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21 pages, 8234 KiB

Open AccessFeature PaperArticle

Different Tectonic Evolution of Fast Cooling Ophiolite Mantles Recorded by Olivine-Spinel Geothermometry: Case Studies from Iballe (Albania) and Nea Roda (Greece)

by Micol Bussolesi, Giovanni Grieco, Alessandro Cavallo and Federica Zaccarini

Minerals 2022, 12(1), 64; https://doi.org/10.3390/min12010064 - 4 Jan 2022

Cited by 10 | Viewed by 3274

Abstract

Mg-Fe²⁺ diffusion patterns in olivine and chromite are useful tools for the study of the thermal history of ultramafic massifs. In the present contribution, we applied the exponential modeling of diffusion patterns to geothermometry and geospeedometry of chromitite ores from two different [...] Read more.

Mg-Fe²⁺ diffusion patterns in olivine and chromite are useful tools for the study of the thermal history of ultramafic massifs. In the present contribution, we applied the exponential modeling of diffusion patterns to geothermometry and geospeedometry of chromitite ores from two different ophiolite contexts. The Iballe ophiolite (Northern Albania) hosts several chromitite pods within dunites. Primary and re-equilibrated Mg#, estimated by using an exponential function, provided re-equilibration and primary temperatures ranging between 677 and 996 °C for chromitites and between 527 and 806 °C for dunites. Cooling rates for chromitites are higher than for dunites, suggesting a different genesis for the two lithologies, confirmed also by spinel mineral chemistry. Chromitites with MORB affinity formed in a SSZ setting at a proto-forearc early stage, explaining the higher cooling rates, while dunites, with boninitic affinity, were formed deeper in the mantle in a more mature subduction setting. At the Nea Roda ophiolite (Northern Greece) olivine in chromitites do not show Mg-Fe variations, and transformation into ferrian chromite produced “fake” diffusion patterns within chromite. The absence of diffusion patterns and the low estimated temperatures (550–656 °C) suggest that Nea Roda chromitites were completely re-equilibrated during an amphibolite-facies metamorphic event that obliterated all primary features. Full article

(This article belongs to the Special Issue Chromite Deposits: Mineralogy, Petrology and Genesis)

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23 pages, 8595 KiB

Open AccessArticle

Chromite-PGM Mineralization in the Lherzolite Mantle Tectonite of the Kraka Ophiolite Complex (Southern Urals, Russia)

by Giorgio Garuti, Evgenii V. Pushkarev, Irina A. Gottman and Federica Zaccarini

Minerals 2021, 11(11), 1287; https://doi.org/10.3390/min11111287 - 19 Nov 2021

Cited by 2 | Viewed by 3088

Abstract

The mantle tectonite of the Kraka ophiolite contains several chromite deposits. Two of them consisting of high-Cr podiform chromitite—the Bolshoi Bashart located within harzburgite of the upper mantle transition zone and Prospect 33 located in the deep lherzolitic mantle—have been investigated. Both deposits [...] Read more.

The mantle tectonite of the Kraka ophiolite contains several chromite deposits. Two of them consisting of high-Cr podiform chromitite—the Bolshoi Bashart located within harzburgite of the upper mantle transition zone and Prospect 33 located in the deep lherzolitic mantle—have been investigated. Both deposits are enveloped in dunite, and were formed by reaction between the mantle protolith and high-Mg, anhydrous magma, enriched in Al₂O₃, TiO₂, and Na₂O compared with boninite. The PGE mineralization is very poor (<100 ppb) in both deposits. Laurite (RuS₂) is the most common PGM inclusion in chromite, although it is accompanied by erlichmanite (OsS₂) and (Ir,Ni) sulfides in Prospect 33. Precipitation of PGM occurred at sulfur fugacity and temperatures of logƒS₂ = (−3.0), 1300–1100 °C in Bolshoi Bashart, and logƒS2 = (−3.0/+1.0), 1100–800 °C in Prospect 33, respectively. The paucity of chromite-PGM mineralization compared with giant chromite deposits in the mantle tectonite in supra-subduction zones (SSZ) of the Urals (Ray-Iz, Kempirsai) is ascribed to the peculiar petrologic nature (low depleted lherzolite) and geodynamic setting (rifted continental margin?) of the Kraka ophiolite, which did not enable drainage of the upper mantle with a large volume of mafic magma. Full article

(This article belongs to the Special Issue Chromite Deposits: Mineralogy, Petrology and Genesis)

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22 pages, 4601 KiB

Open AccessArticle

Chromite Mineralization in the Sopcheozero Deposit (Monchegorsk Layered Intrusion, Fennoscandian Shield)

by Artem V. Mokrushin and Valery F. Smol’kin

Minerals 2021, 11(7), 772; https://doi.org/10.3390/min11070772 - 16 Jul 2021

Cited by 8 | Viewed by 3079

Abstract

In 1990, the Sopcheozero Cr deposit was discovered in the Monchegorsk Paleoproterozoic layered mafic-ultramafic layered intrusion (Monchepluton). This stratiform early-magmatic deposit occurs in the middle part of the Dunite Block, which is a member of the Monchepluton layered series. The Cr₂O [...] Read more.

In 1990, the Sopcheozero Cr deposit was discovered in the Monchegorsk Paleoproterozoic layered mafic-ultramafic layered intrusion (Monchepluton). This stratiform early-magmatic deposit occurs in the middle part of the Dunite Block, which is a member of the Monchepluton layered series. The Cr₂O₃ average-weighted content in ordinary and rich ores of the deposit is 16.65 and 38.76 wt.%, respectively, at gradually changing concentrations within the rich, ordinary and poor ore types and ore body in general. The ores of the Sopcheozero deposit, having a ratio of Cr₂O₃/FeO_total = 0.9–1.7, can serve as raw materials for the refractory and chemical industries. The ore Cr-spinel (magnochromite and magnoalumochromite) is associated with highly magnesian olivine (96–98 Fo) rich in Ni (0.4–1.1 wt.%). It confirms a low S content in the melt and complies with the low oxygen fugacity. The coexisting Cr-spinel-olivine pairs crystallized at temperatures from 1258 to 1163 °C, with accessory Cr-spinel crystallizing at relatively low, while ore Cr-spinel at higher temperatures. The host rock and ore distinguish with widespread plastic deformations of olivine at the postcrystallization phase under conditions of high temperature (above 400 °C) and pressure (5 kbar). At the post magmatic Svecofennian stage (1.84 Ga), the deposit, jointly with the Monchepluton, was subject to diverse tectonic deformations. Full article

(This article belongs to the Special Issue Chromite Deposits: Mineralogy, Petrology and Genesis)

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31 pages, 11043 KiB

Open AccessFeature PaperArticle

Chromite Paleoplacer in the Permian Sediments at the East Edge of the East European Platform: Composition and Potential Sources

by Ildar R. Rakhimov, Evgenii V. Pushkarev and Irina A. Gottman

Minerals 2021, 11(7), 691; https://doi.org/10.3390/min11070691 - 27 Jun 2021

Cited by 4 | Viewed by 3194

Abstract

A chromite occurrence called the Sabantuy paleoplacer was discovered in the Southern Pre-Ural region, at the east edge of the East-European Platform in the transitional zone to the Ural Foredeep. A ca. 1 m-thick chromite-bearing horizon is traced at a depth of 0.7–1.5 [...] Read more.

A chromite occurrence called the Sabantuy paleoplacer was discovered in the Southern Pre-Ural region, at the east edge of the East-European Platform in the transitional zone to the Ural Foredeep. A ca. 1 m-thick chromite-bearing horizon is traced at a depth of 0.7–1.5 m from the earth’s surface for the area of ca. 15,000 m². The chromspinel content in sandstones reaches 30–35%, maximum values of Cr₂O₃ are 16–17 wt.%. The grain size of detrital chromspinel ranges from 0.15 to 0.25 mm. Subangular octahedral crystals dominate; rounded grains and debris are rare. The composition of detrital chromspinel varies widely and is constrained by the substitution of Al³⁺ and Cr³⁺, Fe²⁺ and Mg²⁺ cations. Chemically, low-Al (Al₂O₃ = 12 wt.%) and high-Cr (Cr₂O₃ = 52–56 wt.%) chromspinel prevail. The compositional analysis using discrimination diagrams showed that most chromites correspond to mantle peridotites of subduction settings. Volcanic rocks could be an additional source for detrital chromites. It is confirmed by compositions of monomineralic, polymineralic and melt inclusions in chromspinels. The presented data indicates that ophiolite peridotites and related chromite ore associated with oceanic and island-arc volcanic rocks, widespread in the Ural orogen, could be the main sources of the detrital chromspinel of the Sabantuy paleoplacer. Full article

(This article belongs to the Special Issue Chromite Deposits: Mineralogy, Petrology and Genesis)

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36 pages, 14365 KiB

Open AccessArticle

Testing Trace-Element Distribution and the Zr-Based Thermometry of Accessory Rutile from Chromitite

by Federica Zaccarini, Giorgio Garuti, George L. Luvizotto, Yuri de Melo Portella and Athokpam K. Singh

Minerals 2021, 11(7), 661; https://doi.org/10.3390/min11070661 - 22 Jun 2021

Cited by 3 | Viewed by 2733

Abstract

Trace element distribution and Zr-in-rutile temperature have been investigated in accessory rutile from stratiform (UG2, Merensky Reef, Jacurici), podiform (Loma Peguera), and metamorphic chromitites in cratonic shields (Cedrolina, Nuasahi). Rutile from chromitite has typical finger-print of Cr-V-Nb-W-Zr, whose relative abundance distinguishes magmatic from [...] Read more.

Trace element distribution and Zr-in-rutile temperature have been investigated in accessory rutile from stratiform (UG2, Merensky Reef, Jacurici), podiform (Loma Peguera), and metamorphic chromitites in cratonic shields (Cedrolina, Nuasahi). Rutile from chromitite has typical finger-print of Cr-V-Nb-W-Zr, whose relative abundance distinguishes magmatic from metamorphic chromitite. In magmatic deposits, rutile precipitates as an intercumulus phase, or forms by exsolution from chromite, between 870 °C and 540 °C. The Cr-V in rutile reflects the composition of chromite, both Nb and Zr are moderately enriched, and W is depleted, except for in Jacurici, where moderate W excess was a result of crustal contamination of the mafic magma. In metamorphic deposits, rutile forms by removal of Ti-Cr-V from chromite during metamorphism between 650 °C and 400 °C, consistent with greenschist-amphibolite facies, and displays variable Cr-Nb, low V-Zr, and anomalous enrichment in W caused by reaction with felsic fluids emanating from granitoid intrusions. All deposits, except Cedrolina, contain Rutile+PGM composite grains (<10 µm) locked in chromite, possibly representing relics of orthomagmatic assemblages. The high Cr-V content and the distinctive W-Nb-Zr signature that typifies accessory rutile in chromitite provide a new pathfinder to trace the provenance of detrital rutile in placer deposits. Full article

(This article belongs to the Special Issue Chromite Deposits: Mineralogy, Petrology and Genesis)

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21 pages, 6484 KiB

Open AccessArticle

Accessory Cr-Spinels in the Section of the Nude-Poaz Massif in the Monchegorsk (2.5 Ga) Mafic-Ultramafic Layered Complex (Kola Peninsula, Russia): Comparison with Ore-Forming Chromites

by Tatiana Rundkvist and Pavel Pripachkin

Minerals 2021, 11(6), 602; https://doi.org/10.3390/min11060602 - 3 Jun 2021

Cited by 1 | Viewed by 2872

Abstract

The paper studies accessory Cr-spinels from deep drill holes crossing the Nude-Poaz massif, which is a part of the Monchegorsk mafic-ultramafic layered complex (2.5 Ga, Kola Peninsula, Russia). Cr-spinels occur as two morphological types that differ in their chemical composition, i.e., Cr-spinels of [...] Read more.

The paper studies accessory Cr-spinels from deep drill holes crossing the Nude-Poaz massif, which is a part of the Monchegorsk mafic-ultramafic layered complex (2.5 Ga, Kola Peninsula, Russia). Cr-spinels occur as two morphological types that differ in their chemical composition, i.e., Cr-spinels of the first type are more aluminous, while Cr-spinels of the second type are more ferruginous and titaniferous. Cr-spinels of the Nude-Poaz massif are characterized by a Fe-Ti trend known for layered intrusions in the world. Cr-spinels of the Nude-Poaz massif quite clearly differ in composition from chromites of the Sopcheozero deposit: they are more ferruginous and less chromous. The specific composition of Cr-spinels in rocks of the Nude-Poaz massif can be correlated with the sequence of the magmatic phases intrusion. Full article

(This article belongs to the Special Issue Chromite Deposits: Mineralogy, Petrology and Genesis)

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10 pages, 2103 KiB

Open AccessArticle

Genetic Link between Podiform Chromitites in the Mantle and Stratiform Chromitites in the Crust: A Hypothesis

by Shoji Arai

Minerals 2021, 11(2), 209; https://doi.org/10.3390/min11020209 - 16 Feb 2021

Cited by 9 | Viewed by 6235

Abstract

No genetic link between the two main types of chromitite, stratiform and podiform chromitites, has ever been discussed. These two types of chromitite have very different geological contexts; the stratiform one is a member of layered intrusions, representing fossil magma chambers, in the [...] Read more.

No genetic link between the two main types of chromitite, stratiform and podiform chromitites, has ever been discussed. These two types of chromitite have very different geological contexts; the stratiform one is a member of layered intrusions, representing fossil magma chambers, in the crust, and the podiform one forms pod-like bodies, representing fossil magma conduits, in the upper mantle. Chromite grains contain peculiar polymineralic inclusions derived from Na-bearing hydrous melts, whose features are so similar between the two types that they may form in a similar fashion. The origin of the chromite-hosted inclusions in chromitites has been controversial but left unclear. The chromite-hosted inclusions also characterize the products of the peridotite–melt reaction or melt-assisted partial melting, such as dunites, troctolites and even mantle harzburgites. I propose a common origin for the inclusion-bearing chromites, i.e., a reaction between the mantle peridotite and magma. Some of the chromite grains in the stratiform chromitite originally formed in the mantle through the peridotite–magma reaction, possibly as loose-packed young podiform chromitites, and were subsequently disintegrated and transported to a crustal magma chamber as suspended grains. It is noted, however, that the podiform chromitites left in the mantle beneath the layered intrusions are different from most of the podiform chromitites now exposed in the ophiolites. Full article

(This article belongs to the Special Issue Chromite Deposits: Mineralogy, Petrology and Genesis)

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32 pages, 23030 KiB

Open AccessArticle

Zones of PGE–Chromite Mineralization in Relation to Crystallization of the Pados-Tundra Ultramafic Complex, Serpentinite Belt, Kola Peninsula, Russia

by Andrei Y. Barkov, Andrey A. Nikiforov, Larisa P. Barkova, Vladimir N. Korolyuk and Robert F. Martin

Minerals 2021, 11(1), 68; https://doi.org/10.3390/min11010068 - 12 Jan 2021

Cited by 12 | Viewed by 3532

Abstract

The lopolithic Pados-Tundra layered complex, the largest member of the Serpentinite belt–Tulppio belt (SB–TB) megastructure in the Fennoscandian Shield, is characterized by (1) highly magnesian compositions of comagmatic dunite–harzburgite–orthopyroxenite, with primitive levels of high-field-strength elements; (2) maximum values of Mg# in olivine (Ol, [...] Read more.

The lopolithic Pados-Tundra layered complex, the largest member of the Serpentinite belt–Tulppio belt (SB–TB) megastructure in the Fennoscandian Shield, is characterized by (1) highly magnesian compositions of comagmatic dunite–harzburgite–orthopyroxenite, with primitive levels of high-field-strength elements; (2) maximum values of Mg# in olivine (Ol, 93.3) and chromian spinel (Chr, 57.0) in the Dunite block (DB), which exceed those in Ol (91.7) and Chr (42.5) in the sills at Chapesvara, and (3) the presence of major contact-style chromite–IPGE-enriched zones hosted by the DB. A single batch of primitive, Al-undepleted komatiitic magma crystallized normally as dunite close to the outer contact, then toward the center. A similar magma gave rise to Chapesvara and other suites of the SB–TB megastructure. Crystallization proceeded from the early Ol + Chr cumulates to the later Ol–Opx and Opx cumulates with accessory Chr in the Orthopyroxenite zone. The accumulation of Chr resulted from efficient cooling along boundaries of the Dunite block. The inferred front of crystallization advanced along a path traced by vectors of Ol and Chr compositions. Grains and aggregates of Chr were mainly deposited early after the massive crystallization of olivine. Chromium, Al, Zn and H₂O, all incompatible in Ol, accumulated to produce podiform segregations or veins of chromitites. This occurred episodically along the moving front of crystallization. Crystallization occurred rapidly owing to heat loss at the contact and to a shallow level of emplacement. The Chr layers are not continuous but rather heterogeneously distributed pods or veins of Chr–Ol–clinochlore segregations. Isolated portions of melt enriched in H₂O and ore constituents accumulated during crystallization of Ol. Levels of fO₂ in the melt and, consequently, the content of ferric iron in Chr, increased progressively, as in other intrusions of the SB–TB megastructure. The komatiitic magma vesiculated intensely, which led to a progressive loss of H₂ and buildup in fO₂. In turn, this led to the appearance of anomalous Chr–Ilm parageneses. Diffuse rims of Chr grains, abundant in the DB, contain elevated levels of Fe³⁺ and enrichments in Ni and Mn. In contrast, Zn is preferentially partitioned into the core, leading to a decoupling of Zn from Mn, also known at Chapesvara. The sulfide species display a pronounced Ni-(Co) enrichment in assemblages of cobaltiferous pentlandite, millerite (and heazlewoodite at Khanlauta), deposited at ≤630 °C. The oxidizing conditions have promoted the formation of sulfoselenide phases of Ru in the chromitites. The attainment of high degrees of oxidation during crystallization of a primitive parental komatiitic magma accounts for the key characteristics of Pados-Tundra and related suites of the SB–TB megastructure. Full article

(This article belongs to the Special Issue Chromite Deposits: Mineralogy, Petrology and Genesis)

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