Polymers

31 pages, 12524 KiB

Open AccessArticle

Experimental—FEM Study on Effect of Tribological Load Conditions on Wear Resistance of Three-Component High-Strength Solid-Lubricant PI-Based Composites

by Sergey V. Panin, Jiangkun Luo, Dmitry G. Buslovich, Vladislav O. Alexenko, Lyudmila A. Kornienko, Svetlana A. Bochkareva and Anton V. Byakov

Polymers 2021, 13(16), 2837; https://doi.org/10.3390/polym13162837 - 23 Aug 2021

Cited by 11 | Viewed by 3137

Abstract

The structure, mechanical and tribological properties of the polyimide-based composites reinforced with chopped carbon fibers (CCF) and loaded with solid-lubricant commercially available fillers of various natures were investigated. The metal- and ceramic counterparts were employed for tribological testing. Micron sized powders of PTFE, [...] Read more.

The structure, mechanical and tribological properties of the polyimide-based composites reinforced with chopped carbon fibers (CCF) and loaded with solid-lubricant commercially available fillers of various natures were investigated. The metal- and ceramic counterparts were employed for tribological testing. Micron sized powders of PTFE, colloidal graphite and molybdenum disulfide were used for solid lubrication. It was shown that elastic modulus was enhanced by up to 2.5 times, while ultimate tensile strength was increased by up 1.5 times. The scheme and tribological loading conditions exerted the great effect on wear resistance of the composites. In the tribological tests by the ‘pin-on-disk’ scheme, wear rate decreased down to ~290 times for the metal-polymer tribological contact and to ~285 times for the ceramic-polymer one (compared to those for neat PI). In the tribological tests against the rougher counterpart (R_a~0.2 μm, the ‘block-on-ring’ scheme) three-component composites with both graphite and MoS₂ exhibited high wear resistance. Under the “block-on-ring” scheme, the possibility of the transfer film formation was minimized, since the large-area counterpart slid against the ‘non-renewable’ surface of the polymer composite (at a ‘shortage’ of solid lubricant particles). On the other hand, graphite and MoS₂ particles served as reinforcing inclusions. Finally, numerical simulation of the tribological test according to the ‘block-on-ring’ scheme was carried out. Within the framework of the implemented model, the counterpart roughness level exerted the significantly greater effect on wear rate in contrast to the porosity. Full article

(This article belongs to the Special Issue Synergy Effects in Mechanical and Tribological Properties of Polymers and Polymer Composites)

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10 pages, 2494 KiB

Open AccessArticle

Effect of Filler Particle Size on the Recyclability of Fly Ash Filled HDPE Composites

by Mohammed N. Alghamdi

Polymers 2021, 13(16), 2836; https://doi.org/10.3390/polym13162836 - 23 Aug 2021

Cited by 14 | Viewed by 2534

Abstract

Fly ash polymer composites are innovative high-performance materials that reduce the environmental worries and disposal complications of heavy industry produced fly ash. This study developed and characterized such composites of high-density polyethylene (HDPE) matrices and found that the use of small (50–90 µm) [...] Read more.

Fly ash polymer composites are innovative high-performance materials that reduce the environmental worries and disposal complications of heavy industry produced fly ash. This study developed and characterized such composites of high-density polyethylene (HDPE) matrices and found that the use of small (50–90 µm) particles of fly ash could give rise to the tensile modulus (~95%) and tensile strength (~7%) of their reinforced composites when compared to neat HDPE materials. While these results themselves convey a strong message of how fly ash can be effectively utilized, this was not the key aim of the current study. The study was extended to examine the effect of fly ash particle size on the recyclability of relevant HDPE composites. The extrusion-based multiple recycling of composites gave slightly lower mechanical properties, primarily due to filler/matrix delamination when large fly ash particles were used. Compared to freshly made fly ash-filled HDPE composites, although using small (50–90 µm) fly ash particles reduced the tensile modulus and tensile strength of recycled composites, the values were still far above those from neat HDPE materials. This novel insight directs the effective utilization of fly ash and provides long-term sustainable and economical solutions for their practical applicability. Full article

(This article belongs to the Special Issue Polymer Composites for Structural Applications)

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18 pages, 6927 KiB

Open AccessArticle

Effect of In-Mold Annealing on the Properties of Asymmetric Poly(l-lactide)/Poly(d-lactide) Blends Incorporated with Nanohydroxyapatite

by Martin Boruvka, Cenek Cermak, Lubos Behalek and Pavel Brdlik

Polymers 2021, 13(16), 2835; https://doi.org/10.3390/polym13162835 - 23 Aug 2021

Cited by 7 | Viewed by 2263

Abstract

The proper choice of a material system for bioresorbable synthetic bone graft substitutes imposes strict requirements for mechanical properties, bioactivity, biocompatibility, and osteoconductivity. This study aims to characterize the effect of in-mold annealing on the properties of nanocomposite systems based on asymmetric poly( [...] Read more.

The proper choice of a material system for bioresorbable synthetic bone graft substitutes imposes strict requirements for mechanical properties, bioactivity, biocompatibility, and osteoconductivity. This study aims to characterize the effect of in-mold annealing on the properties of nanocomposite systems based on asymmetric poly(l-lactide) (PLLA)/Poly(d-lactide) (PDLA) blends at 5 wt.% PDLA loading, which was incorporated with nano-hydroxyapatite (HA) at various concentrations (1, 5, 10, 15 wt.%). Samples were melt-blended and injection molded into “cold” mold (50 °C) and hot mold (100 °C). The results showed that the tensile modulus, crystallinity, and thermal-resistance were enhanced with increasing content of HA and blending with 5 wt.% of PDLA. In-mold annealing further improved the properties mentioned above by achieving a higher degree of crystallinity. In-mold annealed PLLA/5PDLA/15HA samples showed an increase of crystallinity by ~59%, tensile modulus by ~28%, and VST by ~44% when compared to neat hot molded PLLA. On the other hand, the % elongation values at break as well as tensile strength of the PLLA and asymmetric nanocomposites were lowered with increasing HA content and in-mold annealing. Moreover, in-mold annealing of asymmetric blends and related nanocomposites caused the embrittlement of material systems. Impact toughness, when compared to neat cold molded PLLA, was improved by ~44% with in-mold annealing of PLLA/1HA. Furthermore, fracture morphology revealed fine dispersion and distribution of HA at 1 wt.% concentration. On the other hand, HA at a high concentration of 15 wt.% show agglomerates that worked as stress concentrators during impact loading. Full article

(This article belongs to the Special Issue Advances in Nanofillers Reinforced Polymer Nanocomposites)

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27 pages, 3783 KiB

Open AccessReview

Advanced Metallic and Polymeric Coatings for Neural Interfacing: Structures, Properties and Tissue Responses

by Pengfei Yin, Yang Liu, Lin Xiao and Chao Zhang

Polymers 2021, 13(16), 2834; https://doi.org/10.3390/polym13162834 - 23 Aug 2021

Cited by 24 | Viewed by 5591

Abstract

Neural electrodes are essential for nerve signal recording, neurostimulation, neuroprosthetics and neuroregeneration, which are critical for the advancement of brain science and the establishment of the next-generation brain–electronic interface, central nerve system therapeutics and artificial intelligence. However, the existing neural electrodes suffer from [...] Read more.

Neural electrodes are essential for nerve signal recording, neurostimulation, neuroprosthetics and neuroregeneration, which are critical for the advancement of brain science and the establishment of the next-generation brain–electronic interface, central nerve system therapeutics and artificial intelligence. However, the existing neural electrodes suffer from drawbacks such as foreign body responses, low sensitivity and limited functionalities. In order to overcome the drawbacks, efforts have been made to create new constructions and configurations of neural electrodes from soft materials, but it is also more practical and economic to improve the functionalities of the existing neural electrodes via surface coatings. In this article, recently reported surface coatings for neural electrodes are carefully categorized and analyzed. The coatings are classified into different categories based on their chemical compositions, i.e., metals, metal oxides, carbons, conducting polymers and hydrogels. The characteristic microstructures, electrochemical properties and fabrication methods of the coatings are comprehensively presented, and their structure–property correlations are discussed. Special focus is given to the biocompatibilities of the coatings, including their foreign-body response, cell affinity, and long-term stability during implantation. This review article can provide useful and sophisticated insights into the functional design, material selection and structural configuration for the next-generation multifunctional coatings of neural electrodes. Full article

(This article belongs to the Special Issue Advances of Polymer Stent and Coating)

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26 pages, 6029 KiB

Open AccessReview

Biomedical Applications of Antiviral Nanohybrid Materials Relating to the COVID-19 Pandemic and Other Viral Crises

by Shahin Homaeigohar, Qiqi Liu and Danial Kordbacheh

Polymers 2021, 13(16), 2833; https://doi.org/10.3390/polym13162833 - 23 Aug 2021

Cited by 10 | Viewed by 3617

Abstract

The COVID-19 pandemic has driven a global research to uncover novel, effective therapeutical and diagnosis approaches. In addition, control of spread of infection has been targeted through development of preventive tools and measures. In this regard, nanomaterials, particularly, those combining two or even [...] Read more.

The COVID-19 pandemic has driven a global research to uncover novel, effective therapeutical and diagnosis approaches. In addition, control of spread of infection has been targeted through development of preventive tools and measures. In this regard, nanomaterials, particularly, those combining two or even several constituting materials possessing dissimilar physicochemical (or even biological) properties, i.e., nanohybrid materials play a significant role. Nanoparticulate nanohybrids have gained a widespread reputation for prevention of viral crises, thanks to their promising antimicrobial properties as well as their potential to act as a carrier for vaccines. On the other hand, they can perform well as a photo-driven killer for viruses when they release reactive oxygen species (ROS) or photothermally damage the virus membrane. The nanofibers can also play a crucial protective role when integrated into face masks and personal protective equipment, particularly as hybridized with antiviral nanoparticles. In this draft, we review the antiviral nanohybrids that could potentially be applied to control, diagnose, and treat the consequences of COVID-19 pandemic. Considering the short age of this health problem, trivially the relevant technologies are not that many and are handful. Therefore, still progressing, older technologies with antiviral potential are also included and discussed. To conclude, nanohybrid nanomaterials with their high engineering potential and ability to inactivate pathogens including viruses will contribute decisively to the future of nanomedicine tackling the current and future pandemics. Full article

(This article belongs to the Special Issue Polymeric Nanocomposites for Tissue Engineering and Wound Dressing)

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14 pages, 25001 KiB

Open AccessArticle

Radiation-Based Crosslinking Technique for Enhanced Thermal and Mechanical Properties of HDPE/EVA/PU Blends

by Jang-Gun Lee, Jin-Oh Jeong, Sung-In Jeong and Jong-Seok Park

Polymers 2021, 13(16), 2832; https://doi.org/10.3390/polym13162832 - 23 Aug 2021

Cited by 16 | Viewed by 4015

Abstract

Crosslinking of polyolefin-based polymers can improve their thermal and mechanical properties, which can then be used in various applications. Radiation-induced crosslinking can be done easily and usefully by irradiation without a crosslinking agent. In addition, polymer blending can improve thermal and mechanical properties, [...] Read more.

Crosslinking of polyolefin-based polymers can improve their thermal and mechanical properties, which can then be used in various applications. Radiation-induced crosslinking can be done easily and usefully by irradiation without a crosslinking agent. In addition, polymer blending can improve thermal and mechanical properties, and chemical resistance, compared to conventional single polymers. In this study, high-density polyethylene (HDPE)/ethylene vinyl acetate (EVA)/polyurethane (PU) blends were prepared by radiation crosslinking to improve the thermal and mechanical properties of HDPE. This is because HDPE, a polyolefin-based polymer, has the weaknesses of low thermal resistance and flexibility, even though it has good mechanical strength and machinability. In contrast, EVA has good flexibility and PU has excellent thermal properties and wear resistance. The morphology and mechanical properties (e.g., tensile and flexure strength) were characterized using scanning electron microscopy (SEM) and a universal testing machine (UTM). The gel fraction, thermal shrinkage, and abrasion resistance of samples were confirmed. In particular, after storing at 180 °C for 1 h, the crosslinked HDPE-PU-EVA blends exhibited ~4-times better thermal stability compared to non-crosslinked HDPE. When subjected to a radiation dose of 100 kGy, the strength of HDPE increased, but the elongation sharply decreased (80%). On the other hand, the strength of the HDPE-PU-EVA blends was very similar to that of HDPE, and the elongation was more than 3-times better (320%). Finally, the abrasion resistance of crosslinked HDPE-PU-EVA was ~9-times better than the crosslinked HDPE. Therefore, this technology can be applied to various polymer products requiring high heat resistance and flexibility, such as electric cables and industrial pipes. Full article

(This article belongs to the Special Issue Synthesis, Processing, Structure and Properties of Polymer Materials)

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23 pages, 12192 KiB

Open AccessArticle

Experimental Characterization and Modeling Multifunctional Properties of Epoxy/Graphene Oxide Nanocomposites

by Kakur Naresh, Kamran A. Khan and Rehan Umer

Polymers 2021, 13(16), 2831; https://doi.org/10.3390/polym13162831 - 23 Aug 2021

Cited by 20 | Viewed by 3448

Abstract

Thermomechanical modeling of epoxy/graphene oxide under quasi-static and dynamic loading requires thermo-mechanical properties such as Young’s modulus, Poisson’s ratio, thermal conductivity, and frequency-temperature dependent viscoelastic properties. In this study, the effects of different graphene oxide (GO) concentrations (0.05, 0.1, and 0.2 wt%) within [...] Read more.

Thermomechanical modeling of epoxy/graphene oxide under quasi-static and dynamic loading requires thermo-mechanical properties such as Young’s modulus, Poisson’s ratio, thermal conductivity, and frequency-temperature dependent viscoelastic properties. In this study, the effects of different graphene oxide (GO) concentrations (0.05, 0.1, and 0.2 wt%) within an epoxy matrix on several mechanical and thermal properties were investigated. The distribution of GO fillers in the epoxy was investigated using transmission electron microscopy (TEM). The digital image correlation (DIC) technique was employed during the tensile testing to determine Young’s modulus and Poisson’s ratio. Analytical models were used to predict Young’s modulus and thermal conductivity, with an error of less than 13% and 9%, respectively. Frequency–temperature dependent phenomenological models were proposed to predict the storage moduli and loss tangent, with a reasonable agreement with experimental data. A relatively high storage modulus, heat-resistance index (T_HRI), and thermal conductivity were observed in 0.2 wt% nanocomposite samples compared with pure epoxy and other lower concentration GO nanocomposites. A high T_HRI and derivative of thermogravimetric analysis peak temperatures (T_m1 and T_m2) were exhibited by adding nano-fillers in the epoxy, which confirms higher thermal stability of nanocomposites than that of pristine epoxy. Full article

(This article belongs to the Special Issue Advances in Graphene-Epoxy Nanocomposites)

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21 pages, 2856 KiB

Open AccessArticle

Membrane Emulsification Process as a Method for Obtaining Molecularly Imprinted Polymers

by Joanna Wolska and Nasim Jalilnejad Falizi

Polymers 2021, 13(16), 2830; https://doi.org/10.3390/polym13162830 - 23 Aug 2021

Cited by 7 | Viewed by 2286

Abstract

The membrane emulsification process (ME) using a metallic membrane was the first stage for preparing a spherical and monodisperse thermoresponsive molecularly imprinted polymer (TSMIP). In the second step of the preparation, after the ME process, the emulsion of monomers was then polymerized. Additionally, [...] Read more.

The membrane emulsification process (ME) using a metallic membrane was the first stage for preparing a spherical and monodisperse thermoresponsive molecularly imprinted polymer (TSMIP). In the second step of the preparation, after the ME process, the emulsion of monomers was then polymerized. Additionally, the synthesized TSMIP was fabricated using as a functional monomer N-isopropylacrylamide, which is thermosensitive. This special type of polymer was obtained for the recognition and determination of trace bisphenol A (BPA) in aqueous media. Two types of molecularly imprinted polymers (MIPs) were synthesized using amounts of BPA of 5 wt.% (MIP-2) and 7 wt.% (MIP-1) in the reaction mixtures. Additionally, a non-imprinted polymer (NIP) was also synthesized. Polymer MIP-2 showed thermocontrolled recognition for imprinted molecules and a higher binding capacity than its corresponding non-imprinted polymer and higher than other molecularly imprinted polymer (MIP-1). The best condition for the sorption process was at a temperature of 35 °C, that is, at a temperature close to the phase transition value for poly(N-isopropylacrylamide). Under these conditions, the highest levels of BPA removal from water were achieved and the highest adsorption capacity of MIP-2 was about 0.5 mmol g⁻¹ (about 114.1 mg g⁻¹) and was approximately 20% higher than for MIP-1 and NIP. It was also observed that during the kinetic studies, under these temperature conditions, MIP-2 sorbed BPA faster and with greater efficiency than its non-imprinted analogue. Full article

(This article belongs to the Special Issue Functional Polymer Composites for Environmental Protection)

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19 pages, 2097 KiB

Open AccessReview

The State of the Art of Material Jetting—A Critical Review

by Orhan Gülcan, Kadir Günaydın and Aykut Tamer

Polymers 2021, 13(16), 2829; https://doi.org/10.3390/polym13162829 - 23 Aug 2021

Cited by 137 | Viewed by 14251

Abstract

Material jetting (MJ) technology is an additive manufacturing method that selectively cures liquid photopolymer to build functional parts. The use of MJ technology has increased in popularity and been adapted by different industries, ranging from biomedicine and dentistry to manufacturing and aviation, thanks [...] Read more.

Material jetting (MJ) technology is an additive manufacturing method that selectively cures liquid photopolymer to build functional parts. The use of MJ technology has increased in popularity and been adapted by different industries, ranging from biomedicine and dentistry to manufacturing and aviation, thanks to its advantages in printing parts with high dimensional accuracy and low surface roughness. To better understand the MJ technology, it is essential to address the capabilities, applications and the usage areas of MJ. Additionally, the comparison of MJ with alternative methods and its limitations need to be explained. Moreover, the parameters influencing the dimensional accuracy and mechanical properties of MJ printed parts should be stated. This paper aims to review these critical aspects of MJ manufacturing altogether to provide an overall insight into the state of the art of MJ. Full article

(This article belongs to the Special Issue Process–Structure–Properties in Polymer Additive Manufacturing II)

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18 pages, 2592 KiB

Open AccessArticle

Characterization of Gelatin and Hydrolysates from Valorization of Farmed Salmon Skin By-Products

by José Antonio Vázquez, Carolina Hermida-Merino, Daniel Hermida-Merino, Manuel M. Piñeiro, Johan Johansen, Carmen G. Sotelo, Ricardo I. Pérez-Martín and Jesus Valcarcel

Polymers 2021, 13(16), 2828; https://doi.org/10.3390/polym13162828 - 23 Aug 2021

Cited by 19 | Viewed by 3637

Abstract

Salmon processing commonly involves the skinning of fish, generating by-products that need to be handled. Such skin residues may represent valuable raw materials from a valorization perspective, mainly due to their collagen content. With this approach, we propose in the present work the [...] Read more.

Salmon processing commonly involves the skinning of fish, generating by-products that need to be handled. Such skin residues may represent valuable raw materials from a valorization perspective, mainly due to their collagen content. With this approach, we propose in the present work the extraction of gelatin from farmed salmon and further valorization of the remaining residue through hydrolysis. Use of different chemical treatments prior to thermal extraction of gelatin results in a consistent yield of around 5%, but considerable differences in rheological properties. As expected from a cold-water species, salmon gelatin produces rather weak gels, ranging from 0 to 98 g Bloom. Nevertheless, the best performing gelatins show considerable structural integrity, assessed by gel permeation chromatography with light scattering detection for the first time on salmon gelatin. Finally, proteolysis of skin residues with Alcalase for 4 h maximizes digestibility and antihypertensive activity of the resulting hydrolysates, accompanied by the sharpest reduction in molecular weight and higher content of essential amino acids. These results indicate the possibility of tuning salmon gelatin properties through changes in chemical treatment conditions, and completing the valorization cycle through production of bioactive and nutritious hydrolysates. Full article

(This article belongs to the Special Issue Marine Biomolecules from Food By-Products: Chitosan and Gelatine)

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12 pages, 3321 KiB

Open AccessArticle

Blended Anion Exchange Membranes for Vanadium Redox Flow Batteries

by Tae Yang Son, Kwang Seop Im, Ha Neul Jung and Sang Yong Nam

Polymers 2021, 13(16), 2827; https://doi.org/10.3390/polym13162827 - 23 Aug 2021

Cited by 10 | Viewed by 3159

Abstract

In this study, blended anion exchange membranes were prepared using polyphenylene oxide containing quaternary ammonium groups and polyvinylidene fluoride. A polyvinylidene fluoride with high hydrophobicity was blended in to lower the vanadium ion permeability, which increased when the hydrophilicity increased. At the same [...] Read more.

In this study, blended anion exchange membranes were prepared using polyphenylene oxide containing quaternary ammonium groups and polyvinylidene fluoride. A polyvinylidene fluoride with high hydrophobicity was blended in to lower the vanadium ion permeability, which increased when the hydrophilicity increased. At the same time, the dimensional stability also improved due to the excellent physical properties of polyvinylidene fluoride. Subsequently, permeation of the vanadium ions was prevented due to the positive charge of the anion exchange membrane, and thus the permeability was relatively lower than that of a commercial proton exchange membrane. Due to the above properties, the self-discharge of the blended anion exchange membrane (30.1 h for QA–PPO/PVDF(2/8)) was also lower than that of the commercial proton exchange membrane (27.9 h for Nafion), and it was confirmed that it was an applicable candidate for vanadium redox flow batteries. Full article

(This article belongs to the Special Issue Advanced Polymers for Electrochemical Applications)

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14 pages, 4025 KiB

Open AccessArticle

Phosphorous-Nitrogen Modification of Epoxy Grafted Poly-Acrylic Resin: Synergistic Flame Retardment Effect

by Chao Liu, Hui Qiao, Guilong Xu, Yun Liang, Jin Yang and Jian Hu

Polymers 2021, 13(16), 2826; https://doi.org/10.3390/polym13162826 - 23 Aug 2021

Cited by 10 | Viewed by 3112

Abstract

A novel high-efficient flame retardant epoxy grafted poly-acrylic resin modified by phosphorus and nitrogen was successfully synthesized by radical grafting polymerization and solution polymerization simultaneously. The flame retardancy of copolymer resin was investigated using thermogravimetric analysis (TGA), cone calorimetric test (CONE), limiting oxygen [...] Read more.

A novel high-efficient flame retardant epoxy grafted poly-acrylic resin modified by phosphorus and nitrogen was successfully synthesized by radical grafting polymerization and solution polymerization simultaneously. The flame retardancy of copolymer resin was investigated using thermogravimetric analysis (TGA), cone calorimetric test (CONE), limiting oxygen index (LOI) and so on. The micro-morphology and chemical composition of char formed after a CONE calorimetric test was analyzed using scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS), respectively. The Kissinger method was used to evaluate the kinetics of thermal decomposition on copolymer resin. The results showed that the flame retardant property of copolymer resin increased with the increase in phosphorus content. With the increase in nitrogen content, however, the flame retardant property first increased and then decreased. The flame retardant property of the resin was the best and the limiting oxygen index could reach 34.3% when the phosphorus content and nitrogen content of the copolymer resin were 6.45 wt% and 2.33 wt%, respectively. Meanwhile, nitrogen-containing compounds will interact with phosphorus-containing compounds to form P-N intermediates during combustion, which have stronger dehydration and carbonization and could further enhance the flame retardant performance of the resin and generate phosphorus-nitrogen synergistic interactions. Full article

(This article belongs to the Special Issue Advances in Phosphorus-Based Polymers)

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22 pages, 3412 KiB

Open AccessArticle

An Effective Package of Antioxidants for Avoiding Premature Failure in Polypropylene Random Copolymer Plastic Pipes under Hydrostatic Pressure and High Temperature

by Enrique Blázquez-Blázquez, Joaquín Lahoz, Ernesto Pérez and María L. Cerrada

Polymers 2021, 13(16), 2825; https://doi.org/10.3390/polym13162825 - 22 Aug 2021

Cited by 6 | Viewed by 3980

Abstract

Pipes of polypropylene random (PP-R) copolymers are the best choice for hot- and cold-water networks. Validation of a severe test, accomplishing the ISO 1167 standard, is mandatory to assess their service lifetime expectancy. This work evaluates the behavior shown by three commercial pipes, [...] Read more.

Pipes of polypropylene random (PP-R) copolymers are the best choice for hot- and cold-water networks. Validation of a severe test, accomplishing the ISO 1167 standard, is mandatory to assess their service lifetime expectancy. This work evaluates the behavior shown by three commercial pipes, either the original ones (new pipes) or after being subjected to a hydrostatic pressure test at elevated temperature (aged pipes). Several features with relevance for the final performance have been examined: crystalline characteristics, phase transitions in crystalline regions, effect of high temperature and pressure on these transitions, and oxidation induction time. Moreover, the presence of inorganic fillers, and the content of different antioxidants together with their depletion, have also been analyzed. Films from the new pipes were also prepared for replication of the different environments in order to achieve a better and complete understanding of the phase transitions in the crystalline regions and of the consumption of antioxidants. Distinct environments surrounded the inner and outer parts of the pipes exposed to the failure aging test at 110 °C: hot water and warm dry air, respectively. These features play a key role in the loss of additives and in the subsequent initiation of degradation. Even if the crystalline characteristics are appropriate in the polymeric matrix, the success of a pipe lies in the homogeneous dispersion of components for avoiding damage at interfacial properties, and in a correct package of antioxidants used in its formulation. Full article

(This article belongs to the Special Issue Assessment of the Ageing and Durability of Polymers III)

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11 pages, 2979 KiB

Open AccessArticle

Colorless Polyimides Derived from an Alicyclic Tetracarboxylic Dianhydride, CpODA

by Hiroki Ozawa, Eriko Ishiguro, Yuri Kyoya, Yasuaki Kikuchi and Toshihiko Matsumoto

Polymers 2021, 13(16), 2824; https://doi.org/10.3390/polym13162824 - 22 Aug 2021

Cited by 34 | Viewed by 4731

Abstract

An alicyclic tetracarboxylic dianhydride having cyclopentanone bis-spironorbornane structure (CpODA) was polycondensated with aromatic dianhydrides to form the corresponding poly(amic acid)s which possessed logarithmic viscosities in the range 1.47–0.54 dL/g. The poly(amic acid) was imidized by three methods: a chemical, a thermal, and a [...] Read more.

An alicyclic tetracarboxylic dianhydride having cyclopentanone bis-spironorbornane structure (CpODA) was polycondensated with aromatic dianhydrides to form the corresponding poly(amic acid)s which possessed logarithmic viscosities in the range 1.47–0.54 dL/g. The poly(amic acid) was imidized by three methods: a chemical, a thermal, and a combined chemical and thermal process. In a thermal method, imidization temperature markedly influenced the film quality and molecular weight of the polyimide. When the poly(amic acid) was cured over the Tg of the corresponding polyimide, the flexible polyimide films were obtained and the molecular weights increased several times, which means that the post-polymerization took place. In spite of low-temperature cure below Tg flexible films with the imidization ratio of 100% were fabricated by a combined chemical and thermal imidization technique. The films possessed the decomposition temperatures in a range of 475–501 °C and Tgs over 330 °C. The high Tg results from a dipole–dipole interaction between the keto groups of the polymer chains as well as development of the rigid polyalicyclic unit. The polyimide films exhibited CTE between 17 and 57 ppm/K. All the films fabricated were entirely colorless and possessed the λcut-offs shorter than 337 nm. Notably, the films prepared by a chemical method exhibited outstanding optical properties. Full article

(This article belongs to the Special Issue Advanced Polyimides and Other High Performance Polymers)

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14 pages, 1831 KiB

Open AccessArticle

Mode II Fracture Analysis of GNP/Epoxy Nanocomposite Film on a Substrate

by Shiuh-Chuan Her and Kai-Chun Zhang

Polymers 2021, 13(16), 2823; https://doi.org/10.3390/polym13162823 - 22 Aug 2021

Cited by 3 | Viewed by 2536

Abstract

Epoxy resin with excellent mechanical properties, chemical stability, and corrosion resistance has been widely used in automotive and aerospace industries. A thin film of epoxy deposited on a substrate has great application in adhesive bonding and protective coating. However, the intrinsic brittleness of [...] Read more.

Epoxy resin with excellent mechanical properties, chemical stability, and corrosion resistance has been widely used in automotive and aerospace industries. A thin film of epoxy deposited on a substrate has great application in adhesive bonding and protective coating. However, the intrinsic brittleness of epoxy with a relatively low fracture toughness limits its applications. In this work, graphene nanoplatelets (GNP) were added to the epoxy resin to enhance its toughness, hardness, and elastic modulus. A series of nanocomposites with different loadings of GNP were fabricated. Ultrasonic sonication in combination with surfactant Triton X-100 were employed to disperse GNP in the epoxy matrix. A nanocomposite film with a thickness of 0.3 mm was deposited on an Al substrate using a spinning coating technology. The hardness and elastic modulus of the nanocomposite film on the Al substrate were experimentally measured by a nanoindentation test. Analytical expression of the mode II interfacial fracture toughness for the nanocomposite film on an Al substrate with an interfacial edge crack was derived utilizing the linear elastic fracture mechanics and Euler’s beam theory. End-notched flexure (ENF) tests were conducted to evaluate the mode II fracture toughness. It was found that the hardness, elastic modulus, and mode II fracture toughness of the nanocomposite film reinforced with 1 wt % of GNP were improved by 71.8%, 63.2%, and 44.4%, respectively, compared with the pure epoxy. The presence of much stiff GNP in the soft epoxy matrix prompts toughening mechanisms such as crack deflection and crack pinning, resulting in the improvements of the fracture toughness, hardness, and elastic modulus. Microscopic observation for the nanocomposite was examined by scanning electron microscopy (SEM) to investigate the dispersion of GNPs in the epoxy matrix. The performance of a nanocomposite film deposited on a substrate was rarely studied, in particular, for the interfacial fracture toughness of the film/substrate composite structure. Utilizing the theoretical model in conjunction with the ENF experimental test presented in this study, an accurate determination of the mode II interfacial fracture toughness of film/substrate composite structure is made possible. Full article

(This article belongs to the Special Issue Multifunctional Polymer Composites Based on 2D Graphene Related Materials)

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13 pages, 3270 KiB

Open AccessArticle

Effect of Position and Structure of the Terminal Moieties in the Side Group on the Liquid Crystal Alignment Behavior of Polystyrene Derivatives

by DaEun Yang, Kyutae Seo and Hyo Kang

Polymers 2021, 13(16), 2822; https://doi.org/10.3390/polym13162822 - 22 Aug 2021

Viewed by 2338

Abstract

We synthesized a series of polystyrene derivatives containing various side groups, such as the 4-(tert-butyl)-phenoxymethyl, 3-(tert-butyl)-phenoxymethyl, 2-(tert-butyl)-phenoxymethyl, 4-cumyl-phenoxymethyl, and 4-trityl-phenoxymethyl groups, through a polymer modification reaction to examine the liquid crystal (LC) alignment of these derivatives. In [...] Read more.

We synthesized a series of polystyrene derivatives containing various side groups, such as the 4-(tert-butyl)-phenoxymethyl, 3-(tert-butyl)-phenoxymethyl, 2-(tert-butyl)-phenoxymethyl, 4-cumyl-phenoxymethyl, and 4-trityl-phenoxymethyl groups, through a polymer modification reaction to examine the liquid crystal (LC) alignment of these derivatives. In general, the vertical LC alignment on polymer films can be affected by the position and structure of the terminal moiety of the polymer side group. For example, the LC cells fabricated with 4-(tert-butyl)-phenoxymethyl-substituted polystyrene having a tert-butyl moiety as a para-type attachment to the phenoxy groups of the polystyrene derivatives exhibited vertical LC alignment, whereas the LC cells prepared from 3-(tert-butyl)- and 2-(tert-butyl)-phenoxymethyl-substituted polystyrene films exhibited planar LC alignment. In addition, the LC cells fabricated from 4-cumyl- and 4-trityl-phenoxymethyl-substituted polystyrene films with additional phenyl rings in the side groups exhibited planar LC alignment, in contrast to the LC alignment of the (tert-butyl)-phenoxymethyl-substituted polystyrene series. The vertical LC orientation was well correlated with the surface energy of these polymer films. For example, vertical LC orientation, which mainly originates due to the nonpolar tertiary carbon moiety having bulky groups, was observed when the surface energy of the polymer was lower than 36.6 mJ/m². Full article

(This article belongs to the Special Issue Polymer-Based Materials in Liquid Crystals)

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15 pages, 10661 KiB

Open AccessArticle

Micropatterned Fibrous Scaffold Produced by Using Template-Assisted Electrospinning Technique for Wound Healing Application

by Norul Ashikin Norzain, Zhi-Wei Yu, Wei-Chih Lin and Hsing-Hao Su

Polymers 2021, 13(16), 2821; https://doi.org/10.3390/polym13162821 - 22 Aug 2021

Cited by 10 | Viewed by 2931

Abstract

This paper describes the fabrication of a structural scaffold consisting of both randomly oriented nanofibers and triangular prism patterns on the scaffold surface using a combination technique of electrospinning and collector templates. The polycaprolactone (PCL) nanofibers were electrospun over a triangular prism pattern [...] Read more.

This paper describes the fabrication of a structural scaffold consisting of both randomly oriented nanofibers and triangular prism patterns on the scaffold surface using a combination technique of electrospinning and collector templates. The polycaprolactone (PCL) nanofibers were electrospun over a triangular prism pattern mold, which acted as a template. The deposited scaffold was removed from the template to produce a standalone structural scaffold of three-dimensional micropatterned nanofibers. The fabricated structural scaffold was compared with flat randomly oriented nanofibers based on in vitro and in vivo studies. The in vitro study indicated that the structural scaffold demonstrated higher fibroblast cell proliferation, cell elongation with a 13.48 ± 2.73 aspect ratio and 70% fibroblast cell orientation compared with flat random nanofibers. Among the treatment groups, the structural scaffold escalated the wound closure to 92.17% on day 14. Histological staining of the healed wound area demonstrated that the structural scaffold exhibited advanced epithelization of the epidermal layer accompanied by mild inflammation. The proliferated fibroblast cells and collagen fibers in the structural scaffold appeared denser and arranged more horizontally. These results determined the potential of micropatterned scaffolds for stimulating cell behavior and their application for wound healing. Full article

(This article belongs to the Special Issue Polymer Scaffolds for Tissue Engineering)

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16 pages, 2265 KiB

Open AccessArticle

DNA Interaction with a Polyelectrolyte Monolayer at Solution—Air Interface

by Nikolay S. Chirkov, Richard A. Campbell, Alexander V. Michailov, Petr S. Vlasov and Boris A. Noskov

Polymers 2021, 13(16), 2820; https://doi.org/10.3390/polym13162820 - 22 Aug 2021

Cited by 6 | Viewed by 2325

Abstract

The formation of ordered 2D nanostructures of double stranded DNA molecules at various interfaces attracts more and more focus in medical and engineering research, but the underlying intermolecular interactions still require elucidation. Recently, it has been revealed that mixtures of DNA with a [...] Read more.

The formation of ordered 2D nanostructures of double stranded DNA molecules at various interfaces attracts more and more focus in medical and engineering research, but the underlying intermolecular interactions still require elucidation. Recently, it has been revealed that mixtures of DNA with a series of hydrophobic cationic polyelectrolytes including poly(N,N-diallyl-N-hexyl-N-methylammonium) chloride (PDAHMAC) form a network of ribbonlike or threadlike aggregates at the solution—air interface. In the present work, we adopt a novel approach to confine the same polyelectrolyte at the solution—air interface by spreading it on a subphase with elevated ionic strength. A suite of techniques–rheology, microscopy, ellipsometry, and spectroscopy–are applied to gain insight into main steps of the adsorption layer formation, which results in non-monotonic kinetic dependencies of various surface properties. A long induction period of the kinetic dependencies after DNA is exposed to the surface film results only if the initial surface pressure corresponds to a quasiplateau region of the compression isotherm of a PDAHMAC monolayer. Despite the different aggregation mechanisms, the micromorphology of the mixed PDAHMAC/DNA does not depend noticeably on the initial surface pressure. The results provide new perspective on nanostructure formation involving nucleic acids building blocks. Full article

(This article belongs to the Section Polymer Networks)

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18 pages, 10192 KiB

Open AccessArticle

A Negative Index Nonagonal CSRR Metamaterial-Based Compact Flexible Planar Monopole Antenna for Ultrawideband Applications Using Viscose-Wool Felt

by Kabir Hossain, Thennarasan Sabapathy, Muzammil Jusoh, Mahmoud A. Abdelghany, Ping Jack Soh, Mohamed Nasrun Osman, Mohd Najib Mohd Yasin, Hasliza A. Rahim and Samir Salem Al-Bawri

Polymers 2021, 13(16), 2819; https://doi.org/10.3390/polym13162819 - 22 Aug 2021

Cited by 15 | Viewed by 2996

Abstract

In this paper, a compact textile ultrawideband (UWB) planar monopole antenna loaded with a metamaterial unit cell array (MTMUCA) structure with epsilon-negative (ENG) and near-zero refractive index (NZRI) properties is proposed. The proposed MTMUCA was constructed based on a combination of a rectangular- [...] Read more.

In this paper, a compact textile ultrawideband (UWB) planar monopole antenna loaded with a metamaterial unit cell array (MTMUCA) structure with epsilon-negative (ENG) and near-zero refractive index (NZRI) properties is proposed. The proposed MTMUCA was constructed based on a combination of a rectangular- and a nonagonal-shaped unit cell. The size of the antenna was 0.825 λ₀ × 0.75 λ₀ × 0.075 λ₀, whereas each MTMUCA was sized at 0.312 λ₀ × 0.312 λ₀, with respect to a free space wavelength of 7.5 GHz. The antenna was fabricated using viscose-wool felt due to its strong metal–polymer adhesion. A naturally available polymer, wool, and a human-made polymer, viscose, that was derived from regenerated cellulose fiber were used in the manufacturing of the adopted viscose-wool felt. The MTMUCA exhibits the characteristics of ENG, with a bandwidth (BW) of 11.68 GHz and an NZRI BW of 8.5 GHz. The MTMUCA was incorporated on the planar monopole to behave as a shunt LC resonator, and its working principles were described using an equivalent circuit. The results indicate a 10 dB impedance fractional bandwidth of 142% (from 2.55 to 15 GHz) in simulations, and 138.84% (from 2.63 to 14.57 GHz) in measurements obtained by the textile UWB antenna. A peak realized gain of 4.84 dBi and 4.4 dBi was achieved in simulations and measurements, respectively. A satisfactory agreement between simulations and experiments was achieved, indicating the potential of the proposed negative index metamaterial-based antenna for microwave applications. Full article

(This article belongs to the Special Issue High Performance Textiles)

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16 pages, 3420 KiB

Open AccessArticle

Thermal Stability and Decomposition Mechanism of PLA Nanocomposites with Kraft Lignin and Tannin

by Nina Maria Ainali, Evangelia Tarani, Alexandra Zamboulis, Klementina Pušnik Črešnar, Lidija Fras Zemljič, Konstantinos Chrissafis, Dimitra A. Lambropoulou and Dimitrios N. Bikiaris

Polymers 2021, 13(16), 2818; https://doi.org/10.3390/polym13162818 - 22 Aug 2021

Cited by 24 | Viewed by 3921

Abstract

Packaging applications cover approximately 40% of the total plastics production, whereas food packaging possesses a high proportion within this context. Due to several environmental concerns, petroleum-based polymers have been shifted to their biobased counterparts. Poly(lactic acid) (PLA) has been proved the most dynamic [...] Read more.

Packaging applications cover approximately 40% of the total plastics production, whereas food packaging possesses a high proportion within this context. Due to several environmental concerns, petroleum-based polymers have been shifted to their biobased counterparts. Poly(lactic acid) (PLA) has been proved the most dynamic biobased candidate as a substitute of the conventional polymers. Despite its numerous merits, PLA exhibits some limitations, and thus reinforcing agents are commonly investigated as fillers to ameliorate several characteristics. In the present study, two series of PLA-based nanocomposites filled with biobased kraft-lignin (KL) and tannin (T) in different contents were prepared. A melt–extrusion method was pursued for nanocomposites preparation. The thermal stability of the prepared nanocomposites was examined by Thermogravimetric Analysis, while thermal degradation kinetics was applied to deepen this process. Pyrolysis–Gas Chromatography/Mass Spectrometry was employed to provide more details of the degradation process of PLA filled with the two polyphenolic fillers. It was found that the PLA/lignin nanocomposites show better thermostability than neat PLA, while tannin filler has a small catalytic effect that can reduce the thermal stability of PLA. The calculated Eα value of PLA-T nanocomposite was lower than that of PLA-KL resulting in a substantially higher decomposition rate constant, which accelerate the thermal degradation. Full article

(This article belongs to the Special Issue Functional Natural-Based Polymers)

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20 pages, 4599 KiB

Open AccessArticle

Effect of Waste Ceramic Powder on Properties of Alkali-Activated Blast Furnace Slag Paste and Mortar

by Gui-Yu Zhang, Yong-Han Ahn, Run-Sheng Lin and Xiao-Yong Wang

Polymers 2021, 13(16), 2817; https://doi.org/10.3390/polym13162817 - 22 Aug 2021

Cited by 22 | Viewed by 3437

Abstract

Every year, ceramic tile factories and the iron smelting industry produce huge amounts of waste ceramic tiles and blast furnace slag (BFS), respectively. In the field of construction materials, this waste can be used as a raw material for binders, thus reducing landfill [...] Read more.

Every year, ceramic tile factories and the iron smelting industry produce huge amounts of waste ceramic tiles and blast furnace slag (BFS), respectively. In the field of construction materials, this waste can be used as a raw material for binders, thus reducing landfill waste and mitigating environmental pollution. The purpose of this study was to mix waste ceramic powder (WCP) into BFS paste and mortar activated by sodium silicate and sodium hydroxide to study its effect on performance. BFS was partially replaced by WCP at the rate of 10–30% by weight. Some experimental studies were conducted on, for example, the fluidity, heat of hydration, compressive strength testing, ultrasonic pulse velocity (UPV), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), electrical resistivity, sulfuric acid attack, and chloride ion diffusion coefficient. Based on the results of these experiments, the conclusions are: (1) increasing the amount of waste ceramic powder in the mixture can improve the fluidity of the alkali-activated paste; (2) adding waste ceramic powder to the alkali-activated mortar can improve the resistance of the mortar to sulfuric acid; (3) adding waste ceramic powder to the alkali-activated mortar can increase the diffusion coefficient of chloride ions; (4) the early strength of alkali-activated mortar is affected by the Ca/Si ratio, while the later strength is affected by the change in the Si/Al ratio. Full article

(This article belongs to the Special Issue Geopolymers - Design, Preparation, Applications)

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19 pages, 2915 KiB

Open AccessArticle

Exohedral Functionalization of Fullerene by Substituents Controlling of Molecular Organization for Spontaneous C₆₀ Dimerization in Liquid Crystal Solutions and in a Bulk Controlled by a Potential

by Malgorzata Czichy, Alessia Colombo, Pawel Wagner, Patryk Janasik, Claudia Dragonetti, Rathinam Raja, David L. Officer and Leeyih Wang

Polymers 2021, 13(16), 2816; https://doi.org/10.3390/polym13162816 - 22 Aug 2021

Cited by 3 | Viewed by 2961

Abstract

A study was carried out on the possibility of orderly and spontaneous dimerization at room temperature of C₆₀ cages in fullerene liquid crystal fullerene dyads (R-C₆₀). For this purpose, dyads with a structural elements feature supporting π-stacking and Van der [...] Read more.

A study was carried out on the possibility of orderly and spontaneous dimerization at room temperature of C₆₀ cages in fullerene liquid crystal fullerene dyads (R-C₆₀). For this purpose, dyads with a structural elements feature supporting π-stacking and Van der Waals interactions were tested, due to the presence of terthiophene donors linked through an α-position or dodecyloxy chains. In addition, this possibility was also tested and compared to dyads with shorter substituents and the pristine C₆₀. Research has shown that only in dyads with the features of liquid crystals, π-dimerization of C₆₀ units occurs, which was verified by electrochemical and spectroelectrochemical (ESR) measurements. Cyclic voltammetry and differential voltammetry studies reveal π-dimerization in liquid crystal dyad solution even without the possibility of previous polymerization (cathodic or anodic) under conditions in the absence of irradiation and without the availability of reaction initiators, and even with the use of preliminary homogenization. These dyads undergo six sequential, one-electron reductions of π-dimer (R-C₆₀···C₆₀-R), where two electrons are added successively to each of the two fullerene cages and first form two radical anion system (R-C₆₀)^•−(R-C₆₀)^•− without pairing with the characteristics of two doublets. Similarly, the second reductions of π-dimer occur at potentials that are close to the reduction potential for the conversion to a system of two triplet dianions (R-C₆₀)²⁻(R-C₆₀)²⁻. Electron paramagnetic resonance spectra indicate a significant interaction between C₆₀ cages. Interestingly, the strength of intermolecular bonds is so significant that it can overcome Coulombic repulsion, even with such highly charged particles as dianions and trianions. Such behavior has been revealed and studied so far only in covalently bonded C₆₀ dimers. Full article

(This article belongs to the Special Issue Spectroelectrochemistry of Electroactive Polymer Materials)

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33 pages, 9640 KiB

Open AccessReview

A Comprehensive Review of Microneedles: Types, Materials, Processes, Characterizations and Applications

by Faisal Khaled Aldawood, Abhay Andar and Salil Desai

Polymers 2021, 13(16), 2815; https://doi.org/10.3390/polym13162815 - 22 Aug 2021

Cited by 182 | Viewed by 15255

Abstract

Drug delivery through the skin offers many advantages such as avoidance of hepatic first-pass metabolism, maintenance of steady plasma concentration, safety, and compliance over oral or parenteral pathways. However, the biggest challenge for transdermal delivery is that only a limited number of potent [...] Read more.

Drug delivery through the skin offers many advantages such as avoidance of hepatic first-pass metabolism, maintenance of steady plasma concentration, safety, and compliance over oral or parenteral pathways. However, the biggest challenge for transdermal delivery is that only a limited number of potent drugs with ideal physicochemical properties can passively diffuse and intercellularly permeate through skin barriers and achieve therapeutic concentration by this route. Significant efforts have been made toward the development of approaches to enhance transdermal permeation of the drugs. Among them, microneedles represent one of the microscale physical enhancement methods that greatly expand the spectrum of drugs for transdermal and intradermal delivery. Microneedles typically measure 0.1–1 mm in length. In this review, microneedle materials, fabrication routes, characterization techniques, and applications for transdermal delivery are discussed. A variety of materials such as silicon, stainless steel, and polymers have been used to fabricate solid, coated, hollow, or dissolvable microneedles. Their implications for transdermal drug delivery have been discussed extensively. However, there remain challenges with sustained delivery, efficacy, cost-effective fabrication, and large-scale manufacturing. This review discusses different modes of characterization and the gaps in manufacturing technologies associated with microneedles. This review also discusses their potential impact on drug delivery, vaccine delivery, disease diagnostic, and cosmetics applications. Full article

(This article belongs to the Special Issue Polymer-Based Systems for Targeted Therapy)

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13 pages, 966 KiB

Open AccessArticle

The Influence of Modified Experimental Dental Resin Composites on the Initial In Situ Biofilm—A Triple-Blinded, Randomized, Controlled Split-Mouth Trial

by Niklas Burgard, Melanie Kienitz, Claudia Jourdan and Stefan Rüttermann

Polymers 2021, 13(16), 2814; https://doi.org/10.3390/polym13162814 - 21 Aug 2021

Cited by 2 | Viewed by 2359

Abstract

The purpose of the study was to investigate the bacterial viability of the initial biofilm on the surface of experimental modified dental resin composites. Twenty-five healthy individuals with good oral hygiene were included in this study. In a split-mouth design, they received acrylic [...] Read more.

The purpose of the study was to investigate the bacterial viability of the initial biofilm on the surface of experimental modified dental resin composites. Twenty-five healthy individuals with good oral hygiene were included in this study. In a split-mouth design, they received acrylic splints with five experimental composite resin specimens. Four of them were modified with either a novel polymeric hollow-bead delivery system or methacrylated polymerizable Irgasan (Antibacterial B), while one specimen served as an unmodified control (ST). A delivery system based on Poly-Pore^® was loaded with one of the active agents: Tego^® Protect 5000 (Antiadhesive A), Dimethicone (Antiadhesive B), or Irgasan (Antibacterial A). All study subjects refrained from toothbrushing during the study period. Specimens were detached from the splints after 8 h and given a live/dead staining before fluorescence microscopy. A Friedman test and a post hoc Nemenyi test were applied with a significance level at p < 0.05. In summary, all materials but Antibacterial B showed a significant antibacterial effect compared to ST. The results suggested the role of the materials’ chemistry in the dominance of cell adhesion. In conclusion, dental resin composites with Poly-Pore-loaded active agents showed antibacterial effectiveness in situ. Full article

(This article belongs to the Special Issue Advanced Polymeric Composites in Dentistry: Synthesis, Properties, and Applications)

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15 pages, 3197 KiB

Open AccessArticle

Study of Different Chitosan/Sodium Carboxymethyl Cellulose Proportions in the Development of Polyelectrolyte Complexes for the Sustained Release of Clarithromycin from Matrix Tablets

by Víctor Guarnizo-Herrero, Carlos Torrado-Salmerón, Norma Sofía Torres Pabón, Guillermo Torrado Durán, Javier Morales and Santiago Torrado-Santiago

Polymers 2021, 13(16), 2813; https://doi.org/10.3390/polym13162813 - 21 Aug 2021

Cited by 22 | Viewed by 3875

Abstract

This study investigated the combination of different proportions of cationic chitosan and anionic carboxymethyl cellulose (CMC) for the development of polyelectrolyte complexes to be used as a carrier in a sustained-release system. Analysis via scanning electron microscopy (SEM) Fourier transform infrared spectroscopy (FTIR), [...] Read more.

This study investigated the combination of different proportions of cationic chitosan and anionic carboxymethyl cellulose (CMC) for the development of polyelectrolyte complexes to be used as a carrier in a sustained-release system. Analysis via scanning electron microscopy (SEM) Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), and powder X-ray diffraction (PXRD) confirmed ionic interactions occur between the chitosan and carboxymethyl cellulose chains, which increases drug entrapment. The results of the dissolution study in acetate buffer (pH 4.2) showed significant increases in the kinetic profiles of clarithromycin for low proportions of chitosan/carboxymethyl cellulose tablets, while the tablets containing only chitosan had high relaxation of chitosan chains and disintegrated rapidly. The Korsmeyer–Peppas kinetic model for the different interpolymer complexes demonstrated that the clarithromycin transport mechanism was controlled by Fickian diffusion. These results suggest that the matrix tablets with different proportions of chitosan/carboxymethyl cellulose enhanced the ionic interaction and enabled the prolonged release of clarithromycin. Full article

(This article belongs to the Special Issue Chitosan, Chitin, and Cellulose Nanofiber Biomaterials)

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22 pages, 5890 KiB

Open AccessArticle

Bioinspired Design of Sericin/Chitosan/Ag@MOF/GO Hydrogels for Efficiently Combating Resistant Bacteria, Rapid Hemostasis, and Wound Healing

by Meng Zhang, Dong Wang, Nana Ji, Shaoxiang Lee, Guohui Wang, Yuqi Zheng, Xin Zhang, Lin Yang, Zhiwei Qin and Yang Yang

Polymers 2021, 13(16), 2812; https://doi.org/10.3390/polym13162812 - 21 Aug 2021

Cited by 47 | Viewed by 5050

Abstract

Due to the spread of drug-resistant bacteria in hospitals, the development of antibacterial dressings has become a strategy to control wound infections caused by bacteria. Here, we reported a green strategy for in situ biomimetic syntheses of silver nanoparticles@organic frameworks/graphene oxide (Ag@MOF–GO) in [...] Read more.

Due to the spread of drug-resistant bacteria in hospitals, the development of antibacterial dressings has become a strategy to control wound infections caused by bacteria. Here, we reported a green strategy for in situ biomimetic syntheses of silver nanoparticles@organic frameworks/graphene oxide (Ag@MOF–GO) in sericin/chitosan/polyvinyl alcohol hydrogel. Ag@MOF–GO was synthesized in situ from the redox properties of tyrosine residues in silk sericin without additional chemicals, similar to a biomineralization process. The sericin/chitosan/Ag@MOF–GO dressing possessed a high porosity, good water retention, and a swelling ratio. The hemolysis rate of the composite was 3.9% and the cell viability rate was 131.2%, which indicated the hydrogel possessed good biocompatibility. The composite also showed excellent lasting antibacterial properties against drug-sensitive and drug-resistant pathogenic bacteria. The composite possessed excellent hemostatic activity. The coagulation effect of the composite may be related to its effect on the red blood cells and platelets, but it has nothing to do with the activation of coagulation factors. An in vitro cell migration assay confirmed and an in vivo evaluation of mice indicated that the composite could accelerate wound healing and re-epithelialization. In summary, the composite material is an ideal dressing for accelerating hemostasis, preventing bacterial infection, and promoting wound healing. Full article

(This article belongs to the Special Issue Hydrogel-Based Composites for Biomedical Applications)

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13 pages, 5679 KiB

Open AccessArticle

Biomaterial-Assisted Anastomotic Healing: Serosal Adhesion of Pectin Films

by Yifan Zheng, Aidan F. Pierce, Willi L. Wagner, Hassan A. Khalil, Zi Chen, Charlotta Funaya, Maximilian Ackermann and Steven J. Mentzer

Polymers 2021, 13(16), 2811; https://doi.org/10.3390/polym13162811 - 21 Aug 2021

Cited by 12 | Viewed by 2763

Abstract

Anastomotic leakage is a frequent complication of intestinal surgery and a major source of surgical morbidity. The timing of anastomotic failures suggests that leaks are the result of inadequate mechanical support during the vulnerable phase of wound healing. To identify a biomaterial with [...] Read more.

Anastomotic leakage is a frequent complication of intestinal surgery and a major source of surgical morbidity. The timing of anastomotic failures suggests that leaks are the result of inadequate mechanical support during the vulnerable phase of wound healing. To identify a biomaterial with physical and mechanical properties appropriate for assisted anastomotic healing, we studied the adhesive properties of the plant-derived structural heteropolysaccharide called pectin. Specifically, we examined high methoxyl citrus pectin films at water contents between 17–24% for their adhesivity to ex vivo porcine small bowel serosa. In assays of tensile adhesion strength, pectin demonstrated significantly greater adhesivity to the serosa than either nanocellulose fiber (NCF) films or pressure sensitive adhesives (PSA) (p < 0.001). Similarly, in assays of shear resistance, pectin demonstrated significantly greater adhesivity to the serosa than either NCF films or PSA (p < 0.001). Finally, the pectin films were capable of effectively sealing linear enterotomies in a bowel simulacrum as well as an ex vivo bowel segment. We conclude that pectin is a biomaterial with physical and adhesive properties capable of facilitating anastomotic healing after intestinal surgery. Full article

(This article belongs to the Special Issue Biomaterials in Medical Applications)

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17 pages, 6718 KiB

Open AccessArticle

Fully Bio-Based Elastomer Nanocomposites Comprising Polyfarnesene Reinforced with Plasma-Modified Cellulose Nanocrystals

by Ilse Magaña, Dimitrios Georgouvelas, Rishab Handa, María Guadalupe Neira Velázquez, Héctor Ricardo López González, Francisco Javier Enríquez Medrano, Ramón Díaz de León and Luis Valencia

Polymers 2021, 13(16), 2810; https://doi.org/10.3390/polym13162810 - 21 Aug 2021

Cited by 7 | Viewed by 3482

Abstract

This article proposes a process to prepare fully bio-based elastomer nanocomposites based on polyfarnesene and cellulose nanocrystals (CNC). To improve the compatibility of cellulose with the hydrophobic matrix of polyfarnesene, the surface of CNC was modified via plasma-induced polymerization, at different powers of [...] Read more.

This article proposes a process to prepare fully bio-based elastomer nanocomposites based on polyfarnesene and cellulose nanocrystals (CNC). To improve the compatibility of cellulose with the hydrophobic matrix of polyfarnesene, the surface of CNC was modified via plasma-induced polymerization, at different powers of the plasma generator, using a trans-β-farnesene monomer in the plasma reactor. The characteristic features of plasma surface-modified CNC have been corroborated by spectroscopic (XPS) and microscopic (AFM) analyses. Moreover, the cellulose nanocrystals modified at 150 W have been selected to reinforce polyfarnesene-based nanocomposites, synthesized via an in-situ coordination polymerization using a neodymium-based catalytic system. The effect of the different loading content of nanocrystals on the polymerization behavior, as well as on the rheological aspects, was evaluated. The increase in the storage modulus with the incorporation of superficially modified nanocrystals was demonstrated by rheological measurements and these materials exhibited better properties than those containing pristine cellulose nanocrystals. Moreover, we elucidate that the viscoelastic moduli of the elastomer nanocomposites are aligned with power–law model systems with characteristic relaxation time scales similar to commercial nanocomposites, also implying tunable mechanical properties. In this foreground, our findings have important implications in the development of fully bio-based nanocomposites in close competition with the commercial stock, thereby producing alternatives in favor of sustainable materials. Full article

(This article belongs to the Special Issue Nanocellulose: Polymer Nanocomposites and all-Cellulose Materials)

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20 pages, 2805 KiB

Open AccessReview

Polymer-Based Additive Manufacturing: Process Optimisation for Low-Cost Industrial Robotics Manufacture

by Kartikeya Walia, Ahmed Khan and Philip Breedon

Polymers 2021, 13(16), 2809; https://doi.org/10.3390/polym13162809 - 21 Aug 2021

Cited by 16 | Viewed by 4636

Abstract

The robotics design process can be complex with potentially multiple design iterations. The use of 3D printing is ideal for rapid prototyping and has conventionally been utilised in concept development and for exploring different design parameters that are ultimately used to meet an [...] Read more.

The robotics design process can be complex with potentially multiple design iterations. The use of 3D printing is ideal for rapid prototyping and has conventionally been utilised in concept development and for exploring different design parameters that are ultimately used to meet an intended application or routine. During the initial stage of a robot development, exploiting 3D printing can provide design freedom, customisation and sustainability and ultimately lead to direct cost benefits. Traditionally, robot specifications are selected on the basis of being able to deliver a specific task. However, a robot that can be specified by design parameters linked to a distinctive task can be developed quickly, inexpensively, and with little overall risk utilising a 3D printing process. Numerous factors are inevitably important for the design of industrial robots using polymer-based additive manufacturing. However, with an extensive range of new polymer-based additive manufacturing techniques and materials, these could provide significant benefits for future robotics design and development. Full article

(This article belongs to the Special Issue Applications of 3D Printing for Polymers)

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14 pages, 6999 KiB

Open AccessArticle

Catalytic Stereoselective Conversion of Biomass-Derived 4′-Methoxypropiophenone to Trans-Anethole with a Bifunctional and Recyclable Hf-Based Polymeric Nanocatalyst

by Yixuan Liu, Dandan Chen, Mingrui Li, Heng Zhang and Hu Li

Polymers 2021, 13(16), 2808; https://doi.org/10.3390/polym13162808 - 21 Aug 2021

Cited by 8 | Viewed by 2673

Abstract

Anethole (AN) is widely used as an odor cleaner in daily necessities, and can also be applied in the fields of food additives, drug synthesis, natural preservatives, and polymeric materials’ preparation. Considering environmental and economic benefits, the use of biomass raw materials with [...] Read more.

Anethole (AN) is widely used as an odor cleaner in daily necessities, and can also be applied in the fields of food additives, drug synthesis, natural preservatives, and polymeric materials’ preparation. Considering environmental and economic benefits, the use of biomass raw materials with non-precious metal catalysts to prepare high-value fine chemicals is a very promising route. Here, we developed an acid-base bifunctional polymeric material (PhP-Hf (1:1.5)) composed of hafnium and phenylphosphonate in a molar ratio of 1:1.5 for catalytic conversion of biomass-derived 4′-methoxypropiophenone (4-MOPP) to AN via cascade Meerwein–Pondorf–Verley (MPV) reduction and dehydration reactions in a single pot. Compared with the traditional catalytic systems that use high-pressure hydrogen as a hydrogen donor, alcohol can be used as a safer and more convenient hydrogen source and solvent. Among the tested alcohols, 2-pentanol was found to be the best candidate in terms of pronounced selectivity. A high AN yield of 98.1% at 99.8% 4-MOPP conversion (TOF: 8.5 h⁻¹) could be achieved over PhP-Hf (1:1.5) at 220 °C for 2 h. Further exploration of the reaction mechanism revealed that the acid and base sites of PhP-Hf (1:1.5) catalyst synergistically promote the MPV reduction step, while the Brønsted acid species significantly contribute to the subsequent dehydration step. In addition, the PhP-Hf polymeric nanocatalyst can be recycled at least five times, showing great potential in the catalytic conversion of biomass. Full article

(This article belongs to the Special Issue MOF-Based Functional Catalytic Materials for Biofuels Production)

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