The conventional V
2O
5 preparation processes include ion exchange, chemical precipitation, solvent extraction, and other processes. Given the long process and complex operation nature of traditional V
2O
5 production methods, we herein developed a short-process, low-temperature, and convenient operation
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The conventional V
2O
5 preparation processes include ion exchange, chemical precipitation, solvent extraction, and other processes. Given the long process and complex operation nature of traditional V
2O
5 production methods, we herein developed a short-process, low-temperature, and convenient operation method of isolating vanadium (in the form of V
2O
5) from shale acid leaching solution. The acid leaching solution was oxidized with NaClO
3 and pH-adjusted with NaOH to form a vanadium-containing precipitate, which was mixed with AlCl
3 (V:AlCl
3 = 1:5, mol/mol) and roasted for 120 min at 170 °C to afford vanadium oxytrichloride (VOCl
3) with a purity of 99.59%. In addition, the vanadium-containing precipitate was mixed with AlCl
3 and NaCl (V:AlCl
3:NaCl = 3:12:8, mol/mol/mol) and roasted for 120 min at 170 °C to afford VOCl
3 with a purity of 99.94%. VOCl
3 (purity of 99.94%) was dissolved in ultrapure water, and the solution (32 g
vanadium/L) was treated with NH
3·H
2O (NH
3:V = 1.34, mol/mol) at 50 °C for 120 min. The obtained precipitate (vanadium precipitation rate = 99.28%) was roasted at 550 °C for 3 h to afford high-purity vanadium pentoxide (V
2O
5) with a purity of 99.86%. Compared with the traditional hydrometallurgical method of V
2O
5 preparation, our method avoided solvent extraction and other undesired processes and the overall process flow is greatly shortened, thus having high practical value.
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