Slow pyrolysis was carried out in biosolids under three different temperatures (400, 500 and 600 °C) and two different carrier gases (CO
2 and N
2) on a fluidized bed reactor. The total concentration, chemical fractionation, and plant availability of the heavy
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Slow pyrolysis was carried out in biosolids under three different temperatures (400, 500 and 600 °C) and two different carrier gases (CO
2 and N
2) on a fluidized bed reactor. The total concentration, chemical fractionation, and plant availability of the heavy metals in biochar were assessed by standard methods. The total concentration of Fe, Zn, Cu, Mn, Cr, Ni and Pb increased with the conversion of biosolids to biochar and with increasing pyrolysis temperature. The community’s Bureau of Reference (BCR) sequential extraction identified the migration of metals from toxic and bioavailable to potentially stable available or non-available forms at higher pyrolysis temperatures. Diethylenetriamine penta-acetic acid (DTPA)-extractable metals (Cu, Zn, Cd, Cu, Fe and Pb) were significantly lower in biochar compared to biosolids. By replacing N
2 with CO
2, the total metal concentration of heavy metals was significantly different for Mn, Ni, Cd, Pb and As. There were larger amounts of metals in the residual and oxidizable fractions compared to when N
2 was used as a carrier gas. Consequently, the biochar produced at higher temperatures (500 and 600 °C) in the N
2 environment exhibited lower potential ecological risks than in CO
2 environments (69.94 and 52.16, respectively, compared to values from 75.95 to 151.38 for biochars prepared in N
2). Overall, the results suggest that the higher temperature biochar can support obtaining environmentally safe biochar and can be effective in attenuating the ecological risks of biosolids.
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