State-of-the-Art Membrane Science and Technology in North America (2023,2024)

A special issue of Membranes (ISSN 2077-0375).

Deadline for manuscript submissions: 30 November 2024 | Viewed by 12955

Special Issue Editors


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Guest Editor
Department of Chemical and Materials Engineering, University of Kentucky, Lexington, KY 40506-0046, USA
Interests: biotechnology; interfacial science; multiscale modeling; nanotechnology; reaction engineering; renewable energy; separations and membranes

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Guest Editor
Mork Family Department of Chemical Engineering & Materials Science, University of Southern California, Los Angeles, CA 90089, USA
Interests: reactor design; reaction engineering; separations; environmental remediation
Special Issues, Collections and Topics in MDPI journals

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Guest Editor
Department of Food Sciences, Institute of Nutrition and Functional Foods (INAF), Dairy Research Center (STELA) & Laboratory of Food Processing and Electro Membrane Processes (LTAPEM), Université Laval, Québec, QC G1V 0A6, Canada
Interests: membrane processes; electrodialytic phenomena; membrane characterization and predictive model; separation; bio-food compounds; plant proteins; bioactive peptides; dairy products; health benefits; eco-efficiency; food production lines; valorization of co-products; circular economy
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,  

Membrane science and technology is a broad and highly interdisciplinary field, where materials science and engineering, chemistry, chemical engineering, process engineering, separation technologies, environmental science, sustainability, and molecular simulation converge to produce membranes that have a wide range of applications. North America is the leading region for this field across the world in terms of market shares, scholarly outcomes, globally active researchers and entrepreneurs, and membrane manufacturing and water treatment companies and startups. For years, the synergy of high-impact research and development by accomplished and inspiring researchers from academia and industry, exceptional infrastructure and expertise in membrane fabrication and characterization and nanoscale materials and strong membrane associations, such as the North American Membrane Society (https://membranes.org) and American Membrane Technology Association (https://www.amtaorg.com), have served as a platform on which the transition of research results to the market has been facilitated. However, the development of energy and cost-efficient membrane materials and processes, with sustainable high product recovery and quality, has always been a challenging endeavor and kept the membrane community creative and vibrant. Despite many successful and continuing efforts to develop high-performance and innovative membranes and membrane-based hybrid processes, there is still a great deal of work to do. 

This Special Issue is devoted to providing an overview of the recent advancements in membrane science and technology in North America. Original research works, review articles, and state-of-the-art communications are welcome. Research topics include, but are not limited to, the following:

- Novel membrane materials

  • Composite and nanocomposite membranes;
  • Active/reactive membranes;
  • Stimuli-responsive membranes ;
  • Protein-based membranes;
  • Electrospun nanofibrous membranes;
  • Affinity membranes  ;
  • Inorganic membranes;
  • Hollow fiber membranes;
  • Thermomechanical and chemical stable membranes;
  • Three-dimensional-printed membranes;
  • New synthesis routes of porous and dense membranes;
  • Prospective of carbon-based nanomaterials (e.g., graphene, CNT and CNF) in membrane fabrication; 
  • Prospective of metal–organic frameworks (MOFs) in membrane fabrication ; 
  • Prospective of zeolites and other minerals in membrane fabrication;
  • Prospective of agricultural materials (e.g., lignin and nanocrystalline cellulose) for membrane fabrication.     

- Membrane processes

  • New membrane processes for water treatment , gas and bioactive molecule separation;
  • Membrane-based integrated processes;
  • Thermally driven membrane processes (e.g., membrane distillation);
  • Osmotically driven membrane processes (e.g., forward osmosis);
  • Pressure-driven membrane processes for water treatment (e.g., MF, UF, NF and RO) ; 
  • Electrically driven membrane processes (e.g., electrodialysis);
  • Membrane contactors;
  • Membrane bioreactors;
  • Organic solvent nanofiltration;
  • New membrane module designs;  
  • Water–energy nexus in membrane processes;
  • Energy management and technoeconomic analysis of membrane processes;
  •  Artificial intelligence and data analysis in membrane technology.  

- Transport phenomena

  • Mathematical modeling of membrane processes;
  • Transport phenomena through porous and dense membranes;
  • CFD simulation;
  • Concentration and temperature polarization effects.  

- Fouling mitigation and membrane cleaning

  • Innovative methods to mitigate membrane fouling, e.g., ultrasound;
  • Novel membrane cleaning methods;
  • Water pretreatment methods for fouling mitigation.

- Characterization methods

  • Advanced membrane characterization techniques;
  • Microfluidic membrane mimics for fouling study at the pore scale;
  • Novel microscopy methods for membrane and fouling characterization;
  • Fouling study by surface energetics analysis methods, e.g., DLVO; 
  • Quartz crystal microbalance method for fouling study;
  • New methods to measure diffusivity and solubility of gases in membranes, e.g., new time-lag methods. 

- Membrane surface modification methods

  • Chemical grafting;
  • Surface coating;
  • Layer-by-layer assembly;
  • Surface patterning.

- Application of membrane technology 

  • Prospective of membranes in the oil and gas industry;
  • Prospective of membranes in the food industry;
  • Prospective of membranes in agricultural wastewater treatment;
  • Prospective of membranes in the textile industry;  
  • Medical applications of membranes;
  • Removal of volatile organic materials by pervaporation;
  • Membrane processes in biotechnology.  

Membrane applications in a circular economy.

Prof. Dr. Stephen E. Rankin
Prof. Dr. Theodore T. Tsotsis
Prof. Dr. Laurent Bazinet
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Membranes is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2200 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

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Published Papers (4 papers)

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Research

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26 pages, 9145 KiB  
Article
Xe Recovery from Nuclear Power Plants Off-Gas Streams: Molecular Simulations of Gas Permeation through DD3R Zeolite Membrane
by Bandar J. Bashmmakh, Xiaoyu Wang, Cynthia J. Jameson and Sohail Murad
Membranes 2023, 13(9), 768; https://doi.org/10.3390/membranes13090768 - 30 Aug 2023
Cited by 1 | Viewed by 1567
Abstract
Recent experimental work has shown zeolite membrane-based separation as a promising potential technology for Kr/Xe gas mixtures due to its much lower energy requirements in comparison to cryogenic distillation, the conventional separation method for such mixtures. Such a separation is also economically rewarding [...] Read more.
Recent experimental work has shown zeolite membrane-based separation as a promising potential technology for Kr/Xe gas mixtures due to its much lower energy requirements in comparison to cryogenic distillation, the conventional separation method for such mixtures. Such a separation is also economically rewarding because Xe is in high demand, as a valuable product for many applications/processes. In this work, we have used Molecular Dynamics (MD) simulations to study the effects of different conditions, i.e., temperature, pressure, and gas feed composition, on Kr/Xe separation performance via DD3R zeolite membranes. We provide a comprehensive study of the permeation of the different gas species, density profiles, and diffusion coefficients. Molecular simulations show that if the feed is changed from pure Kr/Xe to an equimolar mixture, the Kr/Xe separation factor increases, which agrees with experiments. In addition, when Ar is introduced as a sweep gas, the adsorption of both Kr and Xe increases, while the permeation of pure Kr increases. A similar behavior is observed with equimolar mixtures of Kr/Xe with Ar as the sweep gas. High-separation Kr/Xe selectivity is observed at 50 atm and 425 K but with low total permeation rates. Changing pressure and temperature are found to have profound effects on optimizing the separation selectivity and the permeation throughput. Full article
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18 pages, 4436 KiB  
Article
Effect of Heat Treatment on Yellow Field Pea (Pisum sativum) Protein Concentrate Coupled with Membrane Ultrafiltration on Emulsification Properties of the Isolated >50 kDa Proteins
by Nancy D. Asen and Rotimi E. Aluko
Membranes 2023, 13(9), 767; https://doi.org/10.3390/membranes13090767 - 30 Aug 2023
Cited by 3 | Viewed by 1361
Abstract
The aim of this paper was to determine the emulsification properties of protein aggregates obtained from heat pretreated yellow field pea protein concentrate (PPC). PPC dispersions were prepared in distilled water (adjusted to pH 3.0, 5.0, 7.0, or 9.0), heated in a water [...] Read more.
The aim of this paper was to determine the emulsification properties of protein aggregates obtained from heat pretreated yellow field pea protein concentrate (PPC). PPC dispersions were prepared in distilled water (adjusted to pH 3.0, 5.0, 7.0, or 9.0), heated in a water bath (100 °C) for 30 min, centrifuged and the supernatant passed first through a 30 kDa membrane and, then, the first retentate (>30 kDa) through a 50 kDa membrane. The 50 kDa membrane separation yielded a second retentate (>50 kDa proteins), which was isolated for emulsification studies. The near UV circular dichroic spectra of the protein samples showed more unfolded structures at pH 3.0 and 5.0 than at pH 7.0 and 9.0. The presence of small and spherical oil droplets of emulsions stabilized by the >50 kDa proteins at pH 3.0, 7.0, and 9.0 was confirmed by confocal laser scanning microscopy images. Emulsions stabilized at pH 7.0 and 9.0 had a narrower size distribution range than at pH 3.0 and 5.0. A narrow oil droplet size distribution range and lower interfacial protein concentrations of the emulsions stabilized by the >50 kDa proteins were observed at the corresponding pH of the heat treatment when compared to other pH values. Emulsions stabilized by the >50 kDa proteins exhibited a relatively low flocculation and coalescence index, which infers relative stability. The results from this work suggest that heat pretreatment of the PPC led to the formation of new protein aggregates, especially FT9 with enhanced emulsification properties, at some of the test conditions when compared to the unheated PPC. Full article
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12 pages, 2487 KiB  
Article
Simple Bioparticle Filtration Device Based on an Ultralow-Fouling Zwitterionic Polyurethane Membrane for Rapid Large-Volume Separation of Plasma and Viruses from Whole Blood
by Kun Wang, Hyang Seol, Alex Cheng, Nash McKeague, Megan Carlson, Wade Degraff, Sijia Huang and Sangil Kim
Membranes 2023, 13(5), 524; https://doi.org/10.3390/membranes13050524 - 17 May 2023
Cited by 1 | Viewed by 2201
Abstract
Plasma separation from whole blood is oftent required as an essential first step when performing blood tests with a viral assay. However, developing a point-of-care plasma extraction device with a large output and high virus recovery remains a significant obstacle to the success [...] Read more.
Plasma separation from whole blood is oftent required as an essential first step when performing blood tests with a viral assay. However, developing a point-of-care plasma extraction device with a large output and high virus recovery remains a significant obstacle to the success of on-site viral load tests. Here, we report a portable, easy-to-use, cost-efficient, membrane-filtration-based plasma separation device that enables rapid large-volume plasma extraction from whole blood, designed for point-of-care virus assays. The plasma separation is realized by a low-fouling zwitterionic polyurethane-modified cellulose acetate (PCBU-CA) membrane. The zwitterionic coating on the cellulose acetate membrane can decrease surface protein adsorption by 60% and increase plasma permeation by 46% compared with a pristine membrane. The PCBU-CA membrane, with its ultralow-fouling properties, enables rapid plasma separation. The device can yield a total of 1.33 mL plasma from 10 mL whole blood in 10 min. The extracted plasma is cell-free and exhibits a low hemoglobin level. In addition, our device demonstrated a 57.8% T7 phage recovery in the separated plasma. The results of real-time polymerase chain reaction analysis confirmed that the nucleic acid amplification curve of the plasma extracted by our device is comparable to that obtained by centrifugation. With its high plasma yield and good phage recovery, our plasma separation device provides an excellent replacement for traditional plasma separation protocols for point-of-care virus assays and a broad spectrum of clinical tests. Full article
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Review

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23 pages, 3044 KiB  
Review
Gas Separation Membrane Module Modeling: A Comprehensive Review
by Marcos Da Conceicao, Leo Nemetz, Joanna Rivero, Katherine Hornbostel and Glenn Lipscomb
Membranes 2023, 13(7), 639; https://doi.org/10.3390/membranes13070639 - 30 Jun 2023
Cited by 15 | Viewed by 6755
Abstract
Membrane gas separation processes have been developed for diverse gas separation applications that include nitrogen production from air and CO2 capture from point sources. Membrane process design requires the development of stable and robust mathematical models that can accurately quantify the performance [...] Read more.
Membrane gas separation processes have been developed for diverse gas separation applications that include nitrogen production from air and CO2 capture from point sources. Membrane process design requires the development of stable and robust mathematical models that can accurately quantify the performance of the membrane modules used in the process. The literature related to modeling membrane gas separation modules and model use in membrane gas separation process simulators is reviewed in this paper. A membrane-module-modeling checklist is proposed to guide modeling efforts for the research and development of new gas separation membranes. Full article
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