YF
3: (Eu
3+, Nd
3+) nanoparticles (orthorhombic phase, D~130 nm) were synthesized via the co-precipitation method, with subsequent hydrothermal treatment and annealing. The Eu
3+ τ
decay linearly descends with the increase of temperature in the 80–320 K range.
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YF
3: (Eu
3+, Nd
3+) nanoparticles (orthorhombic phase, D~130 nm) were synthesized via the co-precipitation method, with subsequent hydrothermal treatment and annealing. The Eu
3+ τ
decay linearly descends with the increase of temperature in the 80–320 K range. The τ
decay (T) slope values of the annealed YF
3: Eu
3+ (2.5 and 5.0 mol.%) nanoparticles were the highest (110·10
−4 and 67·10
−4, μs/K) in the whole 80–320 K range, respectively. Thus, these samples were chosen for further doping with Nd
3+. The maximum S
a and S
r values based on the LIR (I
Eu/I
Nd) function were 0.067 K
−1 (at 80 K) and 0.86%·K
−1 (at 154 K), respectively. As mentioned above, the single-doped YF
3: Eu
3+ (2.5%) nanoparticles showed the linearly decreasing τ
decay (T) function (
5D
0–
7F
1 emission). The main idea of Nd
3+ co-doping was to increase this slope value (as well as the sensitivity) by increasing the rate of τ
decay (T) descent via the addition of one more temperature-dependent channel of
5D
0 excited state depopulation. Indeed, we managed to increase the slope (S
a) to 180·10
−4 K
−1 at 80 K. This result is one of the highest compared to the world analogs.
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