Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior

Topic Information

Dear Colleagues,

The oil embargo of the 1970s ushered in a new era of lightweighting in the automotive industry, designed to reduce energy consumption and remarkably minimize transportation cost. High density structural materials such as steel and aluminum were replaced by two phase composite materials. Due to their outstanding specific properties, which are remarkably higher than those for steel and aluminum, fibrous composite materials gained ground as the alternative to the conventional structural materials. The ease of design and fabrication into complex and intricate geometries conferred additional benefit to composite materials. The progression from continuous unidirectional fibrous composites to discontinuous unidirectional short fiber composites to laminated composites and nanocomposites has been made without sacrificing the core desire for stiffer and stronger and tougher multiphase composite materials. You are invited to submit your research paper in any area of polymer composite materials, including continuous, discontinuous, and laminated fibrous composites. Papers focusing on particulate composites are also welcome. Submissions focused on nanocomposites reinforced with either graphene, organoclay, or carbon nanotubes are welcome. The availability of assorted matrix materials offers you a wide range of choice, including, but not limited to, thermoplastics, thermosets, and elastomeric matrix materials. The focus of your paper may include, but be not limited to, micromechanics and macromechanics of composite materials. The role of rheology and rheological parameters on the fabrication of composite materials are of interest to this call for papers. Papers focused on the characterization of composite materials and the environmental impact on composites are also welcome. This Topic seeks high-quality works focusing on the following topics:

• Processing of composite materials;
• Characterization of composite materials;
• Mechanical properties of composite materials;
• Additive manufacturing of composite materials;
• Composite materials in construction and rural infrastructure;
• Composite materials for energy storage applications;
• Novel methods for manufacture of composite materials;
• Laminated and hybrid composite materials;
• Manufacture of composite materials for electromagnetic interference shielding;
• Polymer based nanocomposites;
• Sustainable biocomposites;
• Antiflammable polymer nanocomposites;
• Composites for environmental remediation;
• Environmental impact of composite materials.

Prof. Dr. Jude O. Iroh
Dr. Derrick Dean
Prof. Dr. Kirill Levine
Dr. Ramakrishnan Rajagopalan
Topic Editors

Keywords

Participating Journals

Journal Name	Impact Factor	CiteScore	Launched Year	First Decision (median)	APC
Energies energies	3.0	6.2	2008	17.5 Days	CHF 2600	Submit
Journal of Composites Science jcs	3.0	5.0	2017	18.5 Days	CHF 1800	Submit
Materials materials	3.1	5.8	2008	15.5 Days	CHF 2600	Submit
Nanomaterials nanomaterials	4.4	8.5	2010	13.8 Days	CHF 2900	Submit
Polymers polymers	4.7	8.0	2009	14.5 Days	CHF 2700	Submit

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Published Papers (66 papers)

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All Energies J. Compos. Sci. Materials Nanomaterials Polymers

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18 pages, 5148 KiB  

Open AccessArticle

Effects of Titanium Dioxide (TiO₂) on Physico-Chemical Properties of Low-Density Polyethylene

by Peter P. Ndibewu, Tina E. Lefakane and Taki E. Netshiozwi

Polymers 2024, 16(19), 2788; https://doi.org/10.3390/polym16192788 - 1 Oct 2024

Viewed by 2973

Abstract

Hazardous chemicals are transported on rail and road networks. In the case of accidental spillage or terror attack, civilian and military first responders must approach the scene equipped with appropriate personal protective equipment. The plausible manufacturing of chemical protective polymer material, from photocatalyst [...] Read more.

Hazardous chemicals are transported on rail and road networks. In the case of accidental spillage or terror attack, civilian and military first responders must approach the scene equipped with appropriate personal protective equipment. The plausible manufacturing of chemical protective polymer material, from photocatalyst anatase titanium dioxide (TiO₂) doped low-density polyethylene (LDPE), for cost-effective durable lightweight protective garments against toxic chemicals such as 2-chloroethyl ethyl sulphide (CEES) was investigated. The photocatalytic effects on the physico-chemical properties, before and after ultraviolet (UV) light exposure were evaluated. TiO₂ (0, 5, 10, 15% wt) doped LDPE films were extruded and characterized by SEM-EDX, TEM, tensile tester, DSC-TGA and permeation studies before and after exposure to UV light, respectively. Results revealed that tensile strength and thermal analysis showed an increasing shift, whilst CEES permeation times responded oppositely with a significant decrease from 127 min to 84 min due to the degradation of the polymer matrix for neat LDPE, before and after UV exposure. The TiO₂-doped films showed an increasing shift in results obtained for physical properties as the doping concentration increased, before and after UV exposure. Relating to chemical properties, the trend was the inverse of the physical properties. The 15% TiO₂-doped film showed improved permeation times only when the photocatalytic TiO₂ was activated. However, 5% TiO₂-doped film exceptionally maintained better permeation times before and after UV exposure demonstrating better resistance against CEES permeation. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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11 pages, 4732 KiB  

Open AccessArticle

Enhanced Epoxy Composites Reinforced by 3D-Aligned Aluminum Borate Nanowhiskers

by Hyunseung Song, Kiho Song, Haejin Hwang and Changui Ahn

Materials 2024, 17(19), 4727; https://doi.org/10.3390/ma17194727 - 26 Sep 2024

Viewed by 570

Abstract

Recently, the durability of high-performance and multifunctional portable electronic devices such as smartphones and tablets, has become an important issue. Electronic device housing, which protects internal components from external stimuli, such as vibration, shock, and electrical hazards, is essential for resolving durability issues. [...] Read more.

Recently, the durability of high-performance and multifunctional portable electronic devices such as smartphones and tablets, has become an important issue. Electronic device housing, which protects internal components from external stimuli, such as vibration, shock, and electrical hazards, is essential for resolving durability issues. Therefore, the materials used for electronic device housing must possess good mechanical and electrical insulating properties. Herein, we propose a novel high-strength polymer nanocomposite based on 3D-aligned aluminum borate nanowhisker (ABOw) structures. ABOw was synthesized using a facile hydrothermal method, and 3D-aligned ABOw structures were fabricated using a freeze-casting process. The 3D-aligned ABOw/epoxy composites consist of repetitively layered structures, and the microstructures of these composites are controlled by the filler content. The developed 3D-aligned ABOw/epoxy composite had a compressive strength 56.72% higher than that of pure epoxy, indicating that it can provide high durability when applied as a protective material for portable electronic devices. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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21 pages, 4060 KiB  

Open AccessArticle

Electrical Conductivity, Thermo-Mechanical Properties, and Cytotoxicity of Poly(3,4-Ethylenedioxythiophene):Poly(Styrene Sulfonate) (PEDOT:PSS)/Sulfonated Polyurethane Blends

by Gagan Kaur, Gavin E. Collis, Raju Adhikari and Pathiraja Gunatillake

Materials 2024, 17(18), 4602; https://doi.org/10.3390/ma17184602 - 19 Sep 2024

Viewed by 840

Abstract

Electrically conductive polymeric materials have recently garnered significant interest from researchers due to their potential applications in the biomedical field, including medical implants, tissue engineering, flexible electronic devices, and biosensors. Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) is considered the most successful conducting polymer due to its [...] Read more.

Electrically conductive polymeric materials have recently garnered significant interest from researchers due to their potential applications in the biomedical field, including medical implants, tissue engineering, flexible electronic devices, and biosensors. Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) is considered the most successful conducting polymer due to its higher electrical conductivity and chemical stability, but it suffers from limited solubility in common organic solvents, poor mechanical properties, and low biocompatibility. An area of tremendous interest is in combining PEDOT:PSS with another polymer to form a blend or composite material in order to access the beneficial properties of both materials. However, the hydrophilic nature of PEDOT:PSS makes it difficult to produce composites with non-polar polymers. In order to overcome these problems, we have specifically designed and synthesized two new sulfonated polyurethanes (PUS) with high sulfonic acid functionality. The two polyurethanes, one water-soluble (PUS1) and one water-insoluble (PUS2), were used to make blends with two commercially available PEDOT:PSS formulations (Clevios^TM FET and PH1000). Solvent cast films on glass substrates were made from water-soluble PEDOT:PSS/PUS1 blends while free-standing films of PEDOT:PSS/PUS2 blends were fabricated by compression-moulding. Ethylene glycol was used as conductivity enhancer, which showed an increase in the conductivity by several orders of magnitude in most of the compositions investigated. The highest conductivity of 438 S cm⁻¹ was achieved for the blend with 80 wt% of PEDOT:PSS (PH1000) in PUS1. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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12 pages, 4110 KiB  

Open AccessArticle

Laboratory Evaluation of Geosynthetic Interface Friction under Low Stress

by Paolo Carrubba

Polymers 2024, 16(17), 2519; https://doi.org/10.3390/polym16172519 - 5 Sep 2024

Viewed by 500

Abstract

In landfill cover, geosynthetic packages are often used to fulfil different and simultaneous functions: drainage, waterproofing, separation, reinforcement, and soil protection. In this regard, various types of geosynthetics are combined in succession to allow for water and biogas drainage and to waterproof, reinforce, [...] Read more.

In landfill cover, geosynthetic packages are often used to fulfil different and simultaneous functions: drainage, waterproofing, separation, reinforcement, and soil protection. In this regard, various types of geosynthetics are combined in succession to allow for water and biogas drainage and to waterproof, reinforce, and provide protection from erosion over the useful lifetime, ranging over many decades if we consider the long phases of disposal, closure, and quiescence of the landfill itself. The creation of the composite cover barrier requires the evaluation of various interfaces’ frictional strength under low contact stresses, both in static and seismic cases. The main purpose of this study is to summarize the results of past laboratory tests carried out on different geosynthetic–geosynthetic and geosynthetic–soil–geosynthetic interfaces using experimental instrumentation developed at the geotechnical laboratory of the University of Padua, which allows for the characterization of the interface geosynthetic friction at low contact stresses. The main aspects highlighted are the kinematic mode of failure, the wearing of the contact surfaces, the presence or absence of interstitial fluid, and, finally, the density level of the granular soil in contact with the geosynthetics. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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18 pages, 4681 KiB  

Open AccessArticle

Ultrasound-Assisted Extrusion Compounding of Nano Clay/Polypropylene Nano Compounds

by Gaston Francucci, Elena Rodriguez and María Eugenia Rodriguez

Polymers 2024, 16(17), 2426; https://doi.org/10.3390/polym16172426 - 27 Aug 2024

Viewed by 812

Abstract

The incorporation of nanoparticles can significantly enhance the properties of polymers. However, the industrial production of nanocomposites presents a technological challenge in achieving the proper dispersion of nanoparticles within the polymer matrix. In this work, a novel device is presented that can be [...] Read more.

The incorporation of nanoparticles can significantly enhance the properties of polymers. However, the industrial production of nanocomposites presents a technological challenge in achieving the proper dispersion of nanoparticles within the polymer matrix. In this work, a novel device is presented that can be seamlessly integrated with standard twin-screw extruders, enabling the application of ultrasonic vibration to molten polymeric material. The primary objective of this study is to experimentally validate the effectiveness of this technology in improving the dispersion of nanoparticles. To accomplish this, a comparative analysis was carried out between nanocomposites obtained through conventional compounding extrusion and those processed with the assistance of ultrasonic vibrations. The nanocomposites under investigation consist of a polypropylene (PP) matrix reinforced with nano clays (Cloisite 20A) at a target loading ratio of 5% by weight. To comprehensively evaluate the impact of the ultrasound-assisted compounding, various key properties were assessed, such as the melt flow index (MFI) to characterize the flow behavior, mechanical properties to evaluate the structural performance, oxygen barrier properties to assess potential gas permeability, and microstructure analysis using Scanning Electron Microscopy (SEM) for detailed morphology characterization. The results suggested an improvement in nanoparticle dispersion when using the ultrasound device, particularly when the intensity was adjusted to 60%. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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19 pages, 3920 KiB  

Open AccessFeature PaperArticle

Influence of the Processing Conditions on the Rheology and Heat of Decomposition of Solution Processed Hybrid Nanocomposites and Implication to Sustainable Energy Storage

by Andekuba Andezai and Jude O. Iroh

Energies 2024, 17(16), 3930; https://doi.org/10.3390/en17163930 - 8 Aug 2024

Viewed by 1078

Abstract

This study investigates the properties of solution-processed hybrid polyimide (PI) nanocomposites containing a variety of nanofillers, including polyaniline copolymer-modified clay (PNEA), nanographene sheets (NGSs), and carbon nanotube sheets (CNT-PVDFs). Through a series of experiments, the flow behavior of poly(amic acid) (PAA) solution and [...] Read more.

This study investigates the properties of solution-processed hybrid polyimide (PI) nanocomposites containing a variety of nanofillers, including polyaniline copolymer-modified clay (PNEA), nanographene sheets (NGSs), and carbon nanotube sheets (CNT-PVDFs). Through a series of experiments, the flow behavior of poly(amic acid) (PAA) solution and PAA suspension containing polyaniline copolymer-modified clay (PNEA) is determined as a function of the shear rate, processing temperature, and polymerization time. It is shown that the neat PAA solution exhibits a complex rheological behavior ranging from shear thickening to Newtonian behavior with increasing shear rate and testing temperature. The presence of modified clay in PAA solution significantly reduced the viscosity of PAA. Differential scanning calorimetry (DSC) analysis showed that polyimide–nanographene sheet (PI NGS) nanocomposites processed at a high spindle speed (100 rpm) have lower total heat of decomposition, which is indicative of improved fire retardancy. The effect of processing temperature on the specific capacitance of a polyimide–CNT-PVDF composite containing electrodeposited polypyrrole is determined using cyclic voltammetry (CV). It is shown that the hybrid composite working electrode material processed at 90 °C produces a remarkably higher overall stored charge when compared to the composite electrode material processed at 250 °C. Consequently, the specific capacitance obtained at a scan rate of 5 mV/s for the hybrid nanocomposite processed at 90 °C is around 858 F/g after one cycle, which is about 6.3 times higher than the specific capacitance of 136 F/g produced by the hybrid nanocomposite processed at 250 °C. These findings show that the properties of the hybrid nanocomposites are remarkably influenced by the processing conditions and highlight the need for process optimization. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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9 pages, 2128 KiB  

Open AccessArticle

Low-Frequency Raman Spectroscopy on Amorphous Poly(Ether Ether Ketone) (PEEK)

by Tomoko Numata, Naomoto Ishikawa, Toshihiro Shimada, Keith C. Gordon and Makoto Yamaguchi

Materials 2024, 17(15), 3755; https://doi.org/10.3390/ma17153755 - 30 Jul 2024

Cited by 1 | Viewed by 814

Abstract

Low-frequency peaks in the Raman spectra of amorphous poly(ether ether ketone) (PEEK) were investigated. An amorphous sample with zero crystallinity, as confirmed by wide-angle X-ray diffraction, was used in this study. In a previous study, two peaks were observed in the low-frequency Raman [...] Read more.

Low-frequency peaks in the Raman spectra of amorphous poly(ether ether ketone) (PEEK) were investigated. An amorphous sample with zero crystallinity, as confirmed by wide-angle X-ray diffraction, was used in this study. In a previous study, two peaks were observed in the low-frequency Raman spectra of the crystallized samples. Among these, the peaks at 135 cm⁻¹ disappeared for the amorphous sample. Meanwhile, for the first time, the peak at 50 cm⁻¹ was observed in the crystallized sample. Similar to the peak at 135 cm⁻¹, the peak at 50 cm⁻¹ disappeared in the amorphous state, and its intensity increased with increasing crystallinity. The origins of the two peaks were associated with the Ph-CO-Ph-type intermolecular vibrational modes in the simulation. This suggests that the Ph-CO-Ph vibrational mode observed in the low-frequency region of PEEK was strongly influenced by the intermolecular order. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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13 pages, 2076 KiB  

Open AccessArticle

Stereolithography 3D Printing of Stimuli-Responsive Spin Crossover@Polymer Nanocomposites with Optimized Actuating Properties

by Onkar Kulkarni, Alejandro Enriquez-Cabrera, Xinyu Yang, Julie Foncy, Liviu Nicu, Gábor Molnár and Lionel Salmon

Nanomaterials 2024, 14(15), 1243; https://doi.org/10.3390/nano14151243 - 24 Jul 2024

Cited by 2 | Viewed by 1241

Abstract

We used stereolithography to print polymer nanocomposite samples of stimuli-responsive spin crossover materials in the commercial photo-curable printing resins DS3000 and PEGDA-250. The thermomechanical analysis of the SLA-printed objects revealed not only the expected reinforcement of the polymer resins by the introduction of [...] Read more.

We used stereolithography to print polymer nanocomposite samples of stimuli-responsive spin crossover materials in the commercial photo-curable printing resins DS3000 and PEGDA-250. The thermomechanical analysis of the SLA-printed objects revealed not only the expected reinforcement of the polymer resins by the introduction of the stiffer SCO particles, but also a significant mechanical damping, as well as a sizeable linear strain around the spin transition temperatures. For the highest accessible loads (ca. 13–15 vol.%) we measured transformation strains in the range of 1.2–1.5%, giving rise to peaks in the coefficient of thermal expansion as high as 10⁻³ °C⁻¹, which was exploited in 3D printed bilayer actuators to produce bending movement. The results pave the way for integrating these advanced stimuli-responsive composites into mechanical actuators and 4D printing applications. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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14 pages, 3534 KiB  

Open AccessArticle

Abrasion Behaviors of Silica-Reinforced Solution Styrene–Butadiene Rubber Compounds Using Different Abrasion Testers

by Eunji Chae, Seong Ryong Yang and Sung-Seen Choi

Polymers 2024, 16(14), 2038; https://doi.org/10.3390/polym16142038 - 17 Jul 2024

Viewed by 905

Abstract

Solution styrene–butadiene rubber (SSBR) is widely used to improve the properties of tire tread compounds. Tire wear particles (TWPs), which are generated on real roads as vehicles traverse, represent one of significant sources of microplastics. In this study, four SSBR compounds were prepared [...] Read more.

Solution styrene–butadiene rubber (SSBR) is widely used to improve the properties of tire tread compounds. Tire wear particles (TWPs), which are generated on real roads as vehicles traverse, represent one of significant sources of microplastics. In this study, four SSBR compounds were prepared using two SSBRs with high styrene (STY samples) and 1,2-unit (VIN samples) contents, along with dicyclopentadiene resin. The abrasion behaviors were investigated using four different abrasion testers: cut and chip (CC), Lambourn, DIN, and laboratory abrasion tester (LAT100). The abrasion rates observed in the Lambourn and LAT100 abrasion tests were consistent with each other, but the results of CC and DIN abrasion tests differed from them. The addition of the resin improved the abrasion rate and resulted in the generation of large wear particles. The abrasion rates of STY samples in the Lambourn and LAT100 abrasion tests were lower than those of VIN samples, whereas the values in the CC and DIN abrasion tests were higher than those of VIN samples. The wear particles were predominantly larger than 1000 μm, except for the VIN sample in the DIN abrasion test. However, TWPs > 1000 μm are rarely produced on real roads. The size distributions of wear particles > 1000 μm were 74.0–99.5%, 65.9–93.4%, 7.2–95.1%, and 37.5–83.0% in the CC, Lambourn, DIN, and LAT100 abrasion tests, respectively. The size distributions of wear particles in the Lambourn and LAT100 abrasion tests were broader than those in the other tests, whereas the distributions in the CC abrasion test were narrower. The abrasion patterns and the morphologies and size distributions of wear particles generated by the four abrasion tests varied significantly, attributable to differences in the bound rubber contents, crosslink densities, and tensile properties. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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14 pages, 15100 KiB  

Open AccessArticle

Experimental Study on Fracture Behavior of Adhesive-Bonded Structure with V-notch Based on Digital Gradient Sensing Method

by Hai Yu, Yangzhuang An and Yunpeng Liu

Polymers 2024, 16(14), 2011; https://doi.org/10.3390/polym16142011 - 13 Jul 2024

Viewed by 947

Abstract

In this paper, a comparative study of the mode-I fracture behaviors of two types of specimens with a V-notch defect under plane stress conditions was performed using the digital gradient sensing (DGS) method. First, two types of specimens (namely one-piece specimen and bonded [...] Read more.

In this paper, a comparative study of the mode-I fracture behaviors of two types of specimens with a V-notch defect under plane stress conditions was performed using the digital gradient sensing (DGS) method. First, two types of specimens (namely one-piece specimen and bonded specimen) with the same V-notch defect were both made of polymethyl methacrylate (PMMA), and three different V-notch angles’ defect were considered for each type of specimen. Then, three-point bending tests were performed on both types of specimens. The angular deflection field of light near the V-notch region was recorded using a CCD during the experiments. Finally, by utilizing the relationship between the stress gradient and angular deflection as established by the elasto-optic effect, in conjunction with the principles of linear elastic fracture mechanics theory, the stress intensity factors (SIFs) of two types of specimens under different stress conditions were calculated using the least square method. According to the experimental results, the influence of V-notch angle on fracture load and fracture toughness of two kinds of specimens was discussed. Meanwhile, the experimental results show the significant differences in the fracture behaviors of the two types of specimens under mode-I loading conditions. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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15 pages, 3329 KiB  

Open AccessArticle

Influence of Crosslinking Concentration on the Properties of Biodegradable Modified Cassava Starch-Based Films for Packaging Applications

by Sudarat Khadsai, Rapiphun Janmanee, Pornpat Sam-Ang, Yossawat Nuanchawee, Waleepan Rakitikul, Wilawan Mankhong, Wirot Likittrakulwong and Padarat Ninjiaranai

Polymers 2024, 16(12), 1647; https://doi.org/10.3390/polym16121647 - 11 Jun 2024

Viewed by 1447

Abstract

Chitosan/modified cassava starch/curcumin (CS/S/Cur) films with a crosslinker were developed via the solvent casting technique for the application of food packaging. The effects of citric acid (CA) as a natural crosslinker were assessed at different concentrations (0–10.0%, w/w, on a [...] Read more.

Chitosan/modified cassava starch/curcumin (CS/S/Cur) films with a crosslinker were developed via the solvent casting technique for the application of food packaging. The effects of citric acid (CA) as a natural crosslinker were assessed at different concentrations (0–10.0%, w/w, on a dry base on CS and S content). To measure the most favorable film, chemical structure and physical, mechanical, and thermal properties were investigated. Successful crosslinking between CS and S was seen clearly in the Fourier Transform Infrared (FTIR) spectra. The properties of the water resistance of the CS/S/Cur films crosslinked with CA were enhanced when compared to those without CA. Furthermore, it was found that the addition of CA crosslinking would improve the mechanical properties of composite films to some extent. It had been reported that the CA crosslinking level of 7.5 wt% of CS/S/Cur film demonstrated high performance in terms of physical properties. The tensile strength of the crosslinked film increased from 8 ± 1 MPa to 12 ± 1 MPa with the increasing content of CA, while water vapor permeability (WVP), swelling degree (SD), and water solubility (WS) decreased. An effective antioxidant scavenging activity of the CS/S/Cur film decreased with an increase in CA concentrations. This study provides an effective pathway for the development of active films based on polysaccharide-based film for food packaging applications. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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21 pages, 4372 KiB  

Open AccessArticle

Effect of Chemical Treatment of Cotton Stalk Fibers on the Mechanical and Thermal Properties of PLA/PP Blended Composites

by Feng Xu, Jin Shang, Abdukeyum Abdurexit, Ruxangul Jamal, Tursun Abdiryim, Zhiwei Li, Jiangan You, Jin Wei, Erman Su and Longjiang Huang

Polymers 2024, 16(12), 1641; https://doi.org/10.3390/polym16121641 - 10 Jun 2024

Cited by 1 | Viewed by 1599

Abstract

Different chemical treatment methods were employed to modify the surface of cotton stalk fibers, which were then utilized as fillers in composite materials. These treated fibers were incorporated into polylactic acid/polypropylene melt blends using the melt blending technique. Results indicated that increasing the [...] Read more.

Different chemical treatment methods were employed to modify the surface of cotton stalk fibers, which were then utilized as fillers in composite materials. These treated fibers were incorporated into polylactic acid/polypropylene melt blends using the melt blending technique. Results indicated that increasing the surface roughness of cotton stalk fibers could enhance the overall mechanical properties of the composite materials, albeit potentially leading to poor fiber–matrix compatibility. Conversely, a smooth fiber surface was found to improve compatibility with polylactic acid, while Si-O-C silane coating increased fiber regularity and interfacial interaction with the matrix, thereby enhancing heat resistance. The mechanical properties and thermal stability of the composite materials made from alkali/silane-treated fibers exhibited the most significant improvement. Furthermore, better dispersion of fibers in the matrix and more regular fiber orientation were conducive to increasing the overall crystallinity of the composite materials. However, such fiber distribution was not favorable for enhancing impact resistance, although this drawback could be mitigated by increasing the surface roughness of the reinforcing fibers. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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13 pages, 6089 KiB  

Open AccessArticle

Flexible and Multifunctional Composites with Highly Strain Sensing and Impact Resistance Properties

by Shu Wang, Jianyu Pu, Shuquan Xu, Yuanhao Tian, Qian Shu, Rui Zou and Tonghua Zhang

Polymers 2024, 16(11), 1544; https://doi.org/10.3390/polym16111544 - 30 May 2024

Cited by 1 | Viewed by 806

Abstract

The development of smart protective clothing will help detect injuries from contact sports, traffic collisions, and other accidents. The combination of ecoflex, spacer fabric, and graphene-based aerogel provides a multifunctional composite. It shows a strain sensitivity of 17.71 at the strain range of [...] Read more.

The development of smart protective clothing will help detect injuries from contact sports, traffic collisions, and other accidents. The combination of ecoflex, spacer fabric, and graphene-based aerogel provides a multifunctional composite. It shows a strain sensitivity of 17.71 at the strain range of 40~55%, a pressure sensitivity of 0.125 kPa⁻¹ at the pressure range of 0~15 kPa, and a temperature sensitivity of −0.648 °C⁻¹. After 50 impact tests, its protection coefficient only dropped from 60% to 55%. Additionally, it shows thermal insulation properties. The compression and impact process results of finite element numerical simulation analysis are in good agreement with the experimental results. The ecoflex/aerogel/spacer fabric sensor exhibits a simple structure, large pressure strain, high sensitivity, flexibility, and ease of fabrication, making it a candidate for smart protective clothing resistant to impact loads. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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28 pages, 10150 KiB  

Open AccessArticle

Optimizing Epoxy Molding Compound Processing: A Multi-Sensor Approach to Enhance Material Characterization and Process Reliability

by Julian Vogelwaid, Martin Bayer, Michael Walz, Felix Hampel, Larysa Kutuzova, Günter Lorenz, Andreas Kandelbauer and Timo Jacob

Polymers 2024, 16(11), 1540; https://doi.org/10.3390/polym16111540 - 30 May 2024

Viewed by 1572

Abstract

The in-line control of curing during the molding process significantly improves product quality and ensures the reliability of packaging materials with the required thermo-mechanical and adhesion properties. The choice of the morphological and thermo-mechanical properties of the molded material, and the accuracy of [...] Read more.

The in-line control of curing during the molding process significantly improves product quality and ensures the reliability of packaging materials with the required thermo-mechanical and adhesion properties. The choice of the morphological and thermo-mechanical properties of the molded material, and the accuracy of their determination through carefully selected thermo-analytical methods, play a crucial role in the qualitative prediction of trends in packaging product properties as process parameters are varied. This work aimed to verify the quality of the models and their validation using a highly filled molding resin with an identical chemical composition but 10 wt% difference in silica particles (SPs). Morphological and mechanical material properties were determined by dielectric analysis (DEA), differential scanning calorimetry (DSC), warpage analysis and dynamic mechanical analysis (DMA). The effects of temperature and injection speed on the morphological properties were analyzed through the design of experiments (DoE) and illustrated by response surface plots. A comprehensive approach to monitor the evolution of ionic viscosity (IV), residual enthalpy (dH_rest), glass transition temperature (T_g), and storage modulus (E) as a function of the transfer-mold process parameters and post-mold-cure (PMC) conditions of the material was established. The reliability of T_g estimation was tested using two methods: warpage analysis and DMA. The noticeable deterioration in the quality of the analytical signal for highly filled materials at high cure rates is discussed. Controlling the temperature by increasing the injection speed leads to the formation of a polymer network with a lower T_g and an increased storage modulus, indicating a lower density and a more heterogeneous structure due to the high heating rate and shear heating effect. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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Supplementary material:
Supplementary File 1 (ZIP, 1463 KiB)

13 pages, 3641 KiB  

Open AccessArticle

Strain Effect on Dielectricity of Elastic Thermoplastic Polyurethanes

by Yubo Wang, Huali Yang, Yali Xie, Xilai Bao, Lili Pan, Dan Zhao, Jinxia Chen, Mengting Zou, Tian Tian and Runwei Li

Polymers 2024, 16(11), 1465; https://doi.org/10.3390/polym16111465 - 22 May 2024

Viewed by 1016

Abstract

Dielectric elastomers, such as thermoplastic polyurethanes (TPUs), are widely used as the dielectric layer, encapsulation layer, and substrate of flexible and stretchable devices. To construct capacitors and actuators that work stably upon deformation, it has become urgent to investigate the evolution of dielectricity [...] Read more.

Dielectric elastomers, such as thermoplastic polyurethanes (TPUs), are widely used as the dielectric layer, encapsulation layer, and substrate of flexible and stretchable devices. To construct capacitors and actuators that work stably upon deformation, it has become urgent to investigate the evolution of dielectricity under stress and strain. However, the lack of effective methods for estimating the dielectric constant of elastomers under strain poses a big challenge. This study reports a device for the in situ measurement of the dielectric constant of TPU under strain. It is found that upon stretching TPU to a strain of 400%, its dielectric constant decreases from 8.02 ± 0.01 to 2.88 ± 0.25 (at 1 MHz). In addition, combined Fourier-transform infrared spectroscopy, the X-ray scattering technique, and atomic force microscopy were utilized to characterize the evolution of the microstructure under strain. The investigation under tensile strain reveals a decreased density and average size of polarized hard domains, along with a tendency of the molecular chains to align in parallel with the tensile stress. The evolution of the microstructures results in a reduction in the measured dielectric constant in TPU. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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13 pages, 9435 KiB  

Open AccessArticle

Boron Nitride/Carbon Fiber High-Oriented Thermal Conductivity Material with Leaves–Branches Structure

by Dengfeng Shu, Jiachen Sun, Fei Huang, Wenbo Qin, Chengbiao Wang and Wen Yue

Materials 2024, 17(10), 2183; https://doi.org/10.3390/ma17102183 - 7 May 2024

Cited by 1 | Viewed by 1175

Abstract

In the realm of thermal interface materials (TIMs), high thermal conductivity and low density are key for effective thermal management and are particularly vital due to the growing compactness and lightweight nature of electronic devices. Efficient directional arrangement is a key control strategy [...] Read more.

In the realm of thermal interface materials (TIMs), high thermal conductivity and low density are key for effective thermal management and are particularly vital due to the growing compactness and lightweight nature of electronic devices. Efficient directional arrangement is a key control strategy to significantly improve thermal conductivity and comprehensive properties of thermal interface materials. In the present work, drawing inspiration from natural leaf and branch structures, a simple-to-implement approach for fabricating oriented thermal conductivity composites is introduced. Utilizing carbon fibers (CFs), known for their ultra-high thermal conductivity, as branches, this design ensures robust thermal conduction channels. Concurrently, boron nitride (BN) platelets, characterized by their substantial in-plane thermal conductivity, act as leaves. These components not only support the branches but also serve as junctions in the thermal conduction network. Remarkably, the composite achieves a thermal conductivity of 11.08 W/(m·K) with just an 11.1 wt% CF content and a 1.86 g/cm³ density. This study expands the methodologies for achieving highly oriented configurations of fibrous and flake materials, which provides a new design idea for preparing high-thermal conductivity and low-density thermal interface materials. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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19 pages, 8886 KiB  

Open AccessArticle

Experimental and Numerical Investigation of Dynamic Damage and Load Transfer of PBX Substitute Material under Low Velocity Impact

by Youcai Xiao, Qin Fu, Wanqian Yu, Chenyang Fan, Yu Zou and Yi Sun

Polymers 2024, 16(9), 1235; https://doi.org/10.3390/polym16091235 - 28 Apr 2024

Viewed by 1009

Abstract

The accidental initiation of explosives under mechanical loads has caused numerous catastrophic events. Therefore, the dynamic damage behavior of confined polymer-bonded explosives (PBXs) must be assessed to improve their practical applicability. In this study, polymer-bonded sugar (PBS) materials were prepared using a novel [...] Read more.

The accidental initiation of explosives under mechanical loads has caused numerous catastrophic events. Therefore, the dynamic damage behavior of confined polymer-bonded explosives (PBXs) must be assessed to improve their practical applicability. In this study, polymer-bonded sugar (PBS) materials were prepared using a novel agglomerate to develop a PBX substitute material with enhanced experimental safety. The mechanical properties of the PBS shell were evaluated using a dynamic compression test, which revealed that the compression response of the shell was affected by the strain rate. A low-velocity impact experiment was performed to investigate the dynamic damage and load transfer characteristics of the PBX substitute. A constitutive model was developed to characterize the mechanical response of PBS subjected to high strain rates, and implementing this model in ABAQUS ensured successful prediction of the damage evolution process associated with PBS. Simulation results indicated that the PBS specimen was primarily damaged around its center while sliding friction was dominant near the center during pressure application. Notably, different stress states result in distinct crack growth velocity histories along the axial direction, with the damage ratio progressively decreasing toward regions closer to the impact surface. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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15 pages, 9753 KiB  

Open AccessEditor’s ChoiceArticle

Structure and Mechanical Properties of iPP-Based Nanocomposites Crystallized under High Pressure

by Sivanjineyulu Veluri, Przemyslaw Sowinski, Mariia Svyntkivska, Zbigniew Bartczak, Tomasz Makowski and Ewa Piorkowska

Nanomaterials 2024, 14(7), 629; https://doi.org/10.3390/nano14070629 - 4 Apr 2024

Cited by 1 | Viewed by 1164

Abstract

The unique nonparallel chain arrangement in the orthorhombic γ-form lamellae of isotactic polypropylene (iPP) results in the enhancement of the mechanical properties of γ-iPP. Our study aimed at the investigation of the mechanical properties of γ-iPP nanocomposites with 1–5 wt.% multiwall carbon nanotubes [...] Read more.

The unique nonparallel chain arrangement in the orthorhombic γ-form lamellae of isotactic polypropylene (iPP) results in the enhancement of the mechanical properties of γ-iPP. Our study aimed at the investigation of the mechanical properties of γ-iPP nanocomposites with 1–5 wt.% multiwall carbon nanotubes (MWCNT) and 5 wt.% organo-modified montmorillonite prepared by melt-mixing and high-pressure crystallization. Neat iPP and the nanocomposites were crystallized under high pressures of 200 MPa and 300 MPa, and for comparison under 1.4 MPa, in a custom-built high-pressure cell. The structure of the materials was studied using WAXS, SAXS, DSC, and SEM, whereas their mechanical properties were tested in plane-strain compression. Under a small pressure of 1.4 MPa, polymer matrix in all materials crystallized predominantly in the α-form, the most common monoclinic form of iPP, whereas under high pressure it crystallized in the γ-form. This caused a significant increase in the elastic modulus, yield stress, and stress at break. Moreover, due to the presence of MWCNT, these parameters of the nanocomposites exceeded those of the neat polymer. As a result, a 60–70% increase in the elastic modulus, yield stress, and stress at break was achieved by filling of iPP with MWCNT and high-pressure crystallization. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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18 pages, 7228 KiB  

Open AccessArticle

Enhanced Corrosion Resistance and Mechanical Durability of the Composite PLGA/CaP/Ti Scaffolds for Orthopedic Implants

by Konstantin A. Prosolov, Ekaterina G. Komarova, Ekaterina A. Kazantseva, Nikita A. Luginin, Alexander D. Kashin, Pavel V. Uvarkin and Yurii P. Sharkeev

Polymers 2024, 16(6), 826; https://doi.org/10.3390/polym16060826 - 15 Mar 2024

Cited by 2 | Viewed by 1567

Abstract

In addressing the challenge of enhancing orthopedic implants, 3D porous calcium phosphate (CaP) coatings on titanium (Ti) substrates modified with poly(lactic-co-glycolic acid) (PLGA) were proposed. CaP coatings on Ti were deposited using the ultrasonic-assisted micro-arc oxidation (UMAO) method, followed by modification with PLGA [...] Read more.

In addressing the challenge of enhancing orthopedic implants, 3D porous calcium phosphate (CaP) coatings on titanium (Ti) substrates modified with poly(lactic-co-glycolic acid) (PLGA) were proposed. CaP coatings on Ti were deposited using the ultrasonic-assisted micro-arc oxidation (UMAO) method, followed by modification with PLGA through a dip coating process at concentrations of 5%, 8%, and 10%. The addition of PLGA significantly improved adhesive–cohesive strength according to the scratch test, while PLGA to CaP adhesion was found to be not less than 8.1 ± 2.2 MPa according to the peel test. Tensile testing showed a typical fracture of CaP coatings and mechanisms of brittle fracture. Corrosion resistance, assessed via gravimetric and electrochemical methods in 0.9% NaCl and PBS solutions, revealed PLGA’s substantial reduction in corrosion rates, with the corrosion current decreasing by two orders of magnitude even for the 5% PLGA/CaP/Ti sample. Also, the PLGA layer significantly enhanced the impedance modulus by two orders of magnitude, indicating a robust barrier against corrosion at all PLGA concentrations. Higher PLGA concentrations offered even greater corrosion resistance and improved mechanical properties. This research underscores the potential of using CaP- and PLGA-modified coatings to extend the life and functionality of orthopedic implants, addressing a significant challenge in biomedical engineering. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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13 pages, 5241 KiB  

Open AccessArticle

Experimental Investigation of Influence of Fibre Orientation on the Dynamic Properties of Carbon Fibre and Intra-Ply Woven Carbon-Kevlar/Epoxy Hybrid Composite

by Umanath R. Poojary and Sriharsha Hegde

J. Compos. Sci. 2024, 8(2), 78; https://doi.org/10.3390/jcs8020078 - 17 Feb 2024

Cited by 1 | Viewed by 1470

Abstract

Composite materials are popular substitutes for conventional materials owing to their high strength-to-weight ratio. Reinforcements in the form of woven fabric clothes are common due to their ease of availability and preparation. The use of hybrid intra-ply as reinforcements synergises the advantages of [...] Read more.

Composite materials are popular substitutes for conventional materials owing to their high strength-to-weight ratio. Reinforcements in the form of woven fabric clothes are common due to their ease of availability and preparation. The use of hybrid intra-ply as reinforcements synergises the advantages of more than one type of fibre. The current work focuses on the preparation of woven carbon fibre (CF) and carbon–Kevlar (CF-K) intra-ply hybrid fibre-based composites. Epoxy resin was used as the matrix and balsa sheet was used as the sandwich material. The angle of orientation of the woven fibre cloth was varied from 0° to 45° along the direction of loading. The dynamic properties of prepared samples were experimentally investigated using an impact hammer test. The natural frequency and damping ratio were influenced by the angle of orientation and the fibre reinforcement. The CF-K hybrid composite showed better dynamic properties when compared with the CF composite. The natural frequency was highest for the 0° sample, it reduced with the angle of orientation, and a reverse trend was observed for damping ratio. Both CF- and CF-K-based composites showed similar trends. The storage modulus variation also showed a similar trend as that of the natural frequency for both types of samples with orientation, but a reverse trend was observed for loss modulus, i.e., the loss modulus increased with the change in the angle of orientation, indicating the improvement in energy storage ability of the composite. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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18 pages, 14637 KiB  

Open AccessArticle

On the Stability of Electrohydrodynamic Jet Printing Using Poly(ethylene oxide) Solvent-Based Inks

by Alberto Ramon, Ievgenii Liashenko, Joan Rosell-Llompart and Andreu Cabot

Nanomaterials 2024, 14(3), 273; https://doi.org/10.3390/nano14030273 - 27 Jan 2024

Cited by 3 | Viewed by 1804

Abstract

Electrohydrodynamic (EHD) jet printing of solvent-based inks or melts allows for the producing of polymeric fiber-based two- and three-dimensional structures with sub-micrometer features, with or without conductive nanoparticles or functional materials. While solvent-based inks possess great material versatility, the stability of the EHD [...] Read more.

Electrohydrodynamic (EHD) jet printing of solvent-based inks or melts allows for the producing of polymeric fiber-based two- and three-dimensional structures with sub-micrometer features, with or without conductive nanoparticles or functional materials. While solvent-based inks possess great material versatility, the stability of the EHD jetting process using such inks remains a major challenge that must be overcome before this technology can be deployed beyond research laboratories. Herein, we study the parameters that affect the stability of the EHD jet printing of polyethylene oxide (PEO) patterns using solvent-based inks. To gain insights into the evolution of the printing process, we simultaneously monitor the drop size, the jet ejection point, and the jet speed, determined by superimposing a periodic electrostatic deflection. We observe printing instabilities to be associated with changes in drop size and composition and in the jet’s ejection point and speed, which are related to the evaporation of the solvent and the resulting drying of the drop surface. Thus, stabilizing the printing process and, particularly, the drop size and its surface composition require minimizing or controlling the solvent evaporation rate from the drop surface by using appropriate solvents and by controlling the printing ambient. For stable printing and improved jet stability, it is essential to use polymers with a high molecular weight and select solvents that slow down the surface drying of the droplets. Additionally, adjusting the needle voltages is crucial to prevent instabilities in the jet ejection mode. Although this study primarily utilized PEO, the general trends observed are applicable to other polymers that exhibit similar interactions between solvent and polymer. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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17 pages, 5081 KiB  

Open AccessArticle

Mechanical Behavior of Closed-Cell Ethylene-Vinyl Acetate Foam under Compression

by Hongjuan Chen, Deqiang Sun, Lulu Gao, Xiaochen Liu and Meilin Zhang

Polymers 2024, 16(1), 34; https://doi.org/10.3390/polym16010034 - 21 Dec 2023

Cited by 1 | Viewed by 1778

Abstract

The static and dynamic compressions of closed-cell ethylene-vinyl acetate (EVA) foams with different densities were conducted under various strain rates. The stress−strain curves were processed to determine the corresponding curves of energy absorption per unit volume and energy absorption efficiency, and energy absorption [...] Read more.

The static and dynamic compressions of closed-cell ethylene-vinyl acetate (EVA) foams with different densities were conducted under various strain rates. The stress−strain curves were processed to determine the corresponding curves of energy absorption per unit volume and energy absorption efficiency, and energy absorption diagrams were produced. The influences of density and strain rate on the elastic modulus, yield strength, energy absorption per unit volume, optimal strain, densification strain, and energy absorption diagrams were analyzed and discussed. The whole stress−strain curve can be fitted with the Rusch formula. The strain rate does not change the shape of stress−strain curve, and has little influence on the elastic modulus. There exists the optimal density of EVA foam corresponding to its maximum energy absorption efficiency. Under a fixed strain rate, the optical energy absorption per unit volume is proportional to the optical stress on the envelope line in the energy absorption diagrams of EVA foams with different densities. The change in strain rate leads to the envelope line in the energy absorption diagrams of EVA foams with a given density having the larger slope and a negative intercept where the optical energy absorption per unit volume relies linearly on the optical stress. The empirical formulas of elastic modulus, yield strength, optimal strain, and envelope lines and their slopes are derived from the tested results. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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15 pages, 13350 KiB  

Open AccessArticle

Study on Rheological Properties and Pouring Process of Hydroxyl-Terminated Polybutadiene (HTPB) Propellants

by Haoyu Wang, Yongchao Ji, Xiaorui Jiang and Zhuo Li

Polymers 2023, 15(24), 4707; https://doi.org/10.3390/polym15244707 - 14 Dec 2023

Viewed by 1643

Abstract

The process of solid propellant production, which is the most widely used high-energy material, has garnered significant attention from researchers. However, there have been relatively few studies on its processing, due to the unique nature of the casting process. This paper aims to [...] Read more.

The process of solid propellant production, which is the most widely used high-energy material, has garnered significant attention from researchers. However, there have been relatively few studies on its processing, due to the unique nature of the casting process. This paper aims to further analyze the pouring process of the propellant slurry. Initially, we obtained a sample of the propellant slurry and measured its rheological parameters using a rotary rheometer. From the analysis of the experimental results, we derived the viscosity parameters and the yield values of the propellant slurry. Subsequently, we simulated the pouring process, setting the slurry parameters based on the data obtained from the rheological measurement experiment. The simulation results demonstrated that the flower plate significantly impacts upon the cutting and separating effect on the slurry during pouring. Upon leaving the flower plate, the slurry descends onto the core mold platform under the influence of gravity, gradually flowing along the edge of the core mold. Although there may be some small voids in the pouring process, the voids will disappear completely at the end of pouring. A comparison with the actual pouring situation revealed a higher consistency between the simulation results and reality, thus establishing the reliability of the simulation method as a reference for analyzing the pouring process. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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Supplementary File 1 (ZIP, 356 KiB)

32 pages, 13166 KiB  

Open AccessArticle

Processing and Characterization of UV Irradiated HDPE/POSS Fibers

by Ezgi Biçer, Mehmet Kodal and Güralp Özkoç

Nanomaterials 2023, 13(24), 3131; https://doi.org/10.3390/nano13243131 - 13 Dec 2023

Cited by 1 | Viewed by 1369

Abstract

High-performance polyethylene fibers, renowned for their superior attributes encompassing a high strength, modulus, and lightness, are conventionally manufactured through the gel spinning method. However, this method is encumbered by several drawbacks, including the requisite application of a separate process to eliminate solvents from [...] Read more.

High-performance polyethylene fibers, renowned for their superior attributes encompassing a high strength, modulus, and lightness, are conventionally manufactured through the gel spinning method. However, this method is encumbered by several drawbacks, including the requisite application of a separate process to eliminate solvents from the fibers and the utilization of chemicals deleterious to both the environment and human health. Alternatively, the adoption of the melt spinning method presents a cleaner and environmentally friendly approach to attain high-performance fibers. In the present investigation, high-density polyethylene (HDPE) fibers were produced employing the melt spinning method. After the spinning process, strategic orientation procedures were implemented to enhance the crystallinity of the spun fibers. As a concluding step, seeking to elevate the overall performance of the oriented spun HDPE fibers, a cross-linking treatment was applied via UV irradiation. Notably, this study pioneers the incorporation of polyhedral oligomeric silsesquioxane (POSS) hybrid nanoparticles into HDPE during melt spinning, presenting a novel advancement aimed at further enhancing the mechanical properties of oriented HDPE fibers during UV irradiation. For this purpose, two distinct types of POSS, namely octavinyl POSS (OVPOSS) and methacryl POSS (MACPOSS), both having unsaturated double bonds capable of participating in the network structure of oriented HDPE spun during UV cross-linking, were used. The thermal, morphological, and mechanical properties, as well as the crystal structure of samples with and without POSS molecules, were investigated. The mechanical properties of the fibers exhibited higher values in the presence of OVPOSS. The incorporation of OVPOSS and MACPOSS resulted in a noteworthy improvement in the material’s tensile strength, exhibiting a marked increase of 12.5 and 70.8%, respectively. This improvement can be attributed to the more homogeneous dispersion of OVPOSS in HDPE, actively participating in the three-dimensional network structure. After orientation and UV irradiation, the tensile strength of HDPE fibers incorporating OVPOSS increased to 293 MPa, accompanied by a concurrent increase in the modulus to 2.8 GPa. The addition of POSS nanoparticles thus yielded a substantial improvement in the overall performance of HDPE fibers. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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13 pages, 4964 KiB  

Open AccessArticle

A Low-Cost Silica Fiber/Epoxy Composite with Excellent Dielectric Properties, and Good Mechanical and Thermal Stability

by Imran Haider, Iftikhar Hussain Gul, Malik Adeel Umer and Mutawara Mahmood Baig

Materials 2023, 16(23), 7410; https://doi.org/10.3390/ma16237410 - 29 Nov 2023

Cited by 1 | Viewed by 1519

Abstract

In many electronic applications, the dielectric and structural properties of reinforced composites are vital. In this research work, the influence of fiber proportion on the properties of a silica fiber/epoxy (SFE) composite was investigated. The structure, morphology, dielectric constant and loss factor, mechanical [...] Read more.

In many electronic applications, the dielectric and structural properties of reinforced composites are vital. In this research work, the influence of fiber proportion on the properties of a silica fiber/epoxy (SFE) composite was investigated. The structure, morphology, dielectric constant and loss factor, mechanical properties, and thermal stability were determined. The increase of wt.% of silica fiber (SiO_{2 (f)}) x = 30 to 90, reduced the dielectric constant (εr) and dielectric loss (δ) of the SFE composite from their original values to 18.9% and 48.5%, lowering local charge displacement towards the applied electric field. The SFE composite showed higher mechanical properties with the increase in SiO_{2 (f)}, x = 30 to 80, the tensile strength (UTS) was raised from 91.6 MPa to 155.7 MPa, the compression strength (UCS) was increased from 261.1 MPa to 409.6 MPa and the flexural strength was enhanced from 192.3 MPa to 311.9 MPa. Upon further addition of SiO_{2 (f)} to the composite, i.e., x = 90, the mechanical properties were reduced a little, but the dielectric properties were not changed. Increasing SiO_{2 (f)} improved the thermal stability as weight loss was found to be 69% (x = 30) and 24% (x = 90), and average moisture absorption was found to be 1.1 to 1.8%. A silica fiber/epoxy composite, for microelectronics, can be made from a low-cost fiber, and its dielectric properties as well as its mechanical and thermal stability can be tuned or improved by varying fiber fractions. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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23 pages, 3557 KiB  

Open AccessArticle

Polymeric Membranes Doped with Halloysite Nanotubes Imaged using Proton Microbeam Microscopy

by Giovanna Vasco, Valentina Arima, Soufiane Boudjelida, Mauro Carraro, Monica Bianco, Alessandra Zizzari, Elisabetta Perrone, Francesco Galiano, Alberto Figoli and Maura Cesaria

Nanomaterials 2023, 13(22), 2970; https://doi.org/10.3390/nano13222970 - 18 Nov 2023

Viewed by 1589

Abstract

Polymeric membranes are useful tools for water filtration processes, with their performance strongly dependent on the presence of hydrophilic dopants. In this study, polyaniline (PANI)-capped aluminosilicate (halloysite) nanotubes (HNTs) are dispersed into polyether sulfone (PES), with concentrations ranging from 0.5 to 1.5 wt%, [...] Read more.

Polymeric membranes are useful tools for water filtration processes, with their performance strongly dependent on the presence of hydrophilic dopants. In this study, polyaniline (PANI)-capped aluminosilicate (halloysite) nanotubes (HNTs) are dispersed into polyether sulfone (PES), with concentrations ranging from 0.5 to 1.5 wt%, to modify the properties of the PES membrane. Both undoped and HNT-doped PES membranes are investigated in terms of wettability (static and time-dependent contact angle), permeance, mechanical resistance, and morphology (using scanning electron microscopy (SEM)). The higher water permeance observed for the PES membranes incorporating PANI-capped HNTs is, finally, assessed and discussed vis-à-vis the real distribution of HNTs. Indeed, the imaging and characterization in terms of composition, spatial arrangement, and counting of HNTs embedded within the polymeric matrix are demonstrated using non-destructive Micro Particle Induced X-ray Emission (µ-PIXE) and Scanning Transmission Ion Microscopy (STIM) techniques. This approach not only exhibits the unique ability to detect/highlight the distribution of HNTs incorporated throughout the whole thickness of polymer membranes and provide volumetric morphological information consistent with SEM imaging, but also overcomes the limits of the most common analytical techniques exploiting electron probes. These aspects are comprehensively discussed in terms of practical analysis advantages. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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17 pages, 7284 KiB  

Open AccessArticle

Fabrication of High Impact-Resistant Polyimide Nanocomposites with Outstanding Thermomechanical Properties

by Jimmy Longun and Jude O. Iroh

Polymers 2023, 15(22), 4427; https://doi.org/10.3390/polym15224427 - 16 Nov 2023

Cited by 2 | Viewed by 1396

Abstract

Neat polyimide films are known to be dense and rigid. They are therefore not suitable for use in membranes, sensors and sustainable energy storage applications. In this study, a novel technique has been used to simultaneously improve the porosity, rigidity, damping ability and [...] Read more.

Neat polyimide films are known to be dense and rigid. They are therefore not suitable for use in membranes, sensors and sustainable energy storage applications. In this study, a novel technique has been used to simultaneously improve the porosity, rigidity, damping ability and impact resistance of polyimide membranes. It is demonstrated that dispersion of a small amount of polyaniline copolymer-modified clay of about 0.25–0.5 wt.% into the polyimide matrix resulted in an enhanced storage modulus while maintaining high damping ability and glass transition temperature, T_g. Novel polyimide/substituted polyaniline-copolymer-clay nanocomposite membranes containing poly(N-ethyl-aniline-co-aniline-2-sulfonic-acid)-modified-clay (SPNEAC) was successfully prepared and incorporated into the polyimide matrix to form modified clay/polyimide nanocomposites. UV-Vis analysis of the nanocomposite films shows that the optical transparency of the SPNEAC-PI nanocomposite membranes decreased with increasing SPNEAC concentration due to the high UV-Vis absorption of SPNEAC. Transmittance of about 3% was observed in the nanocomposite membrane containing 5 wt.% modified clay at 500 nm wavelength, which is significantly lower than that for the neat PI membrane of about 36%. The dispersion of SPNEAC containing a high concentration of clay (≥40 wt.% clay), in polyimide matrix, resulted in the attainment of a higher degree of imidization than was possible for the organoclay/polyimide nanocomposite. This behavior is believed to be due to the synergistic interaction between PI and SPNEAC. A correlation of the morphology and elastic modulus of the SPNEAC2/PI nanocomposites shows that at low loading of SPNEAC 2 ≤ 0.5 wt.%, the cross-sectional morphology of the composite is an open, spiky, weblike structure with a storage modulus of about 1 GPa, but it progressively evolves into densely packed microspheroids with storage moduli of ≥2 GPa at 10 wt.% SPNEAC2. The impact energy of SPNEAC/PI composites, calculated from the α-transition peak area, increased with increasing SPNEAC loading and were about 4 times that of neat PI at 10 wt.% SPNEAC. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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19 pages, 8705 KiB  

Open AccessArticle

The Effect of Organic Acid Dopants on the Specific Capacitance of Electrodeposited Polypyrrole-Carbon Nanotube/Polyimide Composite Electrodes

by Ruchinda Gooneratne and Jude O. Iroh

Energies 2023, 16(22), 7462; https://doi.org/10.3390/en16227462 - 7 Nov 2023

Viewed by 1300

Abstract

Energy storage materials are constantly being improved and developed to cope with the ever-increasing demand of the electronic devices industry. Various synthetic approaches have been used to manufacture electrode materials. This paper is focused on the use of intrinsically conductive polymers such as [...] Read more.

Energy storage materials are constantly being improved and developed to cope with the ever-increasing demand of the electronic devices industry. Various synthetic approaches have been used to manufacture electrode materials. This paper is focused on the use of intrinsically conductive polymers such as polypyrrole (PPy) in the development of single-walled carbon nanotube-polyimide, SWCNT-PI, supercapacitor electrode materials. The polypyrrole used in the study is doped with different organic acid dopants of various sizes, including styrene sulfonic acid, SSA, toluene sulfonic acid, TSA, dodecylbenzene sulfonic acid, DBSA, naphthalene disulfonic acid, NDSA, and naphthalene trisulfonic acid, NTSA. The number of sulfonic acid functional group per dopant molecule varied from one to three, while the number of benzene rings in the aromatic unit varied from one to two. It is believed that, as the sulfonic acid to the dopant molecule ratio changes, the morphology and electrochemical properties of the doped PPy-coated electrode material will change accordingly. The change in the morphology of the doped PPy, due to the respective dopant, is correlated with the change in the electrochemical properties of the modified composite electrode. The naphthalene trisulfonic acid (NTSA) dopant was found to produce the highest specific capacitance of about 119 F/g at 5 mV/s. Furthermore, the NTSA-doped PPy electrode system showed the highest porosity and highest tan delta damping peak height for the a-transition. The styrene sulfonic acid-doped PPy/SWCNT-PI electrode material showed an impressive storage modulus of more than 2 GPa, but lower porosity. Styrene polymerization is believed to have occurred. The results obtained indicate that the porosity and electrochemical properties of the electrode materials are correlated. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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16 pages, 25054 KiB  

Open AccessArticle

Fractographic Investigation of Cryogenic Temperature Mode-II Delamination Behavior of Filament Wound CFRP Laminates with Varied Resin Systems

by Recep Ufuk, Kaan Bilge, Barış Emre Kıral, Murat Ereke and Arif Karabeyoğlu

J. Compos. Sci. 2023, 7(11), 450; https://doi.org/10.3390/jcs7110450 - 30 Oct 2023

Cited by 2 | Viewed by 2936

Abstract

This study investigates the mode-II delamination performance of filament-wound unidirectional composites with different types of epoxies as their matrix phase under room and cryogenic temperatures. A typical vacuum infusion resin, an aerospace-grade cold-curing resin and crack-resistant toughened resin systems were wet-wound with 12K [...] Read more.

This study investigates the mode-II delamination performance of filament-wound unidirectional composites with different types of epoxies as their matrix phase under room and cryogenic temperatures. A typical vacuum infusion resin, an aerospace-grade cold-curing resin and crack-resistant toughened resin systems were wet-wound with 12K carbon fiber tows to manufacture the composite samples. Test samples with a (0)₁₆ ply sequence were tested according to ASTM D7905-19. The tested samples were investigated via microscopic analysis to assess the failure mechanisms associated with varying the matrix material and temperature. ENF tests at room temperature were found to be susceptible to the inherent variance in the fiber architectures along with resin-viscosity-driven fiber wetting. Cryogenic conditions induce a shift in the mode-II delamination behavior from a rather complex failure mechanism to a consistent fiber/matrix debonding mode with diminishing G_IIc values except for the toughened resin system. The provided comprehensive fractographic analysis enables an understanding of the various causes of fracture, which determines the laminate performance. The combined evaluation of the distinctive damage modes reported in this study provides guidance on the conventional wet-winding process, which still remains a volumetrically dominant and viable option for cryogenic applications, particularly for vessels with limited operational durations like sounding rockets. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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18 pages, 28775 KiB  

Open AccessArticle

Impact Resistance of 3D-Printed Continuous Hybrid Fiber-Reinforced Composites

by Ali Akmal Zia, Xiaoyong Tian, Muhammad Jawad Ahmad, Zhou Tao, Luo Meng, Jin Zhou, Daokang Zhang, Wenxin Zhang, Jiangwei Qi and Dichen Li

Polymers 2023, 15(21), 4209; https://doi.org/10.3390/polym15214209 - 24 Oct 2023

Cited by 4 | Viewed by 2082

Abstract

Improving the resilience of 3D-printed composites through material extrusion technology (MEX) is an ongoing challenge in order to meet the rigorous requirements of critical applications. The primary objective of this research was to enhance the impact resistance of 3D-printed composites by incorporating continuous [...] Read more.

Improving the resilience of 3D-printed composites through material extrusion technology (MEX) is an ongoing challenge in order to meet the rigorous requirements of critical applications. The primary objective of this research was to enhance the impact resistance of 3D-printed composites by incorporating continuous hybrid fibers. Herein, continuous virgin carbon (1k) and Kevlar (130D and 200D) fibers were used with different weight and volume fractions as reinforcing fibers to produce hybrid and non-hybrid composites for impact resistance testing to obtain energy absorption with different impact energies: 20 J, 30 J, 40 J, and 50 J. Moreover, 0°/90° fiber orientations were used. Hybrid composites with combinations of PLA + CF + 130D KF and PLA + CF + 200D KF showed higher impact resistance, less damaged areas (71.45% to 90.486%), and higher energy absorption (5.52–11.64% more) behaviors compared to PLA + CF non-hybrids. CT scan images provided strong evidence to resist the fracture and breakage patterns, because the stiffness and elongation properties of the fibers acted together in the hybrids specimens. Furthermore, positive hybrid effects of the PLA + CF + KF hybrids also showed an ideal match of toughness and flexibility in order to resist the impacts. In the future, these hybrids will have the potential to replace the single type of composites in the fields of aerospace and automobiles. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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21 pages, 9930 KiB  

Open AccessArticle

Impact Testing and Modelling of Composite Laminate Panels for Use in Off-Road Racing Vehicle Belly Guards

by Tim Brinkmann and Christiaan R. Bester

J. Compos. Sci. 2023, 7(10), 440; https://doi.org/10.3390/jcs7100440 - 17 Oct 2023

Viewed by 1475

Abstract

Off-road racing vehicles require protection on the underside of their chassis in order to protect vital components from impact damage. The use of composites in thin laminate form to achieve this protection is widespread, although failure due to impact from foreign objects still [...] Read more.

Off-road racing vehicles require protection on the underside of their chassis in order to protect vital components from impact damage. The use of composites in thin laminate form to achieve this protection is widespread, although failure due to impact from foreign objects still occurs. The use of UHMWPE (Ultra High-Molecular Weight Polyethylene) fibres, which have superior mechanical properties to aramid fibres in vehicle belly guards, is not prevalent and, hence, could prove useful in this application. A comprehensive Finite Element Analysis (FEA) is performed in order to determine suitable laminate panel layups that can be tested, analysed, and compared to the original laminate layup, which comprises six layers of aramid and two layers of carbon fibre fabrics. This provides initial insight into the comparison of the new proposed laminates and reveals if improvements have been made. The laminates found using FEA are manufactured into panels that represent the fixture and loading cases seen in racing vehicles. Experimental testing is carried out on the various panels, and the results are compared to those of the mathematical modelling. Substituting the currently used carbon fibres with more aramid fibres increases the impact resistance of the panel. Using UHMWPE fibres greatly increases the impact resistance of the panel; however, fibre delamination becomes more prevalent. This is due to the poor fibre wettability of UHMWPE fibres and the large strain before failure of the fibres. The modelled results show good agreement with the experimental results in terms of the locations at which damage occurred. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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15 pages, 3808 KiB  

Open AccessArticle

Modified Polyethylene Foams for Insulation Systems

by Sabu Thomas, Karapet Armenovich Ter-Zakaryan, Aleksey Dmitrievich Zhukov and Igor’ Vyacheslavovich Bessonov

Polymers 2023, 15(20), 4104; https://doi.org/10.3390/polym15204104 - 16 Oct 2023

Cited by 2 | Viewed by 2162

Abstract

Effective insulation of buildings and other industrial objects requires the use of materials and system solutions that ensure maximum uniformity and density of insulation shells. The study focuses on the development of insulation systems based on expanded polyethylene and, in particular, on the [...] Read more.

Effective insulation of buildings and other industrial objects requires the use of materials and system solutions that ensure maximum uniformity and density of insulation shells. The study focuses on the development of insulation systems based on expanded polyethylene and, in particular, on the development of modified polyethylene with reduced flammability containing a flame-retardant modified montmorillonite clay, which does not hinder gas formation, and silicate nanofillers in layered construction. Active experiments based on mathematical design methods allowed us to establish an analytical relationship between flame-retardant and modifier consumption and extruder pressure and response functions: average density of polyethylene foam and flammability criterion. The flammability criterion was taken as the oxygen index of the modified polyethylene foam. A foaming agent masterbatch was used as the flame retardant. Analytical optimization of mathematical models obtained as a result of active experiments allowed us to determine the optimal flame-retardant consumption, which was 3.7–3.8% of the polymer mass. Optimised systems for average density and oxygen index of flammability of modified polyethylene were obtained. A nomogram for predicting the material properties and selecting the composition, and an algorithm for a computer program for evaluating the properties of modified polyethylene foam as a function of the values of various factors, were developed. Taking into account the possible expansion of the scope of application of rolled polyethylene foam and seamless insulation shells based on it, possible solutions for insulation systems were studied using the program THERM, and a combined insulation system was adopted. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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13 pages, 3333 KiB  

Open AccessArticle

Investigation of Thermal, Mechanical and Shape Memory Properties of 3D-Printed Functionally Graded Nanocomposite Materials

by Mohamad Alsaadi, Eoin P. Hinchy, Conor T. McCarthy, Vicente F. Moritz, Alexandre Portela and Declan M. Devine

Nanomaterials 2023, 13(19), 2658; https://doi.org/10.3390/nano13192658 - 28 Sep 2023

Cited by 4 | Viewed by 1368

Abstract

In this study, a 3D-printed photocurable resin was developed by incorporating graphene nanoplatelets functionalised with melamine to investigate the thermal, mechanical, fracture and shape memory behaviours. The objective of this work was to produce a printed functionally graded nanocomposite material that has a [...] Read more.

In this study, a 3D-printed photocurable resin was developed by incorporating graphene nanoplatelets functionalised with melamine to investigate the thermal, mechanical, fracture and shape memory behaviours. The objective of this work was to produce a printed functionally graded nanocomposite material that has a smart temperature-responsive structure; presents good thermal stability, strength and fracture toughness; and can demonstrate shape-changing motions, such as sequential transformations, over time. The functionalised graphene nanoplatelets were examined via thermogravimetric analysis, Fourier transform infrared spectroscopy, Raman spectroscopy and ultraviolet–visible spectroscopy. Thermogravimetric analysis showed that the degradation temperature of the nanocomposite containing 0.1 wt% of functionalised graphene nanoplatelets at the weight loss of 5% was 304 °C, greater than that of the neat one by 29%. Dynamic mechanical analysis results showed property enhancements of the storage modulus and glass transition temperature. Fracture toughness, tensile strength and impact resistance were improved by 18%, 35% and 78%, respectively. The shape memory tests were performed to obtain the temperature-time recovery behaviour of the 3D-printed structures. The addition of functionalised graphene nanoplatelets demonstrated an enhancement in the shape recovery ratios. Generally, the five subsequent cycles were notably stable with a high recovery ratio of 97–100% for the flat shape and circular shape of the M-GNP specimens. On the other hand, these values were between 91% and 94% for the corresponding neat specimens. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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16 pages, 10204 KiB  

Open AccessArticle

On the Structural, Thermal, Micromechanical and Tribological Characterizations of Cu-Filled Acrylonitrile Butadiene Styrene Micro-Composites

by Mabrouka Akrout, Basma Ben Difallah, Mohamed Kharrat, Maher Dammak, António Pereira, Filipe J. Oliveira and Isabel Duarte

Materials 2023, 16(19), 6428; https://doi.org/10.3390/ma16196428 - 27 Sep 2023

Cited by 3 | Viewed by 1084

Abstract

The purpose of this work was to investigate the structural, thermal, micromechanical and tribological properties of novel polymer/metal composite materials for bearing applications. Copper (Cu)-filled Acrylonitrile Butadiene Styrene (ABS) composites were mixed in a laboratory scale by an internal mixer with two blade [...] Read more.

The purpose of this work was to investigate the structural, thermal, micromechanical and tribological properties of novel polymer/metal composite materials for bearing applications. Copper (Cu)-filled Acrylonitrile Butadiene Styrene (ABS) composites were mixed in a laboratory scale by an internal mixer with two blade impellers, and then injection-molded. Neat ABS, ABS+5wt% Cu, ABS+10wt% Cu, and ABS+15wt% Cu were the four materials that were tested. The dispersion of Cu particles in the ABS matrix was investigated using Scanning Electron Microscopy (SEM) and a micro-tomography scan. The filler particles have a uniform distribution in the matrix, according to the observations. The incorporation of Cu filler also refined an increase in the glass transition temperature from Differential Scanning Calorimetry (DSC) and less intensity in the amorphous phase by X-ray diffraction (XRD). Nanoindentation tests were carried out to characterize the micro-mechanical behavior of the composites. Friction and wear analysis were also examined using a pin-on-disk tribometer. Compared with neat ABS, all the micro-composites showed much higher indentation hardness, Vickers hardness, and indentation elastic modulus. It was also concluded that the incorporation of Cu filler into ABS simultaneously improved the friction and wear properties of the composites, which contributed to the suitability of the micro-filled composites with hard metallic particles for a wider range of mechanical components for bearing applications. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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17 pages, 16425 KiB  

Open AccessArticle

Analysis of Ballistic Impact of 7.62 mm FMJ M80 Rifle Projectile into Twaron/UHMWPE Composite Armor

by Jindřich Viliš, Vlastimil Neumann, Roman Vítek, Jan Zouhar, Zdeněk Pokorný and Milan Marek

J. Compos. Sci. 2023, 7(9), 390; https://doi.org/10.3390/jcs7090390 - 14 Sep 2023

Cited by 1 | Viewed by 1986

Abstract

This article deals with the ballistic impact of the 7.62 mm FMJ M80 rifle projectile into the laminated Twaron/UHMWPE composite armor. The armor composition consisted of composite panels made from Twaron CT 747 para-aramid fabric and ultra-high-molecular-weight Endumax Shield XF33 polyethylene. To analyze [...] Read more.

This article deals with the ballistic impact of the 7.62 mm FMJ M80 rifle projectile into the laminated Twaron/UHMWPE composite armor. The armor composition consisted of composite panels made from Twaron CT 747 para-aramid fabric and ultra-high-molecular-weight Endumax Shield XF33 polyethylene. To analyze the ballistic impact and to verify the resistance of the designed armor according to the NATO AEP 4569 STANAG standard, protection level 1, 7.62 × 51 mm FMJ NATO M80 rifle cartridges with lead projectiles were used in the ballistic experiment. After the projectile impact, the damage failure mechanisms of the composite panels were documented. As part of the evaluation of the experiments, the initial microstructure of the composite panels was documented, and subsequently, the damaged areas of the composite armor after the ballistic experiment were also documented. Optical and scanning electron microscopy were used to document the structures. The important parameter of composite armor is its mechanical properties. The surface hardness of the composite panels was measured by the Shore D method using the hardness tester DIGI-Test II. The results obtained from the ballistic experiment demonstrate that the designed Twaron/Endumax armor was not penetrated. This armor has sustained multiple impacts for all three 7.62 mm FMJ M80 projectiles and is suitable for the construction of armor protection. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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18 pages, 4895 KiB  

Open AccessArticle

A Hyper-Pseudoelastic Model of Cyclic Stress-Softening Effect for Rubber Composites

by Yifeng Dong, Yutong Fu, Chunwang He and Daining Fang

Polymers 2023, 15(14), 3033; https://doi.org/10.3390/polym15143033 - 13 Jul 2023

Cited by 2 | Viewed by 1392

Abstract

Rubber composites are hyperelastic materials with obvious stress-softening effects during the cyclic loading–unloading process. In previous studies, it is hard to obtain the stress responses of rubber composites at arbitrary loading–unloading orders directly. In this paper, a hyper-pseudoelastic model is developed to characterize [...] Read more.

Rubber composites are hyperelastic materials with obvious stress-softening effects during the cyclic loading–unloading process. In previous studies, it is hard to obtain the stress responses of rubber composites at arbitrary loading–unloading orders directly. In this paper, a hyper-pseudoelastic model is developed to characterize the cyclic stress-softening effect of rubber composites with a fixed stretch amplitude at arbitrary loading–unloading order. The theoretical relationship between strain energy function and cyclic loading–unloading order is correlated by the hyper-pseudoelastic model directly. Initially, the basic laws of the cyclic stress-softening effect of rubber composites are revealed based on the cyclic loading–unloading experiments. Then, a theoretical relationship between the strain energy evolution function and loading–unloading order, as well as the pseudoelastic theory, is developed. Additionally, the basic constraints that the strain energy evolution function must satisfy in the presence or absence of residual deformation effect are derived. Finally, the calibration process of material parameters in the hyper-pseudoelastic model is also presented. The validity of the hyper-pseudoelastic model is demonstrated via the comparisons to experimental data of rubber composites with different filler contents. This paper presents a theoretical model for characterizing the stress-softening effect of rubber composites during the cyclic loading–unloading process. The proposed theoretical model can accurately predict the evolution of the mechanical behavior of rubber composites with the number of loading–unloading cycles, which provides scientific guidance for predicting the durability properties and analyzing the fatigue performance of rubber composites. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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17 pages, 5429 KiB  

Open AccessArticle

Dynamic Crushing Behavior of Ethylene Vinyl Acetate Copolymer Foam Based on Energy Method

by Yueqing Xing, Xiya Guo, Guowei Shu and Xiaolong He

Polymers 2023, 15(14), 3016; https://doi.org/10.3390/polym15143016 - 12 Jul 2023

Cited by 3 | Viewed by 1495

Abstract

This paper aimed to experimentally clarify the dynamic crushing mechanism and performance of ethylene vinyl acetate copolymer (EVA) and analyze the influence of density and thickness on its mechanical behavior and energy absorption properties under dynamic impact loadings. Hence, a series of dynamic [...] Read more.

This paper aimed to experimentally clarify the dynamic crushing mechanism and performance of ethylene vinyl acetate copolymer (EVA) and analyze the influence of density and thickness on its mechanical behavior and energy absorption properties under dynamic impact loadings. Hence, a series of dynamic compression tests were carried out on EVA foams with different densities and thicknesses. When the impact energy is 66.64 J, for foam with a density of 150 kg/m³, the maximum contact force, maximum displacement, maximum strain, absorbed energy, and specific energy absorption (SEA) increased by 20 ± 2%, −38.5 ± 2%, −38.5 ± 2%, 4 ± 2%, and 105 ± 2%, respectively, compared to foam with a density of 70 kg/m³. The ratios of absorbed energy to impact energy for different thickness specimens are almost equal. The specimen density has no effect on the efficiency of energy absorption and has a greater effect on the SEA. Meanwhile, when the impact energy-to-thickness ratio is 1680 J/m, compared to foam with a thickness of 30 mm, the maximum contact force, maximum displacement, maximum strain, absorbed energy, and SEA for foam with a thickness of 60 mm increased by 28.5 ± 2%, 211.3 ± 2%, 56.6 ± 2%, 100.8 ± 2%, and 0.4 ± 0.5%, respectively. When the impact energy is 66.64 J, compared to foam with a thickness of 30 mm, the maximum contact force, maximum displacement, maximum stain, absorbed energy, and SEA for foam with a thickness of 60 mm increased by −42.5 ± 2%, 163.5 ± 2%, 31.7 ± 2%, 4.1 ± 2%, and 4.1 ± 2%, respectively. The SEA of two different-thickness EVA specimens is almost equal, about 2.8 J/g. The ratios of absorbed energy to impact energy for different thickness specimens are almost equal, both at 72%. The specimen thickness has no effect on the efficiency of energy absorption and has a greater effect on the maximum contact force. In the range of impact energy, thickness, and density studied, the absorbed energy and SEA are not affected by the thickness of EVA specimens and are determined by the impact energy. The density has no significant effect on the absorbed energy but has a greater effect on the SEA. However, for EVA foams, the greater the density, the greater the mass, and the higher the cost. Taking into account lightweight and cost factors, when optimizing cushioning design within a safe range, we can choose EVA foams with a smaller density and thickness. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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20 pages, 2890 KiB  

Open AccessArticle

The Influence of the Dispersion Method on the Morphological, Curing, and Mechanical Properties of NR/SBR Reinforced with Nano-Calcium Carbonate

by Mehrnoosh Damircheli and AmirHossein MajidiRad

Polymers 2023, 15(13), 2963; https://doi.org/10.3390/polym15132963 - 6 Jul 2023

Cited by 3 | Viewed by 2018

Abstract

There are several reasons for the development of nanopolymer compounds, such as improving physical, mechanical, and chemical properties, increasing lifespan, reducing costs, and decreasing negative environmental impact. The compatibility of two rubbers and mineral nanofillers in nanocomposites is a challenge that needs to [...] Read more.

There are several reasons for the development of nanopolymer compounds, such as improving physical, mechanical, and chemical properties, increasing lifespan, reducing costs, and decreasing negative environmental impact. The compatibility of two rubbers and mineral nanofillers in nanocomposites is a challenge that needs to be studied, and the effect of nanofillers on morphological, physical, and mechanical properties should be investigated accordingly. In this study, calcium carbonate nanoparticles were added to a polymer compound that included natural rubber (NR), styrene-butadiene rubber (SBR), vulcanization accelerators, and other additives. For mixing nanoparticles in the polymer matrix, various methods were used, including the solvent method in toluene and W410 solvents and the surface modification of calcium carbonate nanoparticles with stearic acid. The effect of dispersion nanoparticles in nanocomposite specimens on morphology, curing characteristics, and mechanical properties was studied. The morphologies of specimens were determined by X-ray diffraction (XRD) analysis and field emission scanning electron microscopy (FESEM). The particle size of the nanocomposite was approximately 34 nm, and the interlayer spacing between crystal plates increased from 2.81 nm to 3.03 nm. These results indicate a uniform dispersion of nanoparticles, specifically with an optimum content of 3.52%, in the compounds prepared through all mixing methods, with no agglomeration observed in the nanocomposites. The results of the nanocomposites’ curing characterization demonstrate that with the addition of nanoparticles, a strong bond is created in the polymer chains, and curing properties are improved. Among the dispersion methods, the highest percentage improvement in curing properties is observed with the solvent method W410. To evaluate the effect of the addition of calcium carbonate nanoparticles and the dispersion method on improving mechanical properties, tensile, tear, hardness, and rebound resilience tests were performed. In tensile tests, the surface modification method showed the highest enhancement in ultimate stress (80%), followed by the W410 method (64%) and toluene method (63.7%). Tear strength improvements were highest in the W410-solvent sample (80%), followed by the surface modification method (57%) and the solvent-toluene method (50%). The W410 method resulted in the hardest samples, while the surface-modified samples had the lowest hardness. The addition of CaCO3 nanofillers reduced rebound resilience, with the W410 method experiencing the largest reduction (10.64%), followed by the toluene method (6.38%), and with the surface-modified samples showing the lowest reduction (4.25%). The results show that in the W410 solvent method, the nanocomposite is more elastic than for other methods. Additionally, for most of the mechanical properties, the W410 method results in the most growth in improvement. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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15 pages, 10504 KiB  

Open AccessArticle

Long-Term Aging Behavior of Plastic/Styrene Butadiene Rubber (SBR) Composite Modified Bitumen

by Chengwei Xing, Mingchen Li, Lingxiao Liu and Ruikang Yang

Materials 2023, 16(13), 4567; https://doi.org/10.3390/ma16134567 - 24 Jun 2023

Cited by 4 | Viewed by 1421

Abstract

The reuse of recycled waste plastics has long been attempted in pavement engineering as bitumen modifier. It was revealed that waste plastics can significantly enhance the high-temperature performance of bitumen and bitumen mixtures. Even so, the application of waste plastics as a bitumen [...] Read more.

The reuse of recycled waste plastics has long been attempted in pavement engineering as bitumen modifier. It was revealed that waste plastics can significantly enhance the high-temperature performance of bitumen and bitumen mixtures. Even so, the application of waste plastics as a bitumen modifier is still not widespread. This is attributable to the generally poor low-temperature performance of plastic-modified bitumen, which often fails to meet specification requirements. For this purpose, styrene butadiene rubber (SBR) was selected to improve the low-temperature performance of plastic-modified bitumen. However, due to the long-term aging process, the composite and structure of the modified bitumen will change, which negatively impacts its performance. The objective of this study is to investigate the long-term aging behavior of plastic/SBR composite-modified bitumen. For this purpose, waste polyethylene was used as a plastic modifier and was mixed with base bitumen and 3% SBR at ratios 4.5%, 6% and 7.5%. The rheological properties and molecular weight distribution of base bitumen, plastic and plastic/SBR-modified bitumen before and after long-term aging were measured. Results show that the incorporation of plastic can improve the complex modulus, rutting factor and percent recovery of bitumen and reduce the non-recoverable creep compliance of the bitumen, indicating the modification process enhances the high-temperature performance of bitumen. The enhancement effect is more pronounced with the increase of plastic content. For modified bitumen with 7.5% plastic modifier, the complex modulus of modified bitumen is increased by 1127.55% compared to base bitumen. The addition of 3% SBR modifier can further improve the high-temperature performance of the modified bitumen. In addition, the modification process also increases the large molecule size percentage (LMSP) and weight average molecular weight of bitumen. Compared with weight average molecular weight, the LMSP correlates well with the rheological properties of modified bitumen. In accordance with the complex modulus, using the LMSP and weight average molecular weight of bitumen before and after aging, the corresponding aging index was calculated. The quantitative results showed that the addition of plastic modifier can improve the aging resistance of bitumen, but the enhancement effect is not as obvious as that of SBR modifier. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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18 pages, 7960 KiB  

Open AccessArticle

Wood Cellulose Nanofibers Grafted with Poly(ε-caprolactone) Catalyzed by ZnEu-MOF for Functionalization and Surface Modification of PCL Films

by Jinying Pang, Tanlin Jiang, Zhilin Ke, Yu Xiao, Weizhou Li, Shuhua Zhang and Penghu Guo

Nanomaterials 2023, 13(13), 1904; https://doi.org/10.3390/nano13131904 - 21 Jun 2023

Cited by 3 | Viewed by 1868

Abstract

Renewable cellulose nanofiber (CNF)-reinforced biodegradable polymers (such as polycaprolactone (PCL)) are used in agriculture, food packaging, and sustained drug release. However, the interfacial incompatibility between hydrophilic CNFs and hydrophobic PCL has limited further application as high-performance biomaterials. In this work, using a novel [...] Read more.

Renewable cellulose nanofiber (CNF)-reinforced biodegradable polymers (such as polycaprolactone (PCL)) are used in agriculture, food packaging, and sustained drug release. However, the interfacial incompatibility between hydrophilic CNFs and hydrophobic PCL has limited further application as high-performance biomaterials. In this work, using a novel ZnEu-MOF as the catalyst, graft copolymers (GCL) with CNFs were grafted with poly(ε-caprolactone) (ε-CL) via homogeneous ring-opening polymerization (ROP), and used as strengthening/toughening nanofillers for PCL to fabricate light composite films (LCFs). The results showed that the ZnEu-MOF ([ZnEu(L)₂(HL)(H₂O)_0.39(CH₃OH)_0.61]·H₂O, H₂L is 5-(1H-imidazol-1-yl)-1,3-benzenedicarboxylic acids) was an efficient catalyst, with low toxicity, good stability, and fluorescence emissions, and the GCL could efficiently promote the dispersion of CNFs and improve the compatibility of the CNFs and PCL. Due to the synergistic effect of the ZnEu-MOF and CNFs, considerable improvements in the mechanical properties and high-intensity fluorescence were obtained in the LCFs. The 4 wt% GCL provided the LCF with the highest strength and elastic modulus, which increased by 247.75% and 109.94% compared to CNF/PCL, respectively, showing the best elongation at break of 917%, which was 33-fold higher than CNF/PCL. Therefore, the ZnEu-MOF represented a novel bifunctional material for ROP reactions and offered a promising modification strategy for preparing high-performance polymer composites for agriculture and biomedical applications. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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16 pages, 29138 KiB  

Open AccessFeature PaperArticle

Modelling Electro-Mechanical Behaviour of an XLPE Insulation Layer for Hi-Voltage Composite Power Cables: Effect of Voids on Onset of Coalescence

by Michele Miceli, Valter Carvelli and Monssef Drissi-Habti

Energies 2023, 16(12), 4620; https://doi.org/10.3390/en16124620 - 9 Jun 2023

Cited by 5 | Viewed by 1718

Abstract

The harshness of the submarine environment represents a serious threat for immersed high voltage power cables, extensively used for offshore wind farms, which in turn are supposed to last for at least 20 years for their total investment to be economically viable. The [...] Read more.

The harshness of the submarine environment represents a serious threat for immersed high voltage power cables, extensively used for offshore wind farms, which in turn are supposed to last for at least 20 years for their total investment to be economically viable. The Crosslinked Polyethylene (XLPE) used for the insulating layer of the cables may suffer different degradation phenomena, leading to unexpected breakdowns and rises in costs. In this work, numerical simulations have been developed to study the mechanisms by which micrometric pores inside XLPE can enlarge and coalesce (namely, water treeing) when the insulation is subjected to the intense electric field generated by hi-voltage wires. The study aim is to predict material plasticization next to voids, which is supposed to represent the onset of coalescence of neighboring pores. A microscale-level finite element coupled electro-mechanics model has been developed to describe the interactions between the intense electric fields and the subsequent Maxwell stresses in a dielectric. The roles of different influencing parameters such as distance, relative volumes, and the shape of two neighboring voids in a representative unit volume are considered. Finally, the behavior of a generic microstructure characterized by randomly distributed voids immersed in an electric field is simulated. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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16 pages, 6327 KiB  

Open AccessArticle

Tensile Performance Mechanism for Bamboo Fiber-Reinforced, Palm Oil-Based Resin Bio-Composites Using Finite Element Simulation and Machine Learning

by Wenjing Wang, Yuchao Wu, Wendi Liu, Tengfei Fu, Renhui Qiu and Shuyi Wu

Polymers 2023, 15(12), 2633; https://doi.org/10.3390/polym15122633 - 9 Jun 2023

Cited by 9 | Viewed by 1771

Abstract

Plant fiber-reinforced composites have the advantages of environmental friendliness, sustainability, and high specific strength and modulus. They are widely used as low-carbon emission materials in automobiles, construction, and buildings. The prediction of their mechanical performance is critical for material optimal design and application. [...] Read more.

Plant fiber-reinforced composites have the advantages of environmental friendliness, sustainability, and high specific strength and modulus. They are widely used as low-carbon emission materials in automobiles, construction, and buildings. The prediction of their mechanical performance is critical for material optimal design and application. However, the variation in the physical structure of plant fibers, the randomness of meso-structures, and the multiple material parameters of composites limit the optimal design of the composite mechanical properties. Based on tensile experiments on bamboo fiber-reinforced, palm oil-based resin composites, finite element simulations were carried out and the effect of material parameters on the tensile performances of the composites was investigated. In addition, machine learning methods were used to predict the tensile properties of the composites. The numerical results showed that the resin type, contact interface, fiber volume fraction, and multi-factor coupling significantly influenced the tensile performance of the composites. The results of the machine learning analysis showed that the gradient boosting decision tree method had the best prediction performance for the tensile strength of the composites (R² was 0.786) based on numerical simulation data from a small sample size. Furthermore, the machine learning analysis demonstrated that the resin performance and fiber volume fraction were critical parameters for the tensile strength of composites. This study provides an insightful understanding and effective route for investigating the tensile performance of complex bio-composites. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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11 pages, 5706 KiB  

Open AccessArticle

Preparation and Characterization of Carbide Particle-Toughened Si–B System of High Thermostability Polycrystalline Diamond by HPHT Sintering

by Yunqi Zhang, Yumei Zhu and Zhihong Li

Materials 2023, 16(11), 3933; https://doi.org/10.3390/ma16113933 - 24 May 2023

Viewed by 1294

Abstract

In this research, we report the synthesis of Si–TmC–B/PCD composites using Si, B, and transition metal carbide particles (TmC) as binders at high pressure and high temperature (HPHT method, 5.5 GPa and 1450 °C). The microstructure, elemental distribution, phase composition, thermal stability, and [...] Read more.

In this research, we report the synthesis of Si–TmC–B/PCD composites using Si, B, and transition metal carbide particles (TmC) as binders at high pressure and high temperature (HPHT method, 5.5 GPa and 1450 °C). The microstructure, elemental distribution, phase composition, thermal stability, and mechanical properties of PCD composites were systematically investigated. The Si–B/PCD sample is thermally stable in air at 919 °C. The initial oxidation temperature of the PCD sample with ZrC particles is as high as 976 °C, and it also has a maximum flexural strength of 762.2 MPa, and the highest fracture toughness of 8.0 MPa·m^1/2. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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20 pages, 3262 KiB  

Open AccessArticle

Effects of the Simultaneous Strengthening of the Glass Fiber Surface and Polyamide-6 Matrix by Plasma Treatment and Nanoclay Addition on the Mechanical Properties of Multiscale Hybrid Composites

by Byeong-Joo Kim, Chang-Bin Oh, Ji Eun Lee and Man Young Lee

J. Compos. Sci. 2023, 7(5), 176; https://doi.org/10.3390/jcs7050176 - 26 Apr 2023

Cited by 2 | Viewed by 1769

Abstract

To strengthen the mechanical properties of a fiber-reinforced plastic without deteriorating its toughness caused by adding nanomaterial, multiscale hybrid composites (MHC) composed of polyamide 6 (PA6), woven glass fibers (WGFs), nanoclay, and various additives were fabricated and characterized. A surfactant was used to [...] Read more.

To strengthen the mechanical properties of a fiber-reinforced plastic without deteriorating its toughness caused by adding nanomaterial, multiscale hybrid composites (MHC) composed of polyamide 6 (PA6), woven glass fibers (WGFs), nanoclay, and various additives were fabricated and characterized. A surfactant was used to improve the dispersion of the nanoclay in the composite, and a compatibilizer and toughening agent were added to enhance the interfacial interactions between the nanoclay and PA6 and the toughness of the MHC, respectively. In addition, the WGFs were pretreated with atmospheric-pressure air plasma to enhance the interfacial bonding between the WGF and the mixture composed of PA6/nanoclay/compatibilizer/toughening agent, which constitutes the matrix. The optimal composition of the PA6 mixture, optimal content of the nanoclay, and optimal conditions of the plasma pretreatment of the WGF surface were experimentally determined. A suitable manufacturing process was employed using a material composition that maximizes the mechanical properties of the MHC by mitigating the toughness deterioration owing to nanoclay addition. An appropriate quantity of the nanoclay increased the tensile properties as well as the elongation at the break of the MHC because the toughening agent prevented the reduction in the degree of elongation caused by increasing the clay content to a certain extent. Moreover, the plasma treatment of the WGF enhanced the flexural properties and impact resistance of the MHC. Therefore, not only the tensile strength, modulus, and elongation at the break of the PA6 nanocomposite, which constitutes the matrix of the MHC, increased up to 39.83, 40.91, and 194.26%, respectively, but also the flexural strength and modulus, absorbed impact energy, and penetration limit of the MHC increased by 20.2, 26.8, 83.7, and 100.0%, respectively. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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19 pages, 4813 KiB  

Open AccessArticle

The Influence of Porosity on Mechanical Properties of PUR-Based Composites: Experimentally Derived Mathematical Approach

by Miroslav Černý, Josef Petruš and Ivana Chamradová

Polymers 2023, 15(8), 1960; https://doi.org/10.3390/polym15081960 - 20 Apr 2023

Cited by 2 | Viewed by 1412

Abstract

The work is focused on the mechanical behavior description of porous filled composites that is not based on simulations or exact physical models, including different assumptions and simplifications with further comparison with real behavior of materials with different extents of accordance. The proposed [...] Read more.

The work is focused on the mechanical behavior description of porous filled composites that is not based on simulations or exact physical models, including different assumptions and simplifications with further comparison with real behavior of materials with different extents of accordance. The proposed process begins by measurement and further fitting of data by spatial exponential function z_c = z_m · p₁^b · p₂^c, where z_c/z_m is mechanical property value for composite/nonporous matrix, p₁/p₂ are suitable dimensionless structural parameters (equal to 1 for nonporous matrix) and b/c are exponents ensuring the best fitting. The fitting is followed by interpolation of b and c, which are logarithmic variables based on the observed mechanical property value of nonporous matrix with additions of further properties of matrix in some cases. The work is dedicated to the utilization of further suitable pairs of structural parameters to one pair published earlier. The proposed mathematical approach was demonstrated for PUR/rubber composites with a wide range of rubber filling, various porosity, and different polyurethane matrices. The mechanical properties derived from tensile testing included elastic modulus, ultimate strength and strain, and energy need for ultimate strain achievement. The proposed relationships between structure/composition and mechanical behavior seem to be suitable for materials containing randomly shaped filler particles and voids and, therefore, could be universal (and also hold materials with less complicated microstructure) after potential following and more exact research. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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15 pages, 5584 KiB  

Open AccessArticle

Study of the Compressive Properties of Heavy Calcium Carbonate-Reinforced Epoxy Composite Spheres (HC-R-EMS) Composite Lightweight Concrete

by Rong Ma, Zheng Cao, Tao Jiang, Ying Wang, Shanshan Shi, Wenge Li, Yuantao Zhao, Ning Zhong, Danda Shi and Xinfeng Wu

Polymers 2023, 15(5), 1278; https://doi.org/10.3390/polym15051278 - 2 Mar 2023

Cited by 4 | Viewed by 1861

Abstract

Lightweight concrete is one of the effective means to solve the problems of structural component weight, energy efficiency, and fire safety in modern civil engineering. Heavy calcium carbonate-reinforced epoxy composite spheres (HC-R-EMS) were prepared by the ball milling method, and HC-R-EMS, cement, and [...] Read more.

Lightweight concrete is one of the effective means to solve the problems of structural component weight, energy efficiency, and fire safety in modern civil engineering. Heavy calcium carbonate-reinforced epoxy composite spheres (HC-R-EMS) were prepared by the ball milling method, and HC-R-EMS, cement, and hollow glass microspheres (HGMS) were mixed into the mold by the molding method to prepare composite lightweight concrete. The relationship between the HC-R-EMS volumetric fraction, the initial inner diameter of the HC-R-EMS, the number of layers of HC-R-EMS, the HGMS volume ratio, the basalt fiber length and content, and the multi-phase composite lightweight concrete density and compressive strength was studied. The experimental results show that the density of the lightweight concrete ranges between 0.953–1.679 g/cm³ and the compressive strength ranges between 1.59–17.26 MPa, where the volume fraction of HC-R-EMS is 90%, the initial internal diameter is 8–9 mm, and the number of layers of HC-R-EMS is three. The lightweight concrete can meet the requirements of high strength (12.67 MPa) and low density (0.953 g/cm³). In addition, the addition of basalt fiber (BF) can effectively improve the compressive strength of the material without changing the density of the material. From a micro-level perspective, HC-R-EMS is closely combined with the cement matrix, which is conducive to increasing the compressive strength of concrete. Basalt fibers connect the matrix into a network, improving the maximum limit force of the concrete. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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12 pages, 3847 KiB  

Open AccessArticle

Investigation on Layer Hybridization of Glass/Carbon Fibre Woven Reinforced Composites Subjected to Low-Speed Impact

by Raluca Maier and Andrei-Cristian Mandoc

J. Compos. Sci. 2023, 7(2), 83; https://doi.org/10.3390/jcs7020083 - 16 Feb 2023

Cited by 6 | Viewed by 1843

Abstract

The present investigation was conducted on the low-speed impact response of quasi-isotropic [±45/0/90°]_xs hybrid composite through laboratory level experimental tests. The purpose was to understand the behaviour that the different stacking sequences of hybrid glass/carbon fibre composites has on the ability of [...] Read more.

The present investigation was conducted on the low-speed impact response of quasi-isotropic [±45/0/90°]_xs hybrid composite through laboratory level experimental tests. The purpose was to understand the behaviour that the different stacking sequences of hybrid glass/carbon fibre composites has on the ability of the material to sustain loads during low-speed impact events without developing critical structural failure in the material and improving the impact energy absorption properties, which is a relevant matter in aerospace and automotive industries. Drop-weight impact tests were carried out on two different laminates, with different stacking sequences, each of which were 16 symmetric inter-ply hybrid laminates named GC [+45G/−45C/0G/90C]₄s and, respectively, G-C [+45G/−45G/0G/90G/+45C/−45C/0C/90C]₂s, where G stands for glass fibre and C for carbon fibre. Both were comprised of epoxy matrix reinforced carbon/E-glass fibre woven fabric composites. The outcome of changing the hybrid stacking sequence, on the impact performances, was discussed. The damage morphologies and local failure mechanisms were analysed using visual inspection and a high-resolution laser scanner. Under 33 J impact energy, both tested hybrid composites exhibited approximately 10 kN peak load. Nevertheless, one key parameter, the time to peak load, significantly changed; the damage initiation threshold for GC samples occurred immediately before 6 kN, whereas for G-C samples this threshold appeared much earlier. This type of behaviour was partly connected to the delay in the propagation of delamination and fibre breakage, which was influenced by the high elastic energy absorption of the carbon fibres when compared with the glass fibres. The absorbed energy was higher for GC configuration, whereas a higher DI was observed for samples G-C indicating that a high percentage of the total energy was dissipated through the propagation of in-plane and out-of-plane fibre/matrix cracks. No perforation was observed on either configuration; nevertheless, the damage area significantly changed both in size and appearance from one configuration to another. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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13 pages, 3195 KiB  

Open AccessArticle

Development of an Innovative Glass/Stainless Steel/Polyamide Commingled Yarn for Fiber–Metal Hybrid Composites

by Anwar Abdkader, Muhammad Furqan Khurshid, Fathi Cherif, Mir Mohammad Badrul Hasan and Chokri Cherif

Materials 2023, 16(4), 1668; https://doi.org/10.3390/ma16041668 - 16 Feb 2023

Cited by 2 | Viewed by 1894

Abstract

Fiber–metal hybrid composites are widely used in high-tech industries due to their unique combination of mechanical, toughness and ductile properties. Currently, hybrid materials made of metals and high-performance fibers have been limited to layer-by-layer hybridization (fiber–metal laminates). However, layer-by-layer hybridization lacks in fiber [...] Read more.

Fiber–metal hybrid composites are widely used in high-tech industries due to their unique combination of mechanical, toughness and ductile properties. Currently, hybrid materials made of metals and high-performance fibers have been limited to layer-by-layer hybridization (fiber–metal laminates). However, layer-by-layer hybridization lacks in fiber to fiber mixing, resulting in poor inter-laminar interfaces. The objective of this paper was to establish the fundamental knowledge and application-related technological principles for the development and fabrication of air-textured commingled yarn composed of glass (GF), stainless steel (SS) and polyamide-6 (PA-6) filaments for fiber–metal hybrid composites. For this purpose, extensive conceptual, design and technological developments were carried out to develop a novel air-texturing nozzle that can produce an innovative metallic commingled yarn. The results show that an innovative metallic commingled yarn was developed using fiber–metal hybrid composites with a composite tensile strength of 700 ± 39 MPa and an E-modulus of 55 ± 7. This shows that the developed metallic commingled yarn is a suitable candidate for producing metal–fiber hybrid composites. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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17 pages, 3089 KiB  

Open AccessArticle

Multiple Reprocessing of Conductive PLA 3D-Printing Filament: Rheology, Morphology, Thermal and Electrochemical Properties Assessment

by Mateusz Cieślik, Agata Rodak, Agnieszka Susik, Natalia Wójcik, Michał Szociński, Jacek Ryl and Krzysztof Formela

Materials 2023, 16(3), 1307; https://doi.org/10.3390/ma16031307 - 3 Feb 2023

Cited by 14 | Viewed by 2925

Abstract

Additive manufacturing technologies are gaining more and more attention, resulting in the development or modification of 3D printing techniques and dedicated materials. On the other hand, economic and ecological aspects force the industry to develop material recycling strategies. In this work, the multiple [...] Read more.

Additive manufacturing technologies are gaining more and more attention, resulting in the development or modification of 3D printing techniques and dedicated materials. On the other hand, economic and ecological aspects force the industry to develop material recycling strategies. In this work, the multiple reprocessing of a commercially available PLA conductive composite with carbon black filler, dedicated to 3D printing, was investigated. The effects of extrusion temperature (190 °C and 200 °C) and reprocessing steps (1–5 steps) on the rheology, morphology, thermal and electrochemical properties of the conductive PLA 3D-printing filament were evaluated. The results showed deterioration of the thermal stability and material strength, as well as the influence of reprocessing on the melting point, which increases after initial melting. The electronic conduction mechanism of the composite depends on the percolation paths and it is also affected by the multiple processing. The reversibility of the [Fe(CN)₆]^3−/4− redox process diminishes with a higher degradation level of the conductive PLA. Importantly, the material fluidity was too high after the multiple reprocessing, which should be considered and suitably corrected during CB–PLA application as a 3D-printed electrode material. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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20 pages, 6988 KiB  

Open AccessArticle

Mechanical Response of Epoxy Resin—Flax Fiber Composites Subjected to Repeated Loading and Creep Recovery Tests

by Constantin Stochioiu, Anton Hadăr and Benoît Piezel

Polymers 2023, 15(3), 766; https://doi.org/10.3390/polym15030766 - 2 Feb 2023

Cited by 2 | Viewed by 2412

Abstract

Flax fiber-reinforced plastics have an innate eco-friendly nature due to the fiber reinforcement and reduced energy requirements in fabrication when compared to current fiber reinforced composite materials. They possess a complex time-dependent material behavior, which is investigated in the present paper. A composite [...] Read more.

Flax fiber-reinforced plastics have an innate eco-friendly nature due to the fiber reinforcement and reduced energy requirements in fabrication when compared to current fiber reinforced composite materials. They possess a complex time-dependent material behavior, which is investigated in the present paper. A composite material with flax fiber reinforcement on the load direction, embedded in an epoxy resin matrix, was studied. The procedures used were tensile tests, repeated loading-recovery, and creep-recovery tests, which were meant to expose the components of the response with respect to stress level and load duration. The results showed an elastic bi-linear behavior, a yield point at approximately 20% of the ultimate tensile stress, and tensile moduli of 35.9 GPa and 26.3 GPa, before and after yield. This is coupled with significant non-linear viscoelastic and, after yield, viscoplastic components, accounting for up to 14% of the strain response. The behavior is inherited from both the matrix and the fiber reinforcement and is attributed to the amorphous nature of the matrix combined with the microstructural re-organization of the fiber under load, which are partially reversible. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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23 pages, 1148 KiB  

Open AccessReview

Small-Scale Mechanical Recycling of Solid Thermoplastic Wastes: A Review of PET, PEs, and PP

by Canice C. Uzosike, Lachlan H. Yee and Ricardo Vasquez Padilla

Energies 2023, 16(3), 1406; https://doi.org/10.3390/en16031406 - 31 Jan 2023

Cited by 7 | Viewed by 3576

Abstract

The mechanical recycling of solid plastic waste on a small-scale level can be accomplished with the correct approaches. Thermoplastics are the types of plastic mostly considered for mechanical recycling because of their physical properties and ease of reprocessing. This paper reviews the mechanical [...] Read more.

The mechanical recycling of solid plastic waste on a small-scale level can be accomplished with the correct approaches. Thermoplastics are the types of plastic mostly considered for mechanical recycling because of their physical properties and ease of reprocessing. This paper reviews the mechanical reprocessing techniques of selected thermoplastics (polyethylene terephthalate and polyolefins), since they constitute a significant proportion of the plastics used commercially. Furthermore, necessary considerations for the effective operation of small-scale plants, including energy requirements of machinery and optimisation in order to improve efficiency and product quality, are discussed. A clearer understanding and addressing of the process-related challenges will lead to the successful establishment and management of small-scale mechanical recycling facilities to benefit communities. Efficient small-scale mechanical reprocessing establishments have become essential in reducing the environmental impacts of solid plastic waste and for energy conservation. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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25 pages, 9820 KiB  

Open AccessArticle

Study on Mechanical Failure Behavior of Steel-Wire Wound Reinforced Thermoplastic Pipe under Combined Internal Pressure and Soil Landslide Conditions

by Jun Shi, Zhijie Hu, Li Zeng, Panlin Lu, Hanxin Chen, Nanming Yu and Xiang Li

Materials 2023, 16(2), 848; https://doi.org/10.3390/ma16020848 - 15 Jan 2023

Cited by 3 | Viewed by 1868

Abstract

A steel-wire wound reinforced thermoplastic pipe (SWW-RTP) has been widely utilized in many industrial areas, and a soil landslide is an inevitable hazardous extreme condition for the SWW-RTP as it is usually buried underground. It is imperative to study the mechanical failure behavior [...] Read more.

A steel-wire wound reinforced thermoplastic pipe (SWW-RTP) has been widely utilized in many industrial areas, and a soil landslide is an inevitable hazardous extreme condition for the SWW-RTP as it is usually buried underground. It is imperative to study the mechanical failure behavior and the failure criterion of the SWW-RTP under the combination of internal pressure and soil landslide conditions, and this paper is the first study to investigate the topic. In this paper, groups of stress–strain curves of high-density polyethylene (HDPE) and steel wires were obtained by uniaxial tensile tests at different strain rates, with the help of a Digital Image Correlation device (DIC). A rate-dependent constitutive model was employed to represent the mechanical behavior of the HDPE and to help deduce the stress–strain curve of the HDPE under the required strain rate, estimated from the static simplification of the dynamic soil landslide. Afterwards, a finite element model of the SWW-RTP, embedded in a cubic of soil, was established with the software ABAQUS. The SWW-RTP model was composed of HDPE solid elements, embedded with steel-wire truss elements, and the soil was characterized with the extended Drucker–Prager model. A quartic polynomial displacement distribution was applied to the soil model to represent the soil landslide. Then, the mechanical response of the SWW-RTP was analyzed. It was found that the failure criterion of the HDPE yield was more suitable for the pipe subjected to internal pressure and soil landslide conditions, instead of the steel-wire strength failure criterion always used in traditional research on the SWW-RTP. Further, the influence of landslide width, internal pressure and steel-wire number were discussed. The larger the width of the landslide area, the gentler the deformation of the pipeline; this resulted in an increase in the maximum landslide and a decrease in the maximum curvature with the width of the landslide area. The relatively high internal pressure was beneficial to the safety of the SWW-RTP under landslide, because the internal pressure could increase the stiffness of the pipeline. The number of steel wires had a limited influence on the maximum landslide required for the SWW-RTP’s failure. This work can be useful for the design and safe assessment of the SWW-RTP under internal pressure and soil landslide conditions. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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19 pages, 13928 KiB  

Open AccessArticle

Dynamic Response and Deformative Mechanism of the Shape Memory Polymer Filled with Low-Melting-Point Alloy under Different Dynamic Loads

by Huanhuan Wang, Yongqiang Zhang and Zhuhua Tan

Polymers 2023, 15(2), 423; https://doi.org/10.3390/polym15020423 - 13 Jan 2023

Cited by 2 | Viewed by 3667

Abstract

Low-melting-point alloy (LMPA) was used as an additive to prepare epoxy-resin-based shape memory polymer composites (LMPA/EP SMP), and dynamic mechanical analyzer (DMA) tests were performed to demonstrate the shape memory effect, storage modulus, and stiffness of the composites under different load cases. The [...] Read more.

Low-melting-point alloy (LMPA) was used as an additive to prepare epoxy-resin-based shape memory polymer composites (LMPA/EP SMP), and dynamic mechanical analyzer (DMA) tests were performed to demonstrate the shape memory effect, storage modulus, and stiffness of the composites under different load cases. The composites exhibited an excellent shape recovery ratio and shape fixity ratio, and a typical turning point was observed in the storage modulus curves, which was attributed to the melting of the LMPA. In order to investigate the dynamic deformation mechanism at high strain rates, split Hopkinson pressure bar (SHPB) experiments were performed to study the influence of the strain rate and plastic work on the dynamic mechanical response of LMPA/EP composites. The results showed that there was a saturated tendency for the flow stress with increasing strain rate, and the composites exhibited a typical brittle failure mode at high strain rate. Moreover, an obvious melting phenomenon of the LMPA was observed by SEM tests, which was due to the heat generated by the plastic work at high strain rate. The fundamental of the paper provided an effective approach to modulate the stiffness and evaluate the characteristics of SMP composites. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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13 pages, 3027 KiB  

Open AccessArticle

Nanomechanics of Ultrathin Carbon Nanomembranes

by Marinos Dimitropoulos, George Trakakis, Nikolaus Meyerbröker, Raphael Gehra, Polina Angelova, Albert Schnieders, Christos Pavlou, Christos Kostaras, Costas Galiotis and Konstantinos Dassios

Nanomaterials 2023, 13(2), 267; https://doi.org/10.3390/nano13020267 - 8 Jan 2023

Cited by 1 | Viewed by 1960

Abstract

Ultrathin carbon nanomembranes (CNMs) are two-dimensional materials (2DM) of a few nm thickness with sub-nm intrinsic pores that mimic the biofiltration membranes found in nature. They enable highly selective, permeable, and energy-efficient water separation and can be produced at large scales on porous [...] Read more.

Ultrathin carbon nanomembranes (CNMs) are two-dimensional materials (2DM) of a few nm thickness with sub-nm intrinsic pores that mimic the biofiltration membranes found in nature. They enable highly selective, permeable, and energy-efficient water separation and can be produced at large scales on porous substrates with tuned properties. The present work reports the mechanical performance of such CNMs produced by p-nitrobiphenyl phosphonic acid (NBPS) or polyvinylbiphenyl (PVBP) and their composite membranes of microporous supporting substrates, which constitute indispensable information for ensuring their mechanical stability during operation. Measuring the nanomechanical properties of the ultrathin material was achieved by atomic force microscopy (AFM) on membranes both supported on flat substrates and suspended on patterned substrates (“composite membrane”). The AFM analysis showed that the CNMs presented Young’s modulus in the range of 2.5–8 GPa. The composite membranes’ responses were investigated by tensile testing in a micro-tensile stage as a function of substrate thickness and substrate pore density and diameter, which were found to affect the mechanical properties. Thermogravimetric analysis was used to investigate the thermal stability of composite membranes at high temperatures. The results revealed the structural integrity of CNMs, while critical parameters governing their mechanical response were identified and discussed. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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12 pages, 4283 KiB  

Open AccessArticle

RETRACTED: The Effect of Intrinsic Mechanical Properties on Reducing the Friction-Induced Ripples of Hard-Filler-Modified HDPE

by Chuanbo Liu, Chengqing Yuan and Shutian Liu

Polymers 2023, 15(2), 268; https://doi.org/10.3390/polym15020268 - 4 Jan 2023

Cited by 2 | Viewed by 1974 | Retraction

Abstract

Ripple deformations induced by friction on polymeric materials have negative effects on the entire stability of operating machineries. These deformations are formed as a response to contacting mechanics, caused by the intrinsic mechanical properties. High-density polyethylene (HDPE) with varying silicon nitride (Si₃ [...] Read more.

Ripple deformations induced by friction on polymeric materials have negative effects on the entire stability of operating machineries. These deformations are formed as a response to contacting mechanics, caused by the intrinsic mechanical properties. High-density polyethylene (HDPE) with varying silicon nitride (Si₃N₄) contents is used to investigate different ripple deformation responses by conducting single-asperity scratch tests. The relationship between the intrinsic mechanical properties and the ripple deformations caused by filler modifications is analyzed in this paper. The results show the coupling of the inherent mechanical properties, and the stick-slip motion of HDPE creates ripple deformations during scratching. The addition of the Si₃N₄ filler changes the frictional response; the filler weakens the ripples and almost smoothens the scratch, particularly at 4 wt.%, but the continued increase in the Si₃N₄ content produces noticeable ripples and fluctuations. These notable differences can be attributed to the yield and post-yield responses; the high yield stress and strain-hardening at 4 wt.% provide good friction resistance and stress distribution, thus a smooth scratch is observed. In contrast, increasing the filler content weakens both the yield and post-yield responses, leading to deformation. The results herein reveal the mechanism behind the initial ripple deformation, thus providing fundamental insights into universally derived friction-induced ripples. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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13 pages, 6518 KiB  

Open AccessArticle

Polypyrrole Modified Carbon Nanotube/Polyimide Electrode Materials for Supercapacitors and Lithium-ion Batteries

by Ruchinda Gooneratne and Jude O. Iroh

Energies 2022, 15(24), 9509; https://doi.org/10.3390/en15249509 - 15 Dec 2022

Cited by 2 | Viewed by 1990

Abstract

Lithium-ion batteries have evolved and transcended in recent years to power every device across the spectrum, from watches to electrical vehicles and beyond. However, the lithium-ion battery requires the use of heavy and expensive transition metal oxides that have limited life cycles. Conductive [...] Read more.

Lithium-ion batteries have evolved and transcended in recent years to power every device across the spectrum, from watches to electrical vehicles and beyond. However, the lithium-ion battery requires the use of heavy and expensive transition metal oxides that have limited life cycles. Conductive polymer nanocomposites have been shown to possess good electrochemical and thermomechanical properties and are considered to be effective alternatives to transition metal oxides. The fabrication and properties of polyimide matrix-single wall carbon nanotube, SWCNT composite electrode materials, modified by the electrodeposition of polypyrrole, PPy was successfully carried out. The doping of PPy with p-Toluene sulfonic acid, T resulted in a dramatic transformation of the morphology and specific capacitance of the electrode material. Electrochemical impedance spectroscopy, EIS, cyclic voltammetry, CV, and galvanic charge–discharge tests were used to measure the electrode’s specific capacitance and specific capacity. Maximum specific capacitance values of up to 84.88 F/g and 127.13 F/g were obtained by CV and charge–discharge tests, respectively. A capacitance retention of over 80% was obtained after over 500 cycles of testing. The insertion of doped PPy into the electrode material by electrochemical polymerization was shown to positively correlate to the improved electrochemical performance of the nanocomposite. An increase in the porosity of about 34.68% over the non-doped polypyrrole was obtained from EIS measurement and supported by the optical microscope pictures. Increasing the process parameters, such as pyrrole, Py concentration and the amount of dopants, lead to a dramatic increase in the specific capacitance and capacity of the composite electrodes. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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19 pages, 15487 KiB  

Open AccessArticle

Influence of Deposition Temperature and Compaction Force on the Infusion Properties of DFP Preforms

by Arne Hindersmann and Constantin Bäns

J. Compos. Sci. 2022, 6(12), 391; https://doi.org/10.3390/jcs6120391 - 15 Dec 2022

Viewed by 1629

Abstract

The deposition of dry fiber materials in the dry fiber placement (DFP) process with subsequent impregnation is becoming increasingly widespread. The wing covers of the Irkut MS 21 are already being manufactured using the DFP process, and research projects at major aircraft manufacturers [...] Read more.

The deposition of dry fiber materials in the dry fiber placement (DFP) process with subsequent impregnation is becoming increasingly widespread. The wing covers of the Irkut MS 21 are already being manufactured using the DFP process, and research projects at major aircraft manufacturers are increasingly incorporating the technology. In this process, the deposition speed depends on the temperature and the compaction force. However, it is not only the laying speed that counts during production, but also the impregnation afterwards. Thus, the effects of the depositing parameters on the infusion properties must be known. In this study, a two-step approach is used. Planar preforms (Hexcel HiTape) that have been deposited with different parameters are divided into four quadrants, and first samples are analyzed for isotropic properties in a two-dimensional infusion test. Then, one-dimensional infusion tests are performed so that infusion times can be compared. The tests show that the lowest infusion time can be obtained at low deposition temperature and high compression force. Additionally, using a comparable material (Solvay TX 1100), it is shown that increasing the gaps between the tows increases the permeability and homogeneity of the preform. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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15 pages, 4466 KiB  

Open AccessArticle

Preparation and Curing Mechanism of Modified Corn Straw by 3-Glycidyl Ether Oxypropyl Trimethoxysilane/Epoxy Resin Composites

by Chunhua Lou, Siyu Jiang, Yongli Zhou, Xiaohua Gu, Yong Zhang and Xianzhi Kong

Polymers 2022, 14(23), 5233; https://doi.org/10.3390/polym14235233 - 1 Dec 2022

Cited by 4 | Viewed by 1702

Abstract

A modified corn straw (CS)/epoxy resin (EP) composite was prepared using bisphenol A EP (i.e., E-51) as matrix, 2-methylimidazole as curing agent, and CS modified by 3-glycidyl ether oxypropyl trimethoxysilane (KHCS) as filler. Its chemical structure was characterized by Fourier transform infrared spectroscopy [...] Read more.

A modified corn straw (CS)/epoxy resin (EP) composite was prepared using bisphenol A EP (i.e., E-51) as matrix, 2-methylimidazole as curing agent, and CS modified by 3-glycidyl ether oxypropyl trimethoxysilane (KHCS) as filler. Its chemical structure was characterized by Fourier transform infrared spectroscopy (FTIR). The dynamic thermodynamic properties, mechanical properties, flame retardant property, and fracture morphology were studied using dynamic mechanical analysis (DMA), a universal testing machine, a micro combustion calorimeter, and a scanning electron microscope (SEM), respectively. The effects of different contents of KHCS on various properties were discussed. The experimental result showed that the CS was bonded toKH560 by a covalent bond. The impact strength, tensile strength, and flexural strength of the composites were all improved compared with those of pure EP. When the content of KHCS was 15 wt%, the maximum impact strength of the composites was 3.31 kJ/m², which was 1.43 times that of the pure EP. The p HRR and THR of MCSEC-20 were 512.44 W/g and 25.03 kJ/g, respectively, which were 40.71% and 27.76% lower than those of pure EP, when the content of KHCS was 20 wt%. Moreover, the mechanism of the curing composites was investigated. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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10 pages, 3936 KiB  

Open AccessArticle

Investigation of Carbon Fiber on the Tensile Property of FDM-Produced PLA Specimen

by Mengyu Cao, Tianqi Cui, Yuhang Yue, Chaoyu Li, Xue Guo, Xin Jia and Baojin Wang

Polymers 2022, 14(23), 5230; https://doi.org/10.3390/polym14235230 - 1 Dec 2022

Cited by 19 | Viewed by 2813

Abstract

Herein, the effect of carbon fibers (CFs) on the tensile property of a polylactic acid (PLA) specimen prepared by utilizing the fused deposition modeling (FDM) method, is investigated. The tensile property, crystal structure, and morphology of FDM-produced specimens were detected by universal testing [...] Read more.

Herein, the effect of carbon fibers (CFs) on the tensile property of a polylactic acid (PLA) specimen prepared by utilizing the fused deposition modeling (FDM) method, is investigated. The tensile property, crystal structure, and morphology of FDM-produced specimens were detected by universal testing machine, X-ray diffraction (XRD), and scanning electron microscopy (SEM), respectively. Meanwhile, the reinforcement mechanism of CFs on the FDM-printed PLA specimens was also studied. The DSC curves indicated that the crystalline structure of the PLA-CF specimen was higher than the PLA specimen. After the introduction of CFs, the XRD results showed the crystal structure of PLA varied from non-crystalline to α crystalline, and the SEM results illustrated the terrible bonding interface between carbon fiber and PLA. Interestingly, after the introduction of carbon fiber, the tensile strength of the PLA specimen reduced from 54.51 to 49.41 MPa. However, compared with the PLA component, the Young’s modulus and the elongation-at-break of the PLA-CF specimen increased from 1.04 GPa and 6.26%, to 1.26 GPa and 7.81%, respectively. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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19 pages, 3388 KiB  

Open AccessArticle

Preform Porosity and Final Thickness Variability Prediction after Controlled Post-Infusion External Pressure Application with the FEA Model

by Igor Zhilyaev, Shun-Hsyung Chang, Sergey Shevtsov and Natalia Snezhina

J. Compos. Sci. 2022, 6(12), 361; https://doi.org/10.3390/jcs6120361 - 25 Nov 2022

Cited by 1 | Viewed by 1426

Abstract

One of the reasons for the insufficiently wide use of the low-cost and low-labor vacuum infusion process in the production of polymer composite structures is the uneven distribution of pore pressure, porosity, and preform thickness at the final stage of filling the preform [...] Read more.

One of the reasons for the insufficiently wide use of the low-cost and low-labor vacuum infusion process in the production of polymer composite structures is the uneven distribution of pore pressure, porosity, and preform thickness at the final stage of filling the preform with liquid resin. This article presents the results of a theoretical study of the factors that govern the effectiveness of the known method of external controlled pressure on the preform in order to eliminate or significantly reduce the listed disadvantages. The study includes an analysis of scenarios for the implementation of this method, which differ in the state of the resin gate when external pressure is applied to the preform (open or closed), as well as the pressure in the vacuum vent (maintained unchanged or gradually increased to atmospheric pressure). The research tool was a finite element (FE) model that simulates resin flow according to Darcy’s law and controlled boundary conditions for a thin-walled rectangular preform. The results of the study confirmed the effectiveness of the process in achieving a more uniform distribution of porosity and preform thickness and are good qualitative agreement with the results of borrowed experiments, revealing the conditions for the occurrence of critical situations associated with the possible penetration of air into the preforms through the vacuum port and the reverse flow into the preform of the resin previously forced out through the resin gate. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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16 pages, 3211 KiB  

Open AccessArticle

Box–Behnken Design for Polycarbonate-Pigment Blending: Applications and Characterization Techniques

by Jamal Alsadi, Mohammed Taleb Obaidat, Rabah Ismail, Issam Trrad, Marwa Aljamal, Mohammed Dahim, Musab Abuaddous, Mohanad Khodier, Randa Hatamleh and Hashem Al-Mattarneh

Polymers 2022, 14(22), 4860; https://doi.org/10.3390/polym14224860 - 11 Nov 2022

Cited by 7 | Viewed by 2054

Abstract

Incorporating pigments into polymers can be done for various purposes, including the introduction of color, interfacial effects, or aesthetics. If these pigments are to disperse properly, then the process of extrusion must be optimized. During polymer compounding extrusion, three effective processing factors were [...] Read more.

Incorporating pigments into polymers can be done for various purposes, including the introduction of color, interfacial effects, or aesthetics. If these pigments are to disperse properly, then the process of extrusion must be optimized. During polymer compounding extrusion, three effective processing factors were investigated: feed rate (FR), speed (Sp.) and temperature (temp.) for a colored compounded polycarbonate (PC) grade (30/70%). The processing design techniques were obtained by applying design experiments in a response surface methodology (RSM) to blend two polycarbonates with pigments and optimize the processing temperatures at center points. The first study decided to utilize the response surface approach of Box–Behnken design (BBD) to design an experiment to optimize the process parameters. Statistical significance was demonstrated by the model passing all diagnostic tests. Furthermore, the three processing factors strongly impacted the characteristics of the tri-stimulus color, according to the results from a variance analysis. The second study identified process variables for the same PC grade at the center level, 25 kg/h FR, 750 rpm speed, and (255 °C) temp. The characterization and scanning morphology were examined using MicroCtscanner image analysis, SEM, DOM, rheology, FT-IR, and color-pigmented values were measured using a color spectrometer. The output response was significantly impacted when excellent color dispersion was observed with few agglomerates and less differences in colors at the center point. By characterizing these results and having good insight into color difference output and processing condition relationships, which have an adverse effect on color variation characteristics and minimize recycling compounds of different grades, results in cleaner environments benefits. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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18 pages, 12551 KiB  

Open AccessArticle

Effects of Rotational Speed on Joint Characteristics of Green Joining Technique of Dissimilar Polymeric Rods Fabricated by Additive Manufacturing Technology

by Chil-Chyuan Kuo, Hong-Wei Chen, Jing-Yan Xu, Chong-Hao Lee and Song-Hua Hunag

Polymers 2022, 14(22), 4822; https://doi.org/10.3390/polym14224822 - 9 Nov 2022

Cited by 4 | Viewed by 1574

Abstract

Friction welding (FW) FW of dissimilar polymer rods is capable of manufacturing green products swiftly and economically. In this study, a green manufacturing technique of joining dissimilar polymer rods was proposed, and the effects of rotational speed on the joint characteristics of friction-welded [...] Read more.

Friction welding (FW) FW of dissimilar polymer rods is capable of manufacturing green products swiftly and economically. In this study, a green manufacturing technique of joining dissimilar polymer rods was proposed, and the effects of rotational speed on the joint characteristics of friction-welded dissimilar polymer rods fabricated by the fused deposition modeling process were investigated experimentally. The shore surface hardness test, impact test, three-point bending test, and differential scanning calorimetry analysis were carried out on the weld joints. The impact energy for FW of polylactic acid (PLA) and PLA, PLA and acrylonitrile butadiene styrene (ABS), PLA and PLA filled with glass fiber (GF), PLA and PLA filled with carbon fiber (CF), PLA and polycarbonate (PC), and PLA and polyamide (PA) rods can be increased by approximately 1.5, 1.5, 1.3, 1.3, 2.1, and 1.5 times by increasing the rotational speed from 330 rpm to 1350 rpm. The bending strength for FW of PLA and PLA, PLA and ABS, PLA and PLA filled with GF, PLA and PLA filled with CF, PLA and PC, and PLA and PA rods can be increased by approximately 1.3, 1.7, 1.3, 1.2, 1.2, and 1.2 times by increasing the rotational speed from 330 rpm to 1350 rpm. However, the surface hardness of the weld bead is not proportional to the rotational speed. The average surface hardness of the weld bead was increased by approximately 5% compared to the surface hardness of the welding base materials. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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12 pages, 5110 KiB  

Open AccessArticle

Influence of Extrusion Temperature on Properties of Graphene Oxide-Carbon Fiber/Epoxy Composite Prepared by Vacuum Infiltration Hot-Press-Forming Experimental System

by Yuqin Ma, Fei Li, Wei Xu, Yuyang Zhang, Yi Xu, Haiyin Guo and Yatao Li

Nanomaterials 2022, 12(21), 3839; https://doi.org/10.3390/nano12213839 - 30 Oct 2022

Cited by 2 | Viewed by 1670

Abstract

Graphene oxide-carbon fiber/epoxy (GO-CF/EP) composites with extrusion temperatures of 30, 40, 50, 60 and 70 °C were prepared by a vacuum infiltration hot-press-forming experimental system (VIHPS). The effects of extrusion temperature on the microstructure, fracture mechanism and mechanical properties of GO-CF/EP composites were [...] Read more.

Graphene oxide-carbon fiber/epoxy (GO-CF/EP) composites with extrusion temperatures of 30, 40, 50, 60 and 70 °C were prepared by a vacuum infiltration hot-press-forming experimental system (VIHPS). The effects of extrusion temperature on the microstructure, fracture mechanism and mechanical properties of GO-CF/EP composites were investigated. It was found that the best mechanical property of composites and infiltration effect of the matrix in the fiber gap were obtained at the temperature of 50 °C, and the bending strength of the composite reached 728 MPa. The fiber was pulled out and broken under the wrapping of the matrix. The matrix viscosity was high, and the fluidity was poor when the extrusion temperature was low. The poor infiltration of the matrix resulted in many fibers failing to bond together, resulting in the disorderly breakage of fiber bundles. Under the condition of higher temperature, the flow speed of the matrix could be improved. However, part of the matrix was extruded during the extrusion process, and cracks and other defects occurred during the loading, which caused the brittle fracture of the specimen. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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22 pages, 3448 KiB  

Open AccessArticle

Incremental Numerical Approach for Modeling the Macroscopic Viscoelastic Behavior of Fiber-Reinforced Composites Using a Representative Volume Element

by Nicolas Gort, Igor Zhilyaev and Christian Brauner

Materials 2022, 15(19), 6724; https://doi.org/10.3390/ma15196724 - 27 Sep 2022

Cited by 2 | Viewed by 1624

Abstract

The objective of this study is to describe the stress relaxation behavior of an epoxy-based fiber-reinforced material. An existing incremental formulation of an orthotropic linear viscoelastic material behavior was adapted to Voigt notation and to the special case of an isotropic material. Virtual [...] Read more.

The objective of this study is to describe the stress relaxation behavior of an epoxy-based fiber-reinforced material. An existing incremental formulation of an orthotropic linear viscoelastic material behavior was adapted to Voigt notation and to the special case of an isotropic material. Virtual relaxation tests on a representative volume element were performed, and the behavior of individual components of the relaxation tensor of the transversely isotropic composite material was determined. The study demonstrated that in the case of only one viscoelastic material, each component of the relaxation tensor can be described in terms of a scalar form factor and the behavior of the neat resin. The developed method was implemented in an incremental finite element model (FEM) analysis to calculate the stress relaxation on the macroscopic ply level. A validation of the approach has shown a promising agreement up to a limit below the glass transition temperature of 15 °C in longitudinal and 35 °C in transverse direction. This study therefore demonstrates a novel way to incrementally describe the macroscopic viscoelastic behavior of materials with a single viscoelastic component with good controllability for engineering purposes. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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15 pages, 3152 KiB  

Open AccessArticle

A Manufacturing Process Simulation of Toughened Cyanate-Ester-Based Composite Structures with Respect to Stress Relaxation

by Nicolas Gort, Fabian Schadt, Martin Liebisch, Christian Brauner and Tobias Wille

Materials 2022, 15(19), 6675; https://doi.org/10.3390/ma15196675 - 26 Sep 2022

Viewed by 1554

Abstract

The objectives of this study were to experimentally determine the effects of the stress relaxation of a cyanate-ester-based composite, derive and integrate constitutive equations into commercial FEM software, and apply this approach to understand the formation of residual stress in a typical aerospace [...] Read more.

The objectives of this study were to experimentally determine the effects of the stress relaxation of a cyanate-ester-based composite, derive and integrate constitutive equations into commercial FEM software, and apply this approach to understand the formation of residual stress in a typical aerospace structure—namely, a stiffened panel. In preliminary studies, a cyanate-ester-based composite with increased fracture toughness for high-temperature applications was developed. High curing temperatures up to 260 °C will inevitably lead to high process-induced stresses. To assess the magnitude of impact on the development of internal stresses, the relaxation behavior of the neat resin was measured and characterized. The system was toughened, and the effect of stress relaxation increased as the temperature got closer to the glass transition temperature of the toughener, which was approximately 240 °C. With the use of an incremental linear viscoelastic model, the relaxation behavior was integrated into a process model with a holistic approach. A stiffened panel was manufactured and used as the validation use case. The displacement field was validated with an optical 3D measuring system, and good agreement was found between the simulated and experimental results. The maximum difference between the elastic and the viscoelastic solution was found to be 15%. Furthermore, the stress magnitude in the transverse material direction resulted in a more critical value higher than the material strength. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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21 pages, 2760 KiB  

Open AccessArticle

Development of a High-Fidelity Framework to Describe the Process-Dependent Viscoelasticity of a Fast-Curing Epoxy Matrix Resin including Testing, Modelling, Calibration and Validation

by Johannes Gerritzen, Michael Müller-Pabel, Jonas Müller, Benjamin Gröger, Niklas Lorenz, Christian Hopmann and Maik Gude

Polymers 2022, 14(17), 3647; https://doi.org/10.3390/polym14173647 - 2 Sep 2022

Cited by 4 | Viewed by 1589

Abstract

Fast-curing epoxy resins enable substantial reduction of cycle times during production of thermoset polymer matrix composites. Due to the snap-cure behaviour, both characterisation and processing of these resins are associated with high complexity which motivates the development of a high-fidelity framework for the [...] Read more.

Fast-curing epoxy resins enable substantial reduction of cycle times during production of thermoset polymer matrix composites. Due to the snap-cure behaviour, both characterisation and processing of these resins are associated with high complexity which motivates the development of a high-fidelity framework for the prediction of the process-dependent behaviour ranging from experiment to model validation. In order to determine influence of time, temperature, and degree of cure, a multitude of rheometer and dynamic mechanical analysis experiments are conducted and evaluated. Building on the experimental results, a material model based on a generalised Maxwell model is developed. It is calibrated on the results obtained in the tests and shown to describe the material’s behaviour with high accuracy under all investigated conditions. The model’s predictive capabilities are further tested by applying it to a dynamic mechanical analysis, exposing the model to previously unknown loading and temperature conditions. It is demonstrated that the model is capable of predicting such changing boundary conditions with high accuracy. Full article

(This article belongs to the Topic Advanced Polymeric Composites: Processing, Characterization and Mechanical Behavior)

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