28(15), 5620; https://doi.org/10.3390/molecules28155620 - 25 Jul 2023
Cited by 1 | Viewed by 1359
Abstract
Metal–organic frameworks (MOFs) with special morphologies provide the geometric morphology and composition basis for the construction of platforms with excellent catalytic activity. In this work, cobalt–cerium composite oxide hollow dodecahedrons (Co/Cex-COHDs) with controllable morphology and tunable composition are successfully prepared via a high-temperature [...] Read more.
Metal–organic frameworks (MOFs) with special morphologies provide the geometric morphology and composition basis for the construction of platforms with excellent catalytic activity. In this work, cobalt–cerium composite oxide hollow dodecahedrons (Co/Cex-COHDs) with controllable morphology and tunable composition are successfully prepared via a high-temperature pyrolysis strategy using Co/Ce-MOFs as self-sacrificial templates. The construction of the hollow structure can expose a larger surface area to provide abundant active sites and pores to facilitate the diffusion of substances. The formation and optimization of phase interface between Co3O4 and CeO2 regulate the electronic structure of the catalytic site and form a fast channel favorable to electron transport, thereby enhancing the electrocatalytic oxygen evolution activity. Based on the above advantages, the optimized Co/Ce0.2-COHDs obtained an enhanced oxygen evolution reaction (OER) performance. Full article
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