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Toxics
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Carbon-Based Materials for Pollutant Immobilization and Removal in Soil and...
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Carbon-Based Materials for Pollutant Immobilization and Removal in Soil and Water

A special issue of Toxics (ISSN 2305-6304). This special issue belongs to the section "Toxicity Reduction and Environmental Remediation".

Deadline for manuscript submissions: 30 December 2024 | Viewed by 941

Special Issue Editor

Prof. Dr. Jianxin Fan

E-Mail Website
Guest Editor
Department of Environmental Science and Engineering, School of River and Ocean Engineering, Chongqing Jiaotong University, Chongqing 400074, China
Interests: distribution of microplastic in environment; migration of microplastics; environmental behavior of heavy metals
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Many hazardous chemicals, which are persistent, bioaccumulative, carcinogenic, and mutagenic and have reproductive toxicity, can enter the soil and water environment and pose potential environmental and health risks.

The immobilization and removal of pollutants in soil and water play very important roles in pollution treatment. The processes that control the fate and distribution of heavy metals and organic pollutants in the environment, include several fundamental physical, chemical, and biological processes. The immobilization and removal of the pollutants means preventing them from entering the biological chain. Thus, the immobilization and removal of toxic pollutants from soil and water environments has been the focus of research.

Carbon-based materials, including activated carbon, graphene, carbon nanotubes, carbon nanofibers, biochar, and carbon aerogels, were widely studied for pollutant immobilization and removal in soil and water due to their good adsorption properties. However, sustainable and carbon-neutral materials are still needed to investigate the immobilization and removal of toxic pollutants in soil and water.

Therefore, in this Special Issue, titled “Carbon-Based Materials for Pollutant Immobilization and Removal in Soil and Water”, we will accept excellent research that addresses one or more of the following topics: carbon-based materials, emerging pollutants, heavy metals, immobilization, and removal.

Prof. Dr. Jianxin Fan
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Toxics is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • carbon-based materials
  • emerging pollutants
  • heavy metals
  • immobilization
  • removal

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Published Papers (1 paper)

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Research

21 pages, 10722 KiB  
Article
The Mechanism of Arsenic Release in Contaminated Paddy Soil with Added Biochar: The Role of Dissolved Organic Matter, Fe, and Bacteria
by Jianxin Fan, Maoyu Liao, Ting Duan, Ying Hu and Jiaoxia Sun
Toxics 2024, 12(9), 661; https://doi.org/10.3390/toxics12090661 - 10 Sep 2024
Viewed by 733
Abstract
The addition of biochar inevitably modifies the acidity (pH), redox potential (Eh), and dissolved organic matter (DOM) level in the soil. These alterations also have coupled effects on the cycling of iron (Fe) and the composition of bacterial communities, thereby impacting the speciation [...] Read more.
The addition of biochar inevitably modifies the acidity (pH), redox potential (Eh), and dissolved organic matter (DOM) level in the soil. These alterations also have coupled effects on the cycling of iron (Fe) and the composition of bacterial communities, thereby impacting the speciation and availability of arsenic (As) in the soil. This study explored the potential mechanisms through which biochar affects As in paddy soil during flooded cultivation with different pyrolysis temperature biochars (300 °C, 400 °C, and 500 °C) added. The results revealed that the TAs concentration increased in the initial 15 days of soil cultivation with SBC300 or SBC400 addition because increasing the concentration of DOM induced the mobility of As though the formation of As-DOM complexes. Meanwhile, biochar addition elevated the pH, decreased the Eh, and promoted the transformation of specific adsorbed As (A-As) and amorphous iron oxide-bound As (Amo-Fe-As) to supernatant As through enhancing the reductive dissolution of Fe(oxy)(hydr)oxides. Moreover, the biochar altered the relative abundance of As (V)-reducing bacteria (such as Firmicutes) and As (III)-oxidizing bacteria (such as Chloroflex), thereby affecting As speciation. However, these mechanistic effects varied depending on the pyrolysis temperature of the biochar. The microbial composition of SBC300 and SBC400 were similar, with both containing larger populations of Enterobacteriaceae (AsRB) and pseudomonas (FeRB) compared to CK and SBC500. It was proposed that lower pyrolysis temperatures (300 °C and 400 °C) are more favorable for the dissolution of Fe(oxy)(hydr)oxides and the reduction of As (V). However, the biochar from the higher pyrolysis temperature (500 °C) showed environmental impacts akin to the control group (CK). This study demonstrated potential mechanisms of biochar’s effect on As and the role of pyrolysis temperature. Full article
(This article belongs to the Special Issue Carbon-Based Materials for Pollutant Immobilization and Removal in Soil and Water)
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