Advanced Nanomaterials and Energetic Application: Experiment and Simulation

A special issue of Nanomaterials (ISSN 2079-4991). This special issue belongs to the section "Nanocomposite Materials".

Deadline for manuscript submissions: 30 June 2025 | Viewed by 1164

Special Issue Editors


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Guest Editor
Xi’an Modern Chemistry Research Institute, Xi’an 710065, China
Interests: composite energetic materials; nanoscale energetic materials (nEMs); microscale energetic materials (mEMs); ignition; combustion; thermal decomposition; deflagration and detonation; energetic formulation
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Guest Editor
Teaching and Research Unit of Energetic Processes, Ecole Militaire Polytechnique, Bordj El-Bahri, Algiers 16046, Algeria
Interests: bio-based materials; nanocellulose; nanomaterials; characterization; analytical methods; thermal analysis; kinetics; advanced materials; nanoenergetic materials; propellant; energetic materials; multifunctional polymer composites and nanocomposites
Special Issues, Collections and Topics in MDPI journals

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Guest Editor
Department of Mechanical Engineering, City University of Hong Kong, Room Y6700, Yeung Building 83 Tat Chee Avenue, Kowloon, Hong Kong 999077, China
Interests: energetics-on-a-chip; energetic materials; Li-ion battery/supercapacitor; energy; thermal science

Special Issue Information

Dear Colleagues,

In recent years, significant advancements have been made in the exploitation, combustion, ignition, and application of innovative nano-metric energetic materials, including solid fuels, energetic combustion catalysts, metal particles, thermites, and energetic composites, etc., due to the technological novelties in the field of nano-scale science and technology. One of the main reasons for utilizing innovative nano-metric energetic materials and their composites in various chemical propulsion systems is due to the high heat of formation, high specific surface area, high reactive activation and high energy density. Although innovative nano-metric energetic materials have the very attractive feature of extremely high heat release rates and tailored burning rates, producing high energy in their combustion processes and high combustion efficiency during their industry application presents a great challenge to many engineers and scientists. Various techniques have recently been developed to overcome the intrinsic difficulties. Fundamental research investigations have also been conducted to explore the detailed physicochemical processes associated with innovative nano-metric energetic material preparation, combustion and application. In particular, state-of-the-art rocket propulsion systems have greatly benefited from innovative nano-metric energetic material development in recent years, especially in terms of future prospective nano-metric energetic materials for rocket fuels and fabrication of propellants, explosives and pyrotechnics.

This Special Issue presents compiled results of the most recent development of innovative nano-sized energetic materials, including nano-sized metal fuels, nano-sized combustion catalysts, nano-sized energetic composite nano-sized oxidizers, nano-sized thermites, etc., for use in simulations, ignition and combustion, with a particular focus on energetic application technology in chemical propulsion systems. This effort focuses on the design and investigation of novel high-tech nano-metric energetic materials for metal fuels, oxidizers, combustion catalysts, thermites, and further additives for solid, liquid, gelled, hybrid, electro-controlled and propellant systems. On the one hand, considerable effort is being spent on the improvement and perfecting of the propulsion systems themselves, which are designed exclusively for the nano-metric ingredients they work with. On the other hand, the research for new nano-metric ingredients for chemical propulsion is a challenge for chemistry. In recent years, for nano-metric energetic material ingredients for chemical propellants, great progress has been made in the development of propellants, explosives, and pyrotechnics. Despite the impressive progress witnessed in the field of nano-EMs during the last century, it must be admitted that the rate of progress is much slower when compared to other fields such as polymer chemistry, electronics, and computers owing to a number of constraints and restrictions that nano-EM scientists have to encounter in developing a new nEM. These include safety, stability (thermal, storage, etc.), cost, and other considerations.

The submission of contributions on the advanced energetic nanomaterials in chemical propulsion from the viewpoint of experiment and simulation aspects, including research papers, reviews, short communications, etc. is encouraged.

Dr. Weiqiang Pang
Dr. Djalal Trache
Prof. Dr. Kaili Zhang
Guest Editors

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Keywords

  • nano-energetic materials
  • nano-metal fuels
  • nano-technology
  • nano-energetic composites
  • nanocatalysts
  • nanothermites
  • solid rocket propellant
  • thermal decomposition
  • combustion
  • molecular dynamic simulation

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Published Papers (1 paper)

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15 pages, 5705 KiB  
Article
Miraculous Al/PDF Composites Using NF2 to Enhance the Energy Release of Al, Prepared Through an Efficient Method
by Junqi He, Jing Lv, Wenfang Zheng, Renming Pan and Yanan Li
Nanomaterials 2024, 14(24), 1980; https://doi.org/10.3390/nano14241980 - 10 Dec 2024
Viewed by 576
Abstract
To enhance the energy release of Al powder in solid propellant, ploy (difluoroaminomethyl-3-methylethoxybutane) (PDF), which has difluoroamino (NF2), was utilized to improve energy and promote combustion efficiency. In this study, Al with three distinct powder sizes (29 μm, 13 μm, and [...] Read more.
To enhance the energy release of Al powder in solid propellant, ploy (difluoroaminomethyl-3-methylethoxybutane) (PDF), which has difluoroamino (NF2), was utilized to improve energy and promote combustion efficiency. In this study, Al with three distinct powder sizes (29 μm, 13 μm, and 1~3 μm) was coated with PDF using the solvent/non-solvent method, leading to the formation of Al/PDF composites. The morphology and characteristics of Al/PDF were then characterized. The results demonstrated that all powder sizes of Al/PDF had core-shell structures, and NF2 of the PDF layer on the Al surface maintained the original structure. The TG curves indicated the amount of the PDF layer related to the powder sizes. Furthermore, Al/PDF exhibited greater hydrophobicity. NF2 prompted Al/PDF, with better catalysis on ammonium perchlorate (AP) decomposition. Compared to Al powder, the ignition delay of Al/PDF was significantly shortened. For mixed samples of Al/PDF and AP, NF2 shorted the ignition delay, improving combustion stability, extending the combustion duration, and forming volatile fluorine compounds. These findings underscore the effects of NF2 in Al/PDF composites, which enhances the energy release of Al and holds promising potential applications. Full article
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