1. Introduction
In metallurgical processes, such as the argon-oxygen decarburization (AOD) converter and ladle furnace, the use of submerged gas nozzles and tuyeres is a major part of the process design. Nozzles or tuyeres are used to inject gas below the surface of the molten metal to cause reactions and stirring. In other metallurgical processes, such as the electric arc furnace (EAF) and blast furnace, submerged oxy-fuel burners are used with combustible gas to provide heat in local regions.
In the AOD converter, oxygen is injected to react with and to reduce the amount of dissolved carbon in the steel. The blowing of oxygen is also often combined with inert gases such as argon and nitrogen to prevent the unnecessary oxidation of chromium, which is a valuable alloy in the steel. Additionally, gas injections are used to provide stirring to the process. Due to the extreme conditions in the melt, a mechanical stirring by impeller is hard to achieve, as the impeller will quickly wear down from the heat and reactions with the steel. By injecting gas into the melt, the bubbles which form will provide stirring by the drag they produce when rising to the surface [
1].
Depending on the gas blowing parameters, the gas will either form discrete bubbles or a plume of coalescing bubbles. For use with low flow rates of gas, porous plugs or tuyeres are often used during bottom blowing in the ladle. These bubbles are mainly propelled by buoyancy and rise dependent on the ratio of the gas to melt density. For higher gas flows, side-blowing through a nozzle can be used to create a gas jet that propagates further into the melt. The gas is propelled into the melt with a high velocity and then rises due to buoyancy.
In most metallurgical processes, the gas is injected at ambient temperature or slightly below ambient temperature due to compression effects [
2]. The contact with the hot molten metal leads to a rapid heating of the gas, which causes an expansion according to the natural gas law (Equation (1), where P is pressure, V is the volume, n is the amount of mole of gas, R is the gas constant, and T is the temperature). This expansion is partially counteracted by the increasing hydrostatic pressure from the weight of the molten steel above the nozzle (Equation (2) [
3], where ρ is the density, g is the gravity, and h is the liquid height).
It is very difficult to directly measure or study the gas penetration and plume behavior in metallurgical systems due to the high temperature and opaque nature of liquid metals. Instead, the gas behavior is commonly predicted by using a combination of water modelling and Computational Fluid Dynamics. Studies of the air–water system can be applied to the gas–metal system by scaling based on dimensionless numbers, such as the modified Froude number. The modified Froude number (N
Fr’) is based on the ratio of inertial forces to buoyancy forces and is defined either as Equation (3) or Equation (4) [
4].
where the density of gas (ρ
g) and liquid (ρ
l), gravitational acceleration (g), and diameter of the inlet (d
0) in the system is used together with the inlet velocity (u
0) or the flow rate of the gas (Q
g). The two definitions result in values that differ by a factor of π
2/16, which is quite significant. For bottom blowing applications, there are other suggested formulations for the modified Froude number that are more appropriate when determining the plume behavior, as studied by Krishnapisharody and Irons [
4]. For this study, the calculated penetration length is defined as a range between the values calculated using Equations (3) and (4).
The gas flow and dimensions of the inlet and reactor are scaled down to the water model to achieve a kinematic similarity between the water model and the industrial reactor. Based on verifying the physical experiments in the air–water system, a mathematical model can be set up in CFD and then scaled up to use the velocities and densities of the gas and liquids in the metallurgical system. This allows for accurate predictions of the bubble behavior in the metallurgical process without the need to measure it directly [
5].
If the modified Froude number is equal in the model and the reactor, the flow behavior is expected to be similar. The flowrate for dynamic similarity can be determined by using Equation (5) [
6]:
where Q
m is the flowrate of the model, Q
r indicates the flowrate of the reactor, and λ is the geometric scaling factor between the reactor and the experimental setup. The latter is usually in the range of 1:3 to 1:10, which results in λ values of 1/3 to 1/10. To ensure equal modified Froude numbers, the diameter of the inlet (d
0) does not follow the geometric scaling and is instead designed to satisfy Equation (6) [
7].
Once an appropriate scaling is done, the model should produce results that are representative for the industrial size reactor. Based on this approach, several studies have been carried out to study the flow behavior in metallurgical processes [
5,
6,
7,
8,
9,
10,
11,
12].
Physical experiments to describe the jet trajectory of gas into liquid were first done by Themelis et al. to study the gas-blowing behavior in a copper converter [
5]. The penetration length (L
p) of side-blown gas jets in metallurgical applications has since then been studied using physical experiments in several different gas–liquid systems at room temperature, a few of which are listed in
Table 1.
The experimental results from Hoefele and Brimacombe were used to establish an empirical equation for the penetration length (L
p) of gas based on the modified Froude number in Equation (3), the diameter of the inlet, and the densities of the gas and liquid [
8]. This empirical equation is widely used today and shown in Equation (7).
Other empirical equations to describe the penetration length (L
p) have also been developed by Igwe et al. (Equation (8)), where the inlet pressure (P
1) is used as a scaling factor [
13]; by Ishibashi et. al. [
14] (Equation (9)), who used the modified Froude number; and by Han et al. [
15] (Equation (10), who developed one similar to the equation presented by Brimacombe et al.
The behavior of a submerged gas jet in liquid is inherently unsteady and turbulent, which makes accurate assessment of the penetration length problematic. In previous studies, it has been found that the stability of the submerged jet is dependent on the nozzle diameter and geometry, as well as the modified Froude number [
16]. Lin et al. also showed that increasing density ratios between the gas and liquid decreased the stability of the jet further [
17].
In addition to the penetration length of the gas jet, the expansion angle of the gas jet has been found to be controlled by the ratio of the gas to liquid densities. Work by Oryall and Brimacombe found that the expansion angle of the injected gas into the ambient liquid is dependent on the liquid density rather than on the modified Froude number. This may cause significant back-expansion in metallurgical processes, which is not observed in water-model experiments. The expansion angle for air in mercury was found to be 155°, but in the air–water system the same angle was found to be only 20° [
9]. This angle is most likely different depending on the application, which further complicates the prediction of penetration length in the actual process. Harby et al. also found that the expansion angle of gas was dependent on the nozzle diameter and flow rate of gas, but less so for low modified Froude numbers. Additionally, an increasing nozzle diameter and decreasing gas flow rate significantly increased the oscillation of the jet [
18].
The entrainment of liquid droplets in a jet stream of air may also be significant when determining the penetration length and plume behavior of the gas injection. Depending on the modified Froude number and the jet velocity at the inlet, different amounts of ambient liquids will be entrained in the gas jet and increase the mass flux of the jet [
18]. This will lead to increased modified Froude numbers if the injected gas has a higher apparent density than the pure gas due to the entrained liquid droplets.
The oscillations of the reactor, as present in the AOD process, are caused by the gas injection and has been studied thoroughly by Odenthal et al. and Fabritius et al., who found that reactor oscillations are prominent when the penetration lengths of the gas jets are too large [
12,
19]. However, the oscillations of the actual gas jet are expected to decrease with an increasing gas flow and modified Froude number [
16]. As presented by Hoefele and Brimacombe, the oscillation frequency of the gas jet also decreases when blowing in a high-density liquid such as mercury as compared to water or a zinc-chloride solution [
8]. It is expected that oscillations of the gas jet are caused when the gas flow is insufficient to form a steady stream of gas, instead the hydrostatic pressure of the liquid surrounding it will cause the gas to collapse and form discrete bubbles. This oscillation of the gas jet with high amplitudes is likely not present at high gas flow rates, as studied by Fabritius and Odenthal, instead some other property of the gas blowing is causing the reactor oscillations.
In the IronArc process, a plasma generator (PG) is used for injection of the reaction gas by side-blowing into the reactor. The PG superheats the gas by passing it through an electric arc before injecting it into the molten metal or slag. Since the gas is superheated, when it is injected into the reactor it will not expand in the same way as when blowing with cold gas. It will instead have a much higher velocity and lower density than gas injected at ambient temperature in established metallurgical processes. Depending on the power settings and gas flow in the PG, the temperature, velocity, and kinetic energy of the gas can be controlled [
20].
All the previously listed equations for the penetration length and scaling assume isothermal systems and do not account for the surface tension between phases. The assumptions in these equations may be valid for the studied systems of molten metal and cold injected gas, but it is not certain that they are universal and cover the IronArc system of the molten slag and hot injected gas. The experimental studies were done in a large range of modified Froude numbers from 5–11,000, but a soft lower limit of 200–500 was also indicated by Brimacombe and Oryall for where the behavior changes from a bubbly flow to a jetting flow [
8]. Below this limit the jet is extremely unstable and has large amplitudes in the oscillations due to the bubbles, which also makes measurement of the penetration length quite uncertain.
To include the effect of surface tension, work by Zhao and Irons [
21] suggest that a Weber number criterion is more appropriate for prediction of the penetration length than the modified Froude number criterion as previously used. However, more recent work by Ma et. al. [
22] used the Buckingham pi theorem to develop a new dimensionless formation for the penetration depth based on the modified Froude number combined with the Reynolds number. From the work by Ma et al., it was further confirmed that the widely used equation of the penetration length by Hoefele (Equation (7)) is well suited for high Fr’ numbers but not for low Fr’ numbers, where it severely underpredicts the penetration length.
The injection of hot gas through a PG may not produce the same behavior in terms of the penetration length of the gas jet as with a cold gas through a nozzle. This, in turn, will affect the bubble plume and stirring of the melt inside the reactor. Previous studies of the penetration length and mixing time in the IronArc reactor were performed by Bölke et al. with the assumption that scaling from a physical model in the air–water system using the previously presented equations appropriately reflected the flow behavior in the IronArc reactor [
23].
The gas behavior of a hot gas entering a hot liquid is perhaps more like the water model than metallurgical systems using cold gas that will expand in the reactor. However, in the work by Odenthal et al., the compressibility and thermal expansion was included when the initial penetration of the gas jet was modelled. A good agreement was found with the empirical equation (Equation (7)) by Brimacombe et. al. at the working point of the AOD at a modified Froude number of 3268 [
12].
Experiments in an air–water system as a scale replica of the IronArc reactor by Bölke et al. suggests that the empirical equation by Brimacombe and Oryall significantly underpredicts the penetration length for the IronArc reactor. However, those simulations were done with low modified Froude numbers from 2–90, which may be below the threshold for a jetting behavior [
24]. At such conditions, the pulsing behavior of the jet would make accurate measurements of the actual penetration length impossible.
The current work aims to study the behavior of gas blowing in liquids for varying gas and liquid densities and surface tensions. An accurate modelling of the gas blowing behavior from a plasma generator is important to determine the viability of the IronArc reactor, due to the requirements on stirring and refractory. The lower limit on the modified Froude numbers for valid calculations using the empirical equation in Equation (7) will be investigated for the IronArc system.
4. Discussion
The gas blowing simulations in the incompressible air–water system fit reasonably well to the experimental work in the air–water system by Chanouian and Ahlin, which is used as validation for the study [
32]. The simulations in the compressible air–water system are similar to the incompressible system, with the main difference being the higher density of the gas because of the high-pressure conditions. As shown in
Table 10, Equation (7) predicts very similar penetration lengths for the incompressible and compressible simulations in the air–water system despite the slightly different velocities and densities of the systems. The increased density of the gas in the compressible system compensates for the slightly lower inlet velocity that sets almost equally predicted penetration lengths. However, the simulated penetration length of the incompressible and compressible models differs by 17%.
The mesh sensitivity analysis revealed that the mesh had a significant impact on the apparent pressure at the inlet in the compressible air–water system. This resulted in increasing velocities and measured penetration lengths with finer meshes, as can be seen in
Table 2 and
Table 3. This is thought to be caused by the poor resolution of the mesh in the areas above the inlet, which leads to differences in the calculation of the hydrostatic pressure. The large plume of gas above the inlet lowers the average density of the fluid, which leads to fluctuations in the hydrostatic pressure which, in turn, affect the stability and velocity of the injected gas jet. This phenomenon needs to be studied further to ensure that the simulations are sufficiently mesh independent to produce a reliable result. This behavior was also observed in the compressible simulations in the IronArc system, but to a lesser degree as the mesh dependence of these variables was only present when switching from the coarse mesh to the medium mesh, not from the medium mesh to the fine mesh.
Despite a 17% difference between the results from the incompressible and compressible simulations in the air–water system, the incompressible simulation setup was used for the study of the varying density ratios. This is motivated by that the incompressible simulation required approximately a third of the computational time as compared to the compressible simulation setup in the air–water system. Since the density variations are performed at isothermal conditions at ambient temperature, the impact of running the study in the incompressible system is expected to be small. The one property which is not considered when running the incompressible system is the changing density of the gas due to the hydrostatic pressure. As was observed in the air–water system, the pressure effect changed the density of the gas to 1.36 kg·m−3 from 1.2 kg·m−3 at the expense of velocity, which resulted in the very similar modified Froude numbers and mass flows of the simulations. For the systems with a ZnCl solution and mercury as the liquid the hydrostatic pressure will be significantly higher than in the air–water system, which may affect the density of a gas significantly.
From the varying density simulations, it was apparent that the density ratio between the liquid and gas affect the stability of the gas jet, even when equal inlet velocities are used. This behavior has also been observed previously by Lin et. al., who showed that increasing density ratios between the gas and liquid decreased the stability of the jet [
17]. Additionally, increasing nozzle diameters and decreasing gas flow rates have also been shown to significantly increase the oscillation of the jet [
18]. These three effects are connected since both increasing density ratios, increasing nozzle diameters, and decreasing gas flow rates will affect the modified Froude number of the gas blowing. A lower modified Froude number has previously been suspected to cause instabilities in the gas jet, as shown previously by Hoefele and Brimacombe [
8]. If the modified Froude number is too low the gas plume will experience a bubbling and pulsing behavior rather than a jetting behavior. Bubbling and pulsing are analogous to an unstable jet and should be avoided to achieve good mixing and avoid interactions between the gas and the refractory wall. A clear example of a bubbling and pulsating jet can be seen in
Figure 7 for the low-pressure simulation of the IronArc system. In this image, the rising plume can clearly be seen in contact with the wall of the domain since the modified Froude number of the gas blowing is too low.
The diagram of the gas blowing behavior presented by Brimacombe and Hoefele indicates that in order to ensure a steady jetting in the IronArc system, a modified Froude number of over 5000 is required. To reach such modified Froude numbers in the current geometry in the IronArc system, a velocity of approximately 5000 m·s
−1 is required in the inlet, which is not feasible to simulate in this work. Instead, the lower end of the jetting region was investigated in the IronArc system by performing simulations of increasing pressures until a steady jetting behavior was found. However, there is no strict modified Froude number limit for when the gas plume shifts from a bubbling and pulsing to a jetting behavior. It is rather a soft transition that is system dependent and, for the IronArc system, starts at modified Froude numbers of roughly 300, below which the flow has significant bubbling and pulsing characteristics, and ends at modified Froude numbers around 5000, where the flow has pure jetting characteristics. As presented in
Table 12, the penetration length for simulations with a low pressure are way underpredicted by Equation (7) since the pulsing of the gas reaches far out into the domain and skews the measurements. When the simulations are done with higher pressure, the predicted penetration length from Equation (7) and the simulated penetration length are much more similar. From these results it is determined that the lower limit for the modified Froude number for a jetting behavior in the IronArc system is 300. However, due to the large variations in velocity over time in the simulations, the jet is not always sufficiently stable and collapses, causing some pulsations even at the highest studied pressure.
The same behavior can be seen in the density variation simulations where it is apparent that the significantly different modified Froude numbers of the systems are correlated to the accuracy of Equation (7). As can be seen in the plot in
Figure 6, the modified Froude number and the accuracy of Equation (7) is closely correlated for all the studied systems. In fact, the same limit that indicates when the blowing will exhibit a jetting behavior appears to be the lower limit for when Equation (7) will accurately predict the penetration length of the gas jet.
However, the lower limit of the modified Froude number is system dependent, as is evident in
Figure 6, where simulations in different systems with similar modified Froude numbers show very different accuracies. Further work has to be done to determine if the system dependence is based in the density ratio as previously theorized or if another property, such as the viscosity of the liquid and/or gas, is the controlling factor. The jet behavior and accuracy of Equation (7) should also be studied for higher modified Froude numbers to see if the accuracy is stable after a certain modified Froude number or if it diverges at higher values.
This knowledge about the gas blowing allows us to improve the design of the inlets in many metallurgical processes to ensure that the gas injection is exhibiting a jetting behavior. To ensure a jetting behavior and a predictable penetration length, the modified Froude number of the gas injection should be increased. This can easily be done by reducing the diameter of the inlet where the plasma generator connects to the reactor to increase the modified Froude number of the gas blowing. When applying this change, calculations using Equation (7) shows that the actual penetration length will not increase when a smaller inlet is used, but rather decrease if used with the same inlet velocity. However, the higher modified Froude number indicates that the jet will be more stable and exhibit a less pulsating and bubbling behavior. A change in the inlet diameter while maintaining the volume flow rate through the nozzle would result in a higher velocity of the gas and an increased pressure requirement to propel the flow. This would further increase the penetration length and the modified Froude number, resulting in an even more stable jet. This theorized behavior of the gas jet should be studied further in future simulations to confirm the behavior.
A possible source of error in the simulations is that the penetration length from the simulations cannot be directly compared to Equation (7), since they are dependent on the bath height above the inlet that is not considered in the equation. The hydrostatic pressure is very important since it affects both the velocity (which is accounted for in the equation) but also the pulse amplitude and frequency. If the pulse amplitude and frequency changes, the average penetration length is hard to measure and the flow pattern will change in the domain.
For further studies, it would also be of interest to study how much of an effect the temperature of the gas has on the penetration length and gas plume behavior, as well as to determine if this needs to be considered when determining the required modified Froude number for jetting or if the changing density with increased temperature is sufficient.