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3D-Printed Polymer and Composite Materials for Dental Applications

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Applications".

Deadline for manuscript submissions: closed (23 December 2024) | Viewed by 8221

Special Issue Editors


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Guest Editor
Department of Stomatology and Maxillofacial Surgery, Faculty of Medicine, Comenius University in Bratislava, 81250 Bratislava, Slovakia
Interests: 3D printing; artificial intelligence; orthodontics; regenerative dentistry; forensic dentistry

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Guest Editor
Head of Laboratory of Additive Technologies in Medicine, Department of Biomedical Engineering and Measurement, Faculty of Mechanical Engineering, Technical University of Kosice, Košice, Slovakia
Interests: biomedical engineering; biomaterials; scaffold; bioinspired engineering and biomimetic design; biomaterial science; additive technologies in medicine
Special Issues, Collections and Topics in MDPI journals

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Guest Editor
Head of Department of Inorganic Materials, Slovak University of Technology, Radlinského 9, SK-812 37 Bratislava, Slovakia
Interests: additive manufacturing; ceramic materials; composites; colloid chemistry; layered silicates; terahertz time domain spestroscopy; dielectric properties in THz region

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Guest Editor
Assistant Professor, Department of Biomedical Engineering and Measurement, Faculty of Mechanical Engineering, Technical University of Kosice, Košice, Slovakia
Interests: additive manufacturing; biomedical engineering; SLM technology; prosthetics and orthotics; dental

Special Issue Information

Dear Colleagues,

3D printing technology has revolutionized the way that various industries manufacture and design products, and the field of dentistry is no exception. The use of 3D-printed polymer materials for dental applications has steadily increased in recent years due to the many benefits that these materials offer.

One of the major advantages of 3D-printed polymer materials in dentistry is the ability to create customized, patient-specific appliances or treatment accessories. Traditional manufacturing methods often use pre-made molds or templates that are less precise and may not fit the unique oral anatomy of a patient. With 3D printing, dentists can design and print products that are tailored to each patient's specific needs and oral dimensions. The result is a better fit and more comfortable and effective treatment.

Another advantage of 3D-printed polymer materials is their durability and strength. Many of these materials were specifically developed for use in dentistry and can withstand the high forces and wear that are common in the oral environment. This makes them well suited for use in dental prosthetics and other applications where a durable, reliable product is required.

In addition to their strength and conformability, 3D-printed polymer materials are also highly biocompatible, meaning they are unlikely to cause an adverse reaction in the body. On the other hand, Bisphenol A (BPA)-based monomers are common in dental resin-based materials dedicated to 3D printing. The highest amounts of BPA are released from conventional composites. However, it should be clear if and how much Bisphenol A is leaching from the 3D-printed polymer matrix over time since it is a proven endocrine disruptor, albeit a key building block of polycarbonate plastic and a precursor for the manufacturing of monomers of epoxy resins. Due to its hormone-like properties, BPA may bind to estrogen receptors, thereby affecting both body weight and tumorigenesis. BPA may also affect metabolism and cancer progression by interacting with GPR30 and may impair male reproductive function by binding to androgen receptors. This is particularly important in dental applications of 3D-printed appliances and accessories, where close contact with mucous membranes and other sensitive tissue is common.

In addition to various clinical implementations, 3D-printed polymer materials are also being used in material research and dental education. Researchers are using these materials to study their mechanical properties, and compatibility with dental tissues, as well as developing new treatments and therapies. In education, 3D-printed models of teeth and other dental structures are used to teach students about the anatomy and function of the mouth and to practice various procedures.

In conclusion, the use of 3D-printed polymer materials in dentistry has the potential to revolutionize the way that dental appliances and accessories are designed and manufactured. With their ability to be customized, strength and durability, and biocompatibility, these materials offer many advantages over conventional materials and are likely to play an increasingly important role in the field of dentistry in the coming years.

Dr. Andrej Thurzo
Prof. Dr. Radovan Hudák
Dr. Marián Janek
Dr. Viktoria Rajtukova
Guest Editors

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Keywords

  • 3D-printed polymers
  • polymer-based material
  • dental applications of 3D printing
  • resin composites
  • dental polymers
  • clinical applications of 3D printed composite accessories
  • 3D printing in medical and dental applications
  • polymers
  • dentistry
  • medicine
  • biomaterials
  • scaffolds

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Published Papers (4 papers)

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Research

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17 pages, 9213 KiB  
Article
Comparative Analysis of Modern 3D-Printed Hybrid Resin-Ceramic Materials for Indirect Restorations: An In Vitro Study
by Miriam Albrecht, Franziska Schmidt, Franziska Menzel, Jamila Yassine, Florian Beuer and Alexey Unkovskiy
Polymers 2024, 16(22), 3161; https://doi.org/10.3390/polym16223161 - 13 Nov 2024
Viewed by 1092
Abstract
The study investigated the impact of aging on surface roughness, color stability, and biocompatibility of hybrid resin-ceramic materials. A total of 225 specimens were produced from three three-dimensional (3D)-printed (HarzLabs Dental Sand Pro (HL), BEGO VarseoSmile Crown plus (BV), Voco V-Print c&b temp [...] Read more.
The study investigated the impact of aging on surface roughness, color stability, and biocompatibility of hybrid resin-ceramic materials. A total of 225 specimens were produced from three three-dimensional (3D)-printed (HarzLabs Dental Sand Pro (HL), BEGO VarseoSmile Crown plus (BV), Voco V-Print c&b temp (VV)) and one milled material (Voco Grandio Blocs (VG)). Specimens were grouped into untreated, polished, and glazed surfaces. 5000 thermal cycles simulated aging. Surface roughness and color stability were analyzed, and surface topography was observed using scanning electron microscopy (SEM). Biocompatibility was evaluated with L929 cells. Surface roughness differed significantly between untreated and other groups, with no changes before and after artificial aging. Untreated milled samples were significantly smoother than 3D-printed ones. SEM analysis revealed roughest surfaces in untreated 3D-printed specimens. Polished and glazed specimens were smoother than untreated ones. Color values showed significant differences between untreated and treated/aged groups. No material showed cytotoxicity. In summary, untreated VG was smoother than 3D-printed materials, but polishing and glazing reduced roughness to levels comparable to VG. Surface treatments induced color changes, with glazing causing more changes than polishing. Aging affected color stability and biocompatibility but not surface roughness. All materials showed acceptable color changes and good biocompatibility. Full article
(This article belongs to the Special Issue 3D-Printed Polymer and Composite Materials for Dental Applications)
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15 pages, 1979 KiB  
Article
Color-Stable Formulations for 3D-Photoprintable Dental Materials
by David Bassenheim, Kai Rist, Norbert Moszner, Yohann Catel, Robert Liska and Patrick Knaack
Polymers 2024, 16(16), 2323; https://doi.org/10.3390/polym16162323 - 16 Aug 2024
Viewed by 920
Abstract
Color stability is crucial for dental materials to ensure they perfectly match a patient’s tooth color. This is particularly challenging in photoresist-based additive manufacturing. Although some studies have addressed this issue, the exact causes of discoloration and ways to minimize it remain unclear. [...] Read more.
Color stability is crucial for dental materials to ensure they perfectly match a patient’s tooth color. This is particularly challenging in photoresist-based additive manufacturing. Although some studies have addressed this issue, the exact causes of discoloration and ways to minimize it remain unclear. In this study, the intrinsic causes of discoloration in materials intended for 3D printing are investigated by examining thin-film samples (1200 µm) of various compositions, which are stored under different conditions. The samples are evaluated by measuring the UV-Vis absorption spectra at regular intervals to monitor changes. The findings reveal that both the composition of the formulations and the storage conditions significantly influence the discoloration behavior. Furthermore, methods have been developed to reduce or completely prevent discoloration. The use of photoinitiators with sterically demanding benzoyl moieties, as well as the addition of stabilizers, effectively decreases the intensity of emerging discoloration. Furthermore, incorporating the oxidizing agent cumene hydroperoxide (CHP) results in materials that maintain color stability. Full article
(This article belongs to the Special Issue 3D-Printed Polymer and Composite Materials for Dental Applications)
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17 pages, 4766 KiB  
Article
Coffee Staining and Simulated Brushing Induced Color Changes and Surface Roughness of 3D-Printed Orthodontic Retainer Material
by Durgesh Bangalore, Abdullah M. Alshehri, Omar Alsadon, Samer M. Alaqeel, Omar Alageel, Majed M. Alsarani, Haitham Almansour and Obaid AlShahrani
Polymers 2023, 15(9), 2164; https://doi.org/10.3390/polym15092164 - 1 May 2023
Cited by 10 | Viewed by 2336
Abstract
This in vitro study evaluated the influence of combined coffee staining and simulated brushing-induced color changes and surface roughness on 3D-printed orthodontic retainers. Specimens measuring 10 × 10 × 0.75 mm3 were obtained either by conventional vacuum forming or 3D printing at [...] Read more.
This in vitro study evaluated the influence of combined coffee staining and simulated brushing-induced color changes and surface roughness on 3D-printed orthodontic retainers. Specimens measuring 10 × 10 × 0.75 mm3 were obtained either by conventional vacuum forming or 3D printing at four print angulations (0°, 15°, 30°, and 45°) (n = 10). The prepared specimens were immersed in a coffee beverage and then mechanically brushed using a simulating device. The specimen’s color difference (ΔE) and surface roughness (Ra) were quantified using a spectrophotometer and a non-contact profilometer, respectively. The highest and lowest mean ΔE values were recorded for the 3D-printed-45° (4.68 ± 2.07) and conventional (2.18 ± 0.87) groups, respectively. The overall mean comparison of ΔE between the conventional and 3D-printed groups was statistically significant (p < 0.01). After simulated brushing, all groups showed a statistically significant increase in the Ra values (p < 0.01). The highest Ra was in the 3D-printed-45° (1.009 ± 0.13 µm) and conventional (0.743 ± 0.12 µm) groups, respectively. The overall ΔE of 3D-printed orthodontic retainers was not comparable to conventional VFRs. Among the different angulations used to print the retainers, 15° angulations were the most efficient in terms of color changes and surface roughness and were comparable to conventional VFRs. Full article
(This article belongs to the Special Issue 3D-Printed Polymer and Composite Materials for Dental Applications)
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Review

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26 pages, 5713 KiB  
Review
Three-Dimensionally-Printed Polymer and Composite Materials for Dental Applications with Focus on Orthodontics
by Daniela Tichá, Juraj Tomášik, Ľubica Oravcová and Andrej Thurzo
Polymers 2024, 16(22), 3151; https://doi.org/10.3390/polym16223151 - 12 Nov 2024
Cited by 2 | Viewed by 2458
Abstract
Three-dimensional printing has transformed dentistry by enabling the production of customized dental restorations, aligners, surgical guides, and implants. A variety of polymers and composites are used, each with distinct properties. This review explores materials used in 3D printing for dental applications, focusing on [...] Read more.
Three-dimensional printing has transformed dentistry by enabling the production of customized dental restorations, aligners, surgical guides, and implants. A variety of polymers and composites are used, each with distinct properties. This review explores materials used in 3D printing for dental applications, focusing on trends identified through a literature search in PubMed, Scopus, and the Web of Science. The most studied areas include 3D-printed crowns, bridges, removable prostheses, surgical guides, and aligners. The development of new materials is still ongoing and also holds great promise in terms of environmentally friendly technologies. Modern manufacturing technologies have a promising future in all areas of dentistry: prosthetics, periodontology, dental and oral surgery, implantology, orthodontics, and regenerative dentistry. However, further studies are needed to safely introduce the latest materials, such as nanodiamond-reinforced PMMA, PLA reinforced with nanohydroxyapatite or magnesium, PLGA composites with tricalcium phosphate and magnesium, and PEEK reinforced with hydroxyapatite or titanium into clinical practice. Full article
(This article belongs to the Special Issue 3D-Printed Polymer and Composite Materials for Dental Applications)
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