Topical Advisory Panel Members' Collection Series: Catalytic Materials for the Production of Renewable Fuels

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Catalytic Materials".

Deadline for manuscript submissions: closed (31 May 2024) | Viewed by 2092

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Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz University of Technology, ul. Zeromskiego 116, 90-924 Lodz, Poland
Interests: catalysis, synthesis and characterization of heterogeneous catalysts; biomass conversion; surface characterization of solids; environmental protection; nanotechnology
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Special Issue Information

Dear Colleagues,

The development of effective methods for the production of renewable fuels is one of the crucial industrial challenges. It is known that the application of catalysts to this process and the use of alternative types of feedstock may contribute to improvements in the sustainability of energy production. This in turn leads to an increase in the competitiveness of renewable fuels in the energy market.

This Special Issue is devoted to the development of catalytic materials for the production of renewable fuels. It is concerned with, but not limited to, the design of new catalysts and their synthesis methods, the optimization of catalyst composition and pretreatment conditions, studies on the effect of catalyst modification, the choice of reaction conditions, research on the reaction mechanism, and the determination of the influence of feedstock or the presence of impurities. Moreover, papers that address these issues from other perspectives but are still within the broad range of research applications of the main topic fields are also encouraged.

Dr. Jacek Grams
Guest Editor

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Keywords

  • catalyst
  • catalytic activity
  • synthesis
  • characterization
  • renewable fuel
  • sustainable processes

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Published Papers (2 papers)

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Research

19 pages, 4084 KiB  
Article
Pt/Nb2O5-Al2O3 Catalysts for the Hydrogenation and Reductive Amination of Furfural
by Maria H. Brijaldo, Hugo A. Rojas, Yutao Xing, Fabio B. Passos and José J. Martínez
Catalysts 2024, 14(8), 493; https://doi.org/10.3390/catal14080493 - 31 Jul 2024
Viewed by 833
Abstract
Furfural is a well-recognized biomass platform. Hydrogenation and reductive amination of furfural are two principal routes in the valorization of this compound. In both reactions, the presence of reducible species (SMSI effect) and acid sites could favor the selectivity toward some interesting products. [...] Read more.
Furfural is a well-recognized biomass platform. Hydrogenation and reductive amination of furfural are two principal routes in the valorization of this compound. In both reactions, the presence of reducible species (SMSI effect) and acid sites could favor the selectivity toward some interesting products. Both conditions could be obtained using metal particles supported on reducible mixed oxides. In this work, we investigate the use of Pt/Nb2O5-Al2O3 catalysts for the hydrogenation and reductive amination of furfural at distinct Nb2O5 contents. A decaniobate salt was used as a precursor of Nb2O5. The solids were reduced at 500 °C to assure the migration of reducible NbOx species. The solids were characterized by XRD, Raman spectroscopy, HR-TEM, N2-physisorption, NH3-TPD and Pyr-DRIFTS. The results showed that higher Nb2O5 loadings led to a lower distribution of Al2O3 and Pt, favoring the catalysts’ acidity. This fact implies that large particle size and the presence of Nb2O5 islands favor the formation of furfuryl alcohol but have a detrimental effect on the amine formation in the reductive amination of furfural. Full article
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16 pages, 4034 KiB  
Article
Exploring the Effect of the Solvothermal Time on the Structural Properties and Catalytic Activity of Cu-ZnO-ZrO2 Catalysts Synthesized by the Solvothermal Method for CO2 Hydrogenation to Methanol
by Jian Han, Yannan Liang, Jun Yu, Guisheng Wu and Dongsen Mao
Catalysts 2024, 14(6), 390; https://doi.org/10.3390/catal14060390 - 18 Jun 2024
Viewed by 880
Abstract
A series of Cu-ZnO-ZrO2 (CCZ) catalysts were prepared by the solvothermal method with different solvothermal times (1 h, 3 h, 6 h, and 12 h). The physicochemical properties of these catalysts and the catalytic performance for CO2 hydrogenation to methanol were [...] Read more.
A series of Cu-ZnO-ZrO2 (CCZ) catalysts were prepared by the solvothermal method with different solvothermal times (1 h, 3 h, 6 h, and 12 h). The physicochemical properties of these catalysts and the catalytic performance for CO2 hydrogenation to methanol were studied. The highest methanol yield was achieved when the solvothermal time was 6 h (CCZ-6). Furthermore, we found that the copper surface area (SCu) increases and then decreases with an increase in the solvothermal time and that there is a strong correlation between the methanol yield and the SCu. This research highlights the crucial influence of the solvothermal time on the structure and catalytic behavior of Cu-ZnO-ZrO2 catalysts, providing a valuable reference for the development of efficient catalysts. Full article
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