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4 pages, 169 KiB

Open AccessEditorial

Editorial for Special Issue “Tectonic–Magmatic Evolution and Mineralization Effect in the Southern Central Asian Orogenic Belt”

by Jiafu Chen, Nan Ju and Zhonghai Zhao

Minerals 2024, 14(10), 994; https://doi.org/10.3390/min14100994 - 30 Sep 2024

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Abstract

The Central Asian Orogenic Belt (CAOB), one of the world’s largest orogens, extending from the Ural Mountains in the west to the Russian and the Chinese Far East, is the result of long-lived multi-stage tectonic evolution, including Proterozoic to Paleozoic accretion and collision, [...] Read more.

The Central Asian Orogenic Belt (CAOB), one of the world’s largest orogens, extending from the Ural Mountains in the west to the Russian and the Chinese Far East, is the result of long-lived multi-stage tectonic evolution, including Proterozoic to Paleozoic accretion and collision, Mesozoic intracontinental modification, and Cenozoic rapid deformation and uplift [...] Full article

(This article belongs to the Special Issue Tectonic–Magmatic Evolution and Mineralization Effect in the Southern Central Asian Orogenic Belt)

Research

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30 pages, 5946 KiB

Open AccessArticle

Geochronology, Geochemical Characterization and Tectonic Background of Volcanic Rocks of the Longjiang Formation in the Lengjimanda Plate Area, Middle Da Hinggan Mountains

by Shi-Chang Wang, Yu-Jie Hao, Lu Shi, Zhen Tang and Shuang Zhu

Minerals 2024, 14(7), 719; https://doi.org/10.3390/min14070719 - 16 Jul 2024

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Abstract

The Lengjimanda plate is situated in the middle section of the Da Hinggan mountains, in the eastern section of the Tianshan Xingmeng orogenic belt. To determine the formation age of the volcanic rocks in the Longjiang formation in this area, to explore their [...] Read more.

The Lengjimanda plate is situated in the middle section of the Da Hinggan mountains, in the eastern section of the Tianshan Xingmeng orogenic belt. To determine the formation age of the volcanic rocks in the Longjiang formation in this area, to explore their origin and tectonic background, and to reconstruct the geodynamic evolution of the region, this study conducted petrological, zircon U–Pb geochronological, geochemical, and isotopic analyses of the volcanic rocks in the Longjiang formation. The Longjiang formation’s volcanic rocks are primarily composed of trachyandesite, trachyte trachydacite, and andesite, which are intermediate basic volcanic rocks. They are enriched in large-ion lithophile elements, are depleted in high-field-strength elements, are significantly fractionated between light and heavy rare earth elements, and exhibit a moderate negative Eu anomaly in most samples. The results of the LA–ICP–MS zircon U–Pb dating indicate that the volcanic rocks in this group were formed in the Early Cretaceous period at 129.1 ± 0.82 Ma. The zircon ε_Hf(t) ranges from +1.13 to +43.77, the t_DM2 ranges from +655 to +1427 Ma, the initial Sr ratio (⁸⁷Sr/⁸⁶Sr)_i ranges from 0.7030 to 0.7036, and the ε_Nd(t) ranges from +2.1 to +6.6. Based on the geochemical compositions and isotopic characteristics of the rocks, the initial magma of the volcanic rocks in the Longjiang formation originated from the partial melting of basaltic crustal materials, with a source material inferred to be depleted mantle-derived young crustal. These rocks were formed in a superimposed post-collisional and continental arc environment, possibly associated with the Mongol-Okhotsk Ocean closure and the oblique subduction of the Pacific plate. This study addresses a research gap regarding the volcanic rocks of the Longjiang formation in this area. Its findings can be applied to exploration and prospecting in the region. Full article

(This article belongs to the Special Issue Tectonic–Magmatic Evolution and Mineralization Effect in the Southern Central Asian Orogenic Belt)

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27 pages, 5945 KiB

Open AccessArticle

Middle Silurian–Middle Devonian Magmatic Rocks in the Eastern Segment of the Northern Margin of the North China Craton: Implications for Regional Tectonics

by Bin Li, Jingsheng Chen, Fan Yang, Miao Liu, Yanqing Zang and Chao Zhang

Minerals 2024, 14(7), 641; https://doi.org/10.3390/min14070641 - 23 Jun 2024

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Abstract

This paper presents a detailed study including LA-ICP-MS zircon U-Pb dating, geochemical, zircon Hf isotope, and whole rock Sr-Nd isotope analysis of magmatic rocks from the Yitong County, Jilin Province, NE China. These data are used to better constrain the Middle Silurian–Middle Devonian [...] Read more.

This paper presents a detailed study including LA-ICP-MS zircon U-Pb dating, geochemical, zircon Hf isotope, and whole rock Sr-Nd isotope analysis of magmatic rocks from the Yitong County, Jilin Province, NE China. These data are used to better constrain the Middle Silurian–Middle Devonian tectonic evolution in the eastern segment of the northern margin of the North China Craton (NCC). Zircon U-Pb dating results show that the Ximangzhang tonalite formed in the Late Silurian (425 ± 6 Ma); the basalt, andesite, and metamorphic olivine-bearing basalt in the Fangniugou volcanic rocks formed in the Middle Silurian (428 ± 6.6 Ma) and Middle Devonian (388.4 ± 3.9 Ma, and 384.1 ± 4.9 Ma). The Late Silurian tonalites are characterized by high SiO₂ and Na₂O and low K₂O, MgO, FeOT, and TiO₂, with an A/CNK ratio of 0.91–1.00, characteristic of calc-alkaline I-type granite. They are enriched in Rb, Ba, Th, U, and K, and depleted in Nb, Sr, P, and Ti, with positive ε_Nd(t) (+0.35) and ε_Hf(t) (+0.44 to +6.31) values, suggesting that they mainly originated from the partial melting of Meso–Neoproterozoic accretionary lower crustal material (basalt). The Middle Silurian basalts are characterized by low SiO₂, P₂O₅, TiO₂, and Na₂O and high Al₂O₃, FeOT, and K₂O, enriched in Rb, Ba, Th, U, and K and depleted in Nb, Ta, Sr, P, and Ti, indicative of shoshonitic basalt. The Late Silurian tonalites have positive ε_Nd(t) (+4.91 to +6.18) values and primarily originated from depleted mantle magmas metasomatized by subduction fluids, supplemented by a small amount of subducted sediments and crustal materials. The Middle Devonian volcanic rocks exhibit low SiO₂, TiO₂, and Na₂O and high K₂O, and MgO, enriched in Rb, K, and LREEs and depleted in Nb, Ta, Sr, and HREEs, characteristic of shoshonitic volcanic rocks. Their ε_Nd(t) (+2.11 to +3.77) and ε_Hf(t) (+5.90 to +11.73) values are positive. These characteristics indicate that the Middle Devonian volcanic rocks primarily originated from depleted mantle magmas metasomatized by subduction fluids, with the addition of crustal materials or subducted sediments during their formation. Based on regional geological data, it is believed that the study area underwent the following evolutionary stages during the Silurian–Devonian period: (1) active continental margin stage of southward subduction of the Paleo–Asian Ocean (PAO) (443–419 Ma); (2) arc-continent collision stage (419–405 Ma); (3) post-collision extension stage (404–375 Ma); (4) active continental margin stage, with the PAO plate subducting southward once again (375–360 Ma). Full article

(This article belongs to the Special Issue Tectonic–Magmatic Evolution and Mineralization Effect in the Southern Central Asian Orogenic Belt)

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21 pages, 8608 KiB

Open AccessArticle

Origin and Geological Implications of Monzogranites and Rhyolitic Porphyries in the Wunugetu Porphyry Copper–Molybdenum Deposit, Northeast China: Evidence from Zircon U-Pb-Hf Isotopes and Whole-Rock Geochemistry

by Qingshuang Wang, Yanchen Yang, Qiulin Fu, Zhongyue Zhang, Xiaodan Guo, Taotao Wu, Lu Chai, Yongheng Zhou and Yonghai An

Minerals 2024, 14(3), 310; https://doi.org/10.3390/min14030310 - 15 Mar 2024

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Abstract

The Wunugetu deposit, a large-scale porphyry copper–molybdenum deposit, is located in the southern Erguna block. Its ore bodies are primarily found within monzogranites, granite porphyries, and biotite monzogranites. Additionally, the deposit contains late-stage intrusive dykes of rhyolitic porphyries. This study examined the deposit’s [...] Read more.

The Wunugetu deposit, a large-scale porphyry copper–molybdenum deposit, is located in the southern Erguna block. Its ore bodies are primarily found within monzogranites, granite porphyries, and biotite monzogranites. Additionally, the deposit contains late-stage intrusive dykes of rhyolitic porphyries. This study examined the deposit’s monzogranites and rhyolitic porphyries using lithogeochemistry, zircon U-Pb dating, and Hf isotopic analysis. The main findings include: (1) Zircon U-Pb dating showed that the monzogranites formed around 209.0 ± 1.0 Ma, whereas the rhyolitic porphyries in the northern portion formed around 170.49 ± 0.81 Ma, suggesting magmatic activity in the deposit spanned from the Late Triassic to the Middle Jurassic. (2) The monzogranites exhibited high silicon content (73.16–80.47 wt.%) and relatively low aluminum content (10.98–14.37 wt.%). They are enriched in alkalis (content: 3.42–10.10 wt.%) and deficient in magnesium and sodium, with aluminum saturation indices (A/CNK) ranging from 1.1 to 2.9. In addition, the monzogranites are enriched in large-ion lithophile elements (LILEs) such as Rb, K, and Ba and deficient in high-field-strength elements (HFSEs) like Nb, P, and Ti. (3) The monzogranites have low Zr + Nb + Ce + Y contents of (151.3–298.6 ppm) × 10⁻⁶ and 10,000 × Ga/Al ratios varying between 1.20 and 2.33, suggesting that they are characteristic of I-type granites. (4) Positive zircon εHf(t) values ranging from +0.3 to +7.6 in both rhyolitic porphyry and monzogranite samples, increasing with younger emplacement ages, imply that the deposit’s rocks originated from magmatic mixing between mantle-derived mafic magmas and remelts of the juvenile crust. Considering these results and the regional geological evolution, this study proposes that the Wunugetu deposit was formed in an active continental margin setting and was influenced by the Late Triassic–Middle Jurassic southeastward subduction of the Mongol-Okhotsk Ocean. Full article

(This article belongs to the Special Issue Tectonic–Magmatic Evolution and Mineralization Effect in the Southern Central Asian Orogenic Belt)

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27 pages, 7762 KiB

Open AccessArticle

Genesis and Prospecting Potential of the Da’anhe Skarn Au Deposit in the Central of the Lesser Xing’an Range, NE China: Evidence from Skarn Mineralogy, Fluid Inclusions and H-O Isotopes

by Chuntao Zhao, Fanting Sun, Jinggui Sun, Jianping Wang, Jilong Han, Xiaolei Chu, Chenglin Bai, Dongmei Yu, Zhikai Xu, Lei Yi and Shan Hua

Minerals 2024, 14(3), 214; https://doi.org/10.3390/min14030214 - 20 Feb 2024

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Abstract

Skarn Au deposits exist in the circum-pacific metallogenic belt. Interestingly, the Da’anhe Au deposit is the only independent skarn gold deposit in the Lesser Xing’an Range. To determine the metallogenic mechanism and prospecting potential of the Da’anhe deposit, we performed skarn mineralogy, fluid [...] Read more.

Skarn Au deposits exist in the circum-pacific metallogenic belt. Interestingly, the Da’anhe Au deposit is the only independent skarn gold deposit in the Lesser Xing’an Range. To determine the metallogenic mechanism and prospecting potential of the Da’anhe deposit, we performed skarn mineralogy, fluid inclusion (FI) and H-O isotope analyses. The results show the following: (1) The Da’anhe deposit is a calcareous reduced skarn Au deposit that formed between an Early Jurassic gabbroic diorite and the Permian Tumenling Formation marble. Its metallogenic process includes five stages: the early skarn stage (Stage I₁), late skarn stage (Stage I₂), early quartz-sulfide stage (Stage II₁), late quartz-sulfide stage (Stage II₂) and quartz-carbonate stage (Stage II₃). Gold precipitated in Stage II₁ and Stage II₂. (2) The initial ore-forming fluid was derived from magmatic water and featured a high temperature and intermediate to high salinity. After boiling and mixing, the fluid eventually changed to a low-temperature and low-salinity reducing fluid dominated by meteoric water. (3) The formation depth of the Au orebodies was 2.27–3.11 km, and the orebodies were later lifted to the surface (<500 m). The potential for finding skarn Au deposits in the study area is limited. (4) The distinctive nature of the ore-related magma (i.e., source, reducing conditions and high water content) was key to the formation of the Da’anhe skarn gold deposit. Full article

(This article belongs to the Special Issue Tectonic–Magmatic Evolution and Mineralization Effect in the Southern Central Asian Orogenic Belt)

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23 pages, 5692 KiB

Open AccessArticle

Petrogenesis and Tectonic Evolution of Huashigou Granitoids in the South Qilian Orogen, NW China: Constraints from Geochronology, Geochemistry, and Sr–Nd–Hf–O Isotopes

by Yuxi Wang, Wanfeng Chen, Jinrong Wang, Zhilei Jia, Qingyan Tang and Pengfei Di

Minerals 2024, 14(1), 71; https://doi.org/10.3390/min14010071 - 6 Jan 2024

Cited by 3 | Viewed by 1607

Abstract

The origin of granitic rocks from the South Qilian orogenic belt is of great significance for understanding the continental tectonic framework of Western China. Currently, scholars have different opinions on the tectonic evolution of the South Qilian. Huashigou granite, which exhibits multiple intrusive [...] Read more.

The origin of granitic rocks from the South Qilian orogenic belt is of great significance for understanding the continental tectonic framework of Western China. Currently, scholars have different opinions on the tectonic evolution of the South Qilian. Huashigou granite, which exhibits multiple intrusive episodes, is a suitable example for studying the tectonic evolution of the South Qilian. New zircon U–Pb ages and the whole-rock elemental and Sr–Nd–Hf–O isotopic compositions of Huashigou granitic rocks are presented here to investigate their petrogenesis and discuss the tectonic implications for the evolution of the South Qilian orogenic belt. LA-ICP-MS zircon U–Pb dating yielded crystallization ages of 368.7 ± 3.5 Ma, 261.5 ± 0.63 Ma, and 262.2 ± 1.4 Ma for granodiorites from the Hua1 pluton, quartz diorites from the Hua2 pluton, and porphyritic tonalites from the Hua4 pluton, respectively. Late Devonian granodiorites from the Hua1 pluton belonged to the metaluminous calc-alkaline series and were characterized by an enrichment in LREEs, a depletion in HREEs, negative Eu anomalies, and Sr/Y ratios of 9.17 to 11.67. They showed (⁸⁷Sr/⁸⁶Sr)_i ratios of 0.712356 to 0.71195, ε_Nd(t) values of −6.56 to −6.14, and an ε_Hf(t) value of −2.06. Middle Permian granitic rocks mainly consisted of quartz diorites and porphyritic tonalites, which are part of the metaluminous tholeiitic series and weakly peraluminous tholeiitic series, respectively. Quartz diorites from the Hua2 pluton were characterized by an enrichment in LREEs, depletions in HREEs and HESEs, weak negative Eu anomalies, and Sr/Y ratios of 13.25 to 14.79. They showed (⁸⁷Sr/⁸⁶Sr)_i ratios of 0.705905 to 0.705971, ε_Nd(t) values of +0.78 to +0.82, and a δ¹⁸O_V-SMOW value of 12.4‰. Porphyritic tonalites of the Hua4 pluton were characterized by an enrichment in LREEs, depletions in HREEs and HESEs, weak negative Eu anomalies, and Sr/Y ratios of 9.22 to 12.74. They showed (⁸⁷Sr/⁸⁶Sr)_i ratios of 0.719528, ε_Nd(t) values of −8.57, and a δ¹⁸O_V-SMOW value of 11.8‰. We can conclude that Late Devonian granodiorites were derived from the partial melting of enriched and shallow-depth crustal materials, whereas Middle Permian granitic rocks were formed by the delamination of a thickened lower crust after the closure of the Paleo-Tethys Ocean, which caused the underplating of mantle-derived basaltic magma, inducing the partial melting of the lower crust at different depths. Our results show that there were at least two important stages of compressional and extensional tectonic switches in the South Qilian orogenic belt during the Late Paleozoic Era, and the evolution of Altyn Tagh–Qilian–North Qaidam had evident stages. Full article

(This article belongs to the Special Issue Tectonic–Magmatic Evolution and Mineralization Effect in the Southern Central Asian Orogenic Belt)

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16 pages, 9744 KiB

Open AccessArticle

Zircon U-Pb-Hf Isotopes and Whole-Rock Geochemistry of the “Kulumudi Formation” from the Laofengkou Area (West Junggar): Implications of the Construction of a Juvenile Arc in the Junggar–Balkhash Ocean

by Bo Liu, Lin-Xiao Hou, Yan Xu, Nan Ju, Jing-Xuan Ma, Zhi-Hao Xie and Yang-Bai-He Hong

Minerals 2024, 14(1), 14; https://doi.org/10.3390/min14010014 - 21 Dec 2023

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Abstract

The properties of ancient magmatic arcs are crucial for understanding the tectonic evolution of the Central Asian Orogenic Belt. The Middle Devonian Kulumudi Formation in the Laofengkou area of West Junggar lacks accurate chronological data constraints, which hampers the knowledge of the nature [...] Read more.

The properties of ancient magmatic arcs are crucial for understanding the tectonic evolution of the Central Asian Orogenic Belt. The Middle Devonian Kulumudi Formation in the Laofengkou area of West Junggar lacks accurate chronological data constraints, which hampers the knowledge of the nature of the Late Paleozoic magmatic arcs in the West Junggar and circum-Balkhash areas. In this contribution, samples of pyroclastic rocks and sedimentary rocks were collected from the volcano–sedimentary strata of the Kulumudi Formation. Petrography, zircon U-Pb-Hf isotopic analysis and whole-rock geochemistry were carried out to constrain the age and the tectonic setting of the Kulumudi Formation. The zircon U-Pb age of the lithic crystal tuff from the Kulumudi Formation on the northeast side of the Alemale Mountains was 386 ± 2 Ma, accurately indicating that this rock unit formed during the Middle Devonian. However, the fine sandstone near the Huojierte Mongolian Township, originally assigned as the “Kulumudi Formation”, yielded a maximum depositional age of 341 ± 3 Ma. Combined with the stratigraphic contact, this rock unit was redefined to belong to the Lower Carboniferous Jiangbasitao Formation. According to the whole-rock geochemistry study, the lithic crystal tuff of the Kulumudi Formation was characterized as medium potassium–calc–alkaline series rock, which is relatively enriched in light rare earth elements and large ion lithophile elements (i.e., Rb, Ba, K) and depleted in high-field-strength elements (i.e., Nb, Ta, Ti), showing similar geochemical characteristics to the volcanic arc rocks. By contrast, the fine sandstone from the Jiangbasitao Formation had Al₂O₃/SiO₂ (0.25–0.29) and K₂O/Na₂O (1.29–1.72) ratios close to those derived from the continental arc and active continental margin and was characterized as part of the continental arc field in the La-Th-Sc and Th-Sc-Zr/10 tectonic discrimination diagrams. Zircon Hf isotope analysis showed that the ε_Hf(t) values of the Kulumudi Formation were +5.6–+12.8, and those of the Jiangbasitao Formation were +11.43–+15.48, both of which show highly positive juvenile characteristics. The above data indicate that the Kulumudi Formation and Jiangbasitao Formation both formed in a juvenile arc setting with ocean–continent subduction. Combined with the previous work, it was concluded that the southward subduction of the ocean basin represented by the Darbut–Karamay ophiolitic mélanges beneath the newly accreted arc crustal segments produced a juvenile arc with positive Hf isotope characteristics. Full article

(This article belongs to the Special Issue Tectonic–Magmatic Evolution and Mineralization Effect in the Southern Central Asian Orogenic Belt)

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27 pages, 15311 KiB

Open AccessArticle

Permian Granitic Plutons from the Northern Margin of the North China Craton: Implications for the Tectonic Evolution of the Central Asian Orogenic Belt

by Jingsheng Chen, Dexin Tian, Bin Li, Yi Shi, Zhonghui Gao, Yi Tian, Weiwei Li, Chao Zhang and Yan Wang

Minerals 2023, 13(12), 1554; https://doi.org/10.3390/min13121554 - 17 Dec 2023

Cited by 2 | Viewed by 1477

Abstract

As the world’s largest accretionary orogen, the Central Asian Orogenic Belt (CAOB) underwent continuous juvenile crustal growth in the Phanerozoic. The northern margin of the North China Craton (NCC) and its adjacent area form the eastern segment of the CAOB, which is a [...] Read more.

As the world’s largest accretionary orogen, the Central Asian Orogenic Belt (CAOB) underwent continuous juvenile crustal growth in the Phanerozoic. The northern margin of the North China Craton (NCC) and its adjacent area form the eastern segment of the CAOB, which is a key area for learning about the geological evolution of the Paleo-Asian Ocean (PAO). In the Permian, the west of the northern margin of the NCC was a post-collision extensional environment, while the east was in a subduction stage. As a connecting area, the Permian evolution of the PAO in the middle of the northern margin of the NCC has not been systematically studied. In order to fill the gap and understand the continuous temporal and spatial evolutionary process of the PAO, this paper focuses on the Permian granitic rocks in the Chifeng area. Zircon U-Pb dating and the geochemical analysis of whole-rock major and trace elements were conducted to build a granite chronological framework, and to discuss the genesis and tectonic background of the granitic rocks, along with tectono-magmatic evolutionary history in the Chifeng area. The respective LA-ICP-MS zircon U-Pb dating results from eight samples are 269 ± 1, 268 ± 3, 260 ± 4, 260 ± 1, 260 ± 1, 255 ± 2, 254 ± 2 and 256 ± 1 Ma, respectively. These results, combined with previous data, revealed that the Permian granitic rocks had undergone three events of magmatism: (1) monzogranitic-syenitic phase (294–284 Ma; Cisuralian); (2) monzogranitic phase (269–260 Ma; Guadalupian) and (3) late monzogranitic-syenitic phase (256–254 Ma; Lopingian). From the Early Permian (294–284 Ma) to the Middle Permian (269–260 Ma), granites with fine-medium-grained locally porphyritic texture and massive structure showed a high-potassium calc-alkaline series formed in a compressional setting, indicating a continuous collision between the Xing’an-Mongolian Orogenic Belt (XMOB) and the NCC. During the Late Permian-Early Triassic (256–248 Ma), granites with massive structure and medium-grained texture in the Chifeng area were magmatism dominated by A- and I-type granites of high-potassium calc-alkaline series, combined with the coeval basic rocks, which constituted a typical “bimodal” rock assemblage. This suggests that the Chifeng area was located in an extensional setting where the subducting slab broke off during the collision between the XMOB and NCC. These granitic plutons from the Permian are believed to have been generated by the subduction-collision of the Paleo-Asian oceanic crust beneath the NCC, according to emplacement time and occurrence location. Our findings provide strong evidence for Permian continuous temporal and spatial tectonic evolution and the characterization of the eventual closure of the PAO in Chifeng area at the northern margin of the NCC. Full article

(This article belongs to the Special Issue Tectonic–Magmatic Evolution and Mineralization Effect in the Southern Central Asian Orogenic Belt)

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21 pages, 8131 KiB

Open AccessArticle

Early Permian Post-Collision Extensional Setting in the Southern Beishan Orogenic Belt: Evidence from the Zhangfangshan Granodiorite and the Baishantang Bimodal Volcanic Rocks

by Lei Wu, Xinwei Zhai, Erteng Wang, Wanfeng Chen, Gaorui Song, Feifei Zheng, Jiaolong Zhao, Jinrong Wang and Haidong Wang

Minerals 2023, 13(12), 1468; https://doi.org/10.3390/min13121468 - 22 Nov 2023

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Abstract

Outcrops of late Paleozoic magmatic rocks are common in the Southern Beishan Orogenic Belt (SBOB), Southern Central Asian Orogenic Belt (CAOB), which is a key object for the understanding of regional tectonism and defining the final closure time of the Paleo-Asian Ocean (PAO). [...] Read more.

Outcrops of late Paleozoic magmatic rocks are common in the Southern Beishan Orogenic Belt (SBOB), Southern Central Asian Orogenic Belt (CAOB), which is a key object for the understanding of regional tectonism and defining the final closure time of the Paleo-Asian Ocean (PAO). We present zircon U-Pb chronology and whole-rock geochemistry data for late Paleozoic granodiorites and bimodal volcanic rocks from the Shuangyingshan-Huaniushan unit in the north Huitongshan-Zhangfangshan ophiolitic belt in the SBOB. The Zhangfangshan granodiorites (LA-ICP-MS, Ca. 288 Ma) are A2-type granite enriched in Rb, Th, Pb and LREEs and depleted in Nb, Ta, Ti, Sr, Ba and HREEs. They have varying MgO and ^TFe₂O₃ contents with high Mg^# (38.56~48.97) values; the Lu/Yb ratios (0.14~0.15) of these granodiorites are similar to mantle-derived magma. A clear plagioclase zoning structure and acicular apatite occur in mineral assemblages derived from magma mixing between mafic and felsic magmas. The Baishantang bimodal volcanic rocks (272 Ma) consist of rhyolite and basaltic andesite. Baishantang rhyolites are A2-type felsic rock enriched in Rb, Th, Pb and LREEs and depleted in Nb, Ta, Ti, Sr, Ba and HREEs, with negative ε_Nd(t) and ε_Hf(t) (−5.2~−4.8 and −2.2~−1.9, respectively). Rhyolites originated from the partial melting of the crust, influenced by mantle material. Basaltic andesites belong to calc-alkaline series and have an enrichment of Rb, Ba, Th, U, Pb and LREEs, are weakly enriched in Zr-Hf, and are depleted in Nb, Ta, Ti and HREEs. The Nd-Hf isotopes of these basaltic andesites are not coupled with negative ε_Nd(t) (−2.8~−0.4) and positive ε_Hf(t) (1.8~5.5) values. These characteristics indicate that they originated from the partial melting of the mantle mixed with sediment-derived melts. In combination with previous studies, our findings show that the early Permian Zhangfangshan granodiorites and Baishantang bimodal volcanic rocks formed in a post-collision extensional setting, and the Huitongshan-Zhangfangshan ocean had been closed before early Permian. Full article

(This article belongs to the Special Issue Tectonic–Magmatic Evolution and Mineralization Effect in the Southern Central Asian Orogenic Belt)

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18 pages, 7136 KiB

Open AccessArticle

Ocean–Continent Conversion in Beishan Orogenic Belt: Evidence from Geochemical and Zircon U-Pb-Hf Isotopic Data of Luotuoquan A-Type Granite

by Wenliang Chen, Minjie Zhang, Guanghuo Tao, Xiaofeng Li, Qian Yu, Xiaojie Fan and Jingwei Zhang

Minerals 2023, 13(11), 1411; https://doi.org/10.3390/min13111411 - 4 Nov 2023

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Abstract

Devonian magmatism is one of the most important tectonothermal events in the Central Asian Orogenic Belt (CAOB). However, little is known regarding the petrogenesis and geodynamic setting of the widely distributed Devonian granitoids in the eastern Southern Beishan Orogenic Belt (SBOB). Early-Devonian granitic [...] Read more.

Devonian magmatism is one of the most important tectonothermal events in the Central Asian Orogenic Belt (CAOB). However, little is known regarding the petrogenesis and geodynamic setting of the widely distributed Devonian granitoids in the eastern Southern Beishan Orogenic Belt (SBOB). Early-Devonian granitic magmatism has been recognized from the Luotuoquan area, and the granites were emplaced between 404.9 Ma and 399.4 Ma according to LA-ICPMS zircon U–Pb dating. Geochemically, the granites exhibit high SiO₂ and Al₂O₃ contents and are enriched in light rare earth elements as well as Rb, Th, Nd, Zr, and Hf, while being depleted in heavy rare earth elements and Ba, U, Sr, and Ti, with distinct rare earth element fractionation and pronounced negative Eu anomalies. According to the comprehensive analysis, they closely resemble the features typically associated with A-type granites. The zircons ε_Hf(t) values are within the range of +0.90–+5.19 (averaged 3.23) for the monzogranite and syenogranite, whereas their T_DM2 values fall between 1.05 and 1.34 Ga, suggesting that the magma source of the monzogranite–syenogranite originated from the partial melting of the Mesoproterozoic crust dominated by metagreywackes. Furthermore, the monzogranite and syenogranite exhibit high temperatures (average 782 °C), thin crustal thickness (average 30 km), and A-type characteristics, suggesting their formation in post-collision extensional settings. We propose the closure of the Beishan Ocean occurred before the early Devonian, followed by a transition in the Southern Beishan Orogenic Belt from a compressional to an extensional setting. Full article

(This article belongs to the Special Issue Tectonic–Magmatic Evolution and Mineralization Effect in the Southern Central Asian Orogenic Belt)

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24 pages, 5819 KiB

Open AccessArticle

Geochemistry, Chronology and Tectonic Implications of the Hadayang Schists in the Northern Great Xing’an Range, Northeast China

by Fuchao Na, Weimin Song, Yingcai Liu, Junyu Fu, Yan Wang and Wei Sun

Minerals 2023, 13(11), 1379; https://doi.org/10.3390/min13111379 - 28 Oct 2023

Viewed by 1020

Abstract

The Late Paleozoic tectonic evolution of the Xing’an block in the eastern Central Asian orogenic belt has long been the subject of debate. In this paper, a comprehensive study of U-Pb zircon ages, Lu-Hf isotopes and whole-rock elemental analyses was carried out on [...] Read more.

The Late Paleozoic tectonic evolution of the Xing’an block in the eastern Central Asian orogenic belt has long been the subject of debate. In this paper, a comprehensive study of U-Pb zircon ages, Lu-Hf isotopes and whole-rock elemental analyses was carried out on Hadayang schists. Representative samples of the epidote-biotite-albite schist and biotite-albite schist yielded the weighted mean ²⁰⁶Pb/²³⁸U ages of 360 ± 2 Ma and 355 ± 3 Ma, respectively. This indicated the presence of Late Devonian–Early Carboniferous intermediate-basic rocks in the eastern Xing’an block. The Hadayang schists exhibited a Na-rich, tholeiitic and calc-alkaline affinity in composition with low Mg# (35.2–53.0), Cr (23.7–86.5 ppm), Ni (21.1–40.0 ppm) and Co (12.1–30.6 ppm). They were characterized by enrichment of LILEs, depletion of HFSEs and highly positive zircon ε_Hf(t) values (the average values were +8.93 and +9.29, respectively). The magma source of the Hadayang schists was a mantle that consisted of both spinel and garnet lherzolite, with a partial melting degree of 1%–5%, and it had undergone fractional crystallization of olivine, orthopyroxene and plagioclase. The Hadayang schists, together with other Late Devonian–Early Carboniferous intermediate-basic magmatic rocks in the eastern Xing’an block, were formed in an intracontinental extension tectonic setting similar to that of the North American Basin and Range basalt. Moreover, Late Devonian–Early Carboniferous ophiolite under a similar tectonic background in the western Xing’an block has been reported. We believe that the Xing’an block would have been in the stage of intracontinental extension during the Late Devonian–Early Carboniferous. Full article

(This article belongs to the Special Issue Tectonic–Magmatic Evolution and Mineralization Effect in the Southern Central Asian Orogenic Belt)

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27 pages, 22770 KiB

Open AccessArticle

Ore Genesis and the Magmatism of the Yuhaixi Mo(Cu) Deposit in Eastern Tianshan, NW China: Constraints from Geology, Geochemistry, Zircon U-Pb and Molybdenite Re-Os Dating

by Di Wang, Chunji Xue, Yun Zhao, Chao Li, Binbin Xi, Yang Yang, Qinglei Tian, Xunshan Kang and Xing Wu

Minerals 2023, 13(11), 1368; https://doi.org/10.3390/min13111368 - 26 Oct 2023

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Abstract

The Yuhaixi Mo(Cu) deposit is a new discovery in the eastern section of the Dananhu-Tousuquan island arc, Eastern Tianshan. However, the genesis of the Yuhaixi Mo(Cu) deposit is still not fully understood. The Yuhaixi intrusion is composed of monzonitic granites, diorites, granites, and [...] Read more.

The Yuhaixi Mo(Cu) deposit is a new discovery in the eastern section of the Dananhu-Tousuquan island arc, Eastern Tianshan. However, the genesis of the Yuhaixi Mo(Cu) deposit is still not fully understood. The Yuhaixi intrusion is composed of monzonitic granites, diorites, granites, and gabbro dikes, among which disseminated or veinlet Mo and Cu mineralization is mainly hosted by the monzonitic granites. The LA-ICP-MS zircon U-Pb dating yields emplacement ages of 359.4 ± 1.6 Ma for the monzonitic granite, 298.8 ± 1.8 Ma for the diorite, and 307.0 ± 2.3 Ma for the granite. The Re-Os dating of molybdenite hosted by monzonitic granite yields a well-constrained ¹⁸⁷Re-¹⁸⁷Os isochron age of 354.1 ± 6.8 Ma (MSWD = 1.7) with a weighted average age of 344.5 ± 3.1 Ma. The Mo mineralization is closely associated with the Yuhaixi monzonitic granite. The Yuhaixi monzonitic granite rocks are characterized by high silica (SiO₂ > 70 wt.%), low MgO (0.23–0.36), Ni, Cr contents, and they are enriched in light rare earth elements (LREEs) and large ion lithophile elements (LILEs: e.g., K, Ba, Pb and Sr), and depleted in heavy rare earth elements (HREEs) and high field-strength elements (HFSEs: e.g., Nb, Ta and Ti). They are weak peraluminous and have high εHf(t) (11.37–17.59) and εNd(t) (1.36–7.75) values, and varied initial ⁸⁷Sr/⁸⁶Sr (0.7037–0.7128) values. The Yuhaixi post-ore granites exhibit similar geochemical and isotopic signatures to the Yuhaixi monzonitic granite. These characteristics suggest that the Yuhaixi felsic rocks are likely sourced from the partial melting of the juvenile lower crust. The Yuhaixi diorite has low SiO₂, and K₂O contents, relatively high Na₂O, MgO (Mg^# = 45–53) contents, and depletions in HFSE (e.g., Nb, Ta, and Ti). These geochemical features, coupled with isotopic data such as low initial ⁸⁷Sr/⁸⁶Sr (≤0.7043), high εNd(t) (2.5 to 3.0) and εHf(t) (≥11.6) values, and young Hf model ages, suggest that their parental magmas possibly originated from the partial melting of the depleted lithospheric mantle that was metasomatized by hydrous melts or fluids from the subducting oceanic plate. Integrating our new results with previous works on the Dananhu-Tousuquan island arc belt, we suggest that the Yuhaixi Mo(Cu)deposit is likely sourced from the juvenile lower crust, which was formed in an arc setting, where the bipolar subduction of the North Tianshan oceanic slab forms the Dananhu Tousuquan belt to the north and the Aqishan-Yamansu belt to the south. The eastern section of the Dananhu-Tousuquan island arc is a promising target for late Paleozoic porphyry Mo(Cu) deposits. Full article

(This article belongs to the Special Issue Tectonic–Magmatic Evolution and Mineralization Effect in the Southern Central Asian Orogenic Belt)

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32 pages, 7755 KiB

Open AccessArticle

Ore Genesis of the Lower Urgen Porphyry Molybdenum Deposit in the Northern Great Xing’an Range, Northeast China: Constraints from Molybdenite Re-Os Dating, Fluid Inclusions, and H-O-S-Pb Isotopes

by Guangliang Zhang, Wei Xie, Shouqin Wen, Qingdong Zeng, Lingli Zhou, Hui Wang, Kailun Zhang, Tieqiao Tang and Pengcheng Ma

Minerals 2023, 13(9), 1189; https://doi.org/10.3390/min13091189 - 10 Sep 2023

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Abstract

The Lower Urgen molybdenum deposit (44,856 t Mo @ 0.141%), situated in the northern Great Xing’an Range, is a newly discovered porphyry molybdenum deposit. Mineralization is characterized by veinlet-disseminated- and vein-type quartz–sulfide orebodies primarily occurring in the cupola of the Early Cretaceous granite [...] Read more.

The Lower Urgen molybdenum deposit (44,856 t Mo @ 0.141%), situated in the northern Great Xing’an Range, is a newly discovered porphyry molybdenum deposit. Mineralization is characterized by veinlet-disseminated- and vein-type quartz–sulfide orebodies primarily occurring in the cupola of the Early Cretaceous granite porphyry stock. In this study, we present a detailed description of the ore geology, molybdenite Re-Os dating, H-O-S-Pb isotopic compositions, and fluid inclusion (FI) analyses including petrography, laser Raman, and microthermometry to precisely constrain the timing of ore formation, the origin of ore-forming fluids and materials, as well as the metal precipitation mechanism. Molybdenite Re-Os dating yielded two model ages of 141.2 ± 1.5 and 147.7 ± 1.7 Ma, coeval with the regional Late Jurassic–Early Cretaceous molybdenum metallogenesis. The hydrothermal process can be divided into three stages: the quartz–molybdenite(–pyrite) stage, quartz–polymetallic sulfide stage, and quartz–carbonate stage. Four types of FIs were distinguished for quartz, including two-phase liquid-rich (L-type), saline (S-type), CO₂-rich (C1-type), and CO₂-bearing (C2-type) FIs. Microthermometric data showed that the homogenization temperatures and salinities from the early to late stages were 240–430 °C, 5.0–11.9, and 30.1–50.8 wt% NaCl equiv.; 180–280 °C and 3.0–9.1 wt% NaCl equiv.; and 120–220 °C and 0.2–7.9 wt% NaCl equiv., respectively, suggesting a decreasing trend. H-O isotopic compositions indicate that the ore-forming fluids were initially of magmatic origin with the increasing incorporation of meteoric water. S-Pb isotopic compositions indicate that the ore-forming materials originated from granitic magmas, and the mineralization is genetically related to the ore-bearing granite porphyry stock in the deposit. Fluid immiscibility and fluid–rock interaction are collectively responsible for the massive deposition of molybdenite in stage 1, whereas fluid mixing and immiscibility played a critical role in the deposition of polymetallic sulfide in stage 2. Full article

(This article belongs to the Special Issue Tectonic–Magmatic Evolution and Mineralization Effect in the Southern Central Asian Orogenic Belt)

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19 pages, 4431 KiB

Open AccessArticle

In Situ Trace Element and Sulfur Isotope Composition of Pyrite from the Beiwagou Pb-Zn Deposit, Liaodong Peninsula, Northeast China: Implications for Ore Genesis

by Qi Yu, Zhigao Wang, Qingfei Sun and Keyong Wang

Minerals 2023, 13(9), 1176; https://doi.org/10.3390/min13091176 - 7 Sep 2023

Cited by 1 | Viewed by 1428

Abstract

The Beiwagou Pb-Zn deposit, located in the western part of the Liaodong Peninsula, is a carbonate-hosted stratiform deposit with a Pb + Zn reserve of 0.08 Mt @ 4.14% (Pb + Zn). The orebodies occur as conformable layers and lenses and are strictly [...] Read more.

The Beiwagou Pb-Zn deposit, located in the western part of the Liaodong Peninsula, is a carbonate-hosted stratiform deposit with a Pb + Zn reserve of 0.08 Mt @ 4.14% (Pb + Zn). The orebodies occur as conformable layers and lenses and are strictly controlled by strata (the Paleoproterozoic Gaojiayu and Dashiqiao Formations) and lithology (plagioclase amphibolite and dolomitic marble). Given that previous studies have focused only on the mineralization features and mineralogy of deposits, herein, we report in situ trace element analyses of pyrite using LA-ICP-MS, together with in situ sulfur isotopes of pyrite, to constrain the composition, substitution mechanisms, source of sulfur, and sulfate reduction pathways of pyrite in the Beiwagou deposit. Based on pyrite morphology, texture, and chemistry, four pyrite types were identified: subhedral, porous-to-massive pyrite (Py1) related to chalcopyrite; subhedral, porous crushed pyrite (Py2) associated with fine-grained sphalerite; rounded and porous pyrite (Py3) related to the Zn-rich part of the laminated ore; and anhedral, porous-to-massive pyrite (Py4) associated with pyrrhotite, arsenopyrite, sphalerite, and galena. Py1 is characterized by high As, Ag, Cd, In, Au, Cu, and Zn concentrations and low Te, Bi, and Mo concentrations, whereas Py2 has high concentrations of Co and Ni and low concentrations of other trace elements, such as Cu, Zn, Bi, and Te. Py3 is characterized by elevated As concentrations, low Co, Ni, In, W, Te, and Tl concentrations, and varying Pb concentrations, whereas Py4 has low Ag, Cd, In, Zn, Cu, and Mn concentrations and varying W, Co, Ni, Pb, Sb, and As concentrations. Significant correlations between some elements in each pyrite type suggest substitution mechanisms, such as (Zn²⁺ + Cu²⁺ + Mn²⁺ + Cd²⁺) ↔ 2Fe²⁺, Ag⁺ + (Sb)³⁺ ↔ 2Fe²⁺, and (Te⁺ + Ag⁺) + Sb³⁺ ↔ 2Fe²⁺, and the existence of a negative correlation between Co and Ni implies competition between both elements. The strongly positive δ³⁴S values (12.11‰–23.54‰) are similar to that of seawater sulfates and likely result from thermochemical sulfate reduction (TSR). In conclusion, the Beiwagou Pb-Zn deposit is a typical SEDEX deposit and mineralization likely occurred during diagenesis. Full article

(This article belongs to the Special Issue Tectonic–Magmatic Evolution and Mineralization Effect in the Southern Central Asian Orogenic Belt)

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18 pages, 13329 KiB

Open AccessArticle

Continental Arc Flare-Ups and Crustal Thickening Events in NE China: Insights from Detrital Zircon U-Pb Dating and Trace Elements from the Heilongjiang Complex

by Yanchen Pan, Mengyu Xu, Kai Liu and Meng Wang

Minerals 2023, 13(9), 1121; https://doi.org/10.3390/min13091121 - 25 Aug 2023

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Abstract

Continental arc is characterized by alternant magmatic flare-ups and lulls. From the Permian to the Middle Jurassic period, two flare-ups with a lull developed in NE China, but the tectonic controls that caused the flare-ups remain unclear. Sedimentary rocks of the Heilongjiang Complex [...] Read more.

Continental arc is characterized by alternant magmatic flare-ups and lulls. From the Permian to the Middle Jurassic period, two flare-ups with a lull developed in NE China, but the tectonic controls that caused the flare-ups remain unclear. Sedimentary rocks of the Heilongjiang Complex were derived from these magmatic rocks; thus, we employed detrital zircon U-Pb dating and trace elements analyses to unravel the regional tectono-magmatic evolution. Eu anomaly, (Dy/Yb)_N and Th/U ratios of the detrital zircons and Sr/Y and (La/Yb)_N of the regional granitoids together indicate the occurrence of two episodes of crustal thickening during the two flare-ups, accompanied with a westward migration of magmatism. We propose that the Permian flare-up was caused by the shallowing subduction from the east, which thickened the upper plate and enhanced the deep crustal melting. During the Middle Triassic period, the mantle wedge was expelled by the flat slab and thickened crust, leading to the magmatic lull. However, the westward subduction of the back-arc oceanic plate occurred before the lull, gradually producing the Jurassic magmatic flare-up and crustal thickening. Closure of the back-arc ocean caused by the outboard Paleo-Pacific oceanic plate subduction was important in the formation of the episodic magmatic flare-ups and crustal thickening in NE China. Full article

(This article belongs to the Special Issue Tectonic–Magmatic Evolution and Mineralization Effect in the Southern Central Asian Orogenic Belt)

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26 pages, 9733 KiB

Open AccessArticle

Late Triassic Tectonic Setting in Northeastern Margin of North China Craton: Insight into Sedimentary and Apatite Fission Tracks

by Shuang Tang, Shichao Li, Xinmei Zhang, Daixin Zhang, Hongtao Wang, Lijun Nie, Xiaodong Zhou and Mengqi Li

Minerals 2023, 13(7), 975; https://doi.org/10.3390/min13070975 - 22 Jul 2023

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Abstract

The closure timing of the Paleo-Asian Ocean and the terminal stage of the Central Asian Orogenic Belt have been widely debated in the geological community. It’s known that the gradual scissor-like closure of the Paleo-Asian Ocean occurred from west to east during the [...] Read more.

The closure timing of the Paleo-Asian Ocean and the terminal stage of the Central Asian Orogenic Belt have been widely debated in the geological community. It’s known that the gradual scissor-like closure of the Paleo-Asian Ocean occurred from west to east during the Paleozoic period. However, it was not until the Triassic period that the complete closure of the ocean occurred at the northeastern margin of the North China Craton. Nevertheless, there is still much uncertainty regarding the Late Triassic tectonic setting in Northeast China. In this study, we focused on the Upper Triassic Dajianggang Formation, located in the Shuangyang area of central Jilin Province, which is situated on the northeastern margin of the North China Plate. Our aim was to determine the formation age of the Dajianggang Formation by analyzing the detrital particle composition, petrogeochemistry, detrital zircon U-Pb isotope dating, and apatite fission track thermochronology. Our results indicated that the primary sandstone provenance area of the Dajianggang Formation in the Shuangyang area is the island arc orogenic belt. The tectonic background of the sandstone provenance area is mainly a continental island arc environment. The provenance area is mostly composed of felsic rocks with sedimentary tendencies, and some of its material may have originated from the northern margin of the North China Craton or the eroded recycle orogenic belt. LA-ICP-MS U-Pb dating of detrital zircons shows that the Dajianggang Formation formed after 226.8 ± 5 Ma. Moreover, analysis of the thermal evolution history modelling shows that the Dajianggang Formation in the Shuangyang area continued to be deposited and heated in the early stage, and then experienced rapid exhumation around 30 Ma. This suggests that the study area underwent an orogenic process during the early stage of formation, but then transitioned into a post-orogenic extension period, which constrained the final closure of the Paleo-Asian Ocean prior to the Late Triassic period. In addition, our study indicates that the remote effect of the Pacific subduction did not reach the study area until 30 Ma. The central age of the detrital apatite fission track of sample 19DJ-1 is 94.2 ± 8.3 Ma, which is younger than its corresponding stratigraphic age. The two peak ages of the fission track analysis are 62.9 ± 5.4 Ma and 126 ± 11 Ma. These findings provide new evidence for the tectonic evolution of Northeast China and shed light on the Late Triassic tectonic setting, as well as the influence time of subsequent tectonic domains in the southern part of Northeast China. Full article

(This article belongs to the Special Issue Tectonic–Magmatic Evolution and Mineralization Effect in the Southern Central Asian Orogenic Belt)

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