Gas insulated switchgear (GIS) plays an important role in the transmission and distribution of electric energy. Detecting and analyzing the decomposed components of SF
6 is one of the important methods to realize the on-line monitoring of GIS equipment. In this paper, considering
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Gas insulated switchgear (GIS) plays an important role in the transmission and distribution of electric energy. Detecting and analyzing the decomposed components of SF
6 is one of the important methods to realize the on-line monitoring of GIS equipment. In this paper, considering the performance limits of intrinsic TiO
2 nanotube gas sensor, the adsorption process of H
2S, SO
2, SOF
2 and SO
2F
2 on fluoride-doped TiO
2 crystal plane was simulated by the first-principle method. The adsorption mechanism of these SF
6 decomposition components on fluorine-doped TiO
2 crystal plane was analyzed from a micro perspective. Calculation results indicate that the order of adsorption effect of four SF
6 decomposition components on fluoride-doped TiO
2 crystal plane is H
2S > SO
2 > SOF
2 > SO
2F
2. Compared with the adsorption results of intrinsic anatase TiO
2 (101) perfect crystal plane, fluorine doping can obviously enhance the adsorption ability of TiO
2 (101) crystal plane. Fluorine-doped TiO
2 can effectively distinguish and detect the SF
6 decomposition components based on theoretical analysis.
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