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Advances in Wood Composites III

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Composites and Nanocomposites".

Deadline for manuscript submissions: closed (31 January 2021) | Viewed by 62081

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Guest Editor
Laboratory of Wood Science, Chemistry and Technology, Department of Forestry and Natural Environment, School of Geotechnical Sciences, International Hellenic University, Thermi, Greece
Interests: wood; wood composites; lignocellulosic materials; chemical and thermal modification technologies; nanotechnology and nanomaterilas; adhesives
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Special Issue Information

Dear Colleagues,

The fibrous nature of wood has made it one of the most appropriate and versatile raw materials for various uses. However, two properties restrict its much wider use, namely dimensional changes when subjected to fluctuating humidity and susceptibility to biodegradation by micro-organisms. Wood may be modified chemically or thermally so that selected properties are enhanced in a more or less permanent fashion. Another option to improve these properties is to exploit the solutions that nanotechnology can offer. The small-size nanoparticles of nanotechnology compounds can deeply penetrate into the wood, effectively alter its surface chemistry, and result in a high degree of protection against moisture and decay. In addition, the use of lignocellulosic materials for the production of advanced wood composites is an innovative avenue for research. This Special Issue on “Advances in Wood Composites” seeks high-quality works on topics including (but not limited to) the latest approaches to the protection of wood and wood composites with chemical or thermal modification technologies; the application of nanomaterials to wood science; the application of carbon fiber fabrics; and the use of lignocellulosic materials for the production of advanced wood composites.

After the successful special issues 'Advances in Wood Composites I' and 'Advances in Wood Composites II', which both collected innovative papers from well known scientists worldwide, a third part of these series is now available and open for submission.

Assoc. Prof.  Antonios Papadopoulos
Guest Editor

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Keywords

  • wood;
  • wood composites;
  • lignocellulosic composites;
  • chemical or thermal modification;
  • nanotechnology;
  • nanomaterials.

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Published Papers (15 papers)

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Editorial

Jump to: Research, Review

3 pages, 181 KiB  
Editorial
Advances in Wood Composites III
by Antonios N. Papadopoulos
Polymers 2021, 13(1), 163; https://doi.org/10.3390/polym13010163 - 5 Jan 2021
Cited by 17 | Viewed by 2467
Abstract
Wood composites are man-made materials that can be easily manufactured from a variety of raw lignocellulosic materials and the appropriate binder [...] Full article
(This article belongs to the Special Issue Advances in Wood Composites III)

Research

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18 pages, 4134 KiB  
Article
Effect of Iron Oxide Nanoparticles on the Physical Properties of Medium Density Fiberboard
by Waheed Gul, Hussein Alrobei, Syed Riaz Akbar Shah and Afzal Khan
Polymers 2020, 12(12), 2911; https://doi.org/10.3390/polym12122911 - 4 Dec 2020
Cited by 25 | Viewed by 3714
Abstract
This paper investigates the influence of iron oxide (Fe2O3) nanoparticles on the physical properties of medium density fiberboard (MDF). In this study, three different nano iron oxide loadings, i.e., 0.5, 1.5 and 2.5 wt %, and untreated poplar fibers [...] Read more.
This paper investigates the influence of iron oxide (Fe2O3) nanoparticles on the physical properties of medium density fiberboard (MDF). In this study, three different nano iron oxide loadings, i.e., 0.5, 1.5 and 2.5 wt %, and untreated poplar fibers were used. The iron oxide (Fe2O3) nanoparticles were initially dispersed into urea formaldehyde resin using a high-vacuum mechanical stirrer before being incorporated into natural fibers. The untreated poplar fibers were wound onto metal frames to produce dry mat layers. Twenty different composite samples were made. All composite samples were tested for physical properties, i.e., thickness swelling, water absorption, moisture content and density in accordance with standards EN-317, ASTM D570, EN-322 and EN-323 respectively. Based on the results, it was found that the incorporation of homogeneously dispersed iron oxide nanoparticles significantly improved thickness swelling (Ts). Moreover, water absorption (WA) improved by up to 49.18 and 34.54%, respectively, at the highest loading of 2.5 wt %. Microstructure was investigated and characterized with scanning electron microscopy (SEM), x-ray diffraction (XRD) and energy dispersive spectroscopy (EDS) and we examined whether iron oxide nanoparticles exhibit good interactions with urea formaldehyde and poplar wood fibers. Heat and mass transfer investigation in the form of differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) was carried out due to the impact of Fe2O3 nanoparticles. The curing temperature and thermal stability of the resin were enhanced due to the addition of Fe2O3 nanoparticles. A one-way ANOVA statistical analysis was established to effectively control the use of Fe2O3 nanoparticles. Therefore, the presence of iron oxide nanoparticles in an epoxy polymer contributes to a stiffer matrix that, effectively, enhances the capability of improving the physical properties of nano MDF. Full article
(This article belongs to the Special Issue Advances in Wood Composites III)
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10 pages, 2184 KiB  
Article
Larch Bark as a Formaldehyde Scavenger in Thermal Insulation Panels
by Marius Cătălin Barbu, Yasmin Lohninger, Simon Hofmann, Günther Kain, Alexander Petutschnigg and Eugenia Mariana Tudor
Polymers 2020, 12(11), 2632; https://doi.org/10.3390/polym12112632 - 10 Nov 2020
Cited by 19 | Viewed by 2638
Abstract
The aim of this study is to investigate the formaldehyde content and emissions of bark-based insulation panels bonded with three types of adhesives: urea formaldehyde, melamine urea-formaldehyde, and tannin-based adhesives. These panels were produced at two levels of density—300 and 500 kg/m3 [...] Read more.
The aim of this study is to investigate the formaldehyde content and emissions of bark-based insulation panels bonded with three types of adhesives: urea formaldehyde, melamine urea-formaldehyde, and tannin-based adhesives. These panels were produced at two levels of density—300 and 500 kg/m3—and a thickness of 20 mm, and the influence of the adhesive amount and type on the formaldehyde emissions and content was measured. Other mechanical and physical properties such as modulus of rupture, modulus of elasticity, internal bond, and dimensional stability were also scrutinized. With one exception, all the panels belonged to the super E0 classification for free formaldehyde content (perforator value ≤1.5 mg/100 g oven dry mass of panels). The measurements using the desiccator method for formaldehyde emissions assigned all the testing specimens in the F **** category for low-emission panels according to the Japanese International Standards. Full article
(This article belongs to the Special Issue Advances in Wood Composites III)
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13 pages, 3354 KiB  
Article
Effect of Lignin Content on Properties of Flexible Transparent Poplar Veneer Fabricated by Impregnation with Epoxy Resin
by Mengting Lu, Wen He, Ze Li, Han Qiang, Jizhou Cao, Feiyu Guo, Rui Wang and Zhihao Guo
Polymers 2020, 12(11), 2602; https://doi.org/10.3390/polym12112602 - 5 Nov 2020
Cited by 25 | Viewed by 3014
Abstract
In this work, poplar veneer (PV) rotary-cut from fast-growing polar was delignified to prepare flexible transparent poplar veneer (TPV). Lignin was gradually removed from the PV and then epoxy resin filled into the delignified PV. The study mainly concerns the effect of lignin [...] Read more.
In this work, poplar veneer (PV) rotary-cut from fast-growing polar was delignified to prepare flexible transparent poplar veneer (TPV). Lignin was gradually removed from the PV and then epoxy resin filled into the delignified PV. The study mainly concerns the effect of lignin content on microstructure, light transmittance, haze, tensile strength, and thermal stability of the PVs impregnated with epoxy resin. The results indicate that the lignin could be removed completely from the PV when the delignification time was around 8 h, which was proved by FTIR spectra and chemical component detection. Moreover, according to SEM observation and XRD testing, the porosity and crystallinity of the PVs were gradually increased with the removal of lignin. Also, the optical properties measurement indicated that the light transmittance and haze of the TPVs gradually increased, and the thermal stability also became more stable as shown by thermogravimetric analysis (TG). However, the tensile strength of the TPVs declined due to the removal of lignin. Among them, TPV8 exhibited excellent optical properties, thermal stability, and tensile strength. Consequently, it has great potential to be used as a substrate in photovoltaics, solar cells, smart windows, etc. Full article
(This article belongs to the Special Issue Advances in Wood Composites III)
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13 pages, 3854 KiB  
Article
Fabrication and Characterization of Cellulose Nanofiber Aerogels Prepared via Two Different Drying Techniques
by Zhe Wang, Wenkai Zhu, Runzhou Huang, Yang Zhang, Chong Jia, Hua Zhao, Wei Chen and Yuanyuan Xue
Polymers 2020, 12(11), 2583; https://doi.org/10.3390/polym12112583 - 3 Nov 2020
Cited by 39 | Viewed by 5862
Abstract
Studies on the influence of drying processes on cellulose nanofiber (CNF) aerogel performance has always been a great challenge. In this study, CNF aerogels were prepared via two different drying techniques. The CNF solution was prepared via existing chemical methods, and the resultant [...] Read more.
Studies on the influence of drying processes on cellulose nanofiber (CNF) aerogel performance has always been a great challenge. In this study, CNF aerogels were prepared via two different drying techniques. The CNF solution was prepared via existing chemical methods, and the resultant aerogel was fabricated through supercritical CO2 drying and liquid nitrogen freeze-drying techniques. The microstructure, shrinkage, specific surface area, pore volume, density, compression strength, and isothermal desorption curves of CNF aerogel were characterized. The aerogel obtained from the liquid nitrogen freeze-drying method showed a relatively higher shrinkage, higher compression strength, lower specific surface area, higher pore volume, and higher density. The N2 adsorption capacity and pore diameter of the aerogel obtained via the liquid nitrogen freeze-drying method were lower than the aerogel that underwent supercritical CO2 drying. However, the structures of CNF aerogels obtained from these two drying methods were extremely similar. Full article
(This article belongs to the Special Issue Advances in Wood Composites III)
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16 pages, 4751 KiB  
Article
Development of Biodegradable Flame-Retardant Bamboo Charcoal Composites, Part II: Thermal Degradation, Gas Phase, and Elemental Analyses
by Shanshan Wang, Liang Zhang, Kate Semple, Min Zhang, Wenbiao Zhang and Chunping Dai
Polymers 2020, 12(10), 2238; https://doi.org/10.3390/polym12102238 - 28 Sep 2020
Cited by 17 | Viewed by 3114
Abstract
Bamboo charcoal (BC) and aluminum hypophosphite (AHP) singly and in combination were investigated as flame-retardant fillers for polylactic acid (PLA). A set of BC/PLA/AHP composites were prepared by melt-blending and tested for thermal and flame-retardancy properties in Part I. Here, in Part II, [...] Read more.
Bamboo charcoal (BC) and aluminum hypophosphite (AHP) singly and in combination were investigated as flame-retardant fillers for polylactic acid (PLA). A set of BC/PLA/AHP composites were prepared by melt-blending and tested for thermal and flame-retardancy properties in Part I. Here, in Part II, the results for differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), Fourier transform infrared (FTIR), thermogravimetry-Fourier transform infrared spectrometry (TG-FTIR), X-ray diffraction (XRD), and X-ray photoelectron analysis (XPS) are presented. The fillers either singly or together promoted earlier initial thermal degradation of the surface of BC/PLA/AHP composites, with a carbon residue rate up to 40.3%, providing a protective layer of char. Additionally, BC promotes heterogeneous nucleation of PLA, while AHP improves the mechanical properties and machinability. Gaseous combustion products CO, aromatic compounds, and carbonyl groups were significantly suppressed in only the BC-PLA composite, but not pure PLA or the BC/PLA/AHP system. The flame-retardant effects of AHP and BC-AHP co-addition combine effective gas-phase and condensed-phase surface phenomena that provide a heat and oxygen barrier, protecting the inner matrix. While it generated much CO2 and smoke during combustion, it is not yet clear whether BC addition on its own contributes any significant gas phase protection for PLA. Full article
(This article belongs to the Special Issue Advances in Wood Composites III)
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18 pages, 6818 KiB  
Article
Development of Biodegradable Flame-Retardant Bamboo Charcoal Composites, Part I: Thermal and Elemental Analyses
by Shanshan Wang, Liang Zhang, Kate Semple, Min Zhang, Wenbiao Zhang and Chunping Dai
Polymers 2020, 12(10), 2217; https://doi.org/10.3390/polym12102217 - 27 Sep 2020
Cited by 21 | Viewed by 3472
Abstract
In this study, bamboo charcoal (BC) was used as a substitute filler for bamboo powder (BP) in a lignocellulose-plastic composite made from polylactic acid (PLA), with aluminum hypophosphite (AHP) added as a fire retardant. A set of BC/PLA/AHP composites were successfully prepared and [...] Read more.
In this study, bamboo charcoal (BC) was used as a substitute filler for bamboo powder (BP) in a lignocellulose-plastic composite made from polylactic acid (PLA), with aluminum hypophosphite (AHP) added as a fire retardant. A set of BC/PLA/AHP composites were successfully prepared and tested for flame-retardancy properties. Objectives were to (a) assess compatibility and dispersibility of BC and AHP fillers in PLA matrix, and (b) improve flame-retardant properties of PLA composite. BC reduced flexural properties while co-addition of AHP enhanced bonding between PLA and BC, improving strength and ductility properties. Adding AHP drastically reduced the heat release rate and total heat release of the composites by 72.2% compared with pure PLA. The formation of carbonized surface layers in the BC/PLA/AHP composites effectively improved the fire performance index (FPI) and reduced the fire growth index (FGI). Flame-retardant performance was significantly improved with limiting oxygen index (LOI) of BC/PLA/AHP composite increased to 31 vol%, providing a V-0 rating in UL-94 vertical flame test. Adding AHP promoted earlier initial thermal degradation of the surface of BC/PLA/AHP composites with a carbon residue rate up to 40.3%, providing a protective layer of char. Further raw material and char residue analysis are presented in Part II of this series. Full article
(This article belongs to the Special Issue Advances in Wood Composites III)
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16 pages, 3446 KiB  
Article
Bark Thermal Insulation Panels: An Explorative Study on the Effects of Bark Species
by Günther Kain, Eugenia Mariana Tudor and Marius-Catalin Barbu
Polymers 2020, 12(9), 2140; https://doi.org/10.3390/polym12092140 - 19 Sep 2020
Cited by 27 | Viewed by 3879
Abstract
Tree bark is a byproduct of the timber industry which accrues in large amounts, because approximately 10% of the volume a log is bark. Bark is used primarily for low-value applications such as fuel or as a soil covering material in agriculture. Within [...] Read more.
Tree bark is a byproduct of the timber industry which accrues in large amounts, because approximately 10% of the volume a log is bark. Bark is used primarily for low-value applications such as fuel or as a soil covering material in agriculture. Within the present study, thermal insulation panels made from larch, pine, spruce, fir and oak tree bark with different resins (urea formaldehyde, melamine formaldehyde, Quebracho, Mimosa) as a binder are discussed. Also, the properties of panels made from larch bark mixed with industrial popcorn are investigated. The physical-mechanical properties of the panels, which are dependent on panel density, bark species, resin type, resin content and particle size, are analyzed. The bark species has a minor effect on the mechanical characteristics of the panels, while the compression ratio is important for the panel strength, and hence, barks with lower bulk density are preferable. Under laboratory conditions, panels made with green tannin resins proved to have adequate properties for practical use. The addition of popcorn is a means to lower the panel density, but the water absorption of such panels is comparably high. The bark type has a minor effect on the thermal conductivity of the panels; rather, this parameter is predominantly affected by the panel density. Full article
(This article belongs to the Special Issue Advances in Wood Composites III)
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14 pages, 19700 KiB  
Article
Thermal Kinetics of a Lignin-Based Flame Retardant
by Xiaoxuan Liang, Qixiang Hu, Xu Wang, Liang Li, Yuguo Dong, Chang Sun, Chengjuan Hu and Xiaoli Gu
Polymers 2020, 12(9), 2123; https://doi.org/10.3390/polym12092123 - 17 Sep 2020
Cited by 18 | Viewed by 3177
Abstract
In order to improve the thermal property of epoxy resin (EP), a lignin-based flame retardant was prepared. Focusing on the lignin-based flame retardant, this paper investigates its pyrolysis behavior and kinetics via a thermogravimetric analyzer coupled with Fourier transform infrared spectrometry (TG–FTIR). Based [...] Read more.
In order to improve the thermal property of epoxy resin (EP), a lignin-based flame retardant was prepared. Focusing on the lignin-based flame retardant, this paper investigates its pyrolysis behavior and kinetics via a thermogravimetric analyzer coupled with Fourier transform infrared spectrometry (TG–FTIR). Based on the FTIR result, which showed a peak at 1222 cm−1, it was assigned a syringyl structure. Its absorption peak intensity was enhanced and this meant that the phenolization of the lignin was successful. Thermogravimetry/derivative thermogravimetry (TG/DTG) results showed that the carbon residues of F-lignin and F-lignin@APP were reduced to 33.5% and 37.5%, respectively. In addition, the maximum decomposition rate of F-lignin@APP20/EP is 11.8%/min, which is 8%/min and 4.7%/min lower than for EP and Al-lignin, respectively. The char residue of F-lignin@APP20/EP is 32.5%, which is much higher than for EP. Lower decomposition rate and higher char residue indicate the improvement of thermal stability of EP by F-lignin@APP. Moreover, the kinetics of Al-lignin20/EP and F-lignin@APP20/EP were conducted by two kinetic methods: Flynn-Wall-Ozawa (FWO) and Kissinger-Akahira-Sunose (KAS). It was concluded that the pyrolysis process of Al-lignin 20/EP and F-lignin@APP 20/EP could be divided into three stages, while the value and growth rate of the activation energy of F-lignin@APP 20/EP were much higher than that of Al-lignin 20/EP in stage III. Full article
(This article belongs to the Special Issue Advances in Wood Composites III)
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13 pages, 2724 KiB  
Article
Preparation of High Strength Plywood from Partially Delignified Densified Wood
by Matthias Jakob, Gregor Stemmer, Ivana Czabany, Ulrich Müller and Wolfgang Gindl-Altmutter
Polymers 2020, 12(8), 1796; https://doi.org/10.3390/polym12081796 - 11 Aug 2020
Cited by 30 | Viewed by 4957
Abstract
Wood and natural fibers exhibit an advantageous combination of good mechanics at comparably low density. Nevertheless, comparing absolute strength and stiffness, wood is clearly inferior to materials such as metals and engineered composites. Since there is a strong correlation between wood density and [...] Read more.
Wood and natural fibers exhibit an advantageous combination of good mechanics at comparably low density. Nevertheless, comparing absolute strength and stiffness, wood is clearly inferior to materials such as metals and engineered composites. Since there is a strong correlation between wood density and wood mechanical performance, densification by transversal compression suggests itself as a route towards improved mechanics. Partially delignified densified spruce veneers with excellent tensile properties were produced by means of an alkaline (AL) and an organosolv (OS) approach. Plywood specimens were manufactured using treated veneers glued with a phenol-resorcinol-formaldehyde adhesive and were compared with plywood samples made of native spruce veneers (Ref) and spruce veneer densified after plasticization by water impregnation (H2O). Roughly, the bending strength and the modulus of elasticity of plywood from partially delignified densified wood were improved by a factor of 2.4 and 3.5, respectively. Interlaminar shear strength did not match this improvement after partial delignification. Together with excessive thickness swelling, this might be a drawback of partially delignified densified wood in need for further research. Full article
(This article belongs to the Special Issue Advances in Wood Composites III)
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10 pages, 1299 KiB  
Article
Water-Resistant Casein-Based Adhesives for Veneer Bonding in Biodegradable Ski Cores
by Ronald Schwarzenbrunner, Marius Catalin Barbu, Alexander Petutschnigg and Eugenia Mariana Tudor
Polymers 2020, 12(8), 1745; https://doi.org/10.3390/polym12081745 - 5 Aug 2020
Cited by 15 | Viewed by 6494
Abstract
The aim of this study is to investigate the performance of casein-based adhesives for the bonding of ash (Fraxinus spp.) veneers for the manufacture of biodegradable skis. Different formulations containing casein powder, water, lime, sodium silicate, and various glue amounts were tested [...] Read more.
The aim of this study is to investigate the performance of casein-based adhesives for the bonding of ash (Fraxinus spp.) veneers for the manufacture of biodegradable skis. Different formulations containing casein powder, water, lime, sodium silicate, and various glue amounts were tested for shear strength after water storage, modulus of rupture and modulus of elasticity, water absorption, and thickness swelling. Two other classic wood adhesives, namely epoxy and polyvinyl acetate (PVAc) type D4 were used as control. The highest efficiency of both mechanical and physical properties was recorded for the samples glued with caseins and an increased amount of lime. There was also an affinity between casein adhesive distribution and physical and mechanical plywood performance. Moreover, the developed casein-based glues were also used to bond the plywood for ski cores and tested in real-life winter conditions. Full article
(This article belongs to the Special Issue Advances in Wood Composites III)
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12 pages, 3581 KiB  
Article
Improvement of Mechanical, Hydrophobicity and Thermal Properties of Chinese Fir Wood by Impregnation of Nano Silica Sol
by Enguang Xu, Yanjuan Zhang and Lanying Lin
Polymers 2020, 12(8), 1632; https://doi.org/10.3390/polym12081632 - 23 Jul 2020
Cited by 49 | Viewed by 3992
Abstract
In this paper, a wood-SiO2 composite material was prepared via in-situ polymerization using vacuum/pressure impregnation technology using commercial scale nano silica sol and Chinese Fir (Cunninghamia lanceolate (Lamb.) Hook.). Scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), [...] Read more.
In this paper, a wood-SiO2 composite material was prepared via in-situ polymerization using vacuum/pressure impregnation technology using commercial scale nano silica sol and Chinese Fir (Cunninghamia lanceolate (Lamb.) Hook.). Scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TG), and water contact angle were used to study the changes in the microstructure and physical and mechanical properties of this composite. The results showed that silica sol can penetrate and distribute into the wood cell cavities and surface of cell walls and hence combine with the substances of wood materials. FTIR results indicated that the –OH groups of wood can polycondense in-situ with silica sol to form Si–O–C covalent bonds, and amorphous SiO2 formed from Si–O–Si bonds between the –OH groups of silica sol did not change the crystalline structure of wood cell walls. This in-situ formulating composite significantly improved the compact microstructure, thermal and mechanical properties, and hydrophobicity of the composites. Full article
(This article belongs to the Special Issue Advances in Wood Composites III)
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9 pages, 1380 KiB  
Article
The Buffer Effect of Different Wood Species and the Influence of Oak on Panel Composites Binders
by Franco Policardi and Marion Thebault
Polymers 2020, 12(7), 1540; https://doi.org/10.3390/polym12071540 - 12 Jul 2020
Cited by 9 | Viewed by 2466
Abstract
The buffer action of certain wood species can intensely affect the curing and hardening of some thermosetting wood adhesives. The present article presents a quantification of such buffering effects, determined under controlled conditions, in various wood species. The buffer capacity of oak has [...] Read more.
The buffer action of certain wood species can intensely affect the curing and hardening of some thermosetting wood adhesives. The present article presents a quantification of such buffering effects, determined under controlled conditions, in various wood species. The buffer capacity of oak has been found to be rather extreme and is likely to affect quite heavily the ability of urea-formaldehyde (UF) and melamine-urea-formaldehyde (MUF) wood panel adhesives in industrial operations. A variation of the buffer capacity of furnishes containing between 0% and 30% oak chips has been investigated. This was correlated with the internal bond (IB) strength of MUF bonded laboratory particleboards. The wood mixture buffering capacity increases with the oak content, while the panel IB strength decreases. Full article
(This article belongs to the Special Issue Advances in Wood Composites III)
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14 pages, 4407 KiB  
Article
Bio-Composites Consisting of Cellulose Nanofibers and Na+ Montmorillonite Clay: Morphology and Performance Property
by Runzhou Huang, Xian Zhang, Huiyuan Li, Dingguo Zhou and Qinglin Wu
Polymers 2020, 12(7), 1448; https://doi.org/10.3390/polym12071448 - 28 Jun 2020
Cited by 13 | Viewed by 2899
Abstract
This paper reports the usage of cellulose nanofibers (CNFs) as a continuous nanoporous matrix and nanoclay (NC) as additive to fabricate hybrid films. CNF/Cloisite Na+ nanoclay composite films containing 10–50 wt % of NC were prepared for the study. The effects of NC [...] Read more.
This paper reports the usage of cellulose nanofibers (CNFs) as a continuous nanoporous matrix and nanoclay (NC) as additive to fabricate hybrid films. CNF/Cloisite Na+ nanoclay composite films containing 10–50 wt % of NC were prepared for the study. The effects of NC incorporation and its content on mechanical, wettability and thermal degradation properties were investigated. The results showed that the film had a multilayer structure with gradually deposited CNT-NC hybrid on the filter paper Pure CNF films had higher moduli compared with those from the composite films, as the incorporation of NC decreased hydrogen bonding and networking ability of CNFs, especially at the high NC loading levels. The composite films demonstrated self-extinguishing ability when being exposed to the open flame. Composites with over 35 wt % NC did not burn because of the formation of a protective barrier containing ordered NC platelets. The addition of montmorillonite NC led to increased surface water contact angle, showing enhanced hydrophobicity of the material. During the film’s thermal pyrolysis, the first process occurred between 100 and 200 °C, resulting mainly from the evaporation of absorbed water; the second, between 280 and 350 °C, indicated thermal decomposition of cellulose; and the slow third stage happened from the 350 to 600 °C, representing carbonization. The results demonstrate that the apparent activation energies for all the CNF/NC composites were higher than the pure CNF film. CNF/NC films fabricated in this process are a promising barrier material for packaging applications. Full article
(This article belongs to the Special Issue Advances in Wood Composites III)
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Review

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21 pages, 601 KiB  
Review
Volatile Organic Compounds (VOCs) from Wood and Wood-Based Panels: Methods for Evaluation, Potential Health Risks, and Mitigation
by Tereza Adamová, Jaromír Hradecký and Miloš Pánek
Polymers 2020, 12(10), 2289; https://doi.org/10.3390/polym12102289 - 6 Oct 2020
Cited by 75 | Viewed by 8455
Abstract
Volatile organic compounds (VOCs) are contained in various construction materials and interior equipment. Their higher concentrations in the indoor air are associated with negative effects on human health and are disputed in terms of health risk, since people spend a considerable part of [...] Read more.
Volatile organic compounds (VOCs) are contained in various construction materials and interior equipment. Their higher concentrations in the indoor air are associated with negative effects on human health and are disputed in terms of health risk, since people spend a considerable part of their lifetime indoors. Therefore, the presence of VOCs in indoor air is a case of concern regarding sick building syndrome (SBS). From a historical point of view, wood and wood-based panels represent a widely used material. Nevertheless, wood appears to be nowadays a product and a material of a sustainable future. Depending on wood extractives’ composition and an abundance of diverse wood species, different profiles of volatiles are emitted. In case of wood-based panels, the impact of adhesives and additives that are essentially applied aiming to adjust the panels’ properties is even enriching this cocktail of chemicals. This paper comprises the issue of VOCs emitted from wood and wood-based panels. The most abundant VOCs were summarized. The options of VOCs for analytical determination from these matrixes are described with their benefits and limitations. Full article
(This article belongs to the Special Issue Advances in Wood Composites III)
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