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A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Processing and Engineering".

Deadline for manuscript submissions: closed (20 September 2022) | Viewed by 21679

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Special Issue Editors

Dr. Mihai Asandulesa

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Electroactive Polymers Department, "Petru Poni" Institute of Macromolecular Chemistry, Grigore Ghica Voda Alley 41A, 700487 Iasi, Romania
Interests: broadband dielectric spectroscopy; impedance spectroscopy; molecular dynamics; conductivity; electrode polarization; interfacial polarization; dielectric polymers; polymer nanocomposites; hybrid materials
Special Issues, Collections and Topics in MDPI journals

Dr. Codrin Tugui

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Laboratory of Advanced Polymers and Materials for Energy Conversion and Storage, Department of Inorganic Polymers, "Petru Poni" Institute of Macromolecular Chemistry, Grigore Ghica Voda Alley 41A, 700487 Iasi, Romania
Interests: silicones; interpenetratig polymer networks; polymers chemistry; dielectric elastomers; stretchable capacitors; sensors; dielectric elastomer actuators; dielectric elastomer transducers; energy harvesting; mechanical properties; breakdown strength; electromechanical properties

Dr. Adrian Bele

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Laboratory of Advanced Polymers and Materials for Energy Conversion and Storage, Department of Inorganic Polymers, "Petru Poni" Institute of Macromolecular Chemistry, Grigore Ghica Voda Alley 41A, 700487 Iasi, Romania
Interests: silicone-based materials as transducers (actuators; sensors and energy harvesting); chemical modification of siloxanes; silicone-based composites and nanocomposites; silicone-based dielectric materials; silicone-based interpenetrated networks; compliant electrodes; siloxane synthesis; siloxane cross-linking pathways; in situ and ex situ nanoparticle synthesis
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

In recent decades, the academic and industrial interest for polymer-based dielectric materials has been reflected in the development of new formulations with polymeric materials for a wide gamut of applications. As science and technology advance further, researchers are facing new challenges and they are pursuing lighter, more cost-effective and more efficient materials. Compared to conventional dielectrics, polymers-based dielectric materials show exciting features, such as easy processability in various required shapes, scalability, flexibility and stretchability, lightweight, controllable optical properties and high reliability.

The aim of this Special Issue is to bring together the latest studies on polymer-based dielectric materials designed for optoelectronics, transducers, capacitors, sensors, etc. The papers may include novel synthesis and preparation methods, advanced characterization techniques, structural characterization, and properties of novel dielectric materials. Papers presenting simulations, theoretical methods or experimental studies are also welcomed. Various types of dielectric polymers, such as free-standing polymer films or coated polymers, polymer blends or organic-inorganic materials-based hybrid nanocomposites are included.

Keywords

dielectric materials
polymer-based composites
dielectric properties
optoelectronics
transducers
capacitors

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Published Papers (7 papers)

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Research

13 pages, 2528 KiB

Open AccessArticle

Rolled Dielectric Elastomer Antagonistic Actuators for Biomimetic Underwater Robots

by Toshiaki Nagai and Jun Shintake

Polymers 2022, 14(21), 4549; https://doi.org/10.3390/polym14214549 - 27 Oct 2022

Cited by 6 | Viewed by 2148

Abstract

In this study, an antagonistic actuator using dielectric elastomer actuators (DEAs) is developed to investigate the use of rolled DEAs in underwater robots. The actuator consists of a backbone, an elastic hinge, and two rolled DEAs placed in an antagonistic fashion, allowing for the generation of bidirectional movements of the actuator tip. To prove this concept, an analytical model of the actuator is built. The experimental samples are fabricated based on the specification determined by the model. In the fabricated actuator, each rolled DEA has a diameter of 6 mm and a length of 21 mm. The whole device weighs 1.7 g. In the tested voltage range of 0–1200 V, the actuator exhibits a voltage-controllable angle and torque of up to 2.2° and 11.3 mN∙mm, respectively. The actuator is then implemented into a swimming robot, which shows forward speed of 0.9 mm/s at the applied voltage of 1000 V and the driving frequency of 10 Hz. The results demonstrate the feasibility of using rolled DEAs in underwater robots. Full article

(This article belongs to the Special Issue Polymer-Based Dielectric Materials)

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17 pages, 5481 KiB

Open AccessArticle

Enhanced Actuation Performance of Polymeric Composites by Simultaneously Incorporating Covalent-Bond-Functionalized Dielectric Nanoparticles and Polar Plasticizer

by Huiwan Lu and Dan Yang

Polymers 2022, 14(19), 4218; https://doi.org/10.3390/polym14194218 - 8 Oct 2022

Cited by 1 | Viewed by 1589

Abstract

Dielectric elastomer actuators (DEAs), similar to artificial muscles, are widely applied in the fields of robotics and biomedical devices. In this work, 3-mercaptopropyl ethyoxyl di(tridecyl-pentaethoxy) silane (Si747)-modified BaTiO₃ (BTO) nanoparticles (denoted as Si747@BTO) were utilized as dielectric filler to improve the dielectric constant while epoxy soybean oil (ESO) was employed as a plasticizer to decrease the elastic modulus, with the aim of improving the actuation performance of epoxy natural rubber (ENR) composites. The participation of Si747 in the vulcanization reaction of ENR led to the formation of covalent bonds between BTO and ENR chains, resulting in a uniform dispersion of BTO nanoparticles in the ENR matrix. Among obtained composites, the 50 phr ESO/Si747@BTO/ENR exhibited a relatively high actuated strain of 8.89% at 22 kV/mm, which is a value about 5.1-fold higher than that of pure ENR (1.45%) under the same electric field. Full article

(This article belongs to the Special Issue Polymer-Based Dielectric Materials)

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19 pages, 6842 KiB

Open AccessArticle

Dielectric, Thermal and Water Absorption Properties of Some EPDM/Flax Fiber Composites

by Anton Airinei, Mihai Asandulesa, Maria Daniela Stelescu, Niţǎ Tudorachi, Nicusor Fifere, Adrian Bele and Valentina Musteata

Polymers 2021, 13(15), 2555; https://doi.org/10.3390/polym13152555 - 31 Jul 2021

Cited by 11 | Viewed by 2948

Abstract

This paper deals with the dielectric and sorption properties of some flax fiber-reinforced ethylene-propylene-diene monomer (EPDM) composites containing different fiber loadings as well as their behavior after exposure to different doses of electron beam irradiation. Three relaxation processes were evinced, a weak relaxation β at sub-T_g temperatures and two α-type relaxations above the T_g. The EPDM/flax composites exhibited higher values of dielectric constant, dielectric loss and conductivity as compared to a pristine EPDM sample. Using thermogravimetric analysis (TG) coupled with Fourier transform infrared spectroscopy (FTIR) and mass spectrometry (MS) (TG/FTIR/MS system), the degradation products can be identified. The water uptake increased as the flax fiber level increased in composites. The water uptake tests of irradiated composites showed that the highest water content was obtained for a flax fiber level of 20 phr. Full article

(This article belongs to the Special Issue Polymer-Based Dielectric Materials)

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18 pages, 7400 KiB

Open AccessArticle

Viscoelasticity Modeling of Dielectric Elastomers by Kelvin Voigt-Generalized Maxwell Model

by TuanDung Nguyen, Jin Li, Lijie Sun, DanhQuang Tran and Fuzhen Xuan

Polymers 2021, 13(13), 2203; https://doi.org/10.3390/polym13132203 - 2 Jul 2021

Cited by 20 | Viewed by 4808

Abstract

Dielectric elastomers (DEs) are polymer materials consisting of a network of polymer chains connected by covalent cross-links. This type of structural feature allows DEs to generate large displacement outputs owing to the nonlinear electromechanical coupling and time-dependent viscoelastic behavior. The major challenge is to properly actuate the nonlinear soft materials in applications of robotic manipulations. To characterize the complex time-dependent viscoelasticity of the DEs, a nonlinear rheological model is proposed to describe the time-dependent viscoelastic behaviors of DEs by combining the advantages of the Kelvin–Voigt model and the generalized Maxwell model. We adopt a Monte Carlo statistical simulation method as an auxiliary method, to the best knowledge of the author which has never reportedly been used in this field, to improve the quantitative prediction ability of the generalized model. The proposed model can simultaneously describe the DE deformation processes under step voltage and alternating voltage excitation. Comparisons between the numerical simulation results and experimental data demonstrate the effectiveness of the proposed generalized rheological model with a maximum prediction error of 3.762% and root-mean-square prediction error of 9.03%. The results presented herein can provide theoretical guidance for the design of viscoelastic DE actuators and serve as a basis for manipulation control to suppress the viscoelastic creep and increase the speed response of the dielectric elastomer actuators (DEA). Full article

(This article belongs to the Special Issue Polymer-Based Dielectric Materials)

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15 pages, 3719 KiB

Open AccessArticle

Novel Polyimide/Copper-Nickel Ferrite Composites with Tunable Magnetic and Dielectric Properties

by Corneliu Hamciuc, Mihai Asandulesa, Elena Hamciuc, Tiberiu Roman, Marius Andrei Olariu and Aurel Pui

Polymers 2021, 13(10), 1646; https://doi.org/10.3390/polym13101646 - 19 May 2021

Cited by 10 | Viewed by 2644

Abstract

Heat-resistant magnetic polymer composites were prepared by incorporating cerium-doped copper-nickel ferrite particles, having the general formula Ni_1-xCu_xFe_1.92Ce_0.08O₄ (x: 0.0, 0.3, 0.6, 1.0), into a polyimide matrix. The effects of particle type and concentration on the thermal, magnetic, and electrical properties of the resulting composites were investigated. The samples were characterized by FTIR, scanning electron microscopy, X-ray diffractometry, thermogravimetric analysis, differential scanning calorimetry, vibrating sample magnetometer, and broadband dielectric spectroscopy. The composites exhibited high thermal stability, having initial decomposition temperatures between 495 and 509 °C. Saturation magnetization (M_s), magnetic remanence (M_r), and coercivity (H_c) were found in range of 2.37–10.90 emu g⁻¹, 0.45–2.84 emu g⁻¹, and 32–244 Oe, respectively. The study of dielectric properties revealed dielectric constant values of 3.0–4.3 and low dielectric losses of 0.016–0.197 at room temperature and a frequency of 1 Hz. Full article

(This article belongs to the Special Issue Polymer-Based Dielectric Materials)

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16 pages, 7970 KiB

Open AccessArticle

Flexible Methyl Cellulose/Polyaniline/Silver Composite Films with Enhanced Linear and Nonlinear Optical Properties

by Ali Atta, Mostufa M. Abdelhamied, Ahmed M. Abdelreheem and Mohamed R. Berber

Polymers 2021, 13(8), 1225; https://doi.org/10.3390/polym13081225 - 10 Apr 2021

Cited by 96 | Viewed by 3042

Abstract

In order to potentiate implementations in optical energy applications, flexible polymer composite films comprising methyl cellulose (MC), polyaniline (PANI) and silver nanoparticles (AgNPs) were successfully fabricated through a cast preparation method. The composite structure of the fabricated film was confirmed by X-ray diffraction and infrared spectroscopy, indicating a successful incorporation of AgNPs into the MC/PANI blend. The scanning electron microscope (SEM) images have indicated a homogenous loading and dispersion of AgNPs into the MC/PANI blend. The optical parameters such as band gap (Eg), absorption edge (Ed), number of carbon cluster (N) and Urbach energy (Eu) of pure MC polymer, MC/PANI blend and MC/PANI/Ag films were determined using the UV optical absorbance. The effects of AgNPs and PANI on MC polymer linear optical (LO) and nonlinear optical (NLO) parameters including reflection extinction coefficient, refractive index, dielectric constant, nonlinear refractive index, and nonlinear susceptibility are studied. The results showed a decrease in the band gap of MC/PANI/AgNPs compared to the pure MC film. Meanwhile, the estimated carbon cluster number enhanced with the incorporation of the AgNPs. The inclusion of AgNPs and PANI has enhanced the optical properties of the MC polymer, providing a new composite suitable for energy conversion systems, solar cells, biosensors, and nonlinear optical applications. Full article

(This article belongs to the Special Issue Polymer-Based Dielectric Materials)

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19 pages, 6235 KiB

Open AccessArticle

Study Analysis of Thermal, Dielectric, and Functional Characteristics of an Ethylene Polyethylene Diene Monomer Blended with End-of-Life Tire Microparticles Amounts

by Marc Marín-Genescà, Ramon Mujal-Rosas, Jordi García-Amorós, Miguel Mudarra, Xavier Ramis Juan and Xavier Colom Fajula

Polymers 2021, 13(4), 509; https://doi.org/10.3390/polym13040509 - 8 Feb 2021

Cited by 7 | Viewed by 2734

Abstract

The recycling and disposal of disused tires is a topic of great concern to today’s companies, researchers, and society in general. In this sense, our research aims to recycle end-of-life tires (GTRs) through the separation of the fraction of vulcanized rubber from the other compounds in order to later grind this fraction and separate it into lower particle sizes. Finally, we aim to incorporate these GTR particles as a filler of an ethylene-polyethylene-diene monomer (EPDM). The obtained composites with EPDM and GTR are tested (5%, 10%, 20%) comparing these values with neat EPDM as a control sample. Thermal tests such as differential calorimetry (DSC) and thermogravimetric analysis (TGA) as well as dielectric tests (DEA) are performed in order to characterize these materials and check their viability as dielectric or semiconductor, for industrial use. It is checked how the presence of GTR increases functional properties such as conductivity/permittivity. The influence of temperature (40 to 120 °C) and addition of GTR particles in electrical properties has also been analyzed. The dielectric behavior of these composites is fully characterized, analyzing the different types of relaxation with increasing frequency (10 mHz to 3 MHz), using the electric modulus, and Argand diagrams among other measures. The influence of GTR and temperature in the dielectric and thermal behavior of these materials has been analyzed, where CB of GTR creates interfacial polarization phenomena in the dielectric behavior of the composite and increases the permittivity (real and imaginary) as well as the conductivity. Finally, with these obtained properties, the possible application of EPDM/GTR composites as industrial dielectrics has been studied. Full article

(This article belongs to the Special Issue Polymer-Based Dielectric Materials)

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