Magnetite, Fe
3O
4, is a promising anode material for lithium ion batteries due to its high theoretical capacity (924 mA h g
−1), high density, low cost and low toxicity. However, its application as high capacity anodes is still
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Magnetite, Fe
3O
4, is a promising anode material for lithium ion batteries due to its high theoretical capacity (924 mA h g
−1), high density, low cost and low toxicity. However, its application as high capacity anodes is still hampered by poor cycling performance. To stabilize the cycling performance of Fe
3O
4 nanoparticles, composites comprising Fe
3O
4 nanoparticles and graphene sheets (GS) were fabricated. The Fe
3O
4/GS composite disks of mm dimensions were prepared by electrostatic self-assembly between negatively charged graphene oxide (GO) sheets and positively charged Fe
3O
4-APTMS [Fe
3O
4 grafted with (3-aminopropyl)trimethoxysilane (APTMS)] in an acidic solution (pH = 2) followed by
in situ chemical reduction. Thus prepared Fe
3O
4/GS composite showed an excellent rate capability as well as much enhanced cycling stability compared with Fe
3O
4 electrode. The superior electrochemical responses of Fe
3O
4/GS composite disks assure the advantages of: (1) electrostatic self-assembly between high storage-capacity materials with GO; and (2) incorporation of GS in the Fe
3O
4/GS composite for high capacity lithium-ion battery application.
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