Cuprous oxide (Cu
2O) nanocubes were synthesized by reducing Cu(OH)
2 in the presence of sodium citrate at room temperature. The samples were characterized in detail by field-emission scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscopy, X-ray powder diffraction, and
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Cuprous oxide (Cu
2O) nanocubes were synthesized by reducing Cu(OH)
2 in the presence of sodium citrate at room temperature. The samples were characterized in detail by field-emission scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscopy, X-ray powder diffraction, and N
2 absorption (BET specific surface area). The equations for acquiring reaction kinetic parameters and surface thermodynamic properties of Cu
2O nanocubes were deduced by establishment of the relations between thermodynamic functions of Cu
2O nanocubes and these of the bulk Cu
2O. Combined with thermochemical cycle, transition state theory, basic theory of chemical thermodynamics, and
in situ microcalorimetry, reaction kinetic parameters, specific surface enthalpy, specific surface Gibbs free energy, and specific surface entropy of Cu
2O nanocubes were successfully determined. We also introduced a universal route for gaining reaction kinetic parameters and surface thermodynamic properties of nanomaterials.
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