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Current Trends in Metal-Organic Framework for Environment and Catalysis

A special issue of International Journal of Molecular Sciences (ISSN 1422-0067). This special issue belongs to the section "Materials Science".

Deadline for manuscript submissions: closed (31 August 2023) | Viewed by 2181

Special Issue Editor


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Guest Editor
WPI-MANA, National Institute for Materials Science (NIMS), Tsukuba 305-0044, Japan
Interests: metal-organic frameworks; porous carbon; carbon dots; fullerene self-assembly; nanoarchitechtonics; heterogeneous catalysis; adsorption; sensing; supercapacitor; electrocatalysis; battery

Special Issue Information

Dear Colleagues,

In recent years, metal–organic frameworks (MOFs) have been recognized as an emerging class of crystalline porous materials and attracted tremendous interest. Numerous MOFs have been developed and found to be promising materials in a wide variety of fields because of their structural, textural, and functional diversity and tunability. Current trends in MOF research have mostly focused on finding a way to use MOFs or MOF-related materials in real-world applications. There are different kinds of devices/systems, such as gas storage/separation, adsorption in polar/non-polar media, molecular sensing, drag storage/delivery, and catalysis, developed using MOF-related materials. Moreover, the performance or new functionalities may be added to a MOF structure via suitable incorporation of secondary metals or ligands to obtain MOFs with bi-metals and bi-ligands, respectively. Moreover, MOFs are very promising materials for composites with other materials, utilizing their pore spaces and metal/ligand sites, which generally result in better functionality in various applications. In addition, MOFs including pristine, bimetallic, and composites are often used as a precursor to obtain fascinating nanohybrid carbon materials with impressive results in adsorption, catalysis, storage/separations, sensing, etc.

This Special Issue on “Current Trends in the Metal–Organic Framework for Environment and Catalysis” welcomes original scientific research articles, comprehensive reviews, and communications in relevant research areas focusing on the design, synthesis, post-modification, and characterization of MOFs (pristine, bimetallic, and composites) and their derived carbons for environmental remediation through adsorption, storage/separation, catalysis, and sensing.

Dr. Biswa Nath Bhadra
Guest Editor

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Keywords

  • metal-organic framework
  • composite MOFs
  • bimetallic-MOFs
  • MOF-membrane
  • MOF-derived carbon
  • adsorption
  • storage
  • separation
  • catalysis

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Published Papers (1 paper)

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Research

15 pages, 10448 KiB  
Article
Fluorescence-Responsive Detection of Ag(I), Al(III), and Cr(III) Ions Using Cd(II) Based Pillared-Layer Frameworks
by Qi-Jin Jiang, Po-Min Chuang and Jing-Yun Wu
Int. J. Mol. Sci. 2023, 24(1), 369; https://doi.org/10.3390/ijms24010369 - 26 Dec 2022
Cited by 4 | Viewed by 1833
Abstract
Two Cd(II) based coordination polymers, {Cd3(btc)2(BTD-bpy)2]∙1.5MeOH∙4H2O}n (1) and [Cd2(1,4-ndc)2(BTD-bpy)2]n (2), where BTD-bpy = bis(pyridin-4-yl)benzothiadiazole, btc = benzene-1,3,5-tricarboxylate, and 1,4-ndc = naphthalene-1,4-dicarboxylate, were hydro(solvo)thermally [...] Read more.
Two Cd(II) based coordination polymers, {Cd3(btc)2(BTD-bpy)2]∙1.5MeOH∙4H2O}n (1) and [Cd2(1,4-ndc)2(BTD-bpy)2]n (2), where BTD-bpy = bis(pyridin-4-yl)benzothiadiazole, btc = benzene-1,3,5-tricarboxylate, and 1,4-ndc = naphthalene-1,4-dicarboxylate, were hydro(solvo)thermally synthesized. Compound 1 has a three-dimensional non-interpenetrating pillared-bilayer open framework with sufficient free voids of 25.1%, which is simplified to show a topological (4,6,8)-connected net with the point symbol of (324256)(344454628)(3442619728). Compound 2 has a three-dimensional two-fold interpenetrating bipillared-layer condense framework regarded as a 6-connected primitive cubic (pcu) net topology. Compounds 1 and 2 both exhibited good water stability and high thermal stability approaching 350 °C. Upon excitation, compounds 1 and 2 both emitted blue light fluorescence at 471 and 479 nm, respectively, in solid state and at 457 and 446 nm, respectively, in the suspension phase of H2O. Moreover, compounds 1 and 2 in the suspension phase of H2O both exhibited a fluorescence quenching effect in sensing Ag+, attributed to framework collapse, and a fluorescence enhancement response in sensing Al3+ and Cr3+, ascribed to weak ion–framework interactions, with high selectivity and sensitivity and low detection limit. Full article
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