Shannon entropy in position (
) and momentum (
) spaces, along with their sum (
) are presented for unit-normalized densities of He, Li
and Be
ions, spatially confined at the center of
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Shannon entropy in position (
) and momentum (
) spaces, along with their sum (
) are presented for unit-normalized densities of He, Li
and Be
ions, spatially confined at the center of an impenetrable spherical enclosure defined by a radius
. Both ground, as well as some selected low-lying singly excited states, viz., 1sns (n = 2–4)
3S, 1snp (n = 2–3)
3P, 1s3d
3D, are considered within a density functional methodology that makes use of a work function-based exchange potential along with two correlation potentials (local Wigner-type parametrized functional, as well as the more involved non-linear gradient- and Laplacian-dependent Lee-Yang-Parr functional). The radial Kohn-Sham (KS) equation is solved using an optimal spatial discretization scheme via the generalized pseudospectral (GPS) method. A detailed systematic analysis of the confined system (relative to the corresponding free system) is performed for these quantities with respect to
in tabular and graphical forms, with and without electron correlation. Due to compression, the pattern of entropy in the aforementioned states becomes characterized by various crossovers at intermediate and lower
regions. The impact of electron correlation is more pronounced in the weaker confinement limit and appears to decay with the rise in confinement strength. The exchange-only results are quite good to provide a decent qualitative discussion. The lower bounds provided by the entropic uncertainty relation hold well in all cases. Several other new interesting features are observed.
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