Air pollution, a major health concern, necessitates innovative solutions such as TiO
2-based photocatalytic building materials to combat its harmful effects. This study focuses on developing high-performance TiO
2 photocatalysts for NO
x removal in building applications, aiming to overcome the limitations
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Air pollution, a major health concern, necessitates innovative solutions such as TiO
2-based photocatalytic building materials to combat its harmful effects. This study focuses on developing high-performance TiO
2 photocatalysts for NO
x removal in building applications, aiming to overcome the limitations of commercial TiO
2. These photocatalysts were synthesized via a hydrothermal method, with parameters such as synthesis time and post-treatment investigated to optimize their properties. Hydrothermal synthesis yielded TiO
2 nanoparticles with reduced aggregation and a high proportion of elongated particles with exposed {010} facets. This resulted in significantly enhanced photocatalytic activity compared to commercial P25 in methylene blue degradation and NO
x depollution. Subsequently, the optimized hydrothermal TiO
2 was successfully integrated into a silica sol–gel coating for application on building materials. The coated concrete demonstrated significantly higher NO
x removal efficiency and lower NO
2 release, achieving a 1.7-fold improvement in overall NO
x removal and significantly higher depolluting effectiveness compared to its P25 counterpart. These findings highlight the potential of hydrothermally synthesized TiO
2 with controlled morphology for the development of high-performance, environmentally friendly building materials with enhanced air purification capabilities.
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