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Geochemistry of Groundwater Used in Balneotherapy and Spa Treatments

A special issue of Water (ISSN 2073-4441). This special issue belongs to the section "Water and One Health".

Deadline for manuscript submissions: closed (30 September 2022) | Viewed by 2872

Special Issue Editors


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Guest Editor
Faculty of Geoengineering, Mining and Geology, Wrocław University of Science and Technology, Wybrzeże S. Wyspiańskiego 27, 50-370 Wrocław, Poland
Interests: groundwater, isotopes; radioactivity; geology; geochemistry; mineralogy; petrology; hydrogeology; meteorites; cosmochemistry
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Guest Editor
University of Warsaw, Faculty of Geology, Department of Applied Hydrogeology and Geophysics, Warsaw, Poland
Interests: groundwater geochemistry, geochemical modelling, isotopes, hydrogeology, therapeutic water, mineral water, water quality
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

For a long time, groundwater has been used not only for drinking, personal hygiene and entertainment, but also in therapeutic treatments. Initially, its use in therapeutic treatments was connected with the use of waters from natural springs, especially thermal waters or waters with specific chemical or gaseous compositions, which were often believed to have “miraculous” properties. Subsequent studies have led to the discovery of the presence of components which are beneficial to human health in these waters, and these helped to explain numerous mechanisms of their activity. Following scientific and technological developments, groundwater used in therapy started to be obtained not only from natural springs, but also from deeper water intakes (dug wells), and, from the late 19th century on, also from boreholes. Nowadays, drilling methods are widely employed to exploit thermal waters and waters which are higher in total dissolved solids (mineral waters or saline waters), often from depths of up to several kilometers. Today, therapeutic treatments in thermal stations (health resorts) using groundwater draw on about 200 years of thermal medicine (balneology) experience, and recently also increasingly on the findings of clinical trials. To increase the understanding of the therapeutic activity of groundwater, there is a growing need for more comprehensive studies of the physico-chemical properties of groundwaters, including their gaseous composition, the presence of trace and ultra-trace elements, and the forms of the occurrence (speciation) of chemical elements in them. For this reason, we would like to dedicate this Special Issue of our journal Water to the broad subject of the geochemistry of groundwater used in therapeutic treatments, i.e., therapeutic (medicinal) water. We wish to include articles on a wide range of topics related to such waters. Our scope of interest comprises not only the origin of these waters, the development of their chemical and isotopic compositions, the mixing processes of different types of waters, and water–reservoir rock interactions, but also the physical and chemical processes providing these waters with features significant in terms of the effectiveness of therapeutic treatments. We also want to dedicate this Special Issue to the modern methods and techniques of analysing such waters. The Issue also offers some space for papers characterizing the hydrogeological structures containing therapeutic waters, and for studies of geochemical methods which are useful for prospecting new therapeutic groundwater resources. We also intend to provide foundations for up-to-date knowledge, based on modern research methods, on groundwater being the key resource for thermal medicine, and for the thriving usage of these waters in recreational and medical spas. We want to provide reliable information reflecting the current state of knowledge of the geochemistry of waters used in modern balneotherapy.

Dr. Tadeusz A. Przylibski
Dr. Dariusz Dobrzyński
Guest Editors

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Keywords

  • groundwater
  • hydrogeochemistry
  • mineral water
  • thermal water
  • therapeutic water
  • radon water
  • CO2-rich water
  • saline water
  • brine
  • thermal station
  • spa

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Published Papers (1 paper)

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Research

14 pages, 1078 KiB  
Article
Perspectives for Quality Evaluation of Some Mineral Waters from Slanic Moldova
by Lavinia Misaila, Narcis Barsan, Florin Marian Nedeff, Dumitra Raducanu, Cristian Radu, Luminita Grosu, Oana-Irina Patriciu, Lucian Gavrila and Adriana-Luminita Finaru
Water 2022, 14(19), 2942; https://doi.org/10.3390/w14192942 - 20 Sep 2022
Cited by 4 | Viewed by 2181
Abstract
In the present study, using a combination of several analytical techniques such as conductometry/total dissolved solids (TDS), pH-metry, ICP-MS and UV-Vis spectrometry, 38 parameters (Na, K, Mg, Ca, Al, Fe, B, Li, Cr, Mn, Ni, Cu, Zn, Se, Sr, Ag, Cd, Ba, Pb, [...] Read more.
In the present study, using a combination of several analytical techniques such as conductometry/total dissolved solids (TDS), pH-metry, ICP-MS and UV-Vis spectrometry, 38 parameters (Na, K, Mg, Ca, Al, Fe, B, Li, Cr, Mn, Ni, Cu, Zn, Se, Sr, Ag, Cd, Ba, Pb, Be, V, Co, Ga, As, Rb, Cs, Hg, Tl, U, F, Cl, SO42, NO3, NO2, HCO3, CO2, electric conductivity (EC)/TDS and pH) for seven natural mineral waters (springs 1 bis, 5, 10, 14, 15, Sonda 2 and Sfantul Spiridon) from the Slanic Moldova area (Romania) were evaluated. Our data were compared with the historical chemical analyses records and also with the limits established by international and Romanian regulations for qualitative evaluation of natural mineral waters. In the case of the Evolution of the mineralization degree over time, it was observed that, in the interval 1933–2021, for all the studied sources, there were variations of mineralization that could be attributed to climatic and geological changes, mode of exploitation, as well as to analysis techniques used. Although decreases in mineralization were observed between 1981 and 2006 for water sources 1 bis, 10, 15 and S2, with a slight recovery and stability period between 2006 and 2021, they have retained their characteristics over time. Moreover, spring 14 retains its status as the most mineralized spring of the seven, although it also recorded a decrease in the mineralization degree between 2013 and 2018. Even if the concentration of major and minor ions showed some variation, highlighting the diversity of the water intakes and its changes over time for some of the springs, it is noticeable that these springs have kept their characteristics over time. It was identified that Sodium (Na+) was present in all natural mineral waters but predominated in sodium chloride, sodium bicarbonate and sodium sulfate. The concentration of potassium ion has shown a fairly significant fluctuation, in 2006 being registered the lowest values for most sources: 1 bis (88.00 mg/L), 5 (6.00 mg/L), 10 (81.00 mg/L), 14 (115.00 mg/L), 15 (45.20 mg/L), S2 (11.00 mg/L). By means of ICP-MS, trace elements that have never before been tested or reported were identified, thus completing the chemical fingerprint of these natural mineral waters to increase their value for routine or therapeutic uses or further sustainable exploitation. Full article
(This article belongs to the Special Issue Geochemistry of Groundwater Used in Balneotherapy and Spa Treatments)
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