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Processes, Volume 13, Issue 2 (February 2025) – 115 articles

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17 pages, 5860 KiB  
Article
Ant Colony Optimization for Accelerated Pathway Identification in Connection Element Method Reservoir Models: A Fast-Track Solution for Large-Scale Simulations
by Yuanhao Zheng, Yongcan Liang, Botao Liu, Huaping Yu, Fei Tian, Jinjun Xia and Xi Zhang
Processes 2025, 13(2), 404; https://doi.org/10.3390/pr13020404 (registering DOI) - 3 Feb 2025
Abstract
In recent years, reservoir models based on the Connection Element Method (CEM) have gained extensive application in reservoir development. This mesh-free modeling approach effectively captures all flow paths and flow-splitting coefficients between nodes, providing a clear view of flow interactions and accurately identifying [...] Read more.
In recent years, reservoir models based on the Connection Element Method (CEM) have gained extensive application in reservoir development. This mesh-free modeling approach effectively captures all flow paths and flow-splitting coefficients between nodes, providing a clear view of flow interactions and accurately identifying primary connectivity pathways between injection and production wells. However, the traditional approach of traversing flow paths and splitting coefficients imposes a significant computational load, particularly when applied to large reservoirs with numerous virtual wells. To enhance simulation efficiency, this paper introduces a novel method leveraging the Ant Colony Optimization (ACO) algorithm to efficiently identify the path with the highest splitting coefficient between well pairs. This approach rapidly calculates and filters the dominant connectivity paths between injection and production wells in CEM models. A comparative analysis shows that, while the ACO algorithm provides limited benefit with a small number of connectivity paths, it significantly outperforms the conventional depth-first search algorithm as the number of experimental wells increases. Full article
(This article belongs to the Section Energy Systems)
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31 pages, 5116 KiB  
Article
Influence of Foaming Agents and Stabilizers on Porosity in 3D Printed Foamed Concrete
by Magdalena Rudziewicz, Marcin Maroszek, Adam Hutyra, Michał Góra, Karina Rusin-Żurek and Marek Hebda
Processes 2025, 13(2), 403; https://doi.org/10.3390/pr13020403 (registering DOI) - 3 Feb 2025
Abstract
This study examines the pore structure and distribution in 3D printed and cast foamed concrete using protein-based and synthetic foaming agents alongside various stabilizing additives. In 3D printed samples, pores are irregular and flattened due to mechanical forces during printing, whereas cast samples [...] Read more.
This study examines the pore structure and distribution in 3D printed and cast foamed concrete using protein-based and synthetic foaming agents alongside various stabilizing additives. In 3D printed samples, pores are irregular and flattened due to mechanical forces during printing, whereas cast samples display uniform, spherical pores from homogeneous foam distribution. Samples containing the CA stabilizer show higher apparent densities (up to 2.05 g/cm3 for printed samples), correlating with lower water absorption. Protein-based foaming agents (PS) produce smaller, more evenly distributed pores, while synthetic agents (AS) result in larger, less uniform pores. Stabilizers significantly influence pore characteristics: commercial stabilizers yield smaller, more uniform pores, while recycled industrial oil (UO) leads to larger, more variable pores. Protein-based agents improve structural stability and reduce water absorption through uniform pore distributions, while synthetic agents lower density and increase water absorption. The highest sorption values were observed in samples with AS without stabilizer (1.7 kg/m2h1/2) and AS and UO (1.6 kg/m2h1/2) in a vertical orientation, with the horizontal orientation of sample AS and UO achieving a peak value of 2.0 kg/m2h1/2. Moreover, stabilization using UO resulted in higher sorption coefficients than stabilization with CA. High porosity in M1 resulted in low strength (0.2 MPa bending, 0.1 MPa perpendicular compression), while M5 showed superior performance (11.5 MPa perpendicular compression). PS-foamed samples (M4, M6) with uniform pores had the highest strengths, with M6 achieving 3.8 MPa bending and 10.3 MPa perpendicular compression. Perpendicular compression (M5: 11.5 MPa) was up to three times stronger than parallel compression due to weak interlayer bonds in 3D printing. Full article
(This article belongs to the Special Issue Advanced Functionally Graded Materials)
14 pages, 2202 KiB  
Article
Fault Diagnosis of Wire Disconnection in Heater Control System Using One-Dimensional Convolutional Neural Network
by Jiawei Guo, Linfeng Sun, Takahiro Kawaguchi and Seiji Hashimoto
Processes 2025, 13(2), 402; https://doi.org/10.3390/pr13020402 - 3 Feb 2025
Viewed by 108
Abstract
Heaters are critical components in various heating control systems, and their faults are often a primary cause of system failure, drawing significant attention from engineers and researchers. Early and accurate fault diagnosis is crucial to prevent cascading failures. Many diagnostic methods target faults [...] Read more.
Heaters are critical components in various heating control systems, and their faults are often a primary cause of system failure, drawing significant attention from engineers and researchers. Early and accurate fault diagnosis is crucial to prevent cascading failures. Many diagnostic methods target faults under generally stable and simple operating conditions, such as constant load or steady-state temperature. However, real-world scenarios are often complex and variable, involving dynamic loads, nonlinear temperature rises, and other challenges, which limit diagnostic accuracy. To address this issue, this paper proposes an intelligent fault diagnosis model based on a one-dimensional convolutional neural network (CNN), using the heater’s current and voltage as the input to the neural network. The effectiveness and accuracy of the proposed model were validated through experimental data under two different conditions, achieving an average accuracy rate of 98%. The disconnection faults were generated during actual operation and occurred in the early stages, differing significantly from artificially simulated faults, thereby increasing the difficulty of accurate diagnosis. Analysis and comparison of the experimental results demonstrate the feasibility of the intelligent diagnostic model and its high diagnostic accuracy. Full article
(This article belongs to the Special Issue Research on Intelligent Fault Diagnosis Based on Neural Network)
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46 pages, 9548 KiB  
Review
Advances in Polyaniline-Based Composites for Room-Temperature Chemiresistor Gas Sensors
by Clinton M. Masemola, Nosipho Moloto, Zikhona Tetana, Linda Z. Linganiso, Tshwafo E. Motaung and Ella C. Linganiso-Dziike
Processes 2025, 13(2), 401; https://doi.org/10.3390/pr13020401 - 3 Feb 2025
Viewed by 140
Abstract
The increasing rate of environmental pollution and the emergence of new infectious diseases have drawn much attention toward the area of gas sensors for air quality monitoring and early-stage disease diagnosis, respectively. Polyaniline (PANI) has become one of the extensively studied polymers in [...] Read more.
The increasing rate of environmental pollution and the emergence of new infectious diseases have drawn much attention toward the area of gas sensors for air quality monitoring and early-stage disease diagnosis, respectively. Polyaniline (PANI) has become one of the extensively studied polymers in the area of chemical sensing due to its good conductivity and sensitivity at room temperature. The development of room-temperature gas sensors represents a significant leap forward in air quality monitoring by conserving energy and enhancing the feasibility of the commercial development of sensing technologies. New research shines a light on the advantages of using PANI with materials such as semiconductor metal chalcogenides, metal oxides, metal nanoparticles, and graphitic carbon materials to form composites that can sense chemicals selectively at room temperature. This review focuses on the advancements in PANI-based gas sensors, exploring the materials, mechanisms, and applications that make these sensors a promising solution for modern air quality monitoring challenges. By examining the latest research and innovations, we aim to highlight this critical technology’s potential and future directions, instilling hope and optimism in safeguarding public health and the environment. Full article
(This article belongs to the Special Issue Development of Smart Materials for Chemical Sensing)
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19 pages, 2040 KiB  
Article
Characterization of Damage and Infiltration Modeling of Coal-Slurry Consolidation Mechanics Under Loaded Conditions
by Yaocai Tang, Peng Lu, Junxiang Zhang and Wang Jian
Processes 2025, 13(2), 400; https://doi.org/10.3390/pr13020400 - 2 Feb 2025
Viewed by 424
Abstract
Coal seam gas drainage is a primary measure for mitigating coal and gas outburst hazards. Grouting sealing can form coal-slurry consolidated bodies, significantly improving the sealing quality of gas drainage boreholes and alleviating coal and gas outburst risks. Therefore, this study conducts triaxial [...] Read more.
Coal seam gas drainage is a primary measure for mitigating coal and gas outburst hazards. Grouting sealing can form coal-slurry consolidated bodies, significantly improving the sealing quality of gas drainage boreholes and alleviating coal and gas outburst risks. Therefore, this study conducts triaxial loading and seepage experiments to analyze the mechanical failure characteristics and permeability variation of coal-slurry consolidated bodies under loading conditions following grouting sealing of gas drainage boreholes. Based on the “cube” model, a permeability model for the damaged coal-slurry consolidated body under loading conditions is established. The findings provide guidance for evaluating the leakage prevention performance of sealing materials in field engineering and optimizing the sealing efficiency of grouting materials. Future research may explore the damage and seepage evolution of coal-slurry consolidated bodies under various loading conditions and sealing material types. Full article
(This article belongs to the Special Issue Advances in Coal Processing, Utilization, and Process Safety)
18 pages, 3569 KiB  
Article
Numerical Study on the Dynamic Characteristics of a Coupled Wind–Wave Energy Device
by Xiaoming Su, Xiaochen Dong, Chuanli Xu, Zhen Liu, Heqiang Ni and Ziqian Han
Processes 2025, 13(2), 399; https://doi.org/10.3390/pr13020399 - 2 Feb 2025
Viewed by 358
Abstract
A wind–wave coupled device integrating an offshore fixed wind turbine and an OWC (oscillating water column) wave energy device is proposed in this study. Its dynamic characteristics under extreme environmental conditions are analyzed for practical design and development using a numerical model established [...] Read more.
A wind–wave coupled device integrating an offshore fixed wind turbine and an OWC (oscillating water column) wave energy device is proposed in this study. Its dynamic characteristics under extreme environmental conditions are analyzed for practical design and development using a numerical model established based on the commercial finite element method platform ANSYS-Workbench, which is then validated using experimental data for an offshore fixed wind turbine model. The modal analysis results indicate that installing the OWC system does not modify the basic dynamic characteristics of the original wind turbine. Under different extreme environmental conditions at different design water levels, stress concentration can be observed at different locations on the structures. Although the gap between the sub-chambers of the OWC system can be increased to reduce stress on the chamber and piles, an excessively large gap will enhance structural complexity and increase construction costs. An appropriate relative size for the gap between the sub-chambers is recommended for practical design. Full article
(This article belongs to the Special Issue Design and Utilization of Wind Turbines/Wave Energy Convertors)
17 pages, 2703 KiB  
Article
Signal Positioning of Lightning Detection and Warning System Combining Direction of Arrival Algorithm and Capon Algorithm
by Yiming Han, Bin He and Hongchun Shu
Processes 2025, 13(2), 398; https://doi.org/10.3390/pr13020398 - 2 Feb 2025
Viewed by 276
Abstract
Aiming at the poor warning effect and slightly low precision of signal positioning in the traditional lightning detection and warning system, the research utilizes the artificial intelligence approach to signal positioning in the lightning detection and warning system for performance improvement. The study [...] Read more.
Aiming at the poor warning effect and slightly low precision of signal positioning in the traditional lightning detection and warning system, the research utilizes the artificial intelligence approach to signal positioning in the lightning detection and warning system for performance improvement. The study first digitized the lightning signal using the arrival direction algorithm and then used the Capon algorithm based on the digitized processing to reduce the interference and improve the accuracy of lightning positioning. The results indicated that the root mean square error value and positioning angle error of lightning warning signal positioning data processing by hybrid algorithm were 6.72% and 5.93%, respectively. Meanwhile, the percentage of detection efficiency and real time was 96.36% and 95.16%, respectively, and the anti-interference ability was 94.02%. Moreover, the average value of time-consuming lightning warning positioning and the positioning error were 2.39 s and 2.69%, respectively. Moreover, the performance of all the comparison indexes was better than that of the comparison methods. This indicates that the method not only improves the precision of lightning signal positioning but also enhances the stability and real-time performance of the system. It has significant application potential in the field of lightning detection and warning and can effectively improve the precision and timeliness of lightning warning. Full article
(This article belongs to the Section Advanced Digital and Other Processes)
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13 pages, 2500 KiB  
Article
Ultrasound-Assisted Extraction of Phenolic Compounds from Tricosanthes cucumerina Leaves: Microencapsulation and Characterization
by Carlos Felipe Vendramini, Talita A. F. de Campos, Natallya M. da Silva, Marcos Antonio Matiucci, Eloize S. Alves, Patrícia D. S. dos Santos, Carlos Eduardo Barão, Oscar de Oliveira, Lucio Cardozo-Filho and Andresa Carla Feihrmann
Processes 2025, 13(2), 397; https://doi.org/10.3390/pr13020397 - 2 Feb 2025
Viewed by 398
Abstract
This study utilized the ultrasound-assisted extraction method to obtain an extract rich in phenolic compounds from the leaves of Tricosanthes cucumerina. The optimization of the experimental design identified the optimal extraction conditions: a temperature of 40 °C, a duration of 6.25 min, [...] Read more.
This study utilized the ultrasound-assisted extraction method to obtain an extract rich in phenolic compounds from the leaves of Tricosanthes cucumerina. The optimization of the experimental design identified the optimal extraction conditions: a temperature of 40 °C, a duration of 6.25 min, and an amplitude of 40%. Under these conditions, the extraction yielded the highest levels of phenolic compounds, measuring 262.54 mg of GAE (gallic acid equivalent) per gram. Further analysis of these extracts using electrospray ionization mass spectrometry (ESI-MS) demonstrated that ultrasound extraction increased the availability of bioactive compounds, such as p-coumaric acid, ferulic acid, and caffeic acid. The resulting extract was microencapsulated with sodium alginate as the wall material and then lyophilized to enhance the shelf life and stability of the phenolic compounds. The thermogravimetric analysis confirmed that the microcapsules exhibited thermal stability, retaining their properties at temperatures up to 250 °C. Additionally, Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) analyses corroborated the effectiveness of the encapsulation process. Consequently, the ultrasound-assisted extraction of T. cucumerina leaves is a promising alternative for incorporating bioactive compounds into food products, nutraceuticals, and cosmetics, thus benefiting consumers. Full article
(This article belongs to the Special Issue Green Chemistry: From Wastes to Value-Added Products (2nd Edition))
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20 pages, 1344 KiB  
Article
Optimization of Extraction Conditions for Phenolic Compounds from Potato Tubers: LC-MS Phenolic Profile as a Powerful Tool to Assess the Genotypes, Vegetation Period, and Production Systems of Potato
by Aleksandra Dramićanin, Nikola Horvacki, Uroš Gašić and Dušanka Milojković-Opsenica
Processes 2025, 13(2), 396; https://doi.org/10.3390/pr13020396 - 2 Feb 2025
Viewed by 351
Abstract
Five different extraction methods were assessed to select an optimal procedure for extracting the phenolic antioxidants from potato tubers. Total phenolic content and antioxidant capacity were determined for each type of extraction. In total, 144 samples of four potato varieties from three production [...] Read more.
Five different extraction methods were assessed to select an optimal procedure for extracting the phenolic antioxidants from potato tubers. Total phenolic content and antioxidant capacity were determined for each type of extraction. In total, 144 samples of four potato varieties from three production systems, over a period of three years, were analyzed. The results show that TPC and RSA tests can be used as parameters for differentiating potato parts and variety and to distinguish the samples depending on ripening time and the production system. Higher values of TPC and RSA were observed in samples from the organic cultivation system compared to integral and conventional cultivation in the same cultivar. Finally, by the employment of UHPLC-LTQ Orbitrap XL, fifty-nine phenolic compounds were identified. It was concluded that the phenolic profile is a powerful tool for confirming botanical origin, distinguishing between genotypes, and distinguishing various production systems of potato. Full article
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22 pages, 3563 KiB  
Article
Flue Gas Recirculation in Steam Boilers: A Comprehensive Assessment Strategy for Energy Optimization and Efficiency Enhancement
by Abdulwahab Alhashem, Abdulrahman S. Almutairi and Saad F. Almokmesh
Processes 2025, 13(2), 395; https://doi.org/10.3390/pr13020395 - 2 Feb 2025
Viewed by 278
Abstract
In modern steam boilers, flue gas recirculation (FGR) is generally adopted as a temperature control method for reheated steam. Some research suggests that FGR does not affect the thermal performance of steam boilers, while other studies report enhanced thermal performance. This investigation aims [...] Read more.
In modern steam boilers, flue gas recirculation (FGR) is generally adopted as a temperature control method for reheated steam. Some research suggests that FGR does not affect the thermal performance of steam boilers, while other studies report enhanced thermal performance. This investigation aims to enhance energy efficiency by using an iterative calculation approach to provide a thorough energy evaluation of a steam boiler with an integrated FGR system. The research applies thermodynamic and heat transfer principles to model combustion characteristics, radiative heat transfer in the furnace waterwall, and convective and inter-tube radiative heat transfer in the economizer, superheaters, and reheater. The model is validated using specifications from an existing power plant boiler and a parametric analysis to examine the effects of varying FGR rates on heat distribution and thermal performance at full and partial loads. The results show that radiative heat accounts for an average of 45% of the total heat supplied, with up to 10% in the heat recovery section. As the FGR rate increases, radiative heat in the heat recovery section decreases by 50%, while the convective heat transfer increases then drops. The model shows that the ideal FGR is bounded between 0.3 at 50% boiler load and 0.4 at full load. An analysis of the impact of FGR on the various parts of the boiler reveals that the economizer experiences the most significant net change in heat gain, followed by the reheater. The effect of gas recirculation on the economizer can be nearly twice as great as on the reheater, indicating that FGR has substantial influence on components beyond the reheater. The findings indicate that reducing excessive heat in the economizer and reheater can be accomplished under different load conditions by regulating the fuel consumption rate according to the analysis of the effects of FGR on radiative and convective heat transfer across various components. Full article
(This article belongs to the Section Energy Systems)
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20 pages, 3897 KiB  
Article
Management and Disposal of Waste Tires to Develop a Company for the Manufacture of Products Based on Recycled Rubber in Tamaulipas, México
by Ricardo Daniel López-García, Araceli Maldonado-Reyes, María Magdalena Reyes-Gallegos, José Amparo Rodríguez-García, Carlos Adrián Calles-Arriaga and Enrique Rocha-Rangel
Processes 2025, 13(2), 394; https://doi.org/10.3390/pr13020394 - 1 Feb 2025
Viewed by 593
Abstract
Currently, the disposal of waste tires is considered one of the priority environmental and public health problems worldwide. Every year, more than 1.4 billion unused tires are placed in landfills. Population growth, economic development, and a strong demand for vehicle production in the [...] Read more.
Currently, the disposal of waste tires is considered one of the priority environmental and public health problems worldwide. Every year, more than 1.4 billion unused tires are placed in landfills. Population growth, economic development, and a strong demand for vehicle production in the automotive industry increase this problem. In Mexico, nearly 36 million unused tires are deposited in landfills or clandestine deposits, the vast majority being burned or accumulated in the open air. The lack of regulations in the handling, disposal, and recycling of tires creates a worrying panorama for environmental care and the problems that this entails. The objective of this work is to propose a viable alternative for the final disposal and recycling of waste tires through the implementation of a company for the manufacture of products based on recycled rubber in the state of Tamaulipas, Mexico, reducing environmental pollution by these wastes and generating sources of employment through a sustainable company. For this purpose, a study was carried out in Tamaulipas, Mexico, through surveys to determine the number of tires that can be obtained and determine the feasibility of the business; subsequently, a prediction was made using simulation software to design and estimate the expected production in the manufacture of parking bumpers using two scenarios with two and four workers. Likewise, specialized software was used to optimize waste tire collection routes from the different tire stores to the company’s location. The results show that with an optimal design of the tire collection routes, up to 483 tons of waste tires can be recovered per year, representing 10% of the total unused tires in Tamaulipas. Because it is an environmental and social problem, installing a company manufacturing products based on recycled rubber is feasible and has a high probability of success for the region studied. According to the simulation, employing four workers increases productivity and decreases manufacturing costs. Through the simulation, three tire collection routes were determined considering the total number of tire stores in the city where the company is located. Full article
(This article belongs to the Special Issue Synthesis, Application and Structural Analysis of Composite Materials)
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34 pages, 4489 KiB  
Review
A Review of Machine Learning in Organic Solar Cells
by Darya Rasul Ahmed and Fahmi F. Muhammadsharif
Processes 2025, 13(2), 393; https://doi.org/10.3390/pr13020393 - 1 Feb 2025
Viewed by 276
Abstract
Organic solar cells (OSCs) are a promising renewable energy technology due to their flexibility, lightweight nature, and cost-effectiveness. However, challenges such as inconsistent efficiency and low stability limit their widespread application. Addressing these issues requires extensive experimentation to optimize device performance, a process [...] Read more.
Organic solar cells (OSCs) are a promising renewable energy technology due to their flexibility, lightweight nature, and cost-effectiveness. However, challenges such as inconsistent efficiency and low stability limit their widespread application. Addressing these issues requires extensive experimentation to optimize device performance, a process hindered by the complexity of OSC molecular structures and device architectures. Machine learning (ML) offers a solution by accelerating material discovery and optimizing performance through the analysis of large datasets and prediction of outcomes. This review explores the application of ML in advancing OSC technologies, focusing on predicting critical parameters such as power conversion efficiency (PCE), energy levels, and absorption spectra. It emphasizes the importance of supervised, unsupervised, and reinforcement learning techniques in analyzing molecular descriptors, processing data, and streamlining experimental workflows. Concludingly, integrating ML with quantum chemical simulations, alongside high-quality datasets and effective feature engineering, enables accurate predictions that expedite the discovery of efficient and stable OSC materials. By synthesizing advancements in ML-driven OSC research, the gap between theoretical potential and practical implementation can be bridged. ML can viably accelerate the transition of OSCs from laboratory research to commercial adoption, contributing to the global shift toward sustainable energy solutions. Full article
(This article belongs to the Section Energy Systems)
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29 pages, 3980 KiB  
Article
Integrating Process Safety and Process Security Risk Management: Practitioner Insights for a Resilience-Oriented Framework
by Muhammad Shah Ab Rahim, Genserik Reniers, Ming Yang and Parthiban Siwayanan
Processes 2025, 13(2), 392; https://doi.org/10.3390/pr13020392 - 1 Feb 2025
Viewed by 402
Abstract
Integrating process safety and process security risk management is increasingly essential for enhancing resilience in the chemical process industry. This study addresses how practitioners perceive the integration of these two domains, identifying key benefits, barriers, and strategies for effective implementation. A mixed-methods approach [...] Read more.
Integrating process safety and process security risk management is increasingly essential for enhancing resilience in the chemical process industry. This study addresses how practitioners perceive the integration of these two domains, identifying key benefits, barriers, and strategies for effective implementation. A mixed-methods approach was applied, combining quantitative survey data from 47 industry professionals with qualitative insights from open-ended responses. The findings highlight significant advantages of integration, such as optimized resource use, reduced operational redundancies, and improved risk management. However, barriers such as knowledge gaps, resource constraints, and communication silos were identified. Respondents emphasized the importance of adopting a resilience-oriented approach involving proactive risk management, continuous improvement, and adaptability in both safety and security practices. Critical enablers for integration include strong leadership, alignment of societal values, cross-disciplinary training, and integrated risk assessment methodologies. Emerging technologies and regulatory alignment were also identified as critical factors in facilitating integration. The study contributes to the theoretical understanding of integrated risk management by supporting resilience engineering and systems theory. It offers actionable strategies for overcoming barriers and leveraging enablers, laying the groundwork for developing a resilience-oriented framework for process safety and process security risk management. Full article
(This article belongs to the Special Issue Technological Processes for Chemical and Related Industries)
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21 pages, 2682 KiB  
Article
Environmental Assessment and Eco-Efficiency Analysis of the Dividing Wall Distillation Column for Separating a Benzene–Toluene–Xylene Mixture
by Fernanda Ribeiro Figueiredo and Diego Martinez Prata
Processes 2025, 13(2), 391; https://doi.org/10.3390/pr13020391 - 1 Feb 2025
Viewed by 296
Abstract
The benzene–toluene–xylene (BTX) system represents an energy-intensive petrochemical process with various industrial applications. Global climate changes have forced modern industry to act toward environmental safety, which requires technological changes. Thus, the divided wall column (DWC) represents a significant advancement in multicomponent mixture separation. [...] Read more.
The benzene–toluene–xylene (BTX) system represents an energy-intensive petrochemical process with various industrial applications. Global climate changes have forced modern industry to act toward environmental safety, which requires technological changes. Thus, the divided wall column (DWC) represents a significant advancement in multicomponent mixture separation. To assess the impact of the conventional BTX process and its intensification proposal based on DWC technology, it is necessary to integrate an eco-efficiency approach that jointly analyzes the economic and environmental variables influencing the system, such as water consumption, CO2 emissions, and utility costs. An auxiliary utility plant was also considered for more realistic results in terms of energy and water consumption, which was identified as a lack in many research studies that performed an overall sustainability analysis. The results showed that the DWC scheme is 37.5% more eco-efficient than the conventional counterpart, mainly due to a 15.6% and 30.3% savings on energy and water consumption, respectively, which provided a 15.5% and 16.7% reduction on CO2 emissions and utility costs, respectively. In addition, all other environmental and safety indicators based on the waste algorithm reduction (WAR) were reduced by approximately 16%. Thus, the DWC proved to be a convenient technology with economic attractiveness and environmental friendliness. Full article
(This article belongs to the Special Issue Circular Economy and Efficient Use of Resources (Volume II))
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17 pages, 593 KiB  
Article
Extraction of High Stearic High Oleic Sunflower Oil Using Eco-Friendly Solvents
by Ana K. de Figueiredo, María B. Fernández and Susana M. Nolasco
Processes 2025, 13(2), 390; https://doi.org/10.3390/pr13020390 - 31 Jan 2025
Viewed by 302
Abstract
The present work aimed to evaluate the extractive p erformance of three green solvents—absolute ethanol, hydrated ethanol (96%), and absolute isopropanol (AIP)—in high stearic high oleic sunflower seeds, comparing them with the conventional solvent hexane. The oil yield from exhaustive Soxhlet extraction with [...] Read more.
The present work aimed to evaluate the extractive p erformance of three green solvents—absolute ethanol, hydrated ethanol (96%), and absolute isopropanol (AIP)—in high stearic high oleic sunflower seeds, comparing them with the conventional solvent hexane. The oil yield from exhaustive Soxhlet extraction with hydrated ethanol was significantly lower, with no significant differences being observed among the other solvents. Extraction with AIP produced the extract with the lowest non-lipid material content and the oil with the lowest concentration of crystallizable waxes, showing a 53% reduction compared to hexane. Since AIP showed a higher extraction efficiency than absolute ethanol after 4 h of processing, its oil extraction kinetics when used as a solvent were further studied. A modified Fick’s diffusion model revealed that, for hexane extraction at 50 °C, the effective diffusion coefficient and the washing fraction were higher than those for AIP extraction (26% and 5.4% higher, respectively). No clear dependence of the oil extraction kinetics on the temperature was observed between the studied temperatures (50 °C and 70 °C). The results showed the feasibility of using absolute ethanol and AIP as alternatives to hexane. Additionally, isopropanol presented operational advantages, producing oil that required less dewaxing during refining than that extracted with hexane or ethanol and showing higher oil selectivity than ethanol. Full article
(This article belongs to the Special Issue Green Chemistry: From Wastes to Value-Added Products (2nd Edition))
21 pages, 13188 KiB  
Article
Study on Acoustic–Vibration Characteristics and Noise Reduction Methods for Elbows
by Shi-Wan Zhang, Fei Wang, Cong Li, Si-Min Zhu and Hui-Qing Lan
Processes 2025, 13(2), 389; https://doi.org/10.3390/pr13020389 - 31 Jan 2025
Viewed by 334
Abstract
Fluid pipelines with large flow changes often result in noise due to multi-physical interactions (fluid–structure and acoustic–vibration interactions) between the pulsating fluid and the pipe wall, especially at the elbows. Therefore, the acoustic–vibration characteristics and noise reduction methods of elbows are studied in [...] Read more.
Fluid pipelines with large flow changes often result in noise due to multi-physical interactions (fluid–structure and acoustic–vibration interactions) between the pulsating fluid and the pipe wall, especially at the elbows. Therefore, the acoustic–vibration characteristics and noise reduction methods of elbows are studied in this paper. Firstly, a two-way fluid–structure interaction (FSI) model is established to analyze the vibration characteristics of the elbow under water excitation. Maximum stress occurs at the elbow inlet, with maximum deformation in the elbow. Experimental validation confirms the model’s accuracy. Secondly, the effects of water and structural parameters on elbow vibration are studied, revealing that increased water pressure, pulsating frequency, and flow rate intensify pipe vibration. Finally, an acoustic–vibration coupled model is built; the simulations suggest that increasing wall thickness and elbow radius and reducing elbow angle effectively reduce the noise level of the elbow. Using elastic supports and damping materials can reduce elbow noise by at least 26.3%. This study provides guidance for the noise reduction and structural optimization of elbows by coupled multi-physics. Full article
(This article belongs to the Special Issue Design, Inspection and Repair of Oil and Gas Pipelines)
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19 pages, 6786 KiB  
Article
Digitised Optimisation of Nanoparticle Synthesis via Laser Ablation: An Industry 4.0 Multivariate Approach for Enhanced Production
by Brian Freeland, Ronan McCann, Burcu Akkoyunlu, Manuel Tiefenthaler, Michal Dabros, Mandy Juillerat, Keith D. Rochfort, Greg Foley and Dermot Brabazon
Processes 2025, 13(2), 388; https://doi.org/10.3390/pr13020388 - 31 Jan 2025
Viewed by 391
Abstract
The synthesis of nanoparticles (NPs) via laser ablation synthesis in solution (LASiS) is a promising method for sustainable and efficient nanoparticle fabrication. This work investigates the transition from one-factor-at-a-time experimentation to a more efficient, multivariate approach for optimising NP production efficiency. By applying [...] Read more.
The synthesis of nanoparticles (NPs) via laser ablation synthesis in solution (LASiS) is a promising method for sustainable and efficient nanoparticle fabrication. This work investigates the transition from one-factor-at-a-time experimentation to a more efficient, multivariate approach for optimising NP production efficiency. By applying the Industry 4.0 principles, the objective is to digitise and automate laboratory processes to increase productivity and robustness. Design of Experiments (DoE) strategies, Taguchi orthogonal arrays and full-factorial design (FFD), have been employed to enhance laser ablation processes. Both models confirmed that increasing laser power led to higher colloid absorbance, with the Taguchi DoE offering rapid initial process mapping and FFD providing a higher-resolution analysis. The optimal laser repetition rate of 30 kHz was identified as a balance between pulse energy and thermal effects on the target, maximising ablation efficiency. The Taguchi model had a prediction of NP size with an R2 value of 0.49, while the FFD struggled with accurate size prediction. Additionally, this study introduced a recirculation flow regime as a rapid test platform for predicting optimal conditions for continuous flow production. Using a semi-autonomous DoE platform decreased the operator involvement and increased the process selectivity. This proof-of-concept for on-the-bench NP rapid manufacturing demonstrated how efficient NP synthesis processes can be developed by clarifying the effects of varying parameters on colloid productivity, paving the way for broader industrial applications in the future. Full article
(This article belongs to the Section Materials Processes)
13 pages, 3952 KiB  
Article
CTAB-Assisted Formation of Hierarchical Porosity in Cu-BDC-NH2 Metal–Organic Frameworks and Its Enhanced Peroxidase-like Catalysis for Xanthine Sensing
by Chao Tan, Junjie He, Fei Zhou, Ruicheng Xu, Yilei Gao, Robert S. Marks and Junji Li
Processes 2025, 13(2), 387; https://doi.org/10.3390/pr13020387 - 31 Jan 2025
Viewed by 487
Abstract
A novel porous metal-organic framework (MOF), pCu-BDC-NH2, with hierarchical porosity was synthesized using cetyltrimethylammonium bromide (CTAB) as a pore-generation agent. In addition to its common functions including structure-directing ligands or soft micelle templates, the judicious use of CTAB effectively modulated pore [...] Read more.
A novel porous metal-organic framework (MOF), pCu-BDC-NH2, with hierarchical porosity was synthesized using cetyltrimethylammonium bromide (CTAB) as a pore-generation agent. In addition to its common functions including structure-directing ligands or soft micelle templates, the judicious use of CTAB effectively modulated pore architecture in Cu-BDC-NH2 MOFs. With additional mesopores generated during the synthesis process, the intrinsic MOF scaffolds further obtained pore hierarchies and interconnectivity, enabling efficient substrate access to the active metal centers, and thus significantly facilitated catalytic performance. As a proof of concept, we applied the finely engineered porous MOF pCu-BDC-NH2 in a cascaded enzymatic system for xanthine sensing. This colorimetric biosensor exhibited a low detection limit of 0.11 μM, and a wide linear range of 1–120 μM. Furthermore, the sensor demonstrated exceptional stability, reproducibility, and was independent of interferences. Our simple yet effective method may find broader applications in tailoring pore architecture, enabling finer engineered structures to improve catalytic activities of nanomaterials. Full article
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39 pages, 6325 KiB  
Article
Solving Dynamic Multi-Objective Flexible Job Shop Scheduling Problems Using a Dual-Level Integrated Deep Q-Network Approach
by Hua Xu, Jianlu Zheng, Lingxiang Huang, Juntai Tao and Chenjie Zhang
Processes 2025, 13(2), 386; https://doi.org/10.3390/pr13020386 - 31 Jan 2025
Viewed by 356
Abstract
Economic performance in modern manufacturing enterprises is often influenced by random dynamic events, requiring real-time scheduling to manage multiple conflicting production objectives simultaneously. However, traditional scheduling methods often fall short due to their limited responsiveness in dynamic environments. To address this challenge, this [...] Read more.
Economic performance in modern manufacturing enterprises is often influenced by random dynamic events, requiring real-time scheduling to manage multiple conflicting production objectives simultaneously. However, traditional scheduling methods often fall short due to their limited responsiveness in dynamic environments. To address this challenge, this paper proposes an innovative online rescheduling framework called the Dual-Level Integrated Deep Q-Network (DLIDQN). This framework is designed to solve the dynamic multi-objective flexible job shop scheduling problem (DMOFJSP), which is affected by six types of dynamic events: new job insertion, job operation modification, job deletion, machine addition, machine tool replacement, and machine breakdown. The optimization focuses on three key objectives: minimizing makespan, maximizing average machine utilization (Uave), and minimizing average job tardiness rate (TRave). The DLIDQN framework leverages a hierarchical reinforcement learning approach and consists of two integrated IDQN-based agents. The high-level IDQN serves as the decision-maker during rescheduling, implementing dual-level decision-making by dynamically selecting optimization objectives based on the current system state and guiding the low-level IDQN’s actions. To meet diverse optimization requirements, two reward mechanisms are designed, focusing on job tardiness and machine utilization, respectively. The low-level IDQN acts as the executor, selecting the best scheduling rules to achieve the optimization goals determined by the high-level agent. To improve scheduling adaptability, nine composite scheduling rules are introduced, enabling the low-level IDQN to flexibly choose strategies for job sequencing and machine assignment, effectively addressing both sub-tasks to achieve optimal scheduling performance. Additionally, a local search algorithm is incorporated to further enhance efficiency by optimizing idle time between jobs. The numerical experimental results show that in 27 test scenarios, the DLIDQN framework consistently outperforms all proposed composite scheduling rules in terms of makespan, surpasses the widely used single scheduling rules in 26 instances, and always exceeds other reinforcement learning-based methods. Regarding the Uave metric, the framework demonstrates superiority in 21 instances over all composite scheduling rules and maintains a consistent advantage over single scheduling rules and other RL-based strategies. For the TRave metric, DLIDQN outperforms composite and single scheduling rules in 20 instances and surpasses other RL-based methods in 25 instances. Specifically, compared to the baseline methods, our model achieves maximum performance improvements of approximately 37%, 34%, and 30% for the three objectives, respectively. These results validate the robustness and adaptability of the proposed framework in dynamic manufacturing environments and highlight its significant potential to enhance scheduling efficiency and economic benefits. Full article
(This article belongs to the Section Automation Control Systems)
19 pages, 3853 KiB  
Article
Sustainable Production of Porous Activated Carbon from Hydrothermally Carbonized Jamoya Fruit Seeds and Its Potential for Adsorbing the Azo Dye Carmoisine B
by Shubham Chaudhary, Monika Chaudhary, Vaishali Tyagi, Shivangi Chaubey, Suhas, Vikas Gupta, Isabel Pestana da Paixão Cansado and Jahangeer Ahmed
Processes 2025, 13(2), 385; https://doi.org/10.3390/pr13020385 - 31 Jan 2025
Viewed by 421
Abstract
Porous carbon materials can serve as effective and versatile adsorbents in water pollution management. This study presents a cost-effective and environmentally friendly method to produce porous carbon materials (JFS-PC) by exploiting Jamoya fruit seeds (JFS) as a precursor using a hydrothermal carbonization (HTC) [...] Read more.
Porous carbon materials can serve as effective and versatile adsorbents in water pollution management. This study presents a cost-effective and environmentally friendly method to produce porous carbon materials (JFS-PC) by exploiting Jamoya fruit seeds (JFS) as a precursor using a hydrothermal carbonization (HTC) process. HTC is a thermochemical process for the conversion of high moisture content biomass into carbon-rich materials. The process is performed in a temperature range of 180–250 °C during which the biomass is submerged in water and heated in a sealed environment under autogenous pressure. The adsorbents obtained were explored using different techniques viz. XRD, FTIR, FE-SEM, and surface area analyses to evaluate their characteristics that are beneficial for the adsorption process. Surface area analysis revealed that the developed activated carbon exhibits appreciable surface area (440.8 m2g−1), with a mean pore diameter of 3.97 nm. Activated carbon was successfully tested on the removal of an azo dye, Carmoisine B (CB), from water systems. Isothermal and kinetic evaluation demonstrated that the dye adsorption agrees well with the Langmuir (R2 = 0.993) and pseudo-second-order (R2 = 0.998) kinetics models. The experiments were designed to investigate the influence of adsorbate concentration (1 × 10−4 and 2 × 10−4 mol L−1), collision time (5–300 min), pH (2–12) of the solution, and temperature (25–45 °C) on the adsorption of the selected dye. The results revealed that pH influences the adsorption capacity of CB and showed maximum adsorption between pH 2 and 5. Experimentally, the CB isotherms showed maximum adsorption capacities of 169.0 mg g−1, at 45 °C. Mechanisms indicate that the surface charge of the adsorbent, and structures of the adsorbate play key roles in adsorption. Thermodynamic parameters revealed an endothermic and a physisorption process supported by Van’t Hoff calculations. The study indicates that the developed porous carbon (JFS-PC) can be successfully used for the removal of CB from water systems. It also highlights the use of an inexpensive and renewable precursor for the development of porous carbon materials. Full article
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21 pages, 1540 KiB  
Article
Synergistic Effect of Ultrasound and Osmotic Pretreatment on the Drying Kinetics and Antioxidant Properties of Satkara (Citrus macroptera): A Novel Preservation Strategy
by Mohammad Afzal Hossain, Limon Chandra Shaha, Tasnim Islam Romen, Animesh Sarkar, Rahul Biswas, Shafi Ahmed, Md. Atiqual Islam, Fahim Muntasir, Md. Amjad Patwary, Rui M. S. C. Morais and Alcina M. M. B. Morais
Processes 2025, 13(2), 384; https://doi.org/10.3390/pr13020384 - 31 Jan 2025
Viewed by 348
Abstract
This study aimed to investigate the effects of combined ultrasound and osmotic pretreatment conditions on the drying kinetics and antioxidant properties, such as total phenolic content (TPC), total flavonoid content (TFC), vitamin C content, and DPPH radical scavenging activity, of dried Citrus macroptera [...] Read more.
This study aimed to investigate the effects of combined ultrasound and osmotic pretreatment conditions on the drying kinetics and antioxidant properties, such as total phenolic content (TPC), total flavonoid content (TFC), vitamin C content, and DPPH radical scavenging activity, of dried Citrus macroptera (Satkara) fruits. The fruit slices were immersed in 10% aqueous solutions of sucrose (S), glucose (G), and fructose (F) followed by an ultrasound treatment (40 kHz) for 10, 20, or 30 min. The samples were then dried in a convective oven at 50, 60, or 70 °C and 30% relative humidity with a constant air velocity of 3 m s−1. Four thin-layer kinetic models, namely Page, Newton, Henderson and Pabis, and Logarithmic, were evaluated. Among these, Page was found to be the most suitable model for predicting the drying kinetics. The pretreatment process accelerated the drying process significantly, reducing the drying time up to 6 h. Additionally, the pretreated samples exhibited improved retention of quality attributes, with vitamin C being best preserved in S solutions, TPC in both S and F solutions, TFC in F solutions, and DPPH in all three sugar solutions (S, F, and G). The application of ultrasound during osmotic treatment also had a positive impact on TPC and TFC retention, whereas it presented a negative effect on vitamin C when used for a prolonged duration and a negligible one on the antioxidant capacity. Overall, this study provides a new perspective on the drying kinetics of Satkara fruits, and their respective properties after drying, and being subjected to combined ultrasound and osmotic pretreatment. These findings will contribute to the development of effective and efficient drying methods suitable for industrial applications to produce dried Satkara products with a minimum quality degradation. Full article
(This article belongs to the Special Issue Advanced Drying Technologies in Food Processing)
13 pages, 493 KiB  
Article
Controllable Preparation and Electrically Enhanced Particle Filtration Performance of Reduced Graphene Oxide Polyester Fiber Materials in Public Buildings
by Xiaolei Sheng, Tuo Yang, Xin Zhang and Tao Yu
Processes 2025, 13(2), 383; https://doi.org/10.3390/pr13020383 - 30 Jan 2025
Viewed by 416
Abstract
How to effectively improve the filtration characteristics of polyester fiber filtration materials in public buildings is particularly important for ensuring the health of indoor environments. This study uses the impregnation method to prepare composite materials by using the characteristics of graphene and its [...] Read more.
How to effectively improve the filtration characteristics of polyester fiber filtration materials in public buildings is particularly important for ensuring the health of indoor environments. This study uses the impregnation method to prepare composite materials by using the characteristics of graphene and its derivatives and, on this basis, enhances the filtration characteristics of the composite materials by applying an external voltage. The structure and particle filtration performance of the composite materials are tested and analyzed. The results indicate that the filtration efficiency of the prepared composite filter material is significantly improved compared to polyester fiber materials. When the applied voltage is 4 V, the new composite filter material has the highest weight filtration efficiency for particulate matter, with filtration efficiencies of 71.3%, 45.3%, and 35.7% for PM10, PM2.5, and PM1.0, respectively. The filtration efficiency is highest when the power on time is 80 s. At this time, the filtration efficiency of the filter material for PM10, PM2.5, and PM1.0 is 70.6%, 43.8%, and 35.3%, respectively. The new composite filter material has a significant lifting effect on particles with a diameter of 0–2.5 μm. It provides reference value for research and the application of new filtering materials. Full article
(This article belongs to the Special Issue Sustainable Development of Energy and Environment in Buildings)
15 pages, 1566 KiB  
Article
Evaluating Potentials of Activated Carbon, Inoculum Diversity, and Total Solids Content for Improved Digestate Quality in Anaerobic Food Waste Treatment
by Julius G. Akinbomi, Regina J. Patinvoh, Omotoyosi S. Atunrase, Benjamin C. Onyenuwe, Chibuike N. Emereonye, Joshua F. Ajeigbe and Mohammad J. Taherzadeh
Processes 2025, 13(2), 382; https://doi.org/10.3390/pr13020382 - 30 Jan 2025
Viewed by 543
Abstract
The potential presence of toxic compounds in the digestate obtained from the anaerobic digestion of biodegradable waste restricts its application as a biofertilizer for soil conditioning and plant growth enhancement. The aim of this study was to assess digestate quality in terms of [...] Read more.
The potential presence of toxic compounds in the digestate obtained from the anaerobic digestion of biodegradable waste restricts its application as a biofertilizer for soil conditioning and plant growth enhancement. The aim of this study was to assess digestate quality in terms of plant nutrient composition by evaluating the effects of activated carbon supplementation, inoculum source, and total solids content in the anaerobic digestion medium. The anaerobic digestion of food waste was conducted over a 60-day period at 25 °C in a 2.5 L bioreactor. The results demonstrated that inoculum diversity significantly impacted the digestate composition, particularly the zinc nutrient, with a p-value of 0.0054. This suggests that microbial diversity influences the valorization of organic waste into biofertilizer. However, the effects of inoculum diversity on other nutrients, aside from zinc, were not significant due to substantial interaction effects. Furthermore, assessing the impact of activated carbon supplementation proved challenging, as it was analyzed as part of a subset of the other two factors. The results of the digestate composition analysis indicated that activated carbon supplementation exhibited some influence on nutrient composition, necessitating further research to elucidate its significance. The findings of this study may contribute to enhancing the quality of digestate as a biofertilizer. Full article
(This article belongs to the Special Issue Fermentation and Bioprocess Engineering Processes)
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19 pages, 5172 KiB  
Article
Study on the Corrosion Behavior of Graphite Materials in Molten CuSn Alloy
by Zhifei Cao, Zongbiao Ye, Xiangyang Luo, Hongrui Tian, Hengxin Guo, Jianjun Wei and Fujun Gou
Processes 2025, 13(2), 381; https://doi.org/10.3390/pr13020381 - 30 Jan 2025
Viewed by 436
Abstract
Graphite, a critical material for furnace walls, is pivotal to the reliability of the carbon-free hydrogen production industry through methane pyrolysis catalyzed by molten metals. This study systematically investigates the corrosion behavior of molten CuSn alloy on three typical commercial graphite materials—low-density graphite [...] Read more.
Graphite, a critical material for furnace walls, is pivotal to the reliability of the carbon-free hydrogen production industry through methane pyrolysis catalyzed by molten metals. This study systematically investigates the corrosion behavior of molten CuSn alloy on three typical commercial graphite materials—low-density graphite (LDG), high-density graphite (HDG), and pyrolytic graphite (PyG)—with a focus on their corrosion resistance and the underlying mechanisms responsible for graphite corrosion over a period of up to 1000 h at 1100 °C. The experimental results show that LDG suffered the most severe corrosion, with a mass loss of up to 60.09% and a hardness decrease from 0.73 GPa to 0.17 GPa, whereas PyG demonstrated the best corrosion resistance, with only a 5.64% mass loss and a hardness drop from 0.52 GPa to 0.35 GPa. SEM and XRD analyses revealed that the porous structures of LDG and HDG suffered significant macroscopic corrosion, caused by the stress from molten metal infiltration and aggregation in the pores, leading to structural collapse. Interestingly, all three types of graphite, including the non-porous PyG, exhibited disordered microstructural degradation as detected by Raman spectroscopy. Molecular dynamics (MD) simulations confirmed that the thermal motion of Cu and Sn atoms primarily drives the microstructural corrosion of graphite, suggesting that the corrosion process involves both micro- and macro-level damage. These findings provide crucial insight into the compatibility of different graphite materials with molten CuSn alloy and valuable guidance for material selection in methane pyrolysis devices. Full article
(This article belongs to the Section Materials Processes)
28 pages, 766 KiB  
Review
Biosensors for Detecting Food Contaminants—An Overview
by António Inês and Fernanda Cosme
Processes 2025, 13(2), 380; https://doi.org/10.3390/pr13020380 - 30 Jan 2025
Viewed by 332
Abstract
Food safety is a pressing global concern due to the risks posed by contaminants such as pesticide residues, heavy metals, allergens, mycotoxins, and pathogenic microorganisms. While accurate, traditional detection methods like ELISA, HPLC, and mass spectrometry are often time-consuming and resource-intensive, highlighting the [...] Read more.
Food safety is a pressing global concern due to the risks posed by contaminants such as pesticide residues, heavy metals, allergens, mycotoxins, and pathogenic microorganisms. While accurate, traditional detection methods like ELISA, HPLC, and mass spectrometry are often time-consuming and resource-intensive, highlighting the need for innovative alternatives. Biosensors based on biological recognition elements such as enzymes, antibodies, and aptamers, offer fast, sensitive, and cost-effective solutions. Using transduction mechanisms like electrochemical, optical, piezoelectric, and thermal systems, biosensors provide versatile tools for detecting contaminants. Advances in DNAzyme- and aptamer-based technologies enable the precise detection of heavy metals, while enzyme- and protein-based biosensors monitor metal-induced changes in biological activity. Innovations like microbial biosensors and DNA-modified electrodes enhance detection accuracy. Biosensors are also highly effective in identifying pesticide residues, allergens, mycotoxins, and pathogens through immunological, enzymatic, and nucleic acid-based techniques. The integration of nanomaterials and bioelectronics has significantly improved the sensitivity and performance of biosensors. By facilitating real-time, on-site monitoring, these devices address the limitations of conventional methods to ensure food quality and regulatory compliance. This review highlights the transformative role of biosensors and how biosensors are improved by emerging technologies in food contamination detection, emphasizing their potential to mitigate public health risks and enhance food safety throughout the supply chain. Full article
20 pages, 687 KiB  
Article
Production and Testing of Carrageenan-Based Films Enriched with Chinese Hawthorn Extract in Strawberry Packaging
by Kristina Cvetković, Natalija Đorđević, Ivana Karabegović, Bojana Danilović, Dani Dordevic, Simona Dordevic and Ivan Kushkevych
Processes 2025, 13(2), 379; https://doi.org/10.3390/pr13020379 - 30 Jan 2025
Viewed by 543
Abstract
The aim of this study was to develop and characterize carrageenan-based films with the addition of aqueous Chinese hawthorn extract in concentrations of 5%, 10%, and 15%, as well as to examine their application and impact on prolongation of fresh strawberries’ shelf life. [...] Read more.
The aim of this study was to develop and characterize carrageenan-based films with the addition of aqueous Chinese hawthorn extract in concentrations of 5%, 10%, and 15%, as well as to examine their application and impact on prolongation of fresh strawberries’ shelf life. The films were prepared using the casting method, and their mechanical, physical, structural, chemical, and barrier properties were investigated, along with the antioxidative and antimicrobial properties of the films and the extract. Tests on strawberries included monitoring changes in acidity, visual characteristics, weight loss, ripening, and oxidative status during storage. The results showed that the addition of aqueous hawthorn extract, due to its high total polyphenol content, contributed to the improvement of the films‘ antioxidant activity but exhibited low antimicrobial potential. Increasing the extract concentration led to higher water content and improved barrier properties at lower concentrations, while excessive concentrations of hawthorn extract (15%) impaired the films’ barrier properties. FTIR analysis confirmed the presence of characteristic peaks for the carrageenan spectrum. The carrageenan-based film with the addition of 15% aqueous blackberry extract demonstrated the best efficiency in preserving the post-harvest quality of strawberries. Carrageenan-based films with the addition of aqueous hawthorn extract have significant potential for application in packaging fresh, perishable foods such as strawberries. In addition to providing the necessary protection to the packaged product, they represent a sustainable solution aimed at reducing waste generated by the use of plastic packaging. Full article
(This article belongs to the Section Food Process Engineering)
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14 pages, 3553 KiB  
Article
Simulation Study of the Effects of Foam Rheology on Hydraulic Fracture Proppant Placement
by Tuan Tran, Giang Hoang Nguyen, Maria Elena Gonzalez Perdomo, Manouchehr Haghighi and Khalid Amrouch
Processes 2025, 13(2), 378; https://doi.org/10.3390/pr13020378 - 30 Jan 2025
Viewed by 344
Abstract
Hydraulic fracture stimulation is one of the most effective methods to recover oil and gas from unconventional resources. In recent years, foam-based fracturing fluids have been increasingly studied to address the limitations of conventional slickwater such as high water and chemical consumption, environmental [...] Read more.
Hydraulic fracture stimulation is one of the most effective methods to recover oil and gas from unconventional resources. In recent years, foam-based fracturing fluids have been increasingly studied to address the limitations of conventional slickwater such as high water and chemical consumption, environmental concerns, and high incompatibility with water-sensitive formations. Due to the gradual breakdown of liquid foams at reservoir conditions, the combination of silica nanoparticles (SNP) and surfactants has attracted a lot of attention to improve liquid foams’ characteristics, including their stability, rheology, and proppant-carrying capacity. This paper investigates and compares the effects of cationic and anionic surfactants on the fracturing performance of SNP-stabilized foams at the reservoir temperature of 90 °C. The experimental results of viscosity measurements were imported into a 3D fracture-propagation model to evaluate the effectiveness of fracturing foams in transporting and distributing proppants in the fracture system. At both ambient and elevated temperatures, cationic surfactant was experimentally found to have better synergistic effects with SNP than anionic surfactant in improving the apparent viscosity and proppant-carrying capacity of foams. The simulation results demonstrate that fracturing with cationic surfactant-SNP foam delivers greater performance with larger propped area by 4%, higher fracture conductivity by 9%, and higher cumulative gas production by 13%, compared to the anionic surfactant-SNP foam. This research work not only helps validate the interrelationship between fluid viscosity, proppant settlement rate, and fracture effectiveness, but it also emphasizes the importance of proppant placement in enhancing fracture conductivity and well productivity. Full article
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17 pages, 4248 KiB  
Article
Determination of Basalt Fiber Reinforcement in Kaolin Clay: Experimental and Neural Network-Based Analysis of Liquid Limit, Plastic Limit, and Unconfined Compressive Strength
by Yasemin Aslan Topçuoğlu, Zeynep Bala Duranay, Zülfü Gürocak and Hanifi Güldemir
Processes 2025, 13(2), 377; https://doi.org/10.3390/pr13020377 - 30 Jan 2025
Viewed by 435
Abstract
The use of basalt fibers, which are employed in various fields, such as construction, automotive, chemical, and petrochemical industries, the sports industry, and energy engineering, is also increasingly common in soil reinforcement studies, another application area of geotechnical engineering, alongside their use in [...] Read more.
The use of basalt fibers, which are employed in various fields, such as construction, automotive, chemical, and petrochemical industries, the sports industry, and energy engineering, is also increasingly common in soil reinforcement studies, another application area of geotechnical engineering, alongside their use in concrete. With this growing application, scientific studies on soil reinforcement with basalt fiber have also gained momentum. This study establishes the effects of basalt fiber on the liquid limit, plastic limit, and strength properties of soils, and the relationships among the liquid limit, plastic limit, and unconfined compressive strength of the soil. For this purpose, 12 mm basalt fiber was used as a reinforcement material in kaolin clay at ratios of 1.0%, 1.5%, 2.0%, 2.5%, and 3.0%. The prepared samples were subjected to liquid limit, plastic limit, and unconfined compressive strength tests. As a result of the experimental studies, the fiber ratio that provided the best improvement in the soil properties was determined, and the relationships among the liquid limit, plastic limit, and unconfined compressive strength were established. The experimental results were then used as input data for an artificial intelligence model. The used neural network (NN) was trained to obtain basalt fiber-to-kaolin ratios based on the liquid limit, plastic limit, and unconfined compressive strength. This model enabled the prediction of the fiber ratio that provides the maximum improvement in the liquid limit, plastic limit, and compressive strength without the need for experiments. The NN results were in great agreement with the experimental results, demonstrating that the fiber ratio providing the maximum improvement in the soil properties can be identified using the NN model without requiring experimental studies. Moreover, the performance and reliability of the NN model were evaluated using 5-fold cross-validation and compared with other AI methods. The ANN model demonstrated superior predictive accuracy, achieving the highest correlation coefficient (R = 0.82), outperforming the other models in terms of both accuracy and reliability. Full article
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20 pages, 4837 KiB  
Article
Nano-Grafted Polymer Suspension Stabilizers for Oil Well Cement: Polymerization Innovation Dominated by Acrylamide and Breakthroughs in High-Temperature Applications
by Lifang Song, Chengwen Wang, Jingping Liu and Yang Li
Processes 2025, 13(2), 376; https://doi.org/10.3390/pr13020376 - 30 Jan 2025
Viewed by 362
Abstract
A high-temperature resistant suspension stabilizer, SIAM-1, for high-density cement slurry used in deep/ultra-deep well cementing has been successfully developed. This suspension stabilizer is based on the temperature-resistant monomers 2-acrylamido-2-methylpropane sulfonic acid (AMPS) and N,N-dimethylacrylamide (NNDMA). Meanwhile, two functional monomers, long-hydrophobic-side-chain [...] Read more.
A high-temperature resistant suspension stabilizer, SIAM-1, for high-density cement slurry used in deep/ultra-deep well cementing has been successfully developed. This suspension stabilizer is based on the temperature-resistant monomers 2-acrylamido-2-methylpropane sulfonic acid (AMPS) and N,N-dimethylacrylamide (NNDMA). Meanwhile, two functional monomers, long-hydrophobic-side-chain temperature-sensitive monomers and temperature-resistant monomer-modified nano-SiO2 monomers, were introduced. To enhance the participation of two functional monomers in the polymerization process, a method combining a small amount of acrylamide (AM) and emulsion polymerization was employed, leading to the successful synthesis of SIAM-1 with a high content of functional monomers. The study also explores the effects of polymerization method and AM on the conformational characteristics of the resulting polymers. The results confirm that the polymer structure aligns with the designed configuration, and SIAM-1 demonstrates excellent high-temperature resistance, with a tolerance of up to 210 °C. The optimal dosage of AM was found to be 4% of the total monomer mass. SIAM-1 exhibits excellent high-temperature rheological properties, maintaining a viscosity as high as 128 mP·s at 210 °C. Moreover, it effectively improves the suspension stability of the cement slurry at 210 °C. The density differences in the conventional-density and high-density cement slurries are 0.006 g∙cm−3 and 0.039 g∙cm−3, respectively. This research is beneficial for increasing the viscosity of the cement slurry at high temperatures, effectively preventing the settlement of solid-phase particles under high-temperature and high-pressure well conditions. Consequently, it enhances the cementing effect of deep/ultra-deep wells and reduces cementing-related risks. Full article
(This article belongs to the Special Issue Advanced Technology in Unconventional Resource Development)
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14 pages, 3148 KiB  
Article
Engineering a Cross-Feeding Synthetic Bacterial Consortium for Degrading Mixed PET and Nylon Monomers
by Ida Putu Wiweka Dharmasiddhi, Jinjin Chen, Bahareh Arab, Ching Lan, Christian Euler, C. Perry Chou and Yilan Liu
Processes 2025, 13(2), 375; https://doi.org/10.3390/pr13020375 - 30 Jan 2025
Viewed by 426
Abstract
Plastics are indispensable to modern life, but their widespread use has created an environmental crisis due to inefficient waste management. Mixed plastic waste, comprising diverse polymers, presents significant recycling challenges due to the high costs of sorting and processing, leading to ecosystem accumulation [...] Read more.
Plastics are indispensable to modern life, but their widespread use has created an environmental crisis due to inefficient waste management. Mixed plastic waste, comprising diverse polymers, presents significant recycling challenges due to the high costs of sorting and processing, leading to ecosystem accumulation and harmful by-product generation. This study addresses this issue by engineering a synthetic bacterial consortium (SBC) designed to degrade mixed plastic monomers. The consortium pairs Escherichia coli Nissle 1917, which uses ethylene glycol (EG), a monomer derived from polyethylene terephthalate (PET), as a carbon source, with Pseudomonas putida KT2440, which metabolizes hexamethylenediamine (HD), a monomer from nylon-6,6, as a nitrogen source. Adaptive evolution of the SBC revealed a novel metabolic interaction where P. putida developed the ability to degrade both EG and HD, while E. coli played a critical role in degrading glycolate, mitigating its by-product toxicity. The evolved cross-feeding pattern enhanced biomass production, metabolic efficiency, and community stability compared to monocultures. The consortium’s performance was validated through flux balance analysis (FBA), high-performance liquid chromatography (HPLC), and growth assays. These findings highlight the potential of cross-feeding SBCs in addressing complex plastic waste, offering a promising avenue for sustainable bioremediation and advancing future polymer degradation strategies. Full article
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