Functionalizing of Cellulose or Chitosan Surfaces with Metallic Nanoparticles

A special issue of Nanomaterials (ISSN 2079-4991).

Deadline for manuscript submissions: closed (1 October 2019) | Viewed by 8777

Special Issue Editor


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Guest Editor
Habillitation at Instituto Superior Técnico, Lisbon University, Lisbon, Portugal
Interests: hybrid chitosan-TiO2/ZnS preparation; functionalization of cotton with nanostructured silver/titania

Special Issue Information

Dear Colleagues,

Cellulose and chitin (or its derivative chitosan) are abundant materials, which are both biodegradable and sustainable materials. In particular, they can be functionalized with metallic (or respective salts) nanoparticles, aiming at several applications, such as biocide wound textiles or smart fabrics to degrade chemical weapon agents. Moreover, some of these nanoparticles can be grown on both materials following the principles of green chemistry since they can be used simultaneously as reducing and/or stabilizer agents. 

The deadline for submitting your contributions will be 31 August 2019. 

If you have new contributions in this area, it will be a great opportunity to publish them in this journal, which is having increasing visibility and quality, attested by the evolution of its impact factor.

Prof. Dr. Ana Maria P. L. R. Botelho do Rego
Guest Editor

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Keywords

  • cellulose
  • chitosan
  • nanoparticles
  • metallic

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Published Papers (2 papers)

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8 pages, 1708 KiB  
Article
Silver Nanoparticles on Cellulose Surfaces: Quantitative Measurements
by Ana Patrícia Carapeto, Ana Maria Ferraria and Ana Maria Botelho do Rego
Nanomaterials 2019, 9(5), 780; https://doi.org/10.3390/nano9050780 - 22 May 2019
Cited by 13 | Viewed by 3672
Abstract
In this work, cellulose films pre-activated with carbonyldiimidazole (CDI) and grafted with 1,6-hexanediamine, were decorated with silver nanoparticles (AgNPs). The generation of AgNPs was followed by quartz crystal microbalance (QCM). The obtained films were characterized by X-Ray Photoelectron Spectroscopy (XPS) and imaged by [...] Read more.
In this work, cellulose films pre-activated with carbonyldiimidazole (CDI) and grafted with 1,6-hexanediamine, were decorated with silver nanoparticles (AgNPs). The generation of AgNPs was followed by quartz crystal microbalance (QCM). The obtained films were characterized by X-Ray Photoelectron Spectroscopy (XPS) and imaged by atomic force microscopy (AFM). XPS confirmed the synthesis in situ of AgNPs on the film attesting their oxidation state. The results from the three techniques were compared showing how sound the quantitative treatment of the results issued from these techniques can be. The main objective of this work is exactly to show that the quantitative exploration of the results of different characterization techniques can and should be practiced systematically instead of just comparing them qualitatively. Full article
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21 pages, 4979 KiB  
Article
Multifunctional Flax Fibres Based on the Combined Effect of Silver and Zinc Oxide (Ag/ZnO) Nanostructures
by Sofia M. Costa, Diana P. Ferreira, Armando Ferreira, Filipe Vaz and Raul Fangueiro
Nanomaterials 2018, 8(12), 1069; https://doi.org/10.3390/nano8121069 - 19 Dec 2018
Cited by 57 | Viewed by 4612
Abstract
Cellulosic fibre-based smart materials exhibiting multiple capabilities are getting tremendous attention due to their wide application areas. In this work, multifunctional flax fabrics with piezoresistive response were developed through the combined functionalization with silver (Ag) and zinc oxide (ZnO) nanoparticles (NPs). Biodegradable polyethylene [...] Read more.
Cellulosic fibre-based smart materials exhibiting multiple capabilities are getting tremendous attention due to their wide application areas. In this work, multifunctional flax fabrics with piezoresistive response were developed through the combined functionalization with silver (Ag) and zinc oxide (ZnO) nanoparticles (NPs). Biodegradable polyethylene glycol (PEG) was used to produce AgNPs, whereas ZnONPs were synthetized via a simple and low-cost method. Flax fabrics with and without NPs were characterized by Ground State Diffuse Reflectance (GSDR), Field Emission Scanning Electron Microscopy (FESEM), Energy Dispersive Spectroscopy (EDS), X-ray Diffraction (XRD), Attenuated Total Reflectance-Fourier Transform Infrared Spectroscopy (ATR-FTIR), and Thermogravimetric analysis (TGA). After creating a conductive surface by flax functionalization with AgNPs, ZnONPs were synthetized onto these fabrics. The developed fibrous systems exhibited piezoresistive response and the sensor sensitivity increased with the use of higher ZnO precursor concentrations (0.4 M). Functionalized fabrics exhibited excellent antibacterial activity against Gram-negative (Escherichia coli) and Gram-positive (Staphylococcus aureus) bacteria, higher hydrophobicity (WCA changed from 00 to >1000), UV radiation resistance, and wash durability. Overall, this work provides new insights regarding the bifunctionalization of flax fabrics with Ag/ZnO nanostructures and brings new findings about the combined effect of both NPs for the development of piezoresistive textile sensors with multifunctional properties. Full article
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