Nanomaterials for Electrocatalysis

A special issue of Nanomaterials (ISSN 2079-4991).

Deadline for manuscript submissions: closed (15 December 2016) | Viewed by 18145

Special Issue Editor


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Guest Editor
School of Materials Science and Engineering, Shanghai Jiao Tong University, 800 Dong Chuan Road, Shanghai 200240, China
Interests: metal catalysts; electrocatalysis; surface chemistry; electron microscope in situ technique in material growth and characterization of catalytic reaction and monitoring

Special Issue Information

Dear Colleagues,

Nanomaterials are the intrinsic base for various electrocatalytic reactions in energy and fuel technologies. A great deal of effort has been made focusing on the manipulation of compositions, sizes, shapes, and structures of nanomaterials for preparing novel catalysts for various electrocatalytic reactions. Electrocatalalysis involves the adsorption of monomers, electron transfer, redox reactions, and desorption of monomers. All these processes are the interactions of monomers and the surface atoms of nanomaterials. It is fundamentally important to understand the effect of size and shape (i.e., facet) on the activity, selectivity and long-term stability of nanomaterials as electrocatalysts.

The purpose of this Special Issue is to collect a series of results from experts to show the current research focuses and recent progress in these respects. From this Special Issue, the readers will be able to learn the synthetic approach and deep characterization techniques of nanomaterials for electrocatalysis, the relationship between their compositions or structures and electrocatalytic performances, and start to build a fundamental understanding of the principles that predict these interactions.

Prof. Dr. Jianbo W
Guest Editor

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Keywords

  • electrocatalysis
  • electrocatalytic performances
  • electrocatalytic reaction
  • electron transfer
  • redox reactions
  • adsorption or desorption of monomers

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Published Papers (2 papers)

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8919 KiB  
Article
Simultaneous Detection of Dopamine and Uric Acid Using a Poly(l-lysine)/Graphene Oxide Modified Electrode
by Yuehua Zhang, Wu Lei, Yujuan Xu, Xifeng Xia and Qingli Hao
Nanomaterials 2016, 6(10), 178; https://doi.org/10.3390/nano6100178 - 28 Sep 2016
Cited by 55 | Viewed by 9647
Abstract
A novel, simple and selective electrochemical method was investigated for the simultaneous detection of dopamine (DA) and uric acid (UA) on a poly(l-lysine)/graphene oxide (GO) modified glassy carbon electrode (PLL/GO/GCE) by differential pulse voltammetry (DPV). The electrochemically prepared PLL/GO sensory platform [...] Read more.
A novel, simple and selective electrochemical method was investigated for the simultaneous detection of dopamine (DA) and uric acid (UA) on a poly(l-lysine)/graphene oxide (GO) modified glassy carbon electrode (PLL/GO/GCE) by differential pulse voltammetry (DPV). The electrochemically prepared PLL/GO sensory platform toward the oxidation of UA and DA exhibited several advantages, including high effective surface area, more active sites and enhanced electrochemical activity. Compared to the PLL-modified GCE (PLL/GCE), GO-modified GCE and bare GCE, the PLL/GO/GCE exhibited an increase in the anodic potential difference and a remarkable enhancement in the current responses for both UA and DA. For the simultaneous detection of DA and UA, the detection limits of 0.021 and 0.074 μM were obtained, while 0.031 and 0.018 μM were obtained as the detection limits for the selective detection of UA and DA, using DPV in the linear concentration ranges of 0.5 to 20.0 and 0.5 to 35 μM, respectively. In addition, the PLL/GO/GCE demonstrated good reproducibility, long-term stability, excellent selectivity and negligible interference of ascorbic acid (AA). The proposed modified electrode was successfully implemented in the simultaneous detection of DA and UA in human blood serum, urine and dopamine hydrochloride injection with satisfactory results. Full article
(This article belongs to the Special Issue Nanomaterials for Electrocatalysis)
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4183 KiB  
Article
Fe3+-Doped TiO2 Nanotube Arrays on Ti-Fe Alloys for Enhanced Photoelectrocatalytic Activity
by Jiangdong Yu, Zhi Wu, Cheng Gong, Wang Xiao, Lan Sun and Changjian Lin
Nanomaterials 2016, 6(6), 107; https://doi.org/10.3390/nano6060107 - 6 Jun 2016
Cited by 26 | Viewed by 8058
Abstract
Highly ordered, vertically oriented Fe3+-doped TiO2 nanotube arrays (Fe-TNTs) were prepared on Ti-Fe alloy substrates with different Fe contents by the electrochemical anodization method. The as-prepared Fe-TNTs were characterized by scanning electron microscope (SEM), transmission electron microscopy (TEM), X-ray diffraction [...] Read more.
Highly ordered, vertically oriented Fe3+-doped TiO2 nanotube arrays (Fe-TNTs) were prepared on Ti-Fe alloy substrates with different Fe contents by the electrochemical anodization method. The as-prepared Fe-TNTs were characterized by scanning electron microscope (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and related electrochemical techniques. XPS results demonstrated that Fe3+ ions were successfully doped into TiO2 nanotubes. The photoelectrochemical activity of Fe-TNTs was compared with that of pure TiO2 nanotube arrays (TNTs). The results showed that Fe-TNTs grown on low concentration (0.5 wt %–1 wt % Fe) Ti-Fe alloys possessed higher photocurrent density than TNTs. The Fe-TNTs grown on Ti-Fe alloy containing 0.8 wt % Fe exhibited the highest photoelectrochemical activity and the photoelectrocatalytic degradation rate of methylene blue (MB) aqueous solution was significantly higher than that of TNTs. Full article
(This article belongs to the Special Issue Nanomaterials for Electrocatalysis)
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