Carbon-Based Polymer Nanocomposites: Preparation, Characterization, and Applications

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Analysis and Characterization".

Deadline for manuscript submissions: 25 January 2025 | Viewed by 5638

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Department of Advanced Materials Engineering for Information and Electronics, Integrated Education Institute for Frontier Science and Technology (BK21 Four), Kyung Hee University, 1732 Deogyeong-daero, Giheung-gu, Yongin-si 17104, Gyeonggi-do, Republic of Korea
Interests: nanocarbon synthesis; preparation of composites; lithium ion battery
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Special Issue Information

Dear Colleagues,

This Special Issue focuses on the preparation and characterization of carbon-based polymer nanocomposites, aiming to improve the mechanical and functional properties of polymer materials. The Special Issue deals with the fabrication techniques employed to incorporate carbon materials into polymer matrices, exploring various methods like solution blending, melt processing, and chemical vapor deposition. Each method offers distinct advantages and challenges, affecting the dispersion and alignment of carbon materials within the polymer matrix. Understanding these fabrication techniques is crucial to achieving optimal composite properties. The characterization process employs a range of sophisticated analytical techniques, which methods provide valuable insights into the composite's microstructure, mechanical behavior, thermal stability, and electrical conductivity.

This Special Issue, “Carbon-Based Polymer Nanocomposites: Preparation, Characterization, and Applications”, aims to be a collection of high-quality original/review papers focusing on recent progress in new preparation and applications of Carbon-based polymer nanocomposites, including (a) synthesis and surface modification of carbon materials, (b) tailored control of carbon materials’ size, concentration, and orientation in polymer matrix, (c) interfacial property control between carbon materials and polymer matrix, (d) evaluation of the carbon materials dispersion state in the polymer matrix, (e) development of new applications by using carbon-based polymer nanocomposites and various nanocomposites.

Prof. Dr. Jea Uk Lee
Guest Editor

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Keywords

  • carbon materials
  • polymer
  • nanocomposites
  • preparation
  • characterization
  • applications

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Published Papers (4 papers)

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Research

17 pages, 17882 KiB  
Article
Evaluation of Shape Recovery Performance of Shape Memory Polymers with Carbon-Based Fillers
by Sungwoong Choi, Seongeun Jang, Seung Hwa Yoo, Gyo Woo Lee and Duyoung Choi
Polymers 2024, 16(17), 2425; https://doi.org/10.3390/polym16172425 - 27 Aug 2024
Viewed by 739
Abstract
This study focuses on enhancing the thermal properties and shape recovery performance of shape memory polymers (SMPs) through the application of carbon-based fillers. Single and mixed fillers were used to investigate their effects on the glass transition temperature (Tg), thermal conductivity, [...] Read more.
This study focuses on enhancing the thermal properties and shape recovery performance of shape memory polymers (SMPs) through the application of carbon-based fillers. Single and mixed fillers were used to investigate their effects on the glass transition temperature (Tg), thermal conductivity, and shape recovery performance. The interaction among the three-dimensional (3D) structures of mixed fillers played a crucial role in enhancing the properties of the SMP. These interactions facilitated efficient heat transfer pathways and conserved strain energy. The application of mixed fillers resulted in substantial improvements, demonstrating a remarkable 290.37% increase in thermal conductivity for SMPCs containing 60 μm carbon fiber (CF) 10 wt% + graphite 20 wt% and a 60.99% reduction in shape recovery time for SMPCs containing CF 2.5 wt% + graphite 2.5 wt%. At a content of 15 wt%, a higher graphite content compared to CF improved the thermal conductivity by 37.42% and reduced the shape recovery time by 6.98%. The findings demonstrate that the application of mixed fillers, especially those with high graphite content, is effective in improving the thermal properties and shape recovery performance of SMPs. By using mixed fillers with high graphite content, the performance of the SMP showed significant improvement in situations where fast response times were required. Full article
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17 pages, 4451 KiB  
Article
Enhanced Mechanical and Thermal Properties of Polyimide Films Using Hydrophobic Fumed Silica Fillers
by Jongin Yeob, Sung Woo Hong, Won-Gun Koh and In Park
Polymers 2024, 16(2), 297; https://doi.org/10.3390/polym16020297 - 22 Jan 2024
Cited by 2 | Viewed by 1828
Abstract
Polyimide (PI) composite films with enhanced mechanical properties were prepared by incorporating modified fumed silica (FS) particles while preserving their optical and thermal characteristics. The PI matrix was synthesized using a fluorinated diamine, a fluorinated dianhydride, and a rigid biphenyl dianhydride via chemical [...] Read more.
Polyimide (PI) composite films with enhanced mechanical properties were prepared by incorporating modified fumed silica (FS) particles while preserving their optical and thermal characteristics. The PI matrix was synthesized using a fluorinated diamine, a fluorinated dianhydride, and a rigid biphenyl dianhydride via chemical imidization. Commercially available FS particles, including unmodified FS particles (0-FS) and particles modified with dimethyl (2-FS), trimethyl (3-FS), octyl (8-FS), octamethylcyclotetrasiloxane (D4-FS), and polydimethylsiloxane (PDMS-FS) were used. Scanning electron microscope images and nitrogen adsorption–desorption isotherms revealed well-defined porous structures in the FS particles. The water contact angles on the composite films increased compared to those of the pristine PI films, indicating improved water resistance. The PI/0-FS films exhibited a typical trade-off relationship between tensile modulus and elongation at break, as observed in conventional composites. Owing to the poor compatibility and agglomeration of the PDMS-FS particles, the PI/PDMS-FS composite films exhibited poor mechanical performance and diminished optical characteristics. Although the longer-chained FS particles (8- and D4-FS) improved the tensile modulus of the PI film by up to 12%, a reduction of more than 20% in toughness was observed. The PI composite films containing the methylated FS particles (2- and 3-FS) outperformed 8- and D4-FS in terms of mechanical properties, with PI/3-FS films showing an over 10% increased tensile modulus (from 4.07 to 4.42 GPa) and 15% improved toughness (from 6.97 to 8.04 MJ/m3) at 7 wt. % silica loading. Except for the PI/PDMS-FS composites, all composite film samples exhibited more than 86% transmittance at 550 nm. Regarding thermal properties, the glass transition temperature (Tg) and thermal stability remained stable for most composite films. In addition, PI/3-FS films demonstrated enhanced dimensional stability with lower coefficients of thermal expansion (from 47.3 to 34.5 ppm/°C). Overall, this study highlights the potential of incorporating specific modified FS particles to tailor the mechanical, optical, and thermal properties of PI composite films. Full article
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13 pages, 10218 KiB  
Article
Dielectrophoretically Assembled SWCNTs Networks on SU-8 Substrate for PEG/SWCNTs Composite Gas Sensor
by Jin-Chern Chiou, Chin-Cheng Wu, Tse-Mei Lin and Yu-Chieh Huang
Polymers 2024, 16(1), 74; https://doi.org/10.3390/polym16010074 - 26 Dec 2023
Viewed by 951
Abstract
This study proposed a SU-8 based gas sensor, integrated with heater and sensing electrodes, to develop a multi-channel gas sensor with PEG/SWCNTs composite films. The impedance of single-walled carbon nanotubes (SWCNTs) on each sensing electrode was well controlled via dielectrophoresis technology. To investigate [...] Read more.
This study proposed a SU-8 based gas sensor, integrated with heater and sensing electrodes, to develop a multi-channel gas sensor with PEG/SWCNTs composite films. The impedance of single-walled carbon nanotubes (SWCNTs) on each sensing electrode was well controlled via dielectrophoresis technology. To investigate dielectrophoretic mobility characteristics, the concentric circular sensing electrode has three different spacing between the inner and outer electrodes, including 10 μm, 15 μm, and 20 μm. The electrodes were applied with a 5 MHz AC source with a voltage ranging from 1 Vpp to 5 Vpp. Polyethylene glycol (PEG) was deposited on the gas sensor via drop casting. The fabricated gas sensor was operated at different working temperatures, including 25 °C, 40 °C, 50 °C and 60 °C, to examine the sensing response. The response results revealed that the PEG/SWCNTs composites gas sensor with 60 °C working temperature exhibited the ability to detect 80 ppm ethanol vapor. Full article
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16 pages, 2837 KiB  
Article
Highly Self-Healable Polymeric Coating Materials Based on Charge Transfer Complex Interactions with Outstanding Weatherability
by Pyong Hwa Hong, Gyeongmin Moon, Jinsil Kim, Kiwon Choi, Min Jae Ko, Ho Gyu Yoon and Sung Woo Hong
Polymers 2023, 15(23), 4544; https://doi.org/10.3390/polym15234544 - 27 Nov 2023
Viewed by 1377
Abstract
In this study, we prepare highly self-healable polymeric coating materials using charge transfer complex (CTC) interactions. The resulting coating materials demonstrate outstanding thermal stability (1 wt% loss thermal decomposition temperature at 420 °C), rapid self-healing kinetics (in 5 min), and high self-healing efficiency [...] Read more.
In this study, we prepare highly self-healable polymeric coating materials using charge transfer complex (CTC) interactions. The resulting coating materials demonstrate outstanding thermal stability (1 wt% loss thermal decomposition temperature at 420 °C), rapid self-healing kinetics (in 5 min), and high self-healing efficiency (over 99%), which is facilitated by CTC-induced multiple interactions between the polymeric chains. In addition, these materials exhibit excellent optical properties, including transmittance over 91% and yellow index (YI) below 2, and show enhanced weatherability with a ΔYI value below 0.5 after exposure to UV light for 72 h. Furthermore, the self-healable coating materials developed in this study show outstanding mechanical properties by overcoming the limitations of conventional self-healing materials. Full article
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