Soil Syst., Volume 6, Issue 2 (June 2022) – 26 articles

To tackle selenium (Se) malnutrition, biofortification is among the proposed strategies. A biostimulant application in soils is thought to support a plant’s growth and productivity. Biofortification with Se(VI) may lead to a leaching hazard due to the high mobility of Se(VI) in the soil environment. In this study, the effect of the application of two Se(VI) rates—5 and 10 mg kg⁻¹ soil—and a biostimulant on the Se uptake by lettuce plants and on the Se(VI) distribution in soil fractions following the plants harvest, was investigated. Phosphorus (P) and sulfur (S) concentrations in plants were also determined. A high Se(VI) rate suppressed plant growth, leading to a significant fresh weight decrease from 12.28 to 7.55 g and from 14.6 to 2.43 g for the control and high Se(VI) without and with biostimulants, respectively. Impaired plant growth was verified by the SPAD, NDVI and NDRE measurements. The significantly highest Se concentration in plants, 325 mg kg⁻¹, was recorded for the high Se(VI) rate in the presence of the biostimulant. Compared to controls, the low Se(VI) rate significantly decreased P and increased the S concentrations in plants. The post-harvest soil fractionation revealed that, in the presence of the biostimulant, the Se(VI) soluble fraction increased from 0.992 to 1.3 mg kg⁻¹ at a low Se(VI) rate, and decreased from 3.T85 to 3.13 mg kg⁻¹ at a high Se(VI) rate. Nevertheless, at a low Se(VI) rate, 3.6 and 3.1 mg kg⁻¹ of the added Se(VI) remained in the soil in less mobile forms, in the presence or absence of the biostimulant, respectively. This study indicated that the exogenous application of Se in soil exerted dual effects on lettuce growth and Se availability, depending on the level of selenate applied. Full article

Environmental pollution by microplastics (MPs) has become a global problem, but little is known about MPs in soils. This is because MP extraction methods from soils have not yet been standardized. In this study, we tried to establish a simple and economical method to extract soil MPs using the buoyancy of canola oil and the density separation process using sodium chloride (NaCl). In addition, the incineration method was adapted to evaluate the effectiveness of extraction methods precisely. First, the ability and suitability of seven different oils to extract MP from soil were investigated and canola oil was selected. Then, the spiking and recovery test was performed with canola oil and NaCl solution for low-density polyethylene (LDPE), polypropylene (PP), and polyvinylchloride (PVC) as follows: (1) soil and MP mixtures were prepared, (2) 5 g L⁻¹ NaCl and canola oil were added and shaken thoroughly, (3) the oil phase containing MPs were separated after sedimentation, (4) the extracted MPs were rinsed with 99.5% ethanol, and (5) the organic adherents to the extracted MPs were digested with hydrogen peroxide. After drying and incineration, the substantial recovery rates were calculated. In the spiking and recovery test for MP particles (<1 mm) from five typical Japanese agricultural soils, the recoveries of LDPE, PP, and PVC were 95.2–98.3%, 95.2–98.7%, and 76.0–80.5%, respectively, higher than those obtained by the density separation using saturated NaCl solution. In conclusion, the method is effective for extracting MPs, especially LDPE and PP, from soils and is less sensitive to soil type, texture, and physicochemical properties. Full article

The impacts of waste management on various soils of agricultural and urban lands may last centuries or even millennia; however, generally, most studies tend to focus only on decadal or shorter timescales. This study investigates the characteristic properties of anthrosols in and around the urban settlement of St Andrews (Scotland), in the context of soil management and organic carbon content and speciation. Formed by the repeated application of fresh organic and pyrogenic wastes since the medieval period, these soils provide a 1000-year urban research context based on historical accounts of town waste management. We employed complementary methods of high-field solid-state ¹³C-CPMAS NMR, in situ magnetic susceptibility measurement, elemental micro-analysis and portable optically stimulated luminescence (OSL). A significant proportion of the soil organic carbon was present as refractory aromatic C structures, including aryl-C moieties. Portable OSL assessment revealed differences in the intensity and rate of sediment accumulation. The medieval urban areas had higher soil phosphorus concentrations, organic carbon content and magnetic susceptibility relative to the extra-urban site located outside of the medieval burgh. The study confirms that specific signatures, including carbon group functionalities, do reveal evidence of such induced long-lasting past anthropogenic soil modifications. Full article

The freeze–thaw process controls several hydrologic processes, including infiltration, runoff, and soil erosion. Simulating this process is important, particularly in cold and mountainous regions. The Soil and Cold Regions Model (SCRM) was used to simulate, study, and understand the behavior of twelve homogenous soils subject to a freeze–thaw process, based on meteorological data at a snow-dominated forest site in Laramie, WY, USA, from 2010 and 2012. The relationships of soil pore size, soil particle contact, and meteorological data were varied. Our analysis of the model compared simulations using metrics such as soil frost depth, days with ice, and maximum ice content. The model showed that the freeze–thaw process was strongest in the period with a shallow snowpack, with particle packing within the soil profile being an important factor in this process; that soil texture and water content control soil thermal properties; and that water movement towards the freezing front was especially important in fine-textured soils, where water and ice were concentrated in the upper layers. Based on these results, future research that combines a broader set of soil conditions with an extended set of field meteorology and real soil data could elucidate the influence of soil texture on the thermal properties related to soil frost. Full article

Volcanic ash soil aggregates can be disaggregated using heat under wet conditions. This study aimed to investigate factors affecting the disaggregation of volcanic ash soil aggregates in a field with organic cattle manure (M plot) and a field with chemical fertilizer (F plot) that were exposed to heat. The two-step wet sieving method, in which aggregates were sieved twice at different water temperatures for different times, was used to investigate the disaggregation caused by heat. It was found that increasing the temperature during the second sieve was more effective in disaggregating aggregates than extending the second-step sieve time. When the water temperature was increased to 80 °C, macroaggregates became more vulnerable, especially those in the F plot. The total carbon (TC) remaining in the soil aggregates was also measured after sieving. Although the TC content in aggregates decreased after sieving, there was only a minor relationship between decreasing TC content and the degree of disaggregation. This suggests that aggregates were not disaggregated by eluting binding agents containing carbon contents, but by partial breakage of the binding agent and/or the peeling of particles with binding agents from the aggregates. Full article

Soil acidity is a strong promoter of the bioavailability of Al, Fe, and Mn, whose concentrations can sometimes reach toxic levels for plants. In agricultural soils, the use of arbuscular mycorrhizal fungi (AMF) has shown a protective influence on wheat growth under Mn toxicity. The intact extraradical mycelium (ERM) promotes faster AMF colonization, leading to a higher wheat shoot weight, lower Mn uptake, and changes in antioxidant enzyme activity. Its effect on the uptake and distribution of plant nutrients according to the developmental stage of shoot organs has seldomly been analyzed. In the present study, Mn, Mg, Ca, and K were quantified by ICP–MS in leaves and apical meristems of wheat grown in soil with two different ERM consortia, developed from the native plants Lolium rigidum (LOL) and Ornithopus compressus (ORN). The ORN treatment induced the highest wheat shoot weights and the lowest Mn levels. In the leaves, no significant differences were detected for Mg, Ca, or K, but in the apical meristems, the ORN treatment slightly lowered the Ca concentration. The AMF associated with ORN was seen to enhance wheat weight partly by protecting the zones of active growth against high Mn levels in Mn toxic soils. The use of ORN in acidic soils with Mn toxicity provides a sustainable alternative and an efficient complement to current farming practices to lower the negative impacts of farming on the environment. Full article

Soil compaction is a major concern in the context of ensuring sustainable forest and agricultural management practices. Productivity gains during the last decades were also achieved by increasing mechanization. This change was associated with growing machine weights and impacts on trafficked soils. Up to now, knowledge about the resilience of compaction phenomena is still poor. At 11 forest sites on compaction-sensitive silt and loam substrates in the federal state of Baden-Wuerttemberg (Germany), fine root distribution, macroporosity, and apparent gas diffusion coefficients were used to characterize the status of recovery from former soil compaction by machine impact. The time span of recovery at the investigated sites ranged from 6 to 37 years. The investigated soil physical parameters indicate the beginning of soil structure recovery in the wheel tracks, comprising the first 10 cm of soil depth at most sites that were trafficked 10 years or more before the investigation. Synchronously with this restructuring, fine root propagation has started to recover in the topsoils. However, a high persistence of damage was observed below that depth. A synoptic interpretation of the data led to the conclusion that time spans up to almost four decades are not sufficient for the restoration of soil functionality in formerly compacted soils characterized by silt loam texture and low activity of soil biota. In view of the long-lasting persistence of the negative compaction effects, soil protection strategies combined with monitoring of their strict compliance must be implemented into forest practice. In case of an insufficient natural recovery potential, active measures to accelerate the regaining of soil functionality in compacted soils at irregular wheel tracks should be considered in order to shorten the time spans of disturbed soil conditions. Full article

The electromagnetic properties (electrical permittivity and electrical conductivity) of three different soil mesocosms polluted with diesel oil were monitored using a time-domain reflectometry probe for 8 months. The main target of the research was to establish a relationship between the development of biological activity within the mesocosms and the temporal behaviour of electromagnetic properties. The trend of the electromagnetic properties exhibited different responses that could be related to the composition of the mesocosms and their variation with time during the runs. We considered three different mesocosms with similar soil conditions and the same diesel oil concentration: porosity of 45%, volumetric diesel oil content of 9%, and volumetric water content of 15%. The first one was subjected to a natural attenuation (NA), the second one was biostimulated without inoculation (BS), and the third one was biostimulated with inoculation (BS + IN). The biostimulated mesocosms showed a marked decrease in electrical permittivity and electrical conductivity, whereas the naturally attenuated mesocosm did not show these variations. Between the biostimulated mesocosms, the inoculated one showed the fastest variations in the electromagnetic properties. The microbial activity and the pollutant degradation were evidenced by the analyses performed at the end of the experiment. As demonstrated by the results for the fluorescein diacetate analysis, the microbial activity was a bit higher for the inoculated microcosm, which also showed faster variations of the electromagnetic properties. In the biostimulated mesocosms, the removal of diesel oil was 66% and 72%, respectively. With natural attenuation, there was a limited removal efficiency, in the order of 2%. Even if the electromagnetic properties evidenced different kinetics of bioremediation in BS and BS + IN, both were able to successfully degrade similar percentages of the contaminant after 8 months. The long monitoring revealed that a substantial decrease in the electromagnetic properties happened only in the first month after contamination. Additionally, an increasing trend of the permittivity was detected in the following months, before reaching a steady-state condition. This study revealed that biodegradation processes with acceptable overall removal efficiency can be monitored successfully by observing the variations in the electromagnetic properties. Full article

Efforts to reduce greenhouse gas (GHG) emissions from cattle production have led to modifications of livestock diet composition aimed at reducing CH₄ emissions from enteric fermentation. These diet modifications can result in varied manure types that may differentially affect GHG emissions when applied to soil. The purpose of this experiment was to examine the effect of different manure types on GHG emissions. We conducted an incubation experiment, comparing the manure from livestock fed a corn-based diet (CM) to that from livestock fed a traditional barley-based diet (BM). The manures were applied to three soil types (with varied soil fertility and pH) and compared to a control (without manure application). Carbon dioxide (CO₂) emissions were greater from CM than from BM across all soil types (29.1 and 14.7 mg CO₂-C kg⁻¹, respectively). However, CM resulted in lower N₂O emissions relative to BM in the low fertility soil (4.21 and 72.67 μg N₂O-N kg⁻¹, respectively) and in lower CH₄ emissions relative to BM in the two acidic soils (0.5 and 2.5 μg CH₄-C kg⁻¹, respectively). Total GHG emissions (sum of CO₂, N₂O, and CH₄) were similar between CM and BM across all soil types, but CM (unlike BM) had 52–66% lower emissions in the low fertility soil relative to both CM and BM in the high fertility soil. Our study shows that manure and soil type interact to affect GHG emissions and that CM may mitigate N₂O emissions relative to BM when applied to low fertility soils. Full article

Soil carbon sequestration (SCS) is a key priority in the Australian government’s Long-Term Emissions Reduction Plan. Under the government’s Emission Reduction Fund (ERF), farmers are encouraged to change to a management practice that will increase their soil carbon (C) stock and earn Australian Carbon Credit Units (ACCUs). The projections of net C abatement nationally range from 17 to 103 Mt carbon dioxide equivalent annually up to 2050. This huge range reflects the uncertainties in achieving net SCS due to biophysical constraints, such as those imposed by the paucity and variability of Australian rainfall and the difficulty of measuring small changes in soil C stock. The uptake by farmers is also uncertain because of compliance costs, opportunity costs of a practice change and the loss of business flexibility when a farmer must commit to a 25-year permanence period. Since the program’s inception in 2014, only one soil C project has been awarded ACCUs. Nevertheless, an increase in soil C is generally beneficial for farm productivity. As a voluntary C market evolves, the government is expecting that farmers will sell their ACCUs to businesses seeking to offset their greenhouse gas emissions. The risk is that, in buying cheap offsets, businesses will not then invest in new energy-efficient technologies to reduce their emissions at source. Full article

Conservation tillage, including no-tillage (NT), is being used increasingly with respect to conventional tillage (CT) to mitigate soil erosion, improve water conservation and prevent land degradation. However, NT increases soil phosphorus (P) stratification, causing P runoff and eutrophication. For sustainable P management, fertilization must be balanced between P sources and actual crop demand. To reduce P losses to the environment, it is important to better understand P spatial variability in NT fields. Little is known about tillage impacts on field-scale P spatial variabi-lity in precision agriculture. This study examines tillage impacts on spatial variability of soil-avai-lable P in a maize–soybean rotation, in two commercial fields, denoted CT (10.8 ha) and NT (9.5 ha), with the aim of improving P fertilizer recommendations in Eastern Canada. NPK fertilizers were applied to the soils (Humic Gleysols) following local recommendations. Soil samples were collected in fall 2014 in regular 35 m by 35 m grids, at 0–5 and 5–20 cm depths, providing 141 and 134 geore-ferenced points for CT and NT fields, respectively. Available P and other elements were analyzed by Mehlich-3 extraction (M3), and the P saturation index (P/Al)_M3 was calculated. Variability of soil-available P in both fields ranged from moderate to very high (32% to 60%). A mean (P/Al)_M3 of 3% was found in both layers under CT, compared to 8% in the 0–5 cm layer and 6% in the 5–20 cm layer under NT. Relationships between P indices and other elements differed between tillage practices. This study highlights the need to improve P fertilizer recommendations in Eastern Canada. Full article

A tef-Acacia decurrens-charcoal production rotation system, a unique indigenous climate-smart agricultural technology of northwest Ethiopia, is increasingly seen as a promising strategy for improving soil properties. This study investigated the effect of the tef-Acacia decurrens-charcoal production rotation system on soil properties. In total, 112 soil samples (7 treatments × 4 depths × 4 replicates) were collected and analyzed inside and outside randomly selected charcoal production spots in the tef-Acacia decurrens-charcoal production rotation system and from an adjacent tef monocropping system. The soil properties examined generally exhibited significant variation between the tef monocropping system and the tef-Acacia decurrens-charcoal production rotation system, and between soil depths, as well as with respect to charcoal production spots in the system. The system resulted in a significant increase in SOC, TN, available phosphorus, available sodium, available nitrate and ammonium in general, and in total contents of K, P and Mn in the 0–20 cm depth. Charcoal production in the system significantly increased the total content of P, Al, and Fe, as well as the available nitrate and sulfate in the charcoal production spot. The variation in soil proprieties between the land use types and with respect to charcoal production spots in the TACP system were possibly due to the effect of the Acacia decurrens trees, and fire and fine charcoal residues from charcoal production, indicating the capacity of the tef-Acacia decurrens-charcoal production rotation system to improve soil properties. Full article

Forest soil compaction caused by heavy machines can cause ecosystem degradation, reduced site productivity and increased greenhouse gas (GHG) emissions. Recent studies investigating the plant-mediated alleviation of soil compaction with black alder showed promising results (Alnus glutinosa). This study aimed to measure soil recovery and GHG fluxes on machine tracks with and without black alders in North-East Switzerland. In 2008, two machine tracks were created under controlled conditions in a European beech (Fagus sylvatica) stand with a sandy loam texture. Directly after compaction, soil physical parameters were measured on one track while the other track was planted with alders. Initial topsoil bulk density and porosity on the track without alders were 1.52 g cm⁻³ and 43%, respectively. Ten years later, a decrease in bulk density to 1.23 g cm⁻³ and an increase in porosity to 57% indicated partial structure recovery. Compared with the untreated machine track, alder had no beneficial impact on soil physical parameters. Elevated cumulative N₂O emission (+30%) under alder compared with the untreated track could result from symbiotic nitrogen fixation by alder. Overall, CH₄ fluxes were sensitive to the effects of soil trafficking. We conclude that black alder did not promote the recovery of a compacted sandy loam while it had the potential to deteriorate the GHG balance of the investigated forest stand. Full article

The objective of the present work was to study the soil solution throughout time in pots under greenhouse conditions. The work consisted of monitoring the solution of calcareous soil and forest soil in the absence of plants, with different types of fertilization: treatment 1: absolute control (irrigation water); treatment 2: Steiner nutrient solution; treatment 3: solid fertilizers; and treatment 4: vermicompost tea (aqueous extract). The samples were collected weekly using lysimeters for 14 weeks. They were analyzed to determine the nitrate content, total nitrogen, calcium, potassium, magnesium, sodium, sulfur, zinc, boron, pH, electrical conductivity, and oxide-reduction potential. To understand the interactions between treatments, soil type, and time over ion behavior and availability, linear and polynomial models were used, selected by a cross-validation method, which resulted in robust models, where it was found that the pH behavior is associated with the type of fertilization and soil type, with the elapsed time being a nonsignificant factor. On the other hand, time influenced the dynamics of the remaining ions and their availability. It was found that the multiple polynomial model fit better for the variables: potassium, calcium, sodium (square degree), electrical conductivity, nitrates, sulfur (cubic degree), zinc, oxidation-reduction potential, nitrogen, magnesium, and boron (quartic degree). Full article

Climate change and rising energy costs have led to increasing interest in the use of tree harvest residues as feedstock for bioenergy in recent years. With an increasing use of wood biomass and harvest residues, essential nutrient elements are removed from the forest ecosystems. Hence, nutrient sustainable management is mandatory for planning of intensive forest use. We used soil nutrient balances to identify regions in Germany where the output of base cations by leaching and biomass utilization was not balanced by the input via weathering and atmospheric deposition. The effects of conventional stem harvesting, stem harvesting without bark, and whole-tree harvesting on Ca, Mg and K balances were studied. The nutrient balances were calculated using regular forest monitoring data supplemented by additional data from scientific projects. Effective mitigation management strategies and options are discussed and calculations for the compensation of the potential depletion of nutrients in the soil are presented. Full article

Atmospheric acid deposition has increased sharply since the beginning of industrialization but has decreased considerably since the 1980s owing to clean-air policies. Soil acidification induced by an input of acidity has been demonstrated in numerous studies using repeated forest-soil inventories. So far, relatively few data have been sampled to analyze long-term soil trends and only a few studies show the recovery of forest soils from acidification, whereas the recovery of surface waters following declining acid deposition is a widespread phenomenon. To assess a possible recovery from acid deposition, soil resampling data from 21 forested permanent soil-monitoring sites in Lower Saxony (Germany) were evaluated. For most sites, at least three repetitions of inventories from a period of 30 to 50 years were available. Trend analyses of indicators for the acid-base status of unlimed forest soils using generalized additive mixed models (GAMM) show either a trend reversal or a stagnation of the acid-base status at a strong acidification level. The recovery, if indicated by an increase of soil pH and base saturation, of soils from plots with deciduous trees appears to have occurred faster than in coniferous forest stands. This observation may be attributed to a larger amount of temporarily stored sulfur in the soil because of the higher atmospheric input into coniferous forests. As indicators for the acid-base status still show considerable soil acidification, mitigation measures such as forest liming still appear to be necessary for accelerating the regeneration process. Full article

The COVID-19 pandemic caused massive use and improper disposal of surgical polypropylene (PP)-based face masks. For a first evaluation of the respective environmental consequences, we performed a 6-month microcosm experiment at 25 °C to determine the microbial degradability of 10 × 10 mm cuts of single mask layers and of a complete mask mixed with topsoil (Cambisol). By analyzing the CO₂ production, we identified a fast pool with a mean residence time (MRT_fast) of 3 to 7 days, corresponding to approximately 4 to 5% of the total mask carbon. Solid-state nuclear magnetic resonance (NMR) spectroscopy of the degraded masks suggests a cut-off of PP units or oligomers as a main degradation mechanism. The slow carbon pool of the center mask revealed an MRT_slow of 7 years and those of the remaining mask material MRT_slows between 19 and 28 years, which is three to five times longer than those of soil organic matter (SOM) of the pure soil. Since the masks were not pretreated, and decomposed in the dark without UV radiation, our data support our hypothesis that in soils, microbes must exist that can decompose PP, although their nature still has to be revealed in future attempts. Full article

Soil organic carbon influences several landscape ecological processes, and soils are becoming recognized as a mechanism to mitigate the negative impacts of climate change. There is a need to define methods and technologies for addressing soils’ spatial variability as well as the time and cost of sampling soil organic carbon (SOC). Visible and near-infrared spectroscopy have been suggested as a sampling tool to reduce inventory cost. We sampled nineteen ranch properties totaling 17,347 ha across Oklahoma and Texas in 2019 to evaluate the effectiveness and accuracy of a handheld reflectometer (Our Sci, Ann Arbor, MI, USA) (370–940 nm) and existing remote sensing approaches to estimate SOC in semi-arid grazing lands. Our data suggest that the Our Sci Reflectometer estimated soil organic carbon with a precision of approximately (±0.3% SOC); however, it was least accurate at higher carbon concentrations. The Our Sci reflectometer, although consistently accurate at lower SOC concentrations, was still less accurate than a model built using only remote sensing and digital soil map data as predictors. Combining the two data sources was the most accurate means of determining SOC. Our results indicated that the Our Sci handheld Vis-NIR reflectometer tested may have only limited applications for reducing inventory costs at scale. Full article

Seed size, sowing depth, and seed disinfection can affect seed germination and seedling establishment, which, in turn, can directly affect crop growth and yield. The current study was comprised of two experiments, the first of which was conducted in the laboratory, and a second which was performed under glasshouse conditions. The objective of these experiments was to investigate the effects of seed size, sowing depth, and seed disinfection on seed germination and initial seedling growth of selected wheat (Triticum aestivum L.) cultivars. The treatments in laboratory experiment were arranged in a completely randomized design, which included: (Ι) four wheat cultivars (Pishgam, Haydari, Soissons, and Mihan), (ΙΙ) two seed size classes (x < 2.25 mm, and x > 2.25 mm), and two disinfection treatments (no-disinfection and disinfection), (ΙΙΙ) with five replicates. In addition to the aforementioned treatments, the effect of planting depth (4, 6, and 8 cm) was also investigated in the subsequent glasshouse experiment. The best results were obtained at a sowing depth of 4 cm, in the non-disinfected treatment, using large seeds. In contrast, the lowest percentage and speed of seed germination and vigor index were observed in seeds sown at 8 cm depth, in the disinfected seed treatment, using small seeds. Large seeds contain larger nutrient stores which may improve seed germination indices, which would therefore result in improved percentage and speed of seed germination, followed by faster coleoptile and seedling growth, higher seedling dry weight and seed vigor. These data also illustrated that seed disinfection in the Pishgam and Haydari cultivars had inhibitory effects upon coleoptile growth and seedling length, which could be related to the fungicide’s chemical composition. Unlike other cultivars, disinfection did not show a significant effect on the Soissons cultivar. Based on our data, in order to improve both the speed of wheat seed germination and subsequent plant growth and development; it is necessary to select high-quality, large seeds, planted at a specific planting depth, which have been treated with an effective disinfectant; all of which will be specific for the wheat cultivar in question. Overall, the current study has provided useful information on the effect size seed, sowing depth, and disinfection have upon germination characteristics and seedling growth of wheat cultivars, which can form the basis for future field scale trails. Full article

Paddy soils in some areas of southern China are contaminated by arsenic (As) and cadmium (Cd), threatening human health via the consumption of As- and/or Cd-tainted rice. To date, a quantitative understanding of how soil characteristics control As and Cd accumulation in rice grains under field conditions is still deficient. Based on 31 paired soil-grain samples collected in southern China, we statistically explored which soil parameter or parameter combination from various soil analyses best estimates As and Cd in rice. We found that CaCl₂ extraction of field-moist soil collected at rice harvest provided the best estimation (R²_adj = 0.47–0.60) for grain Cd followed by dry soil CaCl₂ extraction (R²_adj = 0.38–0.49), where CaCl₂ extractable Cd from moist or dry soil was the dominant soil parameter. Compared to soil totals, parameters from neither dry soil ascorbate-citrate extraction nor anoxic soil incubation improved model performance for grain As (R²_adj ≤ 0.44), despite their closer relevance to soil redox conditions during plant As uptake. A key role of soil-available sulfur in controlling grain As was suggested by our models. Our approach and results may help develop potential soil amendment strategies for decreasing As and/or Cd accumulation from soils. Full article

Percent soil organic matter (SOM), pH and crop yield are among the biophysicochemical process-driven soil health indicators (SHIs). However, identifying sustainable soil health conditions using these SHIs is limited due to the lack of Integrated Productivity Efficiency (IPE) models. We define IPE as a concept that identifies best-to-worst-case soil health outcomes by assessing the effect of agronomic practices on weighted abundance of functional guilds (WAFG) of beneficial soil organisms and SHIs simultaneously. Expressing WAFG of all beneficial nematodes (x-axis) and SHIs (y-axis) as a percent of untreated control and regression of x and y reveals four quadrants describing worst-to-best-case outcomes for soil health and sustainability. We tested the effects of composted cow manure (AC) and plant litter (PC) applied at 135 (1×), 203 (1.5×), and 270 (2×) kg N/ha on WAFG, SOM, pH, and yield in a sandy clay loam field of a processing carrot cultivar over three growing seasons. Untreated control and urea at 1× served as experimental controls. Data that varied by time and were difficult to make sense of were separated into sustainable, unsustainable, or requiring specific modification to be sustainable categories by the IPE model. Within the sustainable category, all AC treatments and 2× rate of PC treatments had the best integrated efficiency outcomes across the SHIs. The IPE model provides a platform where other biophysicochemical process-driven SHIs could be integrated. Full article

Reaching the land-related UN Sustainable Development Goals (SDGs) and similar goals articulated by the EU Green Deal (GD) by 2030 presents a major challenge and requires a pragmatic approach focused on joint learning by land users (mostly farmers), researchers and other stakeholders in “Living Labs” and system experiments at experimental farms of research organizations. Defining specific indicators and thresholds for ecosystem services in line with land-related SDGs is crucial to establish “Lighthouses” that can act as inspiring examples if they meet the various thresholds. This exploratory paper discusses indicators and thresholds for an arable farm operating on marine, calcareous light clay soils in the Netherlands. Studies of a system experiment are used to discuss and test operational methodology to be widely applied when characterizing many “Living Labs” in future, as planned by the European Union. The important role of soils in contributing to ecosystem services is discussed in terms of soil health. Recommendations are made for innovative methodology to be associated with all land-related SDGs. Satisfying the thresholds of ecosystem services, which will vary by soil type, region and farm type, can be the basis for farm subsidies, such as the Common Agricultural Policy (CAP). Research on Living Labs and in system experiments has to be judged by different criteria than those associated with traditional linear research. The important contributions of soils to achieve ecosystem services are framed in terms of soil health and are the most effective way to promote soil science in a by now widely desired inter- and transdisciplinary context. Full article

The aim of the paper is to give an overview on the chemistry of soil organic carbon (SOC) affecting nutrient availability, the emission of greenhouse gases and detoxifying harmful substances in soil. Humic substances represent the stable part of SOC, accounting for between 50 and more than 80% of organically bound carbon in soil. Humic substances strongly affect the soil solution concentration of several plant nutrients and may increase P-, Fe-, and Cu- solubility, thereby increasing their plant availability. Soil organic carbon, mainly humic substances, can detoxify monomeric Al in acid soils, can strongly bind toxic heavy metals, making them unavailable to the plant roots, and may strongly bind a vast variety of harmful organic pollutants. Increasing SOC is an important goal in agriculture. The inclusion of mixtures of semi-perennial plant species and cultivars may strongly increase SOC and humic substance content in soils. To increase SOC, farmyard manure and its rotted or composted forms are superior compared to the separate application of straw and slurry to soil. The storage of carbon, mainly in organic form, in soils is very important in the context of the emission of greenhouse gases. Worldwide, soils release about 10 times more greenhouse gases compared to fossil fuel combustion. Small increments in SOC worldwide will strongly affect the concentration of atmospheric CO₂. The public discussion on soil fertility and greenhouse gas emissionshas been politically controlled in a way that leaves the important and positive contribution of soil organic carbon and mainly humic substances partly misinterpreted and partly underestimated. Full article

Sustainable and adjusted soil management practices are crucial for soil quality, namely in terms of the nutrient budget. On the other hand, soil characteristics are interlinked with agricultural sustainability and food supply. In other words, soil quality influences agricultural performance and food chains, but it is also impacted by agricultural activities. In this context, this research aims to evaluate the spatial correlations of the soil nutrient balance around the world and analyse how this variable is interrelated with agricultural soil emissions, agricultural output, and food supply. To achieve these goals, data from the FAOSTAT database were considered. This statistical information was analysed with spatial autocorrelation approaches to identify spatial clusters around the world that can be considered as a basis for designing common policies. To perform panel data regressions to identify marginal effects between variables, data were first evaluated using correlation matrices and factor analysis. The results highlight that there is space for common strategies worldwide to preserve soil quality, as in some parts of the world the problems are similar. In these frameworks, the international organizations may have a determinant contribution. Full article

The land disturbed by open-pit oil sands mining must be restored to support the survival and growth of native boreal plants. Because tailings sand and sodic shale overburden are commonly used as an underlying parent substrate that is capped by boreal forest cover soils, the soil pH in reclamation sites is often higher compared with undisturbed boreal forest soil. Sulfur is a major byproduct of oil sands refining and could potentially be used as an amendment to lower the soil pH on reclamation sites. In this study, we examined the effects of soil pH and elemental sulfur on growth and physiological responses in Saskatoon berry and beaked hazelnut seedlings. We found that elemental sulfur was effective in lowering soil pH. However, addition of elemental sulfur to a forest soil of pH 5.7 lowered the soil pH to around 3, which impaired the growth and physiological performance of both plant species. The addition of 5 and 25 g kg⁻¹ elemental sulfur to the pH 8.5 soil did not substantially improve the examined growth and physiological parameters in Saskatoon berry and beaked hazelnut seedlings. Further, excess addition of elemental sulfur in high pH soil could reduce the uptake of nitrogen, phosphorus, and calcium in Saskatoon berry. The results demonstrate that the amount of sulfur applied to the soil would need to be carefully determined for different soil types and pH levels to avoid potential toxicity effects. Full article