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Volume 9, January
 
 

J. Compos. Sci., Volume 9, Issue 2 (February 2025) – 18 articles

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12 pages, 970 KiB  
Article
Enhanced Photocatalytic Hydrogen Generation from Methanol Solutions via In Situ Ni/Pt Co-Deposition on TiO2
by Mst. Farhana Afrin, Mai Furukawa, Ikki Tateishi, Hideyuki Katsumata, Monir Uzzaman and Satoshi Kaneco
J. Compos. Sci. 2025, 9(2), 68; https://doi.org/10.3390/jcs9020068 (registering DOI) - 2 Feb 2025
Viewed by 455
Abstract
TiO2 is widely utilized as an excellent photocatalyst in energy production. However, its rapid electron and hole recombination confers poor photocatalytic activity. Cocatalysts are essential for increasing photocatalytic efficacy by introducing improved electron transmission and enlarging the active site. Herein, the photocatalytic [...] Read more.
TiO2 is widely utilized as an excellent photocatalyst in energy production. However, its rapid electron and hole recombination confers poor photocatalytic activity. Cocatalysts are essential for increasing photocatalytic efficacy by introducing improved electron transmission and enlarging the active site. Herein, the photocatalytic degradation of aqueous methanol solution to generate hydrogen was studied with the simultaneous in situ deposition of metals (M = Ag, Cu, Ni, Pd, and Pt) on the TiO2 surface. Adding methanol to water and incorporating a bimetallic cocatalyst enhanced hydrogen production by reducing the electron–hole pair recombination. The studied metal ions could be reduced by the conduction band electrons of TiO2 for the in situ simultaneous deposition of metal. The larger work function value of the studied metals favored the Schottky junction formation, which contributed to increasing photocatalytic efficiency. Among these simultaneous metal-deposited photocatalysts, maximal photocatalytic hydrogen production was achieved with NiPt/TiO2. The optimal component was 0.01 wt.% Ni/1.0 wt.% Pt for TiO2. The hydrogen evolution with NiPt/TiO2 was approximately 341 and 1.3 times better than that with pure TiO2 and Pt/TiO2, respectively. A potential reaction pathway for photocatalytic hydrogen production from an aqueous methanol solution over NiPt/TiO2 photocatalyst has also been proposed. Full article
(This article belongs to the Special Issue Feature Papers in Journal of Composites Science in 2024)
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22 pages, 5276 KiB  
Article
Development of Doum Palm Fiber-Based Building Insulation Composites with Citric Acid/Glycerol Eco-Friendly Binder
by Hicham Elmoudnia, Younoussa Millogo, Paulina Faria, Rachid Jalal, Mohamed Waqif and Latifa Saâdi
J. Compos. Sci. 2025, 9(2), 67; https://doi.org/10.3390/jcs9020067 (registering DOI) - 2 Feb 2025
Viewed by 601
Abstract
This study focuses on the development of an insulation biocomposite using Doum palm (Chamaerops humilis) fibers reinforced with a natural binder based on citric acid and glycerol. The main objective is to optimize the thermal conductivity and mechanical properties of the biocomposite as [...] Read more.
This study focuses on the development of an insulation biocomposite using Doum palm (Chamaerops humilis) fibers reinforced with a natural binder based on citric acid and glycerol. The main objective is to optimize the thermal conductivity and mechanical properties of the biocomposite as a function of fiber preparation (short or powdered fibers) and binder content (20%, 30% and 40%), and relate them to the bonding of the fibers and the binder. The obtained results suggest that the addition of the binder greatly enhances the density, compressive strength and Young’s modulus of biocomposites. More specifically, the addition of 20% by weight of the citric acid/glycerol binder improves the bond between fibers, whether they are short fibers or powders. This leads to an increase in the mechanical properties, with Young’s modulus reaching (212.1) MPa and compressive strength at (24.3) MPa. On the other hand, the results show that these biocomposites also have acceptable thermal insulation performance, achieving a thermal conductivity of (0.102) W/(m·K), making them suitable for a variety of applications in sustainable buildings and for refurbishment. Full article
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22 pages, 13498 KiB  
Article
A Study on the Relationship Between the Pore Characteristics of High-Performance Self-Compacting Concrete (HPSCC) Based on Fractal Theory and the Function of the Water–Binder Ratio (W/C)
by Guihong Xu, Mingwei He, Li He, Yongsheng Chen, Li Duan and Weiguo Jiao
J. Compos. Sci. 2025, 9(2), 66; https://doi.org/10.3390/jcs9020066 (registering DOI) - 2 Feb 2025
Viewed by 149
Abstract
The mechanical properties of High-Performance Self-Compacting Concrete (HPSCC) are strongly influenced by its pore structure, but the impact of varying water–binder ratios (W/C) on this relationship remains unclear. To address this, the present study investigates HPSCC with W/C ratios ranging from 0.19 to [...] Read more.
The mechanical properties of High-Performance Self-Compacting Concrete (HPSCC) are strongly influenced by its pore structure, but the impact of varying water–binder ratios (W/C) on this relationship remains unclear. To address this, the present study investigates HPSCC with W/C ratios ranging from 0.19 to 0.23, aiming to elucidate the connection between pore structure, fractal characteristics, and mechanical performance. Through a combination of compressive strength testing, low-temperature nitrogen adsorption, and Scanning Electron Microscopy (SEM) observations, this study reveals key insights. First, compressive strength initially increases with a decreasing W/C ratio but plateaus beyond W/C = 0.21, identifying an optimal range for balancing strength and workability. Second, the pore structure of HPSCC is characterized by cylindrical, ink-bottle, and planar interstitial pores, with significant fractal characteristics. Notably, the fractal dimension decreases as the W/C ratio increases, indicating reduced pore complexity and improved homogeneity. Finally, a strong linear correlation (R2 > 0.9) between the W/C ratio, fractal dimension, and compressive strength provides a predictive tool for assessing HPSCC performance. This study concludes that the internal pore structure is a critical determinant of HPSCC strength, and the identified optimal W/C ratio range offers guidance for mixture designs. Additionally, fractal dimension analysis emerges as a novel method to evaluate HPSCC’s microstructural quality, enabling predictions of long-term performance and durability. These findings contribute to the scientific basis for designing high-performance concrete materials with improved mechanical properties and durability. Full article
(This article belongs to the Special Issue Novel Cement and Concrete Materials)
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18 pages, 5155 KiB  
Article
Antibacterial UV-Curable Gel with Hydroxyapatite Nanoparticles for Regenerative Medicine in the Field of Orthopedics
by Julia A. Burunkova, Valeria V. Semykina, Vera E. Sitnikova, Dmitry M. Dolgintsev, Faliya F. Zaripova, Alina A. Ponomareva, Diana R. Mizina, Attila Csick, Sandor Kokenyesi and Anton Zhilenkov
J. Compos. Sci. 2025, 9(2), 65; https://doi.org/10.3390/jcs9020065 (registering DOI) - 1 Feb 2025
Viewed by 419
Abstract
The development and analysis of the properties of a new material based on UV-curable acrylate monomers with silicon-containing hydroxyapatite and zinc oxide nanoparticles as an antibacterial component and gelatin was carried out. Using this material in orthopedics and dentistry is very convenient because [...] Read more.
The development and analysis of the properties of a new material based on UV-curable acrylate monomers with silicon-containing hydroxyapatite and zinc oxide nanoparticles as an antibacterial component and gelatin was carried out. Using this material in orthopedics and dentistry is very convenient because it covers any surface geometry of metal implants and hardens under ultraviolet light. In this work, sorption properties, changes in porosity, and mechanical properties of the material were investigated. The conditions for obtaining hydroxyapatite (HA) nanoparticles and the presence of silicon oxide nanoparticles and organic for the shell in an aqueous medium were studied for the pH of the medium, the sequence of administration and concentration of the material components, as well as antibacterial properties. This polymer material is partially resorbable. That supports not only the growth of bone cells but also serves as a protective layer. It reduces friction between organic tissues and a metal implant and can be a solution to the problem of the aseptic instability of metal implants. The material can also be used to repair damaged bones and cartilage tissues, especially in cases where the application and curing procedure is performed using laparoscopic methods. In this work, the authors propose a simple and quite cheap method for obtaining material based on photopolymerizable acrylates and natural gelatin with nanoparticles of HA, zinc oxide, and silicon oxide. The method allows one to obtain a composite material with different nanoparticles in a polymer matrix which retain the requisite properties needed such as active-sized HA, antibacterial ZnO, and structure-forming and stability-improving SiO2 nanoparticles. Full article
(This article belongs to the Section Biocomposites)
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14 pages, 5278 KiB  
Article
Microwave Synthesis of Luminescent Recycled Glass Containing Dy2O3 and Sm2O3
by Achanai Buasri, Apichaya Boonpanya, Arraya Yangderm, Thanaporn Kensopha and Vorrada Loryuenyong
J. Compos. Sci. 2025, 9(2), 64; https://doi.org/10.3390/jcs9020064 (registering DOI) - 1 Feb 2025
Viewed by 405
Abstract
This research studied the recycling of borosilicate glass wastes from damaged laboratory glassware. The luminescent glasses were prepared by doping glass waste powder with rare earth ions, namely, dysprosium ions (Dy3+) and samarium ions (Sm3+), as well as co-doping [...] Read more.
This research studied the recycling of borosilicate glass wastes from damaged laboratory glassware. The luminescent glasses were prepared by doping glass waste powder with rare earth ions, namely, dysprosium ions (Dy3+) and samarium ions (Sm3+), as well as co-doping with Dy3+ and Sm3+ at a concentration of 2% by weight. The sintering process was conducted in a microwave oven for a duration of 15 min. The photoluminescence spectra of the doped glasses were obtained under excitation at 401 nm and 388 nm. The results showed that the emission characteristics depended on the doping concentrations of Dy3+ and Sm3+ and the excitation wavelengths. Upon excitation at 401 nm, the co-doped glasses exhibited the maximum emission peak of Sm3+ at 601 nm (yellowish and orange region in the CIE chromaticity diagram) due to the energy transition from 4G5/2 to 6H7/2. When excited at 388 nm, however, the emission spectra of the co-doped glasses were similar to the characteristic emission peaks of Dy3+ (white region in the CIE chromaticity diagram), but the peak position exhibits a red shift. This could be attributed to an increase in the amount of non-bridging oxygens (NBOs) by co-doping. Full article
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18 pages, 3609 KiB  
Article
Optimization of 3D Printing Parameters for Enhanced Mechanical Strength: Effects of Glass Fiber Reinforcement and Fill Ratio Using RSM and ANOVA
by Hussein Hadi Jawad, Naser Kordani, Abbasali Bagheri and Hamed Aghajani Derazkola
J. Compos. Sci. 2025, 9(2), 63; https://doi.org/10.3390/jcs9020063 (registering DOI) - 1 Feb 2025
Viewed by 191
Abstract
This research aimed to provide valuable insights for future studies and enhance manufacturing processes by investigating the effect of incorporating fibers into 3D printing to improve the mechanical properties of fabricated components. The experimental design was carried out using Design-Expert software, employing the [...] Read more.
This research aimed to provide valuable insights for future studies and enhance manufacturing processes by investigating the effect of incorporating fibers into 3D printing to improve the mechanical properties of fabricated components. The experimental design was carried out using Design-Expert software, employing the Central Composite Design (CCD) methodology. Seventeen experiments were conducted, with predefined input parameters, layer height, filler ratio, and printing speed, analyzed through the Response Surface Methodology (RSM) using Design-Expert version 12. An Analysis of Variance (ANOVA) revealed that the filler ratio had the most significant effect on fracture strength. The influence of different printing parameters printing speed, layer height, and filler ratio on the mechanical properties and print quality was systematically investigated. The results indicated that the filler ratio was the most critical factor, with a 100% fill ratio yielding the highest tensile strength. Conversely, a 50% fill ratio significantly reduced production costs, but at the expense of mechanical performance. Thus, if strength is the primary requirement, a higher fill ratio is recommended. The effect of printing speed was found to be less significant compared to layer height and filler ratio. The maximum recorded tensile strength was 540.65 N, achieved with a layer height of 0.5 mm, a 100% fill ratio, and a printing speed of 8 mm/s. In contrast, the lowest recorded tensile strength was 389.93 N, observed with a layer height of 0.4 mm, a 50% fill ratio, and a printing speed of 4 mm/s. After applying a transformation function, the data showed good alignment with the normal distribution on the probability plot, indicating that the assumption of normality was satisfied. Additionally, the incorporation of glass fibers significantly enhanced the mechanical strength of the printed samples. Full article
(This article belongs to the Special Issue Recent Progress in Hybrid Composites)
18 pages, 4260 KiB  
Article
Influence of Synthesis Conditions on the Structure, Composition, and Electromagnetic Properties of FeCoSm/C Nanocomposites
by Dmitriy Muratov, Lev Kozhitov, Irina Zaporotskova, Alena Popkova, Evgeniy Korovin, Sergey Boroznin and Natalia Boroznina
J. Compos. Sci. 2025, 9(2), 62; https://doi.org/10.3390/jcs9020062 (registering DOI) - 1 Feb 2025
Viewed by 220
Abstract
New materials are actively being developed for use in various fields of electronics, as they can significantly improve the performance of electronic devices and prevent adverse effects. Such materials include nanocomposites, which include nanoparticles of magnetic metals and alloys in a non-magnetic polymer [...] Read more.
New materials are actively being developed for use in various fields of electronics, as they can significantly improve the performance of electronic devices and prevent adverse effects. Such materials include nanocomposites, which include nanoparticles of magnetic metals and alloys in a non-magnetic polymer or carbon matrix. For the first time, we synthesized FeCoSm/C nanocomposites and studied the effect of synthesis conditions on their structure, composition, and electromagnetic properties. Thermogravimetric (TG) analysis and differential scanning calorimetry (DSC) analysis of the heating processes of nanocomposite precursors allowed optimizing the mode of IR processing of precursors. X-ray phase analysis (XPA) showed that nanoparticles of a solid-metal solution based on the FeCo structure are formed, and at temperatures above 700 °C, the formation of SmCo5-x alloy nanoparticles is also possible. As the synthesis temperature increases, the average size of nanoparticles of alloys containing Sm increases. The effect of the metal ratio in the precursor on the structure, composition, and electromagnetic properties of FeCoSm/C nanocomposites is analyzed. It has been established that the most promising of all the studied materials are those obtained at a temperature of 700 °C with a metal ratio of Fe:Co:Sm = 50:40:10. Full article
(This article belongs to the Special Issue Recent Progress in Hybrid Composites)
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10 pages, 3285 KiB  
Article
Correlation Between Soft Magnetic Properties and Microstructure According to Heat Treatment in FeCo-2V Electrical Steel
by Harang Lee, Jihye Park, Hyunkyung Lee and Haein Choi-Yim
J. Compos. Sci. 2025, 9(2), 61; https://doi.org/10.3390/jcs9020061 - 30 Jan 2025
Viewed by 429
Abstract
Fe-Co alloy has the highest saturation magnetic flux density among soft magnetic materials, and Fe50Co50 has the maximum permeability of Fe-Co alloys. However, Fe-Co alloy is difficult to use in applications due to its brittleness. Various attempts have been made [...] Read more.
Fe-Co alloy has the highest saturation magnetic flux density among soft magnetic materials, and Fe50Co50 has the maximum permeability of Fe-Co alloys. However, Fe-Co alloy is difficult to use in applications due to its brittleness. Various attempts have been made to improve its mechanical properties for applications, but its magnetic properties have not been retained. This research focuses on improving the magnetic properties of Fe-Co electrical steels at various heat treatment temperatures with the addition of 2 at.% vanadium. To reveal the ordered body-centered cubic phase, which has good soft magnetic properties, the thermal properties of the steels were investigated with differential scanning calorimetry. The microstructure of the electrical steels after heat treatment was analyzed by scanning electron microscopy, and the tendencies of their magnetic properties, measured by a DC B-H loop tracer and a vibrating sample magnetometer, were explored in connection with the microstructure. The decrease in coercivity up to 800 °C was due to stress relief and grain growth, and its increase at 850 °C is believed to be due to the pinning effect of the V-rich phase in the grain boundary. The optimal heat treatment temperature was found to be 800 °C because the steel had reasonable magnetic saturation (2.28 T) and hysteresis loss (0.47 W/kg), the highest magnetic flux density at 5000 A/m, and the lowest coercivity (56.7 A/m). Full article
(This article belongs to the Special Issue Metal Composites, Volume II)
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17 pages, 2834 KiB  
Article
Mechanical Properties and Vibrational Behavior of 3D-Printed Carbon Fiber-Reinforced Polyphenylene Sulfide and Polyamide-6 Composites with Different Infill Types
by Vasileios Papageorgiou, Konstantinos Tsongas, Michel Theodor Mansour, Dimitrios Tzetzis and Gabriel Mansour
J. Compos. Sci. 2025, 9(2), 59; https://doi.org/10.3390/jcs9020059 - 28 Jan 2025
Viewed by 370
Abstract
The aim of the present study is to investigate the performance of two carbon fiber-reinforced composite polymers used to manufacture end-use parts via the fused filament fabrication (FFF) method. The materials under investigation were carbon fiber-reinforced Polyamide-6 (PA6-CF15) and carbon fiber-reinforced polyphenylene sulfide [...] Read more.
The aim of the present study is to investigate the performance of two carbon fiber-reinforced composite polymers used to manufacture end-use parts via the fused filament fabrication (FFF) method. The materials under investigation were carbon fiber-reinforced Polyamide-6 (PA6-CF15) and carbon fiber-reinforced polyphenylene sulfide (PPS-CF15). To evaluate their mechanical properties and vibrational behavior, specimens were fabricated with four distinct infill patterns: grid, gyroid, triangle and hexagon. In particular, the vibrational behavior of the 3D-printed composites was determined by conducting cyclic compression testing, as well as modal tests. Additionally, the mechanical behavior of the reinforced polymers was determined by conducting both uniaxial tensile and compression tests, as well as three-point bending tests. The results of the mechanical experiments revealed that the grid pattern exhibited the best overall performance, while the gyroid pattern exhibited the greatest strength-to-weight ratio, making it the most durable infill for use with composite filaments. In vibration experiments, PA6-CF15 structures exhibited higher damping ratios than PPS-CF15, indicating superior damping capacity. Among the infill patterns, the hexagon pattern provided the greatest vibration isolation performance. Full article
(This article belongs to the Special Issue Feature Papers in Journal of Composites Science in 2024)
19 pages, 4072 KiB  
Article
Titanium Dioxide/Graphene Oxide Nanocomposite-Based Humidity Sensors with Improved Performance
by Ammar Al-Hamry, Igor A. Pašti and Olfa Kanoun
J. Compos. Sci. 2025, 9(2), 60; https://doi.org/10.3390/jcs9020060 - 27 Jan 2025
Viewed by 422
Abstract
Accurate relative humidity (RH) measurement is critical in many applications, from process control and material preservation to ensuring human comfort and well-being. This study presents high-performance humidity sensors based on titanium oxide nanoparticles/graphene oxide (TiO2/GO) composites, which demonstrate excellent sensing capabilities [...] Read more.
Accurate relative humidity (RH) measurement is critical in many applications, from process control and material preservation to ensuring human comfort and well-being. This study presents high-performance humidity sensors based on titanium oxide nanoparticles/graphene oxide (TiO2/GO) composites, which demonstrate excellent sensing capabilities compared to pure GO-based sensors. The multilayer structure of the TiO2/GO composites enables the enhanced adsorption of water molecules and improved dynamic properties while providing dual-mode sensing capability through both resistive and capacitive measurements. Sensors with different TiO2/GO ratios were systematically investigated to optimize performance over different humidity ranges. The TiO2/GO sensor achieved remarkable sensitivity (8.66 × 104 Ω/%RH), a fast response time (0.61 s), and fast recovery (0.87 s) with minimal hysteresis (4.09%). In particular, the sensors demonstrated excellent mechanical stability, maintaining reliable performance under bending conditions, together with excellent cyclic stability and long-term durability. Temperature dependence studies showed consistent performance under controlled temperature conditions, with the potential for temperature-compensated measurements. These results highlight TiO2/GO nanocomposites as promising candidates for next-generation humidity sensing applications, offering enhanced sensitivity, mechanical flexibility, and operational stability. The dual-mode sensing capability combined with mechanical durability opens up new possibilities for flexible and wearable humidity-sensing devices. Full article
(This article belongs to the Special Issue Recent Progress in Hybrid Composites)
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30 pages, 2795 KiB  
Review
Composite Forms in the RЕЕ2O3–ZrO2–TiO2 System for Minor Actinides (Am, Cm) and REE Immobilization
by Sergey V. Yudintsev, Michael I. Ojovan and Olga I. Stefanovsky
J. Compos. Sci. 2025, 9(2), 58; https://doi.org/10.3390/jcs9020058 - 26 Jan 2025
Viewed by 372
Abstract
The choice of efficient methods for the immobilization of high-level waste (HLW) resulting from the reprocessing of spent nuclear fuel (SNF) is an important scientific and practical task. The current policy of managing HLW within a closed nuclear fuel cycle envisages its vitrification [...] Read more.
The choice of efficient methods for the immobilization of high-level waste (HLW) resulting from the reprocessing of spent nuclear fuel (SNF) is an important scientific and practical task. The current policy of managing HLW within a closed nuclear fuel cycle envisages its vitrification into borosilicate (B-Si) or alumina–phosphate (Al-P) glasses. These wasteforms have rather limited waste loading and can potentially impair their retaining properties on devitrification. The optimal solution for HLW immobilization could be separating radionuclides into groups using dedicated capacious durable matrices. The phases of the Nd2O3–ZrO2–TiO2 system in this respect are promising hosts for the REE (rare earth elements: Nd, Ce, La, Pr, Sm, Gd, Y) –MA (MA: Am, Cm) fraction of HLW. In this manuscript, we present data on the composition of the samples analyzed, their durability in hot water, their behavior under irradiation, and their industrial manufacturing methods. Full article
(This article belongs to the Special Issue Metal Composites, Volume II)
25 pages, 972 KiB  
Article
Study on Dynamic Response of Damping Type Composite Floor Slabs Considering Interlayer Interaction Influences
by Liangming Sun, Ting Xu, Feng Tian, Yijie Zhang, Hanbing Zhao and Aziz Hasan Mahmood
J. Compos. Sci. 2025, 9(2), 57; https://doi.org/10.3390/jcs9020057 - 26 Jan 2025
Viewed by 268
Abstract
In order to explore the vibration mechanism of vibration damping composite floor slabs and further enrich the theory of floor slab vibration calculation, the free vibration characteristics of vibration damped composite floor slabs and the dynamic response of vibration damped composite floor slabs [...] Read more.
In order to explore the vibration mechanism of vibration damping composite floor slabs and further enrich the theory of floor slab vibration calculation, the free vibration characteristics of vibration damped composite floor slabs and the dynamic response of vibration damped composite floor slabs under multi-source excitation is analyzed using first type Chebyshev polynomials to construct the displacement function and derive an analytical solution. The three-dimensional laminated theory is employed, considering the interlayer interaction. Based on the proposed method, the influences of loading types, positions, magnitudes, and frequencies on the vertical vibration of floor slabs are calculated. The study illustrates that, under the action of multi-source excitation, the displacement and acceleration responses calculated by the method proposed in this paper are always greater than those calculated by the single-plate theoretical solution. The dynamic responses of the vibration damping composite floor slab decrease with the increase of the thickness and elastic modulus of the vibration damping layer. Under different thicknesses of the vibration damping layer, the peak accelerations of the vibration damping composite floor slabs increase linearly with the growth of the load amplitude. In addition, the load movement path has a significant effect on the vibration response of the floor slab. When the moving load moves along the short side of the floor, the displacement response of the floor is generally greater than that along the long side of the floor. Full article
25 pages, 4058 KiB  
Article
Optimization of the Properties of Eco-Concrete Dispersedly Reinforced with Hemp and Flax Natural Fibers
by Alexey N. Beskopylny, Evgenii M. Shcherban’, Sergei A. Stel’makh, Andrei Chernilnik, Diana Elshaeva, Oxana Ananova, Liya D. Mailyan and Viktor A. Muradyan
J. Compos. Sci. 2025, 9(2), 56; https://doi.org/10.3390/jcs9020056 - 25 Jan 2025
Viewed by 340
Abstract
Dispersed reinforcement of concrete with various types of plant fibers is currently a fairly popular area in the field of construction materials science. The relevance of this topic is determined by the fact that the issue has not been studied on a large [...] Read more.
Dispersed reinforcement of concrete with various types of plant fibers is currently a fairly popular area in the field of construction materials science. The relevance of this topic is determined by the fact that the issue has not been studied on a large scale in comparison with concrete reinforced with artificial fibers, and the fact that these types of concrete meet the requirements of the Sustainable Development Goals. The purpose of this work was to evaluate the efficiency of using hemp fiber (HF) and flax fiber (FF) for the dispersed reinforcement of concrete, and to compare their efficiency and practical applicability in the construction industry. Before use, HF and FF were treated with a NaOH solution and stearic acid to increase their resistance to the aggressive alkaline environment of concrete. A total of 15 concrete compositions were made. The percentage of dispersed reinforcement for both types of fibers varied from 0.2% to 1.4%, with a step of 0.2%. The standard methods of mechanical testing and microscopy for investigation the properties of fresh and hardened concrete were applied. The optimum amount of HF in concrete was 0.6%, which provided an increase in compressive and flexural strength of 7.46% and 28.68%, respectively, and a decrease in water absorption of 13.58%. The optimum percentage of FF concrete reinforcement was 0.8%, which allowed an increase in compressive and flexural strength of 4.90% and 15.99%, respectively, and a decrease in water absorption of 10.23%. The results obtained during the experiment prove the possibility and effectiveness of the practical application of hemp and flax fibers in concrete composite technology. Full article
(This article belongs to the Special Issue Composites: A Sustainable Material Solution)
29 pages, 3225 KiB  
Article
Hierarchical Free Vibration Analysis of Variable-Angle Tow Shells Using Unified Formulation
by Domenico Andrea Iannotta, Gaetano Giunta, Levent Kirkayak and Marco Montemurro
J. Compos. Sci. 2025, 9(2), 55; https://doi.org/10.3390/jcs9020055 - 24 Jan 2025
Viewed by 386
Abstract
This paper investigates the dynamic behavior of shell structures presenting variable-angle tow laminations. The choice of placing fibers along curvilinear patterns allows for a broader structural design space, which is advantageous in several engineering contexts, provided that more complex numerical analyses are managed. [...] Read more.
This paper investigates the dynamic behavior of shell structures presenting variable-angle tow laminations. The choice of placing fibers along curvilinear patterns allows for a broader structural design space, which is advantageous in several engineering contexts, provided that more complex numerical analyses are managed. In this regard, Carrera’s unified formulation has been widely used for studying variable-angle tow plates and shells. This article aims to expand this formulation through the derivation of the complete formulation for a generic shell reference surface. The principle of virtual displacements is used as a variational statement for obtaining, in a weak sense, the stiffness and mass matrices within the finite element solution method. The free vibration problem of singly and doubly curved variable-angle tow shells is then addressed. The proposed approach is compared to Abaqus three-dimensional reference solutions and classical theories to investigate the effectiveness of the developed models in predicting the vibrational frequencies and modes. The results demonstrate a good agreement between the proposed approach and reference solutions. Full article
(This article belongs to the Special Issue Feature Papers in Journal of Composites Science in 2024)
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18 pages, 10390 KiB  
Article
Determining the Elastic Constants and Thickness of the Interphase in Fiberglass Plastic Composites from Micromechanical and Macromechanical Tests
by Alexander Smirnov, Evgeniya Smirnova, Dmitry Vichuzhanin, Yulia Khudorozhkova, Irina Spirina, Vladislav Kanakin and Olga Muizemnek
J. Compos. Sci. 2025, 9(2), 54; https://doi.org/10.3390/jcs9020054 - 23 Jan 2025
Viewed by 577
Abstract
The aim of this paper is to describe a methodology for determining the elastic constants and thickness of the interphase between matrix and fiber in fiberglass plastic composites from macro- and micromechanical testing. Macromechanical testing is tension of unidirectional fiberglass plastics along and [...] Read more.
The aim of this paper is to describe a methodology for determining the elastic constants and thickness of the interphase between matrix and fiber in fiberglass plastic composites from macro- and micromechanical testing. Macromechanical testing is tension of unidirectional fiberglass plastics along and across the fiber direction. Micromechanical testing is tension of glass fibers and instrumented microindentation into the matrix and the fiberglass. The interphase thickness is determined by dynamic force microscopy on thin sections without a height difference. The measured interphase thickness is 621 nm. Based on the interphase thickness, a mesomechanical finite element model of a fiberglass monolayer is constructed. As a result, it is found that the elastic modulus and Poisson’s ratio are 12.7 GPa, 0.07. It is established that the elastic properties of the interphase differ significantly from those of the matrix. The paper also explores the possibility of determining the interphase thickness through computational experiments. It turns out that by knowing the actual elastic properties of the matrix and the fiber, as well as the fiberglass monolayer, it is feasible to calculate the interphase and its elastic properties with acceptable engineering accuracy. The deviation of the calculated interphase thickness from the experimentally measured one is 6%. Full article
(This article belongs to the Section Composites Modelling and Characterization)
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15 pages, 8902 KiB  
Article
Analysis of Structural and Magnetic Phase Transitions in Multiferroic Y-Type Hexaferrite Systems by Means of Transverse Magnetic Susceptibility
by Pablo Hernández-Gómez, Óscar Bernardo and José María Muñoz
J. Compos. Sci. 2025, 9(2), 53; https://doi.org/10.3390/jcs9020053 - 23 Jan 2025
Viewed by 409
Abstract
Transverse magnetic susceptibility is an excellent tool to study singularity points as anisotropy and switching fields in different bulk and nanostructured systems, as well as phase transitions. This technique has been carried out on polycrystalline Y-type hexaferrites, with compositions Ba2−xSrx [...] Read more.
Transverse magnetic susceptibility is an excellent tool to study singularity points as anisotropy and switching fields in different bulk and nanostructured systems, as well as phase transitions. This technique has been carried out on polycrystalline Y-type hexaferrites, with compositions Ba2−xSrxCo2Fe12O22, (0.0 ≤ x ≤ 2.0), and Ba2−xSrxZn2Fe12O22, (1.3 ≤ x ≤ 1.7), promising candidates to exhibit multiferroic properties due to their noncollinear spin structure. In the Co2Y system, different behavior is observed depending on the Sr substitution rate, with a secondary maximum observed for samples with x ≥ 1.0 and different shapes in the measurement temperature range analyzed. In the Zn2Y system, several peaks related to the phase transitions that take place are observed, with certain variations depending on the degree of Ba substitution and the applied field in a more or less extended region around the ambient temperature. This type of measurement is a valuable tool to determine the bias field and temperature range of spin transitions. Full article
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13 pages, 1404 KiB  
Article
Does Silane Application Affect Bond Strength Between Self-Adhesive Resin Cements and Feldspathic Porcelain?
by Pakpilai Thiranukoon, Awiruth Klaisiri, Tool Sriamporn, Somporn Swasdison and Niyom Thamrongananskul
J. Compos. Sci. 2025, 9(2), 52; https://doi.org/10.3390/jcs9020052 - 23 Jan 2025
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Abstract
This study aimed to evaluate the shear bond strengths of six self-adhesive resin cements (SACs) on porcelain surfaces and to compare the effectiveness with and without silane application. One hundred and twenty feldspathic porcelain specimens were prepared, etched with 9.5% HF, and divided [...] Read more.
This study aimed to evaluate the shear bond strengths of six self-adhesive resin cements (SACs) on porcelain surfaces and to compare the effectiveness with and without silane application. One hundred and twenty feldspathic porcelain specimens were prepared, etched with 9.5% HF, and divided into two main groups: (i) without silane, and (ii) with silane application. Each main group was further divided into six subgroups, testing six various SACs. Shear bond strength was measured using a universal testing machine, and the de-bonded surfaces were examined with a stereomicroscope. The statistical analysis was tested with two-way ANOVA and post hoc with Tukey’s. The results showed that Panavia SA Luting Multi had the highest shear bond strength, especially with silane application, while G-Cem One exhibited the lowest in the absence of silane. The addition of silane application significantly improved the shear bond strengths of G-Cem One, Panavia SA Luting Multi, and RelyX Unicem compared to situations without silane application. The adhesive and mixed failure modes were found to depend on the brand of SACs. No cohesive failure was detected. The study concludes that Panavia SA Luting Multi achieves superior shear bond strength on feldspathic porcelain when used with a separate silane agent. The etched feldspathic porcelain surface primed with silane coupling agent is recommended for optimal bond strength when using with SACs such as G-Cem One, Panavia SA Luting Multi, or RelyX Unicem. Full article
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15 pages, 5807 KiB  
Article
Straightforward Determination of the Average Electron-Hole Distance in Charge-Transfer State Organic Photovoltaic Donor/Acceptor Composites from Out-of-Phase Electron Spin Echo Data
by Anna G. Matveeva, Victoria N. Syryamina, Vyacheslav M. Nekrasov, Ekaterina A. Lukina, Ivan A. Molchanov, Vitalii I. Sysoev and Leonid V. Kulik
J. Compos. Sci. 2025, 9(2), 51; https://doi.org/10.3390/jcs9020051 - 21 Jan 2025
Viewed by 483
Abstract
Photoinduced charge separation at donor–acceptor composites (active layer material of organic solar cells) is an important step of photoelectric energy conversion. It results in the formation of the interfacial charge-transfer state (CTS), which is a Coulombically bound electron-hole pair. We developed the mathematical [...] Read more.
Photoinduced charge separation at donor–acceptor composites (active layer material of organic solar cells) is an important step of photoelectric energy conversion. It results in the formation of the interfacial charge-transfer state (CTS), which is a Coulombically bound electron-hole pair. We developed the mathematical procedure of direct quantification of the electron-hole distance on the basis of time-domain pulse electron paramagnetic resonance data, obtained in an electron spin echo (ESE) experiment. For an ensemble of CTSs characterized by a distribution of electron-hole distances, this procedure derives the average electron-hole distance without numerical simulation of the experimental data, which is a superposition of the oscillating functions, corresponding to CTSs with a certain electron-hole distance. This procedure was tested on model distance distributions, yielding very accurate results. The data for highly efficient organic photovoltaic composite PM6/Y6 were also analyzed; the average electron-hole distance within the CTS and its dependence on temperature were determined. This procedure can be useful for tracing small changes in CTS structure during optimization of the donor–acceptor composite morphology, which is tightly related to the photovoltaic efficiency of the composite. Full article
(This article belongs to the Section Composites Modelling and Characterization)
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