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Sustainable Cultural Heritage Conservation: Green Nuclear Physics for Non-invasive Approach to the Conservation and Preservation of Cultural Heritage Artifacts

A special issue of Sustainability (ISSN 2071-1050). This special issue belongs to the section "Tourism, Culture, and Heritage".

Deadline for manuscript submissions: 31 December 2024 | Viewed by 5832

Special Issue Editor


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Guest Editor
Science and Research Direction, Italian Space Agency (ASI), Via del Politecnico, 00133 Rome, Italy
Interests: materials science; nuclear physics; ionizing radiation; cultural heritage; library and archival heritage; parchment conservation; life sciences and space
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Sustainability of cultural heritage diagnosis and treatment interventions refers to the ability to maintain the preservation and integrity of cultural heritage objects and sites in a way that meets the needs of the present without compromising the ability of future generations to do the same.

This concept encompasses a range of factors, including the use of appropriate and non-invasive diagnostic techniques, the selection of sustainable and reversible conservation treatments, the use of long-lasting materials and the implementation of preventive conservation measures to reduce the need for future interventions.

It also includes the involvement of local communities and stakeholders in the conservation and management of cultural heritage sites to ensure their active participation in the decision-making process, and to promote the cultural heritage value and its meaning to the society.

Another aspect of sustainability in cultural heritage diagnosis and treatment interventions is the creation of digital documentation and archiving of cultural heritage objects and sites, which allows us to share the information with a wider public, promote the heritage and ensure its preservation for future generations.

Additionally, sustainability implies the responsible use of new technologies and innovations, such as Artificial Intelligence, in the field of cultural heritage diagnosis and treatment, ensuring the respect of ethical principles and the protection of the heritage value.

The use of nuclear physics techniques in cultural heritage conservation is a relatively new field of applications known as 'green nuclear physics'. This approach involves non-destructive techniques to study, to analyze and also to treat the cultural artifacts by extending their life and preventing their further damage.

Nuclear physics techniques are viable as sustainable applications of pigments analysis in paintings. They allow conservators to identify compositional elements and the original production techniques of assets and to study the structure of artifacts in a non-invasive way.

Green nuclear physics is fully sustainable in processes of biodegradation removal: ionizing radiations, such as X- and Gamma-rays or electrons, can penetrate deep into the material and break the chemical bonds of deteriogens slowing down the decay process. They are useful for macro- and micro-organisms sterilization, for infestation treatment, for stabilization and preservation of materials, and for the consolidation of fragile artefacts.

Overall, the use of green nuclear physics in cultural heritage conservation is a highly sustainable approach and holds great promise as a non-invasive and effective way to conserve and preserve our cultural heritage for future generations. The scientific literature still needs to be enriched, and it is necessary to disseminate the results of the interesting researches that experts in the sector are conducting with particular attention paid to the sustainability of the used and proposed methods.

Sustainability in cultural heritage conservation requires the active involvement and support of the scientific community: this Special Issue, dedicated to the sustainable use of nuclear techniques for cultural heritage conservation, invites experts in green nuclear physics treatments for cultural heritage conservation, including nuclear scientists, nuclear engineers, physicists, chemists and archaeologists, working in research institutes, universities and government laboratories, which have experience in the fields of nuclear techniques, radiation chemistry, materials science and cultural heritage preservation.

This issue of the journal, promoting the sustainability aspect of the use of green nuclear physics, is also addressed to experts from professional organizations, energy agencies, international councils and international centers for the study of conservation and restoration of cultural heritage, which promotes the use of nuclear physics techniques for the conservation of cultural heritage, and also caters to the operators of many museums, heritage sites and conservation organizations that have personnel with specialized training in the application of physics techniques nuclear power for the conservation of cultural heritage.

Dr. Monia Vadrucci
Guest Editor

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Keywords

  • sustainable systems for the cultural heritage diagnosis with nuclear methods
  • green nuclear physics treatments of the cultural heritage assets
  • technologies and innovations of nuclear physics applied to cultural heritage
  • particle accelerators to produce X-rays and electrons for imaging and material analysis
  • chemical composition analysis based on nuclear physics approach
  • studies of cultural heritage with isotopic techniques
  • neutron activation analysis (NAA) and prompt gamma activation analysis (PGAA)
  • future approaches for the sustainable conservation of cultural heritage

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Published Papers (5 papers)

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Research

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26 pages, 19720 KiB  
Article
Multi-Technique Approach for the Sustainable Characterisation and the Digital Documentation of Painted Surfaces in the Hypogeum Environment of the Priscilla Catacombs in Rome
by Paola Calicchia, Sofia Ceccarelli, Francesco Colao, Chiara D’Erme, Valeria Di Tullio, Massimiliano Guarneri, Loredana Luvidi, Noemi Proietti, Valeria Spizzichino, Margherita Zampelli and Rocco Zito
Sustainability 2024, 16(19), 8284; https://doi.org/10.3390/su16198284 - 24 Sep 2024
Viewed by 912
Abstract
The purpose of this paper is to identify an efficient, sustainable, and “green” approach to address the challenges of the preservation of hypogeum heritage, focusing on the problem of moisture, a recurring cause of degradation in porous materials, especially in catacombs. Conventional and [...] Read more.
The purpose of this paper is to identify an efficient, sustainable, and “green” approach to address the challenges of the preservation of hypogeum heritage, focusing on the problem of moisture, a recurring cause of degradation in porous materials, especially in catacombs. Conventional and novel technologies have been used to address this issue with a completely non-destructive approach. The article provides a multidisciplinary investigation making use of advanced technologies and analysis to quantify the extent and distribution of water infiltration in masonry before damage starts to be visible or irreversibly causes damage. Four different technologies, namely Portable Nuclear Magnetic Resonance (NMR), Audio Frequency–Acoustic Imaging (AF–AI), Laser-Induced Fluorescence (LIF), Infrared Thermography (IRT), and 3D Laser Scanning (RGB-ITR), were applied in the Priscilla catacombs in Rome (Italy). These imaging techniques allow the characterisation of the deterioration of painted surfaces within the delicate environment of the Greek chapel in the Priscilla catacombs. The resulting high-detailed 3D coloured model allowed for easily referencing the data collected by the other techniques aimed also at the study of the potential presence of salt efflorescence and/or microorganisms. The results supply an efficient and sustainable tool aimed at cultural heritage conservation but also at the creation of digital documentation obtained with green methodologies for a wider sharing, ensuring its preservation for future generations. Full article
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15 pages, 6715 KiB  
Article
Real-Time Elemental Analysis Using a Handheld XRF Spectrometer in Scanning Mode in the Field of Cultural Heritage
by Anastasios Asvestas, Demosthenis Chatzipanteliadis, Theofanis Gerodimos, Georgios P. Mastrotheodoros, Anastasia Tzima and Dimitrios F. Anagnostopoulos
Sustainability 2024, 16(14), 6135; https://doi.org/10.3390/su16146135 - 18 Jul 2024
Viewed by 992
Abstract
An X-ray fluorescence handheld spectrometer (hh-XRF) is adapted for real-time qualitative and quantitative elemental analysis in scanning mode for applications in cultural heritage. Specifically, the Tracer-5i (Bruker) is coupled with a low-cost constructed computer-controlled x–y target stage that enables the remote control of [...] Read more.
An X-ray fluorescence handheld spectrometer (hh-XRF) is adapted for real-time qualitative and quantitative elemental analysis in scanning mode for applications in cultural heritage. Specifically, the Tracer-5i (Bruker) is coupled with a low-cost constructed computer-controlled x–y target stage that enables the remote control of the target’s movement under the ionizing X-ray beam. Open-source software synchronizes the spectrometer’s measuring functions and handles data acquisition and data analysis. The spectrometer’s analytical capabilities, such as sensitivity, energy resolution, beam spot size, and characteristic transition intensity as a function of the distance between the spectrometer and the target, are evaluated. The XRF scanner’s potential in real-time imaging, object classification, and quantitative analysis in cultural heritage-related applications is explored and the imaging capabilities are tested by scanning a 19th-century religious icon. The elemental maps provide information on used pigments and reveal an underlying icon. The scanner’s capability to classify metallic objects was verified by analyzing the measured raw spectra of a coin collection using Principal Components Analysis. Finally, the handheld’s capability to perform quantitative analysis in scanning mode is demonstrated in the case of precious metals, applying a pre-installed quantification routine. Full article
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17 pages, 5474 KiB  
Article
Application of Macro X-ray Fluorescence Fast Mapping to Thickness Estimation of Layered Pigments
by Riccardo Zito, Letizia Bonizzoni and Nicola Ludwig
Sustainability 2024, 16(6), 2467; https://doi.org/10.3390/su16062467 - 15 Mar 2024
Viewed by 1269
Abstract
Even though X-ray fluorescence (XRF) is strictly an atomic method, this technique has been developed mostly at research centers for nuclear physics. One of its most valuable variations is the mapping mode that allows it to shift XRF from a punctual to an [...] Read more.
Even though X-ray fluorescence (XRF) is strictly an atomic method, this technique has been developed mostly at research centers for nuclear physics. One of its most valuable variations is the mapping mode that allows it to shift XRF from a punctual to an image technique. Macro X-ray Fluorescence (MA-XRF) is a widespread analytical technique applied in cultural heritage for characterizing the elemental composition of pigments with a non-destructive, rapid and green approach. When dealing with cultural heritage materials, the sustainability of the applied techniques is directly linked to the limited impact on the work of art. MA-XRF can reveal hidden sub-surface layers or restorations, but, nonetheless, it is hardly adopted for estimating the thickness of layers without resorting to complex Monte Carlo simulations or without combining information from other techniques. Exploiting the recurrent presence of lead white under pictorial layers in historical artworks, we perform a calibration on stand-alone layers produced ad hoc for the relative absorption of Pb L fluorescence lines, and then, their ratio is successfully used to estimate the thickness of azurite and ultramarine blue layers over lead white. The final result is rendered as a heatmap, easy to present to non-technical personnel frequently involved in the cultural heritage field. The new proposed procedure for calculating layer thickness extends the concept of non-invasive applications, paving the way to the possibility of performing stratigraphy without sampling. Full article
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18 pages, 3424 KiB  
Article
Angle-Dependent XRF Analyses: Pros and Cons of a Novel Technique in the Field of Cultural Heritage
by Jacopo Orsilli and Anna Galli
Sustainability 2024, 16(4), 1460; https://doi.org/10.3390/su16041460 - 8 Feb 2024
Cited by 1 | Viewed by 1131
Abstract
In the cultural heritage field, non-invasive analyses are becoming more important as they avoid any sampling, allowing in situ measurements to be performed. XRF is one of the most common among those techniques, as it allows elemental speciation of the sample with a [...] Read more.
In the cultural heritage field, non-invasive analyses are becoming more important as they avoid any sampling, allowing in situ measurements to be performed. XRF is one of the most common among those techniques, as it allows elemental speciation of the sample with a range that goes from F to U. However, the main limitation of this technique on cultural heritage objects is due to their intrinsic inhomogeneity, both lateral and in-depth. If MA-XRF has overcome the lateral inhomogeneity through the collection of multiple XRF spectra in different positions, it is more difficult to find an optimal way to perform in-depth analyses. Now, only confocal micro XRF allows for precise 3D analyses, as other techniques are limited to certain kinds of samples. In recent years, however, angle-resolved XRF has given promising results in the analysis of layered samples. In this study, we will review the information about this new analytical technique and its advantages and disadvantages in studying cultural heritage objects following our recent studies. Full article
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Review

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20 pages, 1415 KiB  
Review
Disinfection in Archives—A Short Review of the Sustainable Approaches and Green Perspectives of Using Radiation for Mass Disinfection
by Cristina Cicero, Monia Vadrucci, Giulia Doni and Enrico Trogu
Sustainability 2024, 16(21), 9303; https://doi.org/10.3390/su16219303 - 26 Oct 2024
Viewed by 659
Abstract
The conservation of the immense archival heritage of a country like Italy presents scholars with the enormous challenge of finding techniques and procedures that enable rapid and large-scale interventions, especially in cases of biodeterioration. The volume of material to be preserved and often [...] Read more.
The conservation of the immense archival heritage of a country like Italy presents scholars with the enormous challenge of finding techniques and procedures that enable rapid and large-scale interventions, especially in cases of biodeterioration. The volume of material to be preserved and often the inadequacy of the storage conditions constitute crucial factors that promote microbial growth on substrates such as paper, leather, and parchment. These materials serve as primary sources of sustenance for fungi and bacteria which can infect the collections, and so it is frequently necessary to adopt chemical mass-disinfection treatments. These treatments are often expensive, polluting, and hazardous to the assets, the operators, and the environment. The use of ionizing radiation can provide an environmentally sustainable alternative to the traditional mass disinfection treatments of library and archive materials, which currently involve chemical agents (such as ethylene oxide) that impact the environment and human health. The use of such chemicals is increasingly subject to stringent restrictions. In this work, we report and discuss the advantages and disadvantages of physical disinfection methods, focusing on the use of radiation for disinfection treatments and their effects. Full article
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